scholarly journals Catalytic Removal of Alizarin Red Using Chromium Manganese Oxide Nanorods: Degradation and Kinetic Studies

Catalysts ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1150
Author(s):  
Muhammad Hamza ◽  
Ataf Ali Altaf ◽  
Samia Kausar ◽  
Shahzad Murtaza ◽  
Nasir Rasool ◽  
...  
Keyword(s):  
Kinetic Model ◽  
Manganese Oxide ◽  
Dye Removal ◽  
Dye Degradation ◽  
Uv Light ◽  
Kinetic Studies ◽  
Research Area ◽  
Alizarin Red ◽  
X Ray ◽  
Catalytic Removal

Dye removal through photocatalytic degradation employing nanomaterials as catalysts is a growing research area. In current studies, photocatalytic alizarin red (AR) dye degradation has been investigated by designing a series of Cr based manganese oxide nanomaterials (MH1–MH5). Synthesized nanomaterials were characterized by powder X-ray diffraction, scanning electron microscopy/energy dispersive x-ray, Brunauer–Emmett–Teller, and photoluminescence techniques and were utilized for photocatalytic AR dye degradation under UV light. AR dye degradation was monitored by UV–visible spectroscopy and percent degradation was studied for the effect of time, catalyst dose, different dye concentrations, and different pH values of dye solution. All the catalysts have shown more than 80% dye degradation exhibiting good catalytic efficiencies for dye removal. The catalytic pathway was analyzed by applying the kinetic model. A pseudo second-order model was found the best fitted kinetic model indicating a chemically-rate controlled mechanism. Values of constant R2 for all the factors studied were close to unity depicting a good correlation between experimental data.

scholarly journals UV-Light Mediated Biosynthesis of Silver Nanowires; Characterization, Dye Degradation Potential and Kinetic Studies

2021 ◽  
Vol 13 (23) ◽  
pp. 13220
Author(s):  
Faisal Ali ◽  
Zahid Ali ◽  
Umer Younas ◽  
Awais Ahmad ◽  
Ghulam Mooin-ud-din ◽  
...  
Keyword(s):  
Dye Degradation ◽  
Uv Light ◽  
Silver Nanowires ◽  
Nitrate Solution ◽  
Kinetic Studies ◽  
Silver Nitrate Solution ◽  
Psidium Guajava ◽  
Cubic Phase ◽  
Solution Synthesis ◽  
Catalytic Potential

Herrin, a simple and eco-friendly method for the synthesis of silver nanowires (Ag-NWs) has been reported. Silver nanowires were synthesized using Psidium guajava seed extract that acted as a reducing agent as well as a stabilizing agent for silver nitrate solution. Synthesis was carried out at 50 °C temperature under continuous UV-irradiation. Silver nanowires were initially characterized by a UV-visible and FTIR spectrophotometer. In addition, morphology and particle size of synthesized Ag-NWs were determined using Field Emission Scanning Electron Microscopy and X-ray diffraction (XRD) techniques. Nanowires were found to have 12.8 μm length and 200–500 nm diameter and cubic phase morphology. Furthermore, the catalytic potential of Ag-NWs for the degradation of methyl orange dye (MO) was determined. The selected dye was degraded successfully that confirmed the catalytic potential of Ag-NWs. The authors concluded that Ag-NWs can be synthesized using plant extract having excellent morphological features as well as impressive catalytic potential.

ZnS NANOFLOWERS ON GRAPHENE FOR USE AS A HIGH-PERFORMANCE PHOTOCATALYST

NANO ◽  
2014 ◽  
Vol 09 (08) ◽  
pp. 1450097 ◽  
Author(s):  
ZENG BIN ◽  
LONG HUI
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
High Performance ◽  
Dye Degradation ◽  
Uv Light ◽  
Xps Spectra ◽  
X Ray ◽  
Transmission Electron ◽  
Photocatalytic Activities ◽  
Potential Applications

The nanocomposites of graphene loaded– ZnS nanoflowers (GR– ZnS ) had been successfully prepared. Materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectra (FTIR), photoluminescence (PL) and X-ray photoelectron spectroscopy (XPS) spectra. A possible formation mechanism of this architecture was proposed. The experimental results revealed that these nanoflowers exhibited excellent UV-light photocatalytic activities for pollutant methyl orange (MO) dye degradation. These new nanostructures were expected to show considerable potential applications in the water treatment.

