scholarly journals Nonlinear Heat Transport in Superlattices with Mobile Defects

Entropy ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1200 ◽  
Author(s):  
David Jou ◽  
Liliana Restuccia

We consider heat conduction in a superlattice with mobile defects, which reduce the thermal conductivity of the material. If the defects may be dragged by the heat flux, and if they are stopped at the interfaces of the superlattice, it is seen that the effective thermal resistance of the layers will depend on the heat flux. Thus, the concentration dependence of the transport coefficients plus the mobility of the defects lead to a strongly nonlinear behavior of heat transport, which may be used in some cases as a basis for thermal transistors.

1993 ◽  
Vol 115 (1) ◽  
pp. 7-16 ◽  
Author(s):  
A. Majumdar

Heat conduction in dielectric thin films is a critical issue in the design of electronic devices and packages. Depending on the material properties, there exists a range of film thickness where the Fourier law, used for macroscale heat conduction, cannot be applied. This paper shows that in this microscale regime, heat transport by lattice vibrations or phonons can be analyzed as a radiative transfer problem. Based on Boltzmann transport theory, an equation of phonon radiative transfer (EPRT) is developed. In the acoustically thick limit, ξL ≫ 1, or the macroscale regime, where the film thickness is much larger than the phonon-scattering mean free path, the EPRT reduces to the Fourier law. In the acoustically thin limit, ξL ≪ 1, the EPRT yields the blackbody radiation law q = σ (T14 − T24) at temperatures below the Debye temperature, where q is the heat flux and T1 and T2 are temperatures at the film boundaries. For transient heat conduction, the EPRT suggests that a heat pulse is transported as a wave, which becomes attenuated in the film due to phonon scattering. It is also shown that the hyperbolic heat equation can be derived from the EPRT only in the acoustically thick limit. The EPRT is then used to study heat transport in diamond thin films in wide range of acoustical thicknesses spanning the thin and the thick regimes. The heat flux follows the relation q = 4σT3ΔT/(3ξL/4 + 1) as derived in the modified diffusion approximation for photon radiative transfer. The thermal conductivity, as currently predicted by kinetic theory, causes the Fourier law to overpredict the heat flux by 33 percent when ξL ≪ 1, by 133 percent when ξL = 1, and by about 10 percent when ξL increases to 10. To use the Fourier law in both ballistic and diffusive transport regimes, a simple expression for an effective thermal conductivity is developed.


2021 ◽  
Author(s):  
Xiao-jian Wang ◽  
Liang-Bi Wang

Abstract The most common non-granular fillers are sheet and fiber. When they are distributed along the heat flux direction, the thermal conductivity of composite increases greatly. Meanwhile, the filler contact also has large effect on the thermal conductivity. However, the effect of filler contact on the thermal conductivity of composite with directional fillers has not been investigated. In this paper, the combined effects of filler contact, content and orientation are investigated. The results show that the effect of filler orientation on the thermal conductivity is greater than filler contact in low filler content, and exact opposite in high filler content. The effect of filler contact on fibrous and sheet fillers is far greater than cube and sphere fillers. This rule is affected by the filler contact. The filler content of 8% is the ideal percolation threshold of composite with fibrous and sheet filler. It is lower than cube filler and previous reports. The space for thermal conductivity growth of composite with directional filler is still very large. The effect of interfacial thermal resistance should be considered in predicting the thermal conductivity of composite under high Rc (>10-4).


Author(s):  
Gang Zhang ◽  
Nuo Yang ◽  
Gang Wu ◽  
Baowen Li

In this paper, we report the recent developments in the study of heat transport in nano materials. First of all, we show that phonon transports in nanotube super-diffusively which leads to a length dependence thermal conductivity, thus breaks down the Fourier law. Then we discuss how the introduction of isotope doping can reduce the thermal conductivity efficiently. The theoretical results are in good agreement with experimental ones. Finally, we will demonstrate that nanoscale structures are promising candidates for heat rectification.


2011 ◽  
Vol 483 ◽  
pp. 750-754
Author(s):  
Ya Dong Liu ◽  
Ke Dong Bi ◽  
Yun Fei Chen ◽  
Min Hua Chen

Nonequilibrium molecular dynamics (NEMD) approach is developed to investigate the thermal transport across a solid-solid interface between two different materials with an interlayer around it. The effects of system size and the interlayer material’s properties on the interface thermal resistance are considered in our model. The NEMD simulations show that the addition of an interlayer between two highly dissimilar lattices depresses the interface thermal resistance effectively. Meanwhile, the effective thermal conductivity along the direction of heat flux is enhanced with the increasing system temperature. Moreover, the interface thermal resistance after including an interlayer does not depend strongly on the simulation system size.


Author(s):  
Xingang Liang ◽  
Bao Yue

Heat conduction rectifier is attracting more attention due to its potential application to process thermal currents independently and convert them into electronic signals. This work reports an investigation by molecular dynamics simulation on the heat conduction rectification effect in the nanostructure whose cross-section have step change along the heat flux. It is found that thermal resistance is different with reversed heat flux direction, which is called the heat conduction rectification. The heat conduction rectification depends on the temperature difference. By reducing temperature difference across the nanostructure, the rectification could be reversed. When the temperature difference is small enough, the thermal resistance is larger when the heat flux flows from the thick part to the thin part when the length of the structure is about 10 nm. The larger variation in the cross-section leads the larger difference in the thermal resistance with opposite heat flux. The mechanism of the rectification is discussed. If we take phonons as liquid particles and consider the case of a liquid flowing through a channel with step expansion in cross-section, the flow resistance is less with liquid flowing from the narrow part to the wide part than that in the case with contrary flow direction. In fact, the scattering of phonons at the step face reduces the mean free path of phonon when heat flux conducts from the narrow end to the wide end.


