scholarly journals Entropic Balance Conditions and Optimization of Distillation Column System

Entropy ◽  
2021 ◽  
Vol 23 (11) ◽  
pp. 1468
Author(s):  
Alexander Balunov ◽  
Ivan Sukin ◽  
Anatoly Tsirlin

The paper considers the limitation problem of the distillation column systems separating multicomponent mixtures with serial and parallel structures. The solution takes into account the irreversibility of processes. Using entropic balance conditions, the dependence of load on heat consumption is obtained for a binary distillation column. This dependence is parameterized through two characteristic coefficients–reversible efficiency and irreversibility factor. This dependence was used to solve problems of distribution of heat and raw material fluxes in parallel column structure and selection of optimal separation order in serial structure. The obtained results make it possible to estimate the minimum heat consumption for the separation of a given flow of raw materials, the maximum productivity, and efficiency of the system.

2021 ◽  
Vol 1 (2) ◽  
Author(s):  
Aula Fajar Iman Sakti ◽  
Wiwik Sulistiyowati

CV. Riki Utama Mandiri is a company in distributing an economic fish frozen product. This company distributed any kind of retail and wholesaler, both domestic and export. They distributing many frozen fish products variant such as Patin Fillet and Shark Fin. The all raw materials of those frozen seafood was obtained by three different suppliers. The common problems found in CV. Riki Utama Mandiri mostly about raw patin fish supplier which often committed delivery delays.  The purpose of this research is to fixing the supply chain management in deciding the more accurate selections of raw materials supplier. To overcome the common problems that happen. Analytical network process (ANP) will simplify the criteria weight values and sub criteria of each supplier. Meanwhile, technique for others reference by similarity to ideal solution (TOPSIS) method is used for giving a rank order of the alternative supplier. This research is expected for being a consideration for the company in obtaining a good and more effective kind of raw supplier. We also expecting the company for tighten supplier selection more effective way so that it can fullfilled the existing standard. Also to overcome the common problems such as delivery delays, competing raw materials with uncertain quality, and difficulty in sort out the raw materials due to size issues.


Author(s):  
Anatoly Tsirlin ◽  
Ivan Andreevich Sukin ◽  
Alexander Balunov ◽  
Karsten Schwalbe

AbstractIn this paper an estimate for the reversible molar heat supply needed for fully separating a certain mixture is given on the basis of thermodynamic balance equations. It is shown that in order to estimate this heat supply one should solve the problem of selecting the optimal separation sequence. The algorithm solving this task is given. This algorithm allows to select the separation sequence on the basis of preliminary calculations, knowing only the properties of the component that one wants to separate. The solution algorithm is demonstrated for an exemplary system: a gas-fractionation plant.


Author(s):  
Magdalena Śmiglak-Krajewska

The main purpose of this paper was to identify the factors affecting the selection of raw materials used by feed operators in feed production. An attempt was also made to indicate the barriers to increasing the use of native protein plants by feed operators in feed production. Today, many EU countries (including Poland) primarily rely on vegetable protein derived from genetically modified soya bean meal (mainly imported from South America and the U.S.) in addressing their needs for protein raw material used in animal feed. For many years now, Poland has taken steps to increase the production and use of native protein raw material to partially replace soya bean meal imports. The use of mixes of diverse domestic protein sources derived from grain legumes (peas, field beans, lupine) can provide an advantageous alternative to compound feeding stuff based on imported post-extraction soya bean meal. To meet the objective defined above, this paper relied on the results of a 2018 survey conducted with a sample of 29 feed operators located across the country. More than half (55%) of the enterprises surveyed did not use legumes in feed production; the use of legumes was above 10% in only 3% of respondents. When asked about the key factors affecting the selection of raw materials used in production processes, the respondents declared to be interested in buying large batches of homogeneous raw materials that meet specific quality parameters (33% replied “rather yes” and 67% replied “definitely yes”). The protein content of plant seeds used in feed production was identified as another aspect of extreme importance (55% replied “rather yes” and 24% replied “definitely yes”).


2002 ◽  
Vol 49 (12) ◽  
pp. 801-807
Author(s):  
Yuzoh Asano ◽  
Yuriko Iiyama ◽  
Tetsuo Kubota ◽  
Keiji Iwatsuki ◽  
Kazuyoshi Sotoyama

2020 ◽  
pp. 249-260
Author(s):  
Lyudmila Ivanovna Tikhomirova ◽  
Natal'ya Grigor'yevna Bazarnova ◽  
Aleksandr Aleksandrovich Bondarev ◽  
Yaroslava Viktorovna Ponomareva ◽  
Steniya Olegovna Mironova

