scholarly journals Comprehensive Fractal Model and Pore Structural Features of Medium- and Low-Rank Coal from the Zhunnan Coalfield of Xinjiang, China

Energies ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 7
Author(s):  
Haifei Lin ◽  
Yang Bai ◽  
Jingting Bu ◽  
Shugang Li ◽  
Min Yan ◽  
...  

Medium and low-rank coal from the Zhunnan coalfield of Xinjiang in China was investigated for quantitatively characterizing its range of aperture structure. The pore parameters were determined by nitrogen adsorption at low temperature and mercury injection at high pressure, and the full aperture was determined. The FHH model, Menger model, Sierpinski model, and a thermodynamic model were used to calculate the comprehensive fractal dimension of the coal samples over the full range of aperture. The fractal characteristics of the pores of medium- and low-rank coal were quantitatively analyzed, which provided a reference for the overall characterization of pore structure heterogeneity in this coalfield. The results show that the FHH model and thermodynamic model more accurately calculate the fractal dimensions of less and greater than the joint pore position, respectively. The comprehensive fractal dimension of the low-rank coal pore is 2.8005–2.8811 and that of medium rank coal is 2.5710–2.6147. When compared with the medium-rank coal, pores of the low-rank coal are more developed and they exhibit a more complex structure with stronger heterogeneity. The comprehensive fractal dimension of the pores is a negative correlation with average pore size, vitrinite content, and maximum vitrinite reflectance, and positive correlation with pore volume, pore specific surface area, inertinite content, and exinite content.

Fractals ◽  
2019 ◽  
Vol 27 (01) ◽  
pp. 1940006 ◽  
Author(s):  
LEI ZHANG ◽  
XUEJUAN ZHANG ◽  
HAO CHAI ◽  
YAOCAI LI ◽  
YONGJIE ZHOU

Fractal dimension is an important parameter in the evaluation of tight reservoirs. For an outcrop section of the Nenjiang formation in the Songliao Basin, China, the pore structure and pore fractal characteristics of shale parasequences were investigated using fractal theory. In addition, factors causing pore structure changes were analyzed using the results of low-temperature nitrogen adsorption and scanning electron microscope (SEM) experiments. Conducive to gas migration and secondary pores development such as dissolution, results showed that nanoscale pores dominated by fracture-like morphology and consequent good internal connectivity were observed in each pore size section within the target layer. Each parasequence is characterized by a sequential upward decrease of average pore size and an upward increase of total pore volume, with an increasing number of pores from 2[Formula: see text]nm to 50[Formula: see text]nm. Pores are isolated from each other, with poor connectivity and relatively complex composition of brittle minerals and clay minerals. Main components of the brittle minerals, quartz and feldspar, occur in 20–50% and higher clay mineral content ranging from 50% to 70%. In the parasequence cycle, clay mineral gradually decreases while the brittle mineral content increases. Fractal dimension is negatively correlated with clay mineral content and positively correlated with brittle mineral (quartz and feldspar) content. The fractal dimension calculated by the imaging method and the FHH method shows an upward increasing tendency in each of the parasequence cycles. This is as a result of different phenomena, varied sediment hydrodynamic forces leading to particle size differences and increased brittle minerals resulting in microcracks, therefore, the fractal dimension of the large pores (imaging method) increases upward in the parasequence. Simultaneously, with increased content and accompanied dissolution of brittle minerals causing an increase of small pores from base to top of the parasequence, the fractal dimension of the small pores (FHH method) grows.


2018 ◽  
Vol 2018 ◽  
pp. 1-11
Author(s):  
Xuyang Shi ◽  
Wei Zhou ◽  
Qingxiang Cai ◽  
Xiang Lu

Seepage mutation of fractured rock mass is one of the main inducements of dump slide and other disasters. Pore structure is a significant factor affecting the seepage characteristics of fractured rock mass, while particle size gradation has an important effect on the distribution of pore structure. Through the self-developed experimental system, the nonlinear seepage test on the fractured sandstones of the coalseam roof was conducted to investigate the influence of seepage pressure, porosity, and fractal dimension. Besides, the nonlinear seepage model was established by Barree–Conway theory. The results showed that, during the seepage process of fractured sandstone, there were significant nonlinear characteristics, which increased with the increase of the seepage pressure. With the increasing porosity, there was greater average pore size of fractured sandstone, stronger permeability, and weaker nonlinear seepage. The seepage characteristics approximated to that of Darcy model. However, with increasing grading fractal dimension, there were smaller average pore size of fractured sandstone, weaker permeability, and stronger nonlinear seepage. The seepage characteristics approximated to that of Forchheimer model.


