scholarly journals Adsorption of Mixtures of a Pegylated Lipid with Anionic and Zwitterionic Surfactants at Solid/Liquid

2020 ◽  
Vol 4 (4) ◽  
pp. 47
Author(s):  
Sara Llamas ◽  
Eduardo Guzmán ◽  
Francisco Ortega ◽  
Ramón G. Rubio
Keyword(s):  
Hydrophobic Interactions ◽  
Deposition Process ◽  
Surfactant Mixtures ◽  
Zwitterionic Surfactants ◽  
Charged Surfaces ◽  
Surfactant Aggregates ◽  
Ternary Polymer ◽  
Solid Liquid ◽  
Polymer Surfactant ◽  
The Impact

This work explores the association of a pegylated lipid (DSPE-PEG) with different anionic and zwitterionic surfactants (pseudo-binary and pseudo-ternary polymer+ surfactant mixtures), and the adsorption of the polymer + surfactant aggregates onto negatively charged surfaces, with a surface charge density similar to that existing on the damaged hair epicuticle. Dynamic light scattering and zeta potential measurements shows that, in solution, the polymer + surfactant association results from an intricate balance between electrostatic and hydrophobic interactions, which leads to the formation of at least two different types of micellar-like polymer + surfactant aggregates. The structure and physicochemical properties of such aggregates were found strongly dependent on the specific nature and concentration of the surfactant. The adsorption of the polymer + surfactant aggregates onto negatively charged surface was studied using a set of surface-sensitive techniques (quartz crystal microbalance with dissipation monitoring, ellipsometry and Atomic Force Microscopy), which allows obtaining information about the adsorbed amount, the water content of the layers and the topography of the obtained films. Ion-dipole interactions between the negative charges of the surface and the oxyethylene groups of the polymer + surfactant aggregates appear as the main driving force of the deposition process. This is strongly dependent on the surfactant nature and its concentration, with the impact of the latter on the adsorption being especially critical when anionic surfactant are incorporated within the aggregates. This study opens important perspectives for modulating the deposition of a poorly interacting polymer onto negatively charged surfaces, which can impact in the fabrication on different aspects with technological and industrial interest.

Nonequilibrium Mesoscale Surface Structures:  The Adsorption of Polymer−Surfactant Mixtures at the Solid/Liquid Interface

Langmuir ◽  
1999 ◽  
Vol 15 (25) ◽  
pp. 8719-8725 ◽  
Author(s):  
Barry D. Fleming ◽  
Erica J. Wanless ◽  
Simon Biggs
Keyword(s):  
Liquid Interface ◽  
Surface Structures ◽  
Surfactant Mixtures ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Polymer Surfactant

scholarly journals Self-Consistent Mean Field Calculations of Polyelectrolyte-Surfactant Mixtures in Solution and upon Adsorption onto Negatively Charged Surfaces

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 624 ◽  
Author(s):  
Eduardo Guzmán ◽  
Laura Fernández-Peña ◽  
Gustavo S. Luengo ◽  
Ana María Rubio ◽  
Antonio Rey ◽  
...  
Keyword(s):  
Self Assembly ◽  
Quantitative Description ◽  
Mean Field ◽  
Chemical Behavior ◽  
Surfactant Mixtures ◽  
Charged Surfaces ◽  
Physico Chemical ◽  
Self Consistent ◽  
Polymer Surfactant ◽  
Scf Calculations

Self-Consistent Mean-Field Calculations (SCF) have provided a semi-quantitative description of the physico-chemical behavior of six different polyelectrolyte-surfactant mixtures. The SCF calculations performed showed that both the formation of polymer-surfactant in bulk and the adsorption of the formed complexes onto negatively-charged surfaces are strongly affected by the specific nature of the considered systems, with the polymer-surfactant interactions playing a central role in the self-assembly of the complexes that, in turn, affects their adsorption onto interfaces and surfaces. This work evidences that SCF calculations are a valuable tool for deepening on the understanding of the complex physico-chemical behavior of polyelectrolyte-surfactant mixtures. However, it is worth noting that the framework obtained on the basis of an SCF approach considered an equilibrium situation which may, in some cases, be far from the real situation appearing in polyelectrolyte-surfactant systems.

scholarly journals Surfactant-Like Behavior for the Adsorption of Mixtures of a Polycation and Two Different Zwitterionic Surfactants at the Water/Vapor Interface