For optimal accumulation of biomass and phenolic compounds (flavonoids, tannins, xanthones, hydroxycinnamic acids) from Iris sibirica and Iris spuria in tissue culture, it is desirable to use a medium containing 1.0 to 2.5 µm BAP. The high content of cytokinin caused a stressful situation, at the first stage of which there was a mass formation of adventitious and axillary shoots, then with an increase in the concentration of the hormone, the reproduction coefficient decreased, the plants stopped reproducing, stopped growing and died. In extreme conditions, phenolic compounds are spent on the performance of protective functions, in connection with which there was a drop in their overall level in the tissues of irises. For biotechnological raw materials of Iris L. representatives, the efficiency of subcritical sequential extraction was compared with traditional methods (in Soxlet type apparatus). In subcritical conditions have been removed more flavonoids and tannins: in fraction 96% ethanol of flavonoids and tannins – in 2 times; at a fraction of 60% ethanol flavonoids – 2 times, tanning – 3 times; at a fraction of the water of flavonoids in 3 times, tanning – 1.4 times. The water in the apparatus of soxlet extracted 1.3 times more hydroxycinnamic acids than in subcritical conditions. The ratio of condensed and hydrolyzable tannins tannins in aeroponic raw material of Iris sibirica L. varieties Sterkh traditional extraction was determined as 13 : 1, the extraction in subcritical conditions 8 : 1.


2020 ◽  
Vol 30 (2) ◽  
pp. 135-146
Author(s):  
Mery Budiarti ◽  
Anshary Maruzy ◽  
Nengah Ratri RK ◽  
Endang Brotojoyo

Abstract The use of gempol (Nauclea orientalis (L.) L) stem as a malaria medicine has been empirically and scientifically proven. This condition encourages exploitation which can lead to scarcity of raw materials. Substitution of plant parts as raw material for medicine is one of the innovations that can be done for the sustainability of the plant species. Leaves are one part of the plant that is often used as a raw material for medicine. The selection of leaves as the main ingredient has many advantages over other parts. Until now, research related to the antimalarial bioactive potential of N. orientalis (L.) L leaves has not been published. Therefore, this study aimed to explore the potential for leaf antimalarial activity as an alternative to substitution of stem parts. The leaf extract of N. orientalis (L.) L was prepared by maceration method with 96% ethanol then fractionation was carried out in stage using hexane, ethyl acetate and methanol as solvents. Antimalarial activity testing was carried out in vitro against Plasmodium falciparum 3D7 and Thin Layer Chromatography (TLC) for screening phytochemical compounds in each sample. The hexane solvent was known to produce the most optimum extract by with a yield of 20%. The antimalarial activity of the hexane (IC 50 1.93 μg/mL) and methanol (IC 3.91 μg/ mL) fractions were classified as ‘very active’ and had a tendency to be able to compete with chloroquine phosphate activity. The potential for antimalarial activity in both samples was influenced by the content of alkaloids, steroids, flavonoids and terpenoids which had been developed as active ingredients for malaria drugs. The results of this study indicate that the leaves of Nauclea orientalis (L.) L have the potential to be developed as an alternative to malaria medicine. Abstrak Pemanfaatan batang gempol (Nauclea orientalis (L.) L) sebagai obat malaria telah terbukti secara empiris dan ilmiah. Kondisi tersebut mendorong terjadinya eksploitasi hingga dapat berujung pada kelangkaan bahan baku. Substitusi bagian tumbuhan sebagai bahan baku obat merupakan salah satu inovasi yang dapat dilakukan untuk keberlanjutan hidup spesies tumbuhan tersebut. Daun merupakan salah satu bagian tumbuhan yang sering digunakan sebagai bahan baku obat. Pemilihan daun sebagai bahan utama memiliki banyak kelebihan dibandingkan bagian lainnya. Penelitian terkait potensi bioaktif antimalaria daun Nauclea orientalis (L.) L hingga saat ini belum dipublikasikan. Oleh karena itu, penelitian ini bertujuan untuk menggali potensi aktivitas antimalaria daun sebagai alternatif subtitusi bagian batang. Ekstrak daun Nauclea orientalis (L.) L disiapkan dengan metode maserasi dengan etanol 96%, kemudian dilakukan fraksinasi cair-cair bertingkat menggunakan pelarut heksana, etil asetat, dan metanol. Pengujian aktivitas antimalaria dilakukan secara in vitro terhadap Plasmodium falciparum 3D7 dan Kromatografi Lapis Tipis (KLT) untuk penapisan senyawa fitokimia pada masingmasing sampel. Pelarut heksana diketahui menghasilkan ekstrak paling optimum dengan rendemen 20%. Aktivitas antimalaria fraksi heksana (IC 50 1,93 µg/mL) dan metanol (IC 3,91 µg/mL) yang tergolong dalam kategori ‘sangat aktif, serta memiliki kecenderungan mampu bersaing dengan aktivitas klorokuin fosfat. Potensi aktivitas antimalaria pada kedua sampel tersebut dipengaruhi oleh kandungan senyawa alkaloid, steroid, flavonoid dan terpenoid yang telah banyak dikembangkan sebagai bahan aktif obat malaria. Hasil penelitian ini menunjukkan bahwa daun Nauclea orientalis (L.) L berpotensi untuk dikembangkan sebagai alternatif obat malaria.


