scholarly journals A New Process of Extracting Titanium from Vanadium–Titanium Magnetite

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 327
Author(s):  
Yandong Li ◽  
Shuangyin Chen ◽  
Huamei Duan
Keyword(s):  
Recovery Rate ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Optimum Conditions ◽  
Solid Ratio ◽  
New Process ◽  
Leaching Experiments ◽  
Panxi Area ◽  
Vanadium Titanium ◽  
Titanium Magnetite

A new process of extracting titanium from vanadium–titanium magnetite (VTM) in the Panxi area in Sichuan, China is introduced in this work. Various experiments, including reduction–magnetic separation, leaching and hydrolyzing experiments, are carried out. The results show that the optimum conditions for leaching experiments are an acid/slag ratio of 4:1, a leaching temperature of 60 °C, a leaching time of 80 min, and a liquid/solid ratio of 3.2:1. The leaching rate of titanium in Ti-bearing slag is 92.41%. The optimum conditions for hydrolyzing experiments are an H+ concentration of 0.75 g·L−1, hydrolyzing temperature of 100 °C, and hydrolyzing time of 180 min, and the hydrolyzing rate of titanium in acid leaching liquor is 96.80%. After the leaching and hydrolyzing experiments, the recovery rate of titanium from the Ti-bearing slag is 89.45%.

Effect of Oxidant on the Leaching Rate of Indium from Water Quenching Slag

2013 ◽  
Vol 591 ◽  
pp. 122-125
Author(s):  
Li Jiao Yang ◽  
Si Chen ◽  
Yan Zhang ◽  
Nan Chun Chen ◽  
Jun Gao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Sulfuric Acid ◽  
Potassium Permanganate ◽  
Crystal Violet ◽  
Acid Leaching ◽  
Water Quenching ◽  
Test Results ◽  
Leaching Rate ◽  
Initial Concentration ◽  
Solid Ratio

Extracting indium from water quenching slag, which contains poor indium, by two process of leaching, the effect of different oxidants and dosages on the leaching rate of indium in water quenching slag were studied. The leaching conditions: temperature 80 °C, leaching time 2 h, the liquid to solid ratio of neutral leaching 8︰1, the liquid to solid ratio of acid leaching 2︰1, initial concentration of sulfuric acid 500 g·L-1, adding different oxidants, the concentration was detected by crystal violet spectrophotometry. Test results showed that the leaching rate of indium was significantly improved by adding hydrogen peroxide and potassium permanganate. Compared with the effect of different oxidants, the effect of potassium permanganate was significantly higher than that of hydrogen peroxide on the leaching rate of indium.

scholarly journals Mechanism of Novel K2SO4/KCl Composite Roasting Additive for Strengthening Vanadium Extraction from Vanadium–Titanium Magnetite Concentrate

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 426
Author(s):  
Renmin Li ◽  
Tao Liu ◽  
Yimin Zhang ◽  
Jing Huang
Keyword(s):  
Sulfuric Acid Concentration ◽  
X Ray Diffraction ◽  
Volume Percentage ◽  
Solid Ratio ◽  
Vanadium Extraction ◽  
Magnetite Concentrate ◽  
Main Decomposition ◽  
Vanadium Titanium ◽  
Hematite Fe2o3 ◽  
Titanium Magnetite

In this paper, a novel K2SO4/KCl composite roasting additive was used to extract vanadium from vanadium–titanium magnetite concentrate. Further, the mechanism of K2SO4/KCl for extracting vanadium was studied. The results indicate that the vanadium leaching efficiency reached 82.04%, an increase of 7.43% compared to that of single K2SO4 and 10.05% compared to single KCl under the following conditions: a total dosage of K2SO4/KCl of 7 wt % with a mass ratio of 6/4, a roasting temperature of 950 °C, a roasting time of 1 h, a leaching temperature of 95 °C, a sulfuric acid concentration of 10% (v/v: volume percentage), and a leaching time of 1.5 h with a liquid-to-solid ratio of 3 mL/g. Moreover, crystal chemistry analyses indicated that the essence of the vanadium extraction with roasting was the conversion of cubic crystal systemic vanadium-bearing magnetite (FeO(Fe,V)2O3) to trigonal crystal systemic hematite (α-Fe2O3), and as most Fe(V)–O bonds were broken with the reconstructed conversion, the dissociation of V(III) occurred. Furthermore, the main decomposition products of K2SO4/KCl were K2O, SO2, and Cl2. X-ray diffraction (XRD) and related SEM-EDS analyses indicated that there were mainly three aspects in the mechanism of K2SO4/KCl for extracting vanadium. Firstly, activated K2O could combine with vanadium to generate soluble KVO3 rather insoluble Ca(VO3)2; secondly, SO2 could react with CaO to form CaSO4 to prevent the generation of acid-consuming Ca(VO3)2, which was beneficial to the dissolution of vanadium-bearing sphene (Ca(Ti,V)SiO4O); thirdly, Cl2 could destroy the structure of hematite (Fe2O3) to reduce its wrapping extent to KVO3.