Molecules ◽  
2019 ◽  
Vol 24 (19) ◽  
pp. 3442 ◽  
Author(s):  
Andrew Akanno ◽  
Eduardo Guzmán ◽  
Laura Fernández-Peña ◽  
Francisco Ortega ◽  
Ramón G. Rubio
Keyword(s):  
Interfacial Properties ◽  
Zwitterionic Surfactant ◽  
Fluid Interface ◽  
Surfactant Mixtures ◽  
Zwitterionic Surfactants ◽  
Dimethylammonium Chloride ◽  
Polymer Surfactant ◽  
Charged Group ◽  
Positively Charged ◽  
Dilational Rheology

The bulk and interfacial properties of solutions formed by a polycation (i.e., poly(diallyl-dimethylammonium chloride), PDADMAC) and two different zwitterionic surfactants (i.e., coco-betaine (CB) and cocoamidopropyl-betaine (CAPB)) have been studied. The bulk aggregation of the polyelectrolyte and the two surfactants was analyzed by turbidity and electrophoretic mobility measurements, and the adsorption of the solutions at the fluid interface was studied by surface tension and interfacial dilational rheology measurements. Evidence of polymer–surfactant complex formation in bulk was only found when the number of surfactant molecules was closer to the number of charged monomers in solutions, which suggests that the electrostatic repulsion associated with the presence of a positively charged group in the surfactant hinders the association between PDADMAC and the zwitterionic surfactant for concentrations in which there are no micelles in solution. This lack of interaction in bulk is reflected in the absence of an influence of the polyelectrolyte in the interfacial properties of the mixtures, with the behavior being controlled by the presence of surfactant. This work has evidenced the significant importance of the different interactions involved in the system for controlling the interaction and complexation mechanisms of in polyelectrolyte–surfactant mixtures.

Adsorption and Desorption of Polymer/Surfactant Mixtures at Solid−Liquid Interfaces:  Substitution Experiments

Langmuir ◽  
2004 ◽  
Vol 20 (19) ◽  
pp. 8114-8123 ◽  
Author(s):  
D. Zimin ◽  
V. S. J. Craig ◽  
W. Kunz
Keyword(s):  
Liquid Interfaces ◽  
Surfactant Mixtures ◽  
Adsorption And Desorption ◽  
Solid Liquid ◽  
Polymer Surfactant

Computer simulation study about the dependence of amorphous silicon photonic waveguides efficiency on the material quality

2020 ◽  
Vol 90 (3) ◽  
pp. 30502
Author(s):  
Alessandro Fantoni ◽  
João Costa ◽  
Paulo Lourenço ◽  
Manuela Vieira
Keyword(s):  
Amorphous Silicon ◽  
High Throughput Screening ◽  
Simulation Analysis ◽  
Low Cost ◽  
Deposition Process ◽  
Large Area ◽  
Sidewall Roughness ◽  
Sensing Applications ◽  
Fabrication Defects ◽  
The Impact

Amorphous silicon PECVD photonic integrated devices are promising candidates for low cost sensing applications. This manuscript reports a simulation analysis about the impact on the overall efficiency caused by the lithography imperfections in the deposition process. The tolerance to the fabrication defects of a photonic sensor based on surface plasmonic resonance is analysed. The simulations are performed with FDTD and BPM algorithms. The device is a plasmonic interferometer composed by an a-Si:H waveguide covered by a thin gold layer. The sensing analysis is performed by equally splitting the input light into two arms, allowing the sensor to be calibrated by its reference arm. Two different 1 × 2 power splitter configurations are presented: a directional coupler and a multimode interference splitter. The waveguide sidewall roughness is considered as the major negative effect caused by deposition imperfections. The simulation results show that plasmonic effects can be excited in the interferometric waveguide structure, allowing a sensing device with enough sensitivity to support the functioning of a bio sensor for high throughput screening. In addition, the good tolerance to the waveguide wall roughness, points out the PECVD deposition technique as reliable method for the overall sensor system to be produced in a low-cost system. The large area deposition of photonics structures, allowed by the PECVD method, can be explored to design a multiplexed system for analysis of multiple biomarkers to further increase the tolerance to fabrication defects.

scholarly journals Mechanical Behavior of Hydroxyapatite-Chitosan Composite: Effect of Processing Parameters

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 213
Author(s):  
Hamid Ait Said ◽  
Hassan Noukrati ◽  
Hicham Ben Youcef ◽  
Ayoub Bayoussef ◽  
Hassane Oudadesse ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Compressive Strength ◽  
Mechanical Strength ◽  
Bone Repair ◽  
Mechanical Stability ◽  
Three Dimensional ◽  
Processing Parameters ◽  
Composite Effect ◽  
Solid Liquid ◽  
The Impact