2020 ◽  
Vol 24 (10) ◽  
pp. 13-19
Author(s):  
Ya.I. Vaisman ◽  
I.S. Glushankova ◽  
L.V. Rudakova ◽  
A.A. Surkov ◽  
A.S. Atanova

The results of studies on the thermal processing of synthetic multi-tonnage polymeric waste (polypropylene, polycarbonate, textolite, PET, organoplastics and tire rubber) with the production of carbon sorbents for technological and environmental purposes are presented. The influence of the nature of the activating agent and the conditions of the process with the production of sorbents with predetermined properties was studied. Analysis of the research results allowed us to establish that the main factors affecting the yield of carbonizate and the formation of a porous structure of carbon sorbents from synthetic polymer waste are the degree of aromaticity and the location of benzene rings in the polymer structure, the proportion of oxygen in the precursor. The criteria for selecting synthetic polymer wastes as raw materials for obtaining carbon sorbents with predetermined properties are established. The results of the research can be used in the development of technologies for obtaining carbon sorbents with predetermined properties from waste synthetic polymers and the selection of technological parameters for processes.


2015 ◽  
Vol 1128 ◽  
pp. 224-229 ◽  
Author(s):  
Emilia Florina Binchiciu ◽  
Traian Fleşer ◽  
Ionelia Voiculescu ◽  
Aurelia Binchiciu

The paper presents research made in order to assure additional conditions, compared to those in the general standard, to brazing rods, in order to guarantee safety for the environment and for the brazed joints, against corrosion and embrittlement, in high risk conditions. Environmental safety is ensured by limiting the amount, at 0.25% in depositions, of dangerous residual elements at: Cd<0.1%; Hg<0.1%; Pb<0.1%; Cr<0.1%; As<0.1%. The safety of structures against corrosion is provided by the alloying level of deposits and by neutralizing the coat’s activity. The structure safety towards the embrittlement of brazed joints is ensured by limiting the content of embrittling elements, namely: Sb+Fe+Bi at a maximum of 0.3% and the content of diffusible hydrogen at maximum 5 cm3/100g raw material and by limiting the coat humidity at maximum 10%. The experiments were performed to ensure the set out requirements by following the selection of raw materials on the input criteria of prohibited chemicals, reducing the water content from the elements that make up the coat and by diminishing it’s hygroscopicity by neutralizing it. Prescribing additional conditions has an effect on manufacturing costs, which requires productivity increase at brazing, diminishing work temperature, increasing the moistening capacity of products, reducing the smoke level, effects pursued by the research.


2015 ◽  
Vol 226 ◽  
pp. 111-114
Author(s):  
Grzegorz Kopeć ◽  
Roman Przeliorz

The selection of quartzites most suitable for the production of ferrosilicon is realized by way of time-consuming industrial trials or laboratorial studies of, among others, the ability of the silica contained in quartzite to form silicon carbide with a selected reducer. Under industrial conditions, the basic criterion for the evaluation of the suitability of a raw material for the production of ferrosilicon are the technical and economic indicators of the process. Under laboratorial conditions, simple and reliable research methods are searched for, which would allow to determine the usefulness of quartzite in the process of carbon silica reduction. The article discusses comparative thermogravimetric studies as well as alternative investigations of the specific heat of three selected quartzites which fulfill the chemical composition criterion, used in the mixed charge as raw materials for ferrosilicon FeSi75 smelting.


2021 ◽  
Vol 447 (3) ◽  
pp. 94-98
Author(s):  
A. Tyan ◽  
M.M. Bayazitova

In recent years, according to the sharp increase in the number of breweries and high competition on the consumer market, it is very important to extend the raw material base of the industry and the range of produced beer from the recommended raw materials. One of the ways to expand the raw material base of breweries is developing recommendations for the use of new zoned varieties of barley, in particular as well as the use of special malts, wheat malt, the development of new recipes and technologies for beer producing. As it is known, barley, wheat, rye, and malt produced from these cereal crops are processed to a greater extent at present. Along with traditional types of cereals, such cereals as amaranth, buckwheat, triticale, sorghum, oats, etc. are used. Among the listed alternative crops, wheat should be noted as the most promising type of cereal raw materials. Wheat (Triticum) is an herbaceous annual plant of the cereal family. Hard wheat (T. durum) and soft wheat (T. aestivum) are the most important. Both species are holo-grain, i.e., the grain is covered with fruiting and seed shells, fused and consisting of several layers of cells, and do not have flower (chaff) shells. At present time, high-yielding winter and spring wheat (T.aestivum) is mainly cultivated. This species has loose floury grains and rather low protein content. It should be noted that unmalted wheat is rarely used in brewing. This is because that the use of this cereal as unmalted material leads to significant deviations in the technological process, in particular, the filtration of wort and beer slows down, reduces the colloidal stability of the final product. At the same time, as a raw material for malt, wheat has some advantages over barley. The article deals with the effect of different amounts of wheat malt on the mashing process, the percentage of mashing and mashing modes of barley and wheat malt are selected experimentally.


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