scholarly journals The Alteration Mechanism of Copper-bearing Biotite and Leachable Property of Copper-bearing Minerals in Mulyashy Copper Mine, Zambia

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Gai-rong Wang ◽  
Hong-ying Yang ◽  
Yuan-yuan Liu ◽  
Lin-lin Tong ◽  
Ali Auwalu
Keyword(s):  
Sample Size ◽  
Acid Leaching ◽  
Special Structure ◽  
Leaching Rate ◽  
Polarizing Microscopy ◽  
Copper Mine ◽  
Copper Leaching ◽  
Different Temperatures ◽  
Leaching Experiments

Abstract The XRF, XRD, polarizing microscopy and SEM-EDS were used to study the alteration mechanism of copper-bearing biotite and the leachable property of copper-bearing minerals in Mulyashy Copper Mine, Zambia. It was found that biotite can be divided into copper-bearing biotite and copper-free biotite. Some copper-bearing biotite existed in the form of monomer, and others aggregated with copper-bearing chlorite, malachite or copper-bearing limonite. The main reason for the occurrence of biotite aggregations was that copper-bearing biotite underwent two kinds of alteration mechanisms as follows: altering into copper-bearing chlorite and malachite, and altering into copper-bearing chlorite and copper-bearing limonite. The order of factors effecting the copper leaching rate of the ores in acid leaching experiments was temperature > sample size > H2SO4 concentration > leaching time > stirring speed. In addition, the copper leaching rate of copper-bearing minerals at different temperatures was in the following order: malachite, chrysocolla and pseudomalachite > copper-bearing chlorite > copper-bearing muscovite > copper-bearing biotite > copper-bearing limonite. The leachable property of biotite is closely related to its special structure.

Study on Leaching Zinc Calcine with High Iron

2013 ◽  
Vol 826 ◽  
pp. 118-121
Author(s):  
Jin Lin Yang ◽  
Hong Mei Zhang ◽  
Xiu Juan Su ◽  
Shao Jian Ma
Keyword(s):  
Sulfuric Acid ◽  
Acid Concentration ◽  
Great Influence ◽  
Sulfuric Acid Concentration ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Iron Extraction ◽  
High Iron ◽  
Solid Ratio ◽  
Leaching Efficiency

In recent years, recovering zinc from zinc calcine with high iron has been a matter of discussion. In this paper, sulfuric acid leaching was carried out to assess the effect of several parameters on zinc and iron extraction in zinc calcine with high iron in which the grade of zinc and iron is 53.90% and 19.38%, respectively. Parameters, such as stirring speed, sulfuric acid concentration, liquid to solid ratio and leaching time, were investigated. The results show that leaching time has done nothing to the leaching rate, but has great influence on leaching efficiency. Liquid to solid ratio and sulfuric acid concentration have significant influence on leaching results, and stirring rate has not obvious influence on leaching results. Under the condition of 120g/L sulfuric acid, 6:1 liquid to solid ratio, 55°C leaching temperature and 120min leaching time, the recovery of zinc and iron is 82.24% and 9.64%, respectively. It is obvious that ZnO in zinc calcine is easy to dissolve in acidity solution, which shown in two aspects: high leaching rate and high leaching speed. ZnO can be dissolved entirely in sufficient sulfuric acid in 10min.

Oxygen Pressure Acid Leaching of Vanadium Slag

2011 ◽  
Vol 79 ◽  
pp. 242-247 ◽  
Author(s):  
Wang Zhong Mu ◽  
Ting An Zhang ◽  
Zhi He Dou ◽  
Guo Zhi Lü ◽  
Lan Hu ◽  
...  
Keyword(s):  
Oxygen Pressure ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Vanadium Slag ◽  
Solid Ratio ◽  
Leaching Process ◽  
Oxygen Pressure Acid Leaching ◽  
Effects Of Temperature ◽  
Pressure Acid Leaching ◽  
Single Factor Experiment

Oxygen pressure acid leaching process was used to extract vanadium from vanadium slag (Panzhihua steelmaking plant of China). The single factor experiment was finished and the effects of temperature, leaching time, liquid to solid ratio, stirring speed, initial concentration of sulfuric acid, and were investigated on the leaching rate of vanadium, titanium and iron. The leachate and residue were characterized by ICP, XRF, XRD, SEM and EDX. The experiment results indicate when temperature is 140 °C, leaching time is 120 min, liquid to solid ratio is 20:1(ml:g), stirring speed is 500 rpm, initial acid concentration is 200 g/L, oxygen partial pressure is 0.5 MPa, and particle size is -0.075~+0.055 mm, leaching rate of vanadium is 97.89% and the content of vanadium in the residue is 0.586%. Leaching rate of titanium and iron is 12.78% and 94.45% respectively. Vanadium could be extracted effectively through the oxygen pressure acid leaching process.