Three-dimensional hydroxyapatite-chitosan (HA-CS) composites were formulated via solid-liquid technic and freeze-drying. The prepared composites had an apatitic nature, which was demonstrated by X-ray diffraction and Infrared spectroscopy analyses. The impact of the solid/liquid (S/L) ratio and the content and the molecular weight of the polymer on the composite mechanical strength was investigated. An increase in the S/L ratio from 0.5 to 1 resulted in an increase in the compressive strength for HA-CSL (CS low molecular weight: CSL) from 0.08 ± 0.02 to 1.95 ± 0.39 MPa and from 0.3 ± 0.06 to 2.40 ± 0.51 MPa for the HA-CSM (CS medium molecular weight: CSM). Moreover, the increase in the amount (1 to 5 wt%) and the molecular weight of the polymer increased the mechanical strength of the composite. The highest compressive strength value (up to 2.40 ± 0.51 MPa) was obtained for HA-CSM (5 wt% of CS) formulated at an S/L of 1. The dissolution tests of the HA-CS composites confirmed their cohesion and mechanical stability in an aqueous solution. Both polymer and apatite are assumed to work together, giving the synergism needed to make effective cylindrical composites, and could serve as a promising candidate for bone repair in the orthopedic field.

Modeling and Experiments of Laser Cladding With Droplet Injection

2005 ◽  
Vol 127 (9) ◽  
pp. 978-986 ◽  
Author(s):  
J. Choi ◽  
L. Han ◽  
Y. Hua
Keyword(s):  
Fluid Flow ◽  
Laser Cladding ◽  
Dynamic Motion ◽  
Cladding Layer ◽  
Melt Pool ◽  
Material Deposition ◽  
Modeling And Experiments ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
The Impact

Laser aided Directed Material Deposition (DMD) is an additive manufacturing process based on laser cladding. A full understanding of laser cladding is essential in order to achieve a steady state and robust DMD process. A two dimensional mathematical model of laser cladding with droplet injection was developed to understand the influence of fluid flow on the mixing, dilution depth, and deposition dimension, while incorporating melting, solidification, and evaporation phenomena. The fluid flow in the melt pool that is driven by thermal capillary convection and an energy balance at the liquid–vapor and the solid–liquid interface was investigated and the impact of the droplets on the melt pool shape and ripple was also studied. Dynamic motion, development of melt pool and the formation of cladding layer were simulated. The simulated results for average surface roughness were compared with the experimental data and showed a comparable trend.

Dilational rheology of polymer/surfactant mixtures at water/hexane interface

2011 ◽  
Vol 391 (1-3) ◽  
pp. 130-134 ◽  
Author(s):  
A. Sharipova ◽  
S. Aidarova ◽  
N. Mucic ◽  
R. Miller
Keyword(s):  
Surfactant Mixtures ◽  
Polymer Surfactant ◽  
Dilational Rheology

Solid–liquid two-phase flow and erosion calculation of butterfly valves at small opening based on DEM method

2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Benliang Xu ◽  
Zuchao Zhu ◽  
Zhe Lin ◽  
Dongrui Wang
Keyword(s):  
Peer Review ◽  
Two Phase Flow ◽  
Solid Particles ◽  
Phase Flow ◽  
Butterfly Valve ◽  
Two Phase ◽  
Content Type ◽  
Small Opening ◽  
Solid Liquid ◽  
The Impact

Purpose The study aims to decrease the effect of solid particles on a butterfly valve, which will cause seal failure and leakage, providing a reference for anti-wear design. Design/methodology/approach In this paper, computational fluid dynamics discrete element method (CFD-DEM) simulation was conducted to study the solid–liquid two-phase flow characteristics and erosion characteristics of a butterfly valve with a different opening. Findings Abrasion at 10% opening is affected by high-speed jets in upper and lower parts of the pipeline, where the erosion is intense. The impact of the jet on the upper part of 20% opening begins to weaken. With the top backflow vortex disappearing, the effect of lower jet is enhanced. Meanwhile, the bottom backflow vortex phenomenon is obvious, and the abrasion position moves downward. At 30% opening, the velocity is further weakened, and the circulation effect of lower flow channel is more obvious than that of the upper one. Originality/value It is the first time to use DEM to investigate the two-phase flow and erosion characteristics at a small opening of a butterfly valve, considering the effect of inter-particle collision. Therefore, this study carries on the thorough analysis and discussion. At the same opening degree, with increasing of the particle size, the abrasion of valve frontal surface increases when the size is less than 150 µm and decreases when it is greater than 150 µm. For the valve backflow surface, this boundary value becomes 200 µm. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-07-2020-0264/

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