scholarly journals Integrated Profiling of Fatty Acids, Sterols and Phenolic Compounds in Tree and Herbaceous Peony Seed Oils: Marker Screening for New Resources of Vegetable Oil

Foods ◽  
2020 ◽  
Vol 9 (6) ◽  
pp. 770
Author(s):  
Xiaoqin Wang ◽  
Chunhuan Li ◽  
María del Mar Contreras ◽  
Vito Verardo ◽  
Ana María Gómez-Caravaca ◽  
...  

Tree peonies (Paeonia ostii and Paeonia rockii) are popular ornamental plants. Moreover, these plants have become oil crops in recent years. However, there are limited compositional studies focused on fatty acids. Therefore, this work aims to reveal compositional characteristics, regarding fatty acids, sterols, γ-tocopherol and phenolic compounds, of tree peony seed oils from all major cultivation areas in China, and to compare with herbaceous peony seed oil. For that, an integrative analysis was performed by GC-FID, GC-MS and UHPLC-Q-TOF-MS technologies. The main fatty acid was α-linolenic acid (39.0–48.3%), while β-sitosterol (1802.5–2793.7 mg/kg) and fucosterol (682.2–1225.1 mg/kg) were the dominant phytosterols. Importantly, 34 phenolic compounds, including paeonol and “Paeonia glycosides” (36.62–103.17 μg/g), were characterized in vegetable oils for the first time. Conclusively, this work gives new insights into the phytochemical composition of peony seed oil and reveals the presence of bioactive compounds, including “Paeonia glycosides”.

2021 ◽  
Vol 4 (1) ◽  
pp. 52-67
Author(s):  
Banyaladzi Doctor Paphane ◽  
Bonang Nkoane ◽  
Olayinka Adebisi Oyetunji

Croton megalobotrys and Ricinus cummunis plants produce high-quality non-edible seed oils at relatively high quantities of 39.65 ± 0.06 % w/w to 53.74 ± 0.04 % w/w. The Iodine values of 85.97 ± 1.62 g I2/100 g to 96.51 ± 1.31 g I2/100 g; the low acid values of 0.96 ± 0.05 mg KOH/g to 5.31 ± 0.76 mg KOH/g; and high saponification values of 139.65 ± 1.06 mg KOH/g to 153.01 ± 1.67 mg KOH/g show that these seed oils can be useful feedstocks in the petroleum, soap, and cosmetics industries. GC-MS results revealed that R. cummunis seed oil is made up of eight (8) fatty acids with the bulk being ricinoleic acid at 81.51 %. Ricinoleic acid is the main fatty acid used in oleochemical industries. C. megalobotrys seed oil is made up of five (5) fatty acids, the most abundant being Linoleic acid which makes up 58.01 % of the seed oil. The other two significant fatty acids in C. megalobotrys seed oil are palmitic and oleic acids at 19.51 % and 18.37 %, respectively. These acids are important as starting materials in soap, cosmetic, and pharmaceutical industries. The fatty acids of the two seed oils absorb light at the ultraviolet region of the electromagnetic spectrum. This means that cosmetic products made from these seed oils will be effective in protecting the human skin against ultraviolet radiation. The FT-IR peaks for the two seed oils show that even though these seed oils are made up of different fatty acids, the active sites of their fatty acids are similar, implying that these seed oils can be used as starting materials in similar industries.