ZnO Tetrapods for Potential Photocatalytic Dye Degradation

2018 ◽  
Vol 779 ◽  
pp. 97-101 ◽  
Author(s):  
Shynggys Sadyk ◽  
Timur Sh. Atabaev
Keyword(s):  
Photocatalytic Activity ◽  
Electron Microscope ◽  
Dye Degradation ◽  
Uv Light ◽  
Photocatalytic Properties ◽  
Light Illumination ◽  
X Ray ◽  
Vis Spectroscopy ◽  
Photocatalytic Dye Degradation ◽  
Scanning Electron

In this study, a facile method was used to prepare ZnO tetrapods for potential dye degradation applications. Field emission scanning electron microscope (FESEM), energy-dispersive X-ray spectroscopy (EDX) and UV-Vis spectroscopy were employed to investigate the morphology, chemical composition, and photocatalytic properties of prepared ZnO tetrapods. A Rhodamine B (RB) dye was used as a model dye to study the photocatalytic activity of the prepared sample. It was shown that RB dye can be efficiently degraded in the presence of ZnO tetrapods under continuous UV-light illumination. Thus, prepared ZnO tetrapods with excellent photocatalytic properties can be potentially used in wastewater treatment.

scholarly journals High Photocatalytic Performance of Modified Bismuth Oxychloride Semiconductor under Sunlight

2021 ◽  
Vol 37 (4) ◽  
pp. 770-778
Author(s):  
Preeja. P. Thattil ◽  
A. Leema Rose
Keyword(s):  
Dye Degradation ◽  
Diffuse Reflectance Spectrum ◽  
Ultra Violet ◽  
Analytical Techniques ◽  
Kinetic Studies ◽  
Degradation Process ◽  
Bet Surface Area ◽  
X Ray ◽  
Bismuth Oxychloride ◽  
Potential Applications

In recent years, the bismuth compounds have gained much interest due to their potential applications in the field of Photocatalysis. In our present work, Bismuth oxychloride Photocatalyst and Aluminium fluoride doped Bismuth oxychloride photocatalyst were synthesized by simple chemical methods using Bismuth nitrate pentahydrate as the precursor. The synthesized photocatalysts were characterized by different analytical techniques such as X-ray diffraction analyses, Ultra Violet –Diffuse reflectance spectrum, Field Emission – Scanning Electron Microscopy, Energy dispersive X-ray analyses,Fourier transform infrared spectroscopy studies and BET surface area analysis. The photocatalytic performances of the as-synthesized doped and undoped Bismuth oxychloride photocatalyst were tested towards the degradation of Acid green 1 dye. The parameters such as the effect of pH, catalyst concentration and initial dye concentration are optimized, and the kinetic studies are carried out for the photocatalytic dye degradation process. The experimental results showed that about 80% of the Acid green 1 dye got decolourized within 90 minutes by effective air purging under natural sunlight radiation in the presence of the AlF-BiOCl photocatalyst under optimized conditions.

scholarly journals Photocatalytic Degradation of Alizarin Red S, Amaranth, Congo Red, and Rhodamine B Dyes Using UV Light Modified Reactor and ZnO, TiO2, and SnO2 as Catalyst

2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Rabia Rehman ◽  
Waheed-Uz-Zaman ◽  
Asma Raza ◽  
Warda Noor ◽  
Amna Batool ◽  
...  
Keyword(s):  
Photocatalytic Degradation ◽  
Rhodamine B ◽  
Congo Red ◽  
Uv Light ◽  
Kinetic Studies ◽  
Alizarin Red S ◽  
Alizarin Red ◽  
First Order ◽  
Degradation Of Dyes ◽  
Uv Lamp

The photocatalytic degradation of dyes (alizarin red S, amaranth, congo red, and rhodamine B) present in wastewater was performed with UV lamp. The catalysts employed for this investigation were ZnO, TiO2, and SnO2. The kinetic studies of dyes degradation followed first order reaction. ZnO was found to be most efficient photo-catalyst for degrading these dyes. The optimal result for alizarin red S was k = 0.2118 min−1, t1/2 = 3.27 min, and R2 = 0.7998, for amaranth was k = 0.146 min−1, t1/2 = 4.74 min, and R2 = 0.8348, for congo red was k = 0.2452 min−1, t1/2 = 2.8 min, and R2 = 0.8382, and for rhodamine B was k = 0.1915 min−1, t1/2 = 3.6 min, and R2 = 0.76.

scholarly journals Adsorption, Kinetic, Equilibrium, Thermodynamic and Photocatalytic Investigations of the Removal of Nigrosin, Alizarin, Indigo and Acid Fuchsin Dyes on Modified CaO Surface

2020 ◽  
pp. 19-32
Author(s):  
Mouayed A. Hussein ◽  
Ibtighaa K. Radhi ◽  
Zaki N. Kadhim
Keyword(s):  
Indigo Carmine ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Acid Fuchsin ◽  
X Ray Diffraction ◽  
Alizarin Red ◽  
Photocatalytic Ability ◽  
X Ray ◽  
Adsorption Processes ◽  
Pseudo Second Order

Calcium oxide was obtained from eggshell and modified with Sulfur, Nitrogen and, Oxygen. The adsorbents were characterized using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX) and, scanning electron microscopy (SEM). The adsorbents were used for the removing of the dyes of Nigrosin, Alizarin red S, Indigo carmine, and Acid fuchsin from their aqueous solutions. The adsorption isotherm experiments were studied, and the equilibrium adsorption found either obeyed the Langmuir or Freundlich isotherm depending on the Sips isotherm results. Thermodynamic studies showed that the adsorption processes of the studied dyes were spontaneous, endothermic and randomness increases according to their ΔG, ΔH and ΔS values, respectively. The kinetic studies revealed that the pseudo second-order model best represented adsorption kinetics. Moreover, the photocatalytic ability of adsorbents was investigated under the sunlight, the results revealed the adsorbents have a strong photo-catalytic ability to absorb the dyes, particularly that observed for Acid fuchsin.

