scholarly journals Advancements in Solar Desalination of Seawater by Various Ti3C2 MXene Based Morphologies for Freshwater Generation: A Review

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1435
Author(s):  
Adem Sreedhar ◽  
Jin-Seo Noh

For a few years, we have been witnessing ubiquitous fresh and drinking water scarcity in various countries. To mitigate these problematic situations, many countries relied on non-conventional freshwater generation technologies through solar desalination of seawater. In this manner, we excel the ability of new class 2D Ti3C2 MXenes as a photothermal material (solar absorber) for freshwater generation via the solar desalination technique. In this review, the air–water interfacial interaction is highlighted for improving the evaporation efficiency. To provide the dependence of the desalination efficiency on the microstructure of the solar absorbers, we summarized various forms of 2D Ti3C2 MXenes (aerosol, films, foam, hydrogel, membrane, monolith and porous structure) and their characteristics. These microstructures prevailed ultrahigh photoconversion efficiency. In this aspect, we further explained key features such as light absorption, reflection, multiple internal reflection, hydrophilicity, lower thermal conduction, light-to-heat generation, and salt rejection for achieving efficient desalination output throughout the visible and broadband region. Specifically, we targeted to explore the self-floating and salt rejection nature of various state-of-the-art 2D Ti3C2 MXene structures. Further, we highlighted the long-term stability. Among the above morphologies, Ti3C2 MXene in the form of a membrane is believed to be a promising morphology which effectively desalinates seawater into freshwater. Finally, we highlighted the challenges and future perspectives, which can pave a potential path for advancing the sustainable solar desalination of seawater into freshwater.

2020 ◽  
Vol 8 (24) ◽  
pp. 12089-12096 ◽  
Author(s):  
Wei Zhang ◽  
Xi Chen ◽  
Gong Zhang ◽  
Jianfei Li ◽  
Qinghua Ji ◽  
...  

Heat–mass decoupling enabled by anisotropy can simultaneously ensure rapid salt rejection and enhanced heat localization, achieving long-term efficient solar desalination.


Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 1089
Author(s):  
Claudio Falco ◽  
Ethan L. W. Gardner ◽  
Andrea De Luca ◽  
Nicolas André ◽  
Laurent A. Francis ◽  
...  

The effect of membrane deflection has been investigated for thermal flow sensors. Catastrophic membrane breakage is a common occurrence in membrane based thermal flow sensors due to thermal expansion and internal stresses. This work analyses three sensors comprising a tungsten heater embedded in buried oxide membrane with a silicon nitride passivation layer, the use of back etching creates a cavity underneath to reduce the thermal conduction. The investigation is done using interferometry to measure the membrane shape at room and operating temperature for three membranes of different sizes. As expected, the deflection increases with temperature up to 15 µm at operating temperature and with the reduction of membrane size the deflection is reduced to a minimum of 3 µm for the smallest membrane. The lower deflection measured in devices with a smaller cavity can be related to a reduced internal stress, improving the long term stability.


2021 ◽  
Vol 9 ◽  
Author(s):  
Xiaoqiang Yu ◽  
Qian Zhang ◽  
Xin Liu ◽  
Ning Xu ◽  
Lin Zhou

Solar interfacial evaporation, featured by high energy transfer efficiency, low cost, and environmental compatibility, has been widely regarded as a promising technology for solar desalination. However, the interplay between energy transfer and water transport in the same channels suggests that the tradeoff between high efficiency and long-term stability inherently exists in conventional photothermal nanomaterials. We summarize state-of-the-art research on various anti-salt clogging photothermal microstructures as long-term stable interfacial solar evaporators for solar desalination. The review starts with an overview of the current status and the fundamental limit of photothermal materials for solar desalination. Four representative strategies are analyzed in detail with the most recent experimental demonstrations, including fluid convection enhancement, surface wettability engineering, energy-mass-path decoupling, and surface chemistry engineering. Finally, this article focuses on the challenges in anti-salt clogging solar interfacial evaporators and potential point-of-use applications in the future.


2013 ◽  
Vol 20 (4) ◽  
pp. 522-530 ◽  
Author(s):  
Maria Brzhezinskaya ◽  
Alexander Firsov ◽  
Karsten Holldack ◽  
Torsten Kachel ◽  
Rolf Mitzner ◽  
...  