Study on Direct Acid Leaching Vanadium without Grinding and Roasting from Clay Vanadium Ore in Hunan

2013 ◽  
Vol 316-317 ◽  
pp. 882-886
Author(s):  
Wei He ◽  
Guo Hua Ye ◽  
Xiong Tong
Keyword(s):  
Sulfuric Acid ◽  
New Technology ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Solid Ratio ◽  
Acid Type ◽  
Temperature Liquid ◽  
The Cost ◽  
Grinding System ◽  
Acid Dosage

Abstract：A new technology of direct acid leaching vanadium without grinding and roasting was put forward, and the effects of leaching factors including dosage of sulfuric acid, type and dosage of assistant leaching agent, leaching time and temperature, liquid-solid ratio on the vanadium leaching rate were systematically investigated. The results show that vanadium leaching rate could be up to 92.58% under the optimal conditions of sulfuric acid dosage of 30%, MnO2 as assistant leaching agent and its dosage of 1.5%, leaching time of 6h, leaching temperature of 90°C, liquid-solid ratio of 1:1, and the leaching performance is perfect. Due to leaving out the high costing grinding system and the complex roasting system, the new technology has advantages in shortening the process, decreasing the cost, avoiding pollution generated by roasting comparing with the traditional technologies, and it can meet the requirement of modern metallurgy very well.

Sulfuric Acid Leaching on Low Grade Oxide Ore

2013 ◽  
Vol 826 ◽  
pp. 122-125 ◽  
Author(s):  
Jin Lin Yang ◽  
Hong Mei Zhang ◽  
Gui Fang Wang ◽  
Shao Jian Ma ◽  
Min Zhang
Keyword(s):  
Sulfuric Acid ◽  
Sulfuric Acid Concentration ◽  
Acid Leaching ◽  
Strong Acid ◽  
Metal Extraction ◽  
Low Grade ◽  
Leaching Rate ◽  
Sulfuric Acid Leaching ◽  
Solid Ratio ◽  
Iron Leaching

In this paper, sulfuric acid leaching was carried out to assess the effect of several parameters on metal extraction in a low grade complex gossan ore in which the grade of zinc and iron is 13% and 40.2%, respectively. Parameters, such as sulfuric acid concentration, liquid to solid ratio and leaching temperature, were studied. The results show that the zinc leaching rate is almost 80%, while the iron leaching rate is about 45% used strong acid with 200g/L. It can be seen from the results that sulfuric acid leaching could not effectively recover zinc from gossan ores studied in this paper because of iron dissolving greatly.

Investigation on the Beneficiation of Low-Grade Manganese Ore in Sichuan

2011 ◽  
Vol 402 ◽  
pp. 518-522 ◽  
Author(s):  
Xiao Mu ◽  
Jian Hua Chen ◽  
Xing Yu Yin
Keyword(s):  
Magnetic Separation ◽  
Sulphuric Acid ◽  
Low Grade ◽  
Manganese Ore ◽  
Optimum Conditions ◽  
Solid Ratio ◽  
Leaching Experiments

Flotation, magnetic separation and leaching experiments have been carried out for the beneficiation of low-grade manganese ore. The results indicated that flotation and magnetic separation could improve the grade of Mn concentrate while the recovery was lower. Better recovery of Mn could be achieved by leaching on optimum conditions, 91.78% of Mn could be recovered by 30 minutes leaching with 25g of sulphuric acid at the liquid/solid ratio of 3:1.

scholarly journals Extraction of REEs (Ce, Tb, Y, Eu) from Phosphors Waste by a Combined Alkali Roasting–Acid Leaching Process

Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 437
Author(s):  
Bing-Xuan He ◽  
Yong Liang ◽  
Lue-Wei Xu ◽  
Long-Bin Shao ◽  
De-Gang Liu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Oxygen Concentration ◽  
Acid Leaching ◽  
Solution Concentration ◽  
Mass Ratio ◽  
Optimum Conditions ◽  
Solid Ratio ◽  
Roasting Temperature ◽  
Leaching Efficiency ◽  
Hcl Solution

Rare Earth (RE) phosphors waste contains valuable rare Earth elements (REEs), such as cerium, terbium, yttrium, and europium. In industry, the process of NaOH roasting followed by acid leaching is usually used to extract the REEs from the waste in China. Using this process, the leaching efficiencies of cerium and terbium are clearly lower than those of other REEs, which results in uneven extraction of REEs in the waste and low total REE leaching efficiency. The key reason is that the trivalent cerium and terbium in the waste are oxidized into RE oxides during NaOH roasting, which are difficult to dissolve in acid solution. To solve this problem, an optimized process of controlling the oxygen concentration during NaOH roasting is proposed in this paper. The influences of the oxygen concentration, roasting temperature, roasting time, mass ratio of waste phosphor to NaOH, HCl solution concentration, acid leaching temperature, acid leaching time, and liquid–solid ratio on the REE leaching efficiency were investigated. Under the optimum conditions, the leaching efficiencies of cerium and terbium increased dramatically and the total REE leaching efficiency is 99.11%.

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