Synthesis of HTCMgFe for the degradation of indigo carmine through heterogeneous photo-Fenton treatment

MRS Advances ◽  
2020 ◽  
Vol 5 (62) ◽  
pp. 3273-3282
Author(s):  
I. Cosme-Torres ◽  
M.G. Macedo-Miranda ◽  
S.M. Martinez-Gallegos ◽  
J.C. González-Juárez ◽  
G. Roa-Morales ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Treatment Time ◽  
Uv Light ◽  
Indigo Carmine ◽  
Oh Radicals ◽  
Absorption Bands ◽  
Chromophore Group ◽  
X Ray ◽  
Catalytic Sites ◽  
Scanning Electron

AbstractThe heterogeneous catalyst HTCMgFe was used in the degradation of the IC, through the heterogeneous photo-fenton treatment, this material in combination with H2O2 and UV light degraded the dye in 30 min at pH 3. As the amount of HTCMgFe increases the degradation it was accelerated because there are more active catalytic sites of Fe2+ on the surface of the material, which generates a greater amount of •OH radicals. The HTCMgFe was characterized by infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray energy dispersive elemental analysis (EDS). The UV-vis spectrum shows that the absorption bands belonging to the chromophore group of the IC disappear as the treatment time passes, indicating the degradation of the dye.

scholarly journals X-ray and UV emission of the ultrashort-period, low-mass eclipsing binary system BX Trianguli

2018 ◽  
Vol 619 ◽  
pp. A138
Author(s):  
V. Perdelwitz ◽  
S. Czesla ◽  
J. Robrade ◽  
T. Pribulla ◽  
J. H. M. M. Schmitt
Keyword(s):  
Binary System ◽  
Light Curve ◽  
Binary Systems ◽  
Uv Light ◽  
Close Binary ◽  
Eclipsing Binary ◽  
X Ray ◽  
Uv Emission ◽  
Low Mass ◽  
Orbital Modulation

Context.Close binary systems provide an excellent tool for determining stellar parameters such as radii and masses with a high degree of precision. Due to the high rotational velocities, most of these systems exhibit strong signs of magnetic activity, postulated to be the underlying reason for radius inflation in many of the components. Aims.We extend the sample of low-mass binary systems with well-known X-ray properties. Methods.We analyze data from a singular XMM-Newton pointing of the close, low-mass eclipsing binary system BX Tri. The UV light curve was modeled with the eclipsing binary modeling tool PHOEBE and data acquired with the EPIC cameras was analyzed to search for hints of orbital modulation. Results.We find clear evidence of orbital modulation in the UV light curve and show that PHOEBE is fully capable of modeling data within this wavelength range. Comparison to a theoretical flux prediction based on PHOENIX models shows that the majority of UV emission is of photospheric origin. While the X-ray light curve does exhibit strong variations, the signal-to-noise ratio of the observation is insufficient for a clear detection of signs of orbital modulation. There is evidence of a Neupert-like correlation between UV and X-ray data.

scholarly journals Release of toxic methylene blue from water by mesoporous silicalite-1: characterization, kinetics and isotherm studies

2021 ◽  
Vol 11 (7) ◽  
Author(s):  
Sabarish Radoor ◽  
Jasila Karayil ◽  
Aswathy Jayakumar ◽  
Jyotishkumar Parameswaranpillai ◽  
Suchart Siengchin
Keyword(s):  
Electron Microscopy ◽  
Contact Time ◽  
Dye Removal ◽  
Batch Adsorption ◽  
Aqueous Environment ◽  
Order Kinetic ◽  
Adsorption Method ◽  
X Ray ◽  
Ft Ir ◽  
Adsorption Desorption

AbstractIn the present work, we have developed a mesoporous silicalite-1 using CMC as a template for the removal of MB from aqueous solution. The synthesized silicalite-1 were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Energy-dispersive X-ray spectroscopy (EDAX) and N2 adsorption–desorption isotherm (BET). XRD and FT-IR analysis confirmed the formation of crystallinity and development of MFI structure in the mesoporous silicalite-1. The adsorption of MB dye on mesoporous silicalite-1 was conducted by batch adsorption method. The effect of various parameters such as adsorbent dosage, initial dye concentration, contact time and temperature on the dye uptake ability of silicalite-1 was investigated. The operating parameters for the maximum adsorption are silicalite-1 dosage (0.1 wt%), contact time (240 min), initial dye concentration (10 ppm) and temperature (30 ℃). The MB dye removal onto mesoporous silicalite-1 followed pseudo-second-order kinetic and Freundlich isotherm. The silicalite-1 exhibits 86% removal efficiency even after six adsorption–desorption cycle. Therefore, the developed mesoporous silicalite-1 is an effective eco-friendly adsorbent for MB dye removal from aqueous environment.

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