2013 ◽  
Vol 209 ◽  
pp. 129-132 ◽  
Author(s):  
Shreya Shah ◽  
Tejal N. Shah ◽  
P.N. Gajjar

The temperature profile, heat flux and thermal conductivity are investigated for the chain length of 67 one-dimensional (1-D) oscillators. FPU-β and FK models are used for interparticle interactions and substrate interactions, respectively. As harmonic chain does not produce temperature gradient along the chain, it is required to introduce anharmonicity in the numerical simulation. The anharmonicity dependent temperature profile, thermal conductivity and heat flux are simulated for different strength of anharmonicity β = 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1. It is concluded that heat flux obeys J = 0.3947 e0.553β with R2 = 0.9319 and thermal conductivity obeys κ = 0.0276 e0.5559β with R2 = 0.9319.


1989 ◽  
Vol 169 ◽  
Author(s):  
D.T. Morelli ◽  
G.L. Doll ◽  
J.P. Heremans ◽  
H.P. Jenssen ◽  
A. Cassanho ◽  
...  

AbstractThe thermal conductivities of superconducting, Sr-doped lanthanum copper oxide single crystals have been measured from room temperature to below 100 mK parallel and perpendicular to the copper oxide planes. While the results indicate that the heat conduction is strongly anisotropic, the data have been analyzed in terms of a modified Bardeen-Rickhayzen-Tewordt theory of lattice thermal conductivity. It is shown that while electron scattering plays an important role in limiting the in-plane heat conductivity, this scattering channel is masked by other mechanisms for heat transport across the planes.


1985 ◽  
Vol 6 ◽  
pp. 168-170 ◽  
Author(s):  
T. Kuroda

We have derived an analytical expression for the growth rate of sea ice by taking account of the processes relevant to the growth, eg heat conduction, diffusion of salt molecules, radiation, sensible heat transport, evaporation and so on. We discuss the role of each process as rate determining processes under various environmental conditions. It is shown that because of coupling of salt diffusion and heat conduction, the growth rate feeds back to the heat flux Qw from water to ice which controls the growth rate and that Qw decreases with the thickness I of sea ice, even if the environmental conditions are kept constant.


2012 ◽  
Vol 134 (5) ◽  
Author(s):  
Hai-Dong Wang ◽  
Bing-Yang Cao ◽  
Zeng-Yuan Guo

Fourier’s law is a phenomenological law to describe the heat transfer process. Although it has been widely used in a variety of engineering application areas, it is still questionable to reveal the physical essence of heat transfer. In order to describe the heat transfer phenomena universally, Guo has developed a general heat conduction law based on the concept of thermomass, which is defined as the equivalent mass of phonon gas in dielectrics according to Einstein’s mass–energy relation. The general law degenerates into Fourier’s law when the thermal inertia is neglected as the heat flux is not very high. The heat flux in carbon nanotubes (CNTs) may be as high as 1012 W/m2. In this case, Fourier’s law no longer holds. However, what is estimated through the ratio of the heat flux to the temperature gradient by molecular dynamics (MD) simulations or experiments is only the apparent thermal conductivity (ATC); which is smaller than the intrinsic thermal conductivity (ITC). The existing experimental data of single-walled CNTs under the high-bias current flows are applied to study the non-Fourier heat conduction under the ultrahigh heat flux conditions. The results show that ITC and ATC are almost equal under the low heat flux conditions when the thermal inertia is negligible, while the difference between ITC and ATC becomes more notable as the heat flux increases or the temperature drops.


Author(s):  
Bing-Yang Cao ◽  
Quan-Wen Hou

Carbon nanotubes (CNTs) have attracted much attention in nanotechnology fields because of their unique thermal properties. The thermal conductivity of CNTs was reported to be as high as several thousand W/mK. The heat flux in CNTs can reach 109−1012 W/m2 under normal heat conduction conditions. In this paper we demonstrate that Fourier’s heat conduction law breaks down for so high heat flux. Based on a novel concept of thermomanss, which is defined as the equivalent mass of thermal energy according to Einstein’s mass-energy relation, heat conduction in CNTs can be regarded as the flow of a phonon gas governed by its mass and momentum conservation equations like in fluid mechanics. The momentum conservation equation, including driving force, inertial force and resistance terms, reduces to Fourier’s law as the heat flux is not very high and the inertial force of phonon gas is negligible with respect to the driving force. However, Fourier’s law of heat conduction no longer holds if the heat flux is very high such that the inertial force of the phonon gas is not negligible. The heat conduction behavior deviates from Fourier’s law even for steady state conditions so that the heat conduction is characterized by a non-linear relationship between the heat flux and the temperature gradient. In this case, the thermal conductivity of the CNTs can no longer be defined as the ratio of the heat flux to the temperature gradient in experiments or numerical computations. Furthermore, the ratio of the phonon gas velocity to the thermal sound speed can be defined as the thermal Mach number. Heat flow in CNTs will be choked, just like gas flows in a converging nozzle, and a temperature jump will be observed when the thermal Mach number equals or exceeds unity. In this case, the predicted temperature profile of the CNTs based on Fourier’s law is much lower than that based on the thermomass theory considering a CNT electrically heated by high-bias current flows. The intrinsic thermal conductivity can be only calculated by the present thermomass theory, rather than Fourier’s heat conduction law. The present study shows that the thermomass based theory should be applied for high flux heat conduction in CNTs where Fourier’s heat conduction law breaks down.


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