Plants ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1219
Author(s):  
Marek Bunse ◽  
Peter Lorenz ◽  
Florian C. Stintzing ◽  
Dietmar R. Kammerer

The present study aimed at the identification and quantitation of phenolic compounds, fatty acids, and further characteristic substances in the seeds of Geum urbanum L. and Geum rivale L. For this purpose, individual components of extracts recovered with MeOH, CH2Cl2, and by cold-pressing, respectively, were characterized by HPLC-DAD/ESI-MSn and GC/MS and compared with reference compounds. For both Geum species, phenolic compounds, such as flavonoids and gallic acid derivatives, and triterpenes, such as saponins and their aglycones, were detected. Surprisingly, both Geum species revealed the presence of derivatives of the triterpenoid aglycons asiatic acid and madecassic acid, which were characterized for the first time in the genus Geum. Furthermore, the fatty acids of both species were characterized by GC–MS after derivatization. Both species showed a promising fatty-acid profile in terms of nutritional properties because of high proportions of unsaturated fatty acids. Linoleic acid and linolenic acid were most abundant, among other compounds such as palmitic acid and stearic acid. In summary, the present study demonstrates the seeds of G. urbanum and G. rivale to be a valuable source of unsaturated fatty acids and bioactive phenolics, which might be exploited for nutritional and cosmetic products and for phytotherapeutic purposes.


OCL ◽  
2020 ◽  
Vol 27 ◽  
pp. 13
Author(s):  
Ihssane Ouassor ◽  
Younes Aqil ◽  
Walid Belmaghraoui ◽  
Souad El Hajjaji

The purpose of this study is to assess and evaluate the physicochemical properties of the seed oils of two Moroccan varieties of watermelon “Citrullus lanatus” extracted by three different techniques, a mechanical process using cold press, and two chemical processes using a Soxhlet apparatus and a sonotrode ultrasound assisted extraction (UAE) using n-hexane. The total phenolic compounds (TPC) and antioxidant properties against the DPPH radicals (2,2-diphenyl-1-picrylhydrazyl) were also studied. The seed oils of both varieties of watermelon exhibited high concentrations of unsaturated fatty acids with the predominance of linoleic and oleic fatty acids. The primary sterol was β-sitosterol, and high levels of total tocopherols were observed. Ɣ-tocopherol was the predominant tocopherol in all tested oils. The Citrullus lanatus var. lanatus variety seeds oil exhibited the highest TPC value (89.5 ± 0.06 mg EGA/100 g; EGA: gallic acid equivalent), with 82.4 ± 0.03% DPPH free radical inhibition efficiency. Nevertheless, all tested seeds oils showed a significant amount of total phenolic compounds and a good inhibition against DPPH radicals ranging from 51.1 ± 0.1% to 84.8 ± 0.04%. In addition, the influence of the ultrasonic extraction parameters was studied using two different solvents (n-hexane and the methanol-chloroform mixture), with different particle sizes (500–300 µm), duration (10 and 20 minutes), cycle (1–0.5), amplitude (80–100%) and solvent/seed ratios (1:5 and 1:10), and the seed roasting parameter was also studied. The oil yield was mainly affected by the extraction solvent, then the solvent/seed ratio and the duration, respectively.


Processes ◽  
2020 ◽  
Vol 8 (5) ◽  
pp. 542
Author(s):  
Thi Thuy Nguyen ◽  
Lan Phuong Doan ◽  
Thu Huong Trinh Thi ◽  
Hong Ha Tran ◽  
Quoc Long Pham ◽  
...  

This research aimed to investigate the chemical composition of seed oils extracted from three Vietnamese Dalbergia species (D. tonkinensis, D. mammosa, and D. entadoides). The fatty acid profiles and contents of tocopherols and sterols of the seed oils, and total phenolic compounds extracted from the fresh seeds were characterized using different methods. Among the examined samples, D. tonkinensis seed oils showed high contents of linoleic acid (64.7%), whereas in D. mammosa, oleic acid (51.2%) was predominant. In addition, α- and γ-tocopherol and β-sitosterol were major ingredients in the seed oils, whereas ferulic acid and rosmarinic acid are usually predominant in the seeds of these species. Regarding sterol composition, the D. entadoides seed oil figured for remarkably high content of Δ5,23-stigmastadienol (1735 mg/kg) and Δ7-stigmastenol (1298 mg/kg). In addition, extracts with methanol/water (80:