Aiming at advancing storage-ring-based ultrafast X-ray science, over the past few years many upgrades have been undertaken to continue improving beamline performance and photon flux at the Femtoslicing facility at BESSY II. In this article the particular design upgrade of one of the key optical components, the zone-plate monochromator (ZPM) beamline, is reported. The beamline is devoted to optical pump/soft X-ray probe applications with 100 fs (FWHM) X-ray pulses in the soft X-ray range at variable polarization. A novel approach consisting of an array of nine off-axis reflection zone plates is used for a gapless coverage of the spectral range between 410 and 1333 eV at a designed resolution ofE/ΔE= 500 and a pulse elongation of only 30 fs. With the upgrade of the ZPM the following was achieved: a smaller focus, an improved spectral resolution and bandwidth as well as excellent long-term stability. The beamline will enable a new class of ultrafast applications with variable optical excitation wavelength and variable polarization.


2005 ◽  
Vol 26 (2) ◽  
pp. 100-106 ◽  
Author(s):  
James D.A. Parker ◽  
Donald H. Saklofske ◽  
Laura M. Wood ◽  
Jennifer M. Eastabrook ◽  
Robyn N. Taylor

Abstract. The concept of emotional intelligence (EI) has attracted growing interest from researchers working in various fields. The present study examined the long-term stability (32 months) of EI-related abilities over the course of a major life transition (the transition from high school to university). During the first week of full-time study, a large group of undergraduates completed the EQ-i:Short; 32 months later a random subset of these students (N = 238), who had started their postsecondary education within 24 months of graduating from high school, completed the measures for a second time. The study found EI scores to be relatively stable over the 32-month time period. EI scores were also found to be significantly higher at Time 2; the overall pattern of change in EI-levels was more than can be attributed to the increased age of the participants.


1991 ◽  
Vol 65 (03) ◽  
pp. 263-267 ◽  
Author(s):  
A M H P van den Besselaar ◽  
R M Bertina

SummaryIn a collaborative trial of eleven laboratories which was performed mainly within the framework of the European Community Bureau of Reference (BCR), a second reference material for thromboplastin, rabbit, plain, was calibrated against its predecessor RBT/79. This second reference material (coded CRM 149R) has a mean International Sensitivity Index (ISI) of 1.343 with a standard error of the mean of 0.035. The standard error of the ISI was determined by combination of the standard errors of the ISI of RBT/79 and the slope of the calibration line in this trial.The BCR reference material for thromboplastin, human, plain (coded BCT/099) was also included in this trial for assessment of the long-term stability of the relationship with RBT/79. The results indicated that this relationship has not changed over a period of 8 years. The interlaboratory variation of the slope of the relationship between CRM 149R and RBT/79 was significantly lower than the variation of the slope of the relationship between BCT/099 and RBT/79. In addition to the manual technique, a semi-automatic coagulometer according to Schnitger & Gross was used to determine prothrombin times with CRM 149R. The mean ISI of CRM 149R was not affected by replacement of the manual technique by this particular coagulometer.Two lyophilized plasmas were included in this trial. The mean slope of relationship between RBT/79 and CRM 149R based on the two lyophilized plasmas was the same as the corresponding slope based on fresh plasmas. Tlowever, the mean slope of relationship between RBT/79 and BCT/099 based on the two lyophilized plasmas was 4.9% higher than the mean slope based on fresh plasmas. Thus, the use of these lyophilized plasmas induced a small but significant bias in the slope of relationship between these thromboplastins of different species.


1979 ◽  
Vol 42 (04) ◽  
pp. 1135-1140 ◽  
Author(s):  
G I C Ingram

SummaryThe International Reference Preparation of human brain thromboplastin coded 67/40 has been thought to show evidence of instability. The evidence is discussed and is not thought to be strong; but it is suggested that it would be wise to replace 67/40 with a new preparation of human brain, both for this reason and because 67/40 is in a form (like Thrombotest) in which few workers seem to use human brain. A �plain� preparation would be more appropriate; and a freeze-dried sample of BCT is recommended as the successor preparation. The opportunity should be taken also to replace the corresponding ox and rabbit preparations. In the collaborative study which would be required it would then be desirable to test in parallel the three old and the three new preparations. The relative sensitivities of the old preparations could be compared with those found in earlier studies to obtain further evidence on the stability of 67/40; if stability were confirmed, the new preparations should be calibrated against it, but if not, the new human material should receive a calibration constant of 1.0 and the new ox and rabbit materials calibrated against that.The types of evidence available for monitoring the long-term stability of a thromboplastin are discussed.


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