2020 ◽  
Vol 58 (2) ◽  
pp. 103-111
Author(s):  
Kyu-Sik Kim ◽  
Min-Chul Shim ◽  
Man-Ho Park ◽  
Jung-Yeul Yun ◽  
Kee-Ahn Lee

A block Ni-Cr-Al superalloy foam with dimensions of 300 mm (width direction, WD) × 500 mm (rolling direction, RD) × 60 mm (normal direction, ND) was fabricated using powder alloying, multi-sheet stacking, and hot rolling processes. The structural characteristics, microstructure, and mechanical asymmetry of the block Ni-based foam were investigated. Analysis of the structural features showed that the interfaces between the sheets had complex strut interactions, such as contacted (deformed) and intersected struts. The average pore size along the directions was measured to be 2569.6 μm (WD), 2988.1 μm (RD), and 2493.2 μm (ND). The average thickness of the strut was 340.8 μm, and the wall thickness of the strut was 27.7 μm. The elemental distributions in the struts were uniformly controlled, and the block foam consisted of γ (matrix) and γ ' (Ni<sub>3</sub>Al) phases. Tensile properties in the ND direction showed a yield strength of 0.175 MPa, tensile strength of 0.233 MPa, and elongation of 2.54%, while the tensile properties in the RD direction were 1.27 MPa (YS), 3.01 MPa (UTS), 8.92% (El.) respectively. The foam was observed to have a compressive yield strength of 0.795 MPa in the ND direction, and that of 2.18 MPa in the RD direction were obtained. The asymmetry and anisotropy of these mechanical properties could be explained by the difference in pore sizes along the direction, and the structural characteristics of the sheet interface generated by sheet stacking and rolling.


2014 ◽  
Vol 59 (2) ◽  
pp. 509-516
Author(s):  
Andrzej Olajossy

Abstract Methane sorption capacity is of significance in the issues of coalbed methane (CBM) and depends on various parameters, including mainly, on rank of coal and the maceral content in coals. However, in some of the World coals basins the influences of those parameters on methane sorption capacity is various and sometimes complicated. Usually the rank of coal is expressed by its vitrinite reflectance Ro. Moreover, in coals for which there is a high correlation between vitrinite reflectance and volatile matter Vdaf the rank of coal may also be represented by Vdaf. The influence of the rank of coal on methane sorption capacity for Polish coals is not well understood, hence the examination in the presented paper was undertaken. For the purpose of analysis there were chosen fourteen samples of hard coal originating from the Upper Silesian Basin and Lower Silesian Basin. The scope of the sorption capacity is: 15-42 cm3/g and the scope of vitrinite reflectance: 0,6-2,2%. Majority of those coals were of low rank, high volatile matter (HV), some were of middle rank, middle volatile matter (MV) and among them there was a small number of high rank, low volatile matter (LV) coals. The analysis was conducted on the basis of available from the literature results of research of petrographic composition and methane sorption isotherms. Some of those samples were in the form (shape) of grains and others - as cut out plates of coal. The high pressure isotherms previously obtained in the cited studies were analyzed here for the purpose of establishing their sorption capacity on the basis of Langmuire equation. As a result of this paper, it turned out that for low rank, HV coals the Langmuire volume VL slightly decreases with the increase of rank, reaching its minimum for the middle rank (MV) coal and then increases with the rise of the rank (LV). From the graphic illustrations presented with respect to this relation follows the similarity to the Indian coals and partially to the Australian coals.


2017 ◽  
Vol 54 (3) ◽  
pp. 181-201
Author(s):  
Rebecca Johnson ◽  
Mark Longman ◽  
Brian Ruskin

The Three Forks Formation, which is about 230 ft thick along the southern Nesson Anticline (McKenzie County, ND), has four “benches” with distinct petrographic and petrophysical characteristics that impact reservoir quality. These relatively clean benches are separated by slightly more illitic (higher gamma-ray) intervals that range in thickness from 10 to 20 ft. Here we compare pore sizes observed in scanning electron microscope (SEM) images of the benches to the total porosity calculated from binned precession decay times from a suite of 13 nuclear magnetic resonance (NMR) logs in the study area as well as the logarithmic mean of the relaxation decay time (T2 Log Mean) from these NMR logs. The results show that the NMR log is a valid tool for quantifying pore sizes and pore size distributions in the Three Forks Formation and that the T2 Log Mean can be correlated to a range of pore sizes within each bench of the Three Forks Formation. The first (shallowest) bench of the Three Forks is about 35 ft thick and consists of tan to green silty and shaly laminated dolomite mudstones. It has good reservoir characteristics in part because it was affected by organic acids and received the highest oil charge from the overlying lower Bakken black shale source rocks. The 13 NMR logs from the study area show that it has an average of 7.5% total porosity (compared to 8% measured core porosity), and ranges from 5% to 10%. SEM study shows that both intercrystalline pores and secondary moldic pores formed by selective partial dissolution of some grains are present. The intercrystalline pores are typically triangular and occur between euhedral dolomite rhombs that range in size from 10 to 20 microns. The dolomite crystals have distinct iron-rich (ferroan) rims. Many of the intercrystalline pores are partly filled with fibrous authigenic illite, but overall pore size typically ranges from 1 to 5 microns. As expected, the first bench has the highest oil saturations in the Three Forks Formation, averaging 50% with a range from 30% to 70%. The second bench is also about 35 ft thick and consists of silty and shaly dolomite mudstones and rip-up clast breccias with euhedral dolomite crystals that range in size from 10 to 25 microns. Its color is quite variable, ranging from green to tan to red. The reservoir quality of the second bench data set appears to change based on proximity to the Nesson anticline. In the wells off the southeast flank of the Nesson anticline, the water saturation averages 75%, ranging from 64% to 91%. On the crest of the Nesson anticline, the water saturation averages 55%, ranging from 40% to 70%. NMR porosity is consistent across the entire area of interest - averaging 7.3% and ranging from 5% to 9%. Porosity observed from samples collected on the southeast flank of the Nesson Anticline is mainly as intercrystalline pores that have been extensively filled with chlorite clay platelets. In the water saturated southeastern Nesson Anticline, this bench contains few or no secondary pores and the iron-rich rims on the dolomite crystals are less developed than those in the first bench. The chlorite platelets in the intercrystalline pores reduce average pore size to 500 to 800 nanometers. The third bench is about 55 ft thick and is the most calcareous of the Three Forks benches with 20 to 40% calcite and a proportionate reduction in dolomite content near its top. It is also quite silty and shaly with a distinct reddish color. Its dolomite crystals are 20 to 50 microns in size and partly abraded and dissolved. Ferroan dolomite rims are absent. This interval averages 7.1% porosity and ranges from 5% to 9%, but the pores average just 200 nanometers in size and occur mainly as microinterparticle pores between illite flakes in intracrystalline pores in the dolomite crystals. This interval has little or no oil saturation on the southern Nesson Anticline. Unlike other porosity tools, the NMR tool is a lithology independent measurement. The alignment of hydrogen nuclei to the applied magnetic field and the subsequent return to incoherence are described by two decay time constants, longitudinal relaxation time (T1) and transverse relaxation time (T2). T2 is essentially the rate at which hydrogen nuclei lose alignment to the external magnetic field. The logarithmic mean of T2 (T2 Log Mean) has been correlated to pore-size distribution. In this study, we show that the assumption that T2 Log Mean can be used as a proxy for pore-size distribution changes is valid in the Three Forks Formation. While the NMR total porosity from T2 remains relatively consistent in the three benches of the Three Forks, there are significant changes in the T2 Log Mean from bench to bench. There is a positive correlation between changes in T2 Log Mean and average pore size measured on SEM samples. Study of a “type” well, QEP’s Ernie 7-2-11 BHD (Sec. 11, T149N, R95W, McKenzie County), shows that the 1- to 5-micron pores in the first bench have a T2 Log Mean relaxation time of 10.2 msec, whereas the 500- to 800-nanometer pores in the chlorite-filled intercrystalline pores in the second bench have a T2 Log Mean of 4.96 msec. This compares with a T2 Log Mean of 2.86 msec in 3rd bench where pores average just 200 nanometers in size. These data suggest that the NMR log is a useful tool for quantifying average pore size in the various benches of the Three Forks Formation.


2018 ◽  
Author(s):  
Jayeeta Chakraborty ◽  
◽  
Robert B. Finkelman ◽  
William H. Orem ◽  
Matthew S. Varonka ◽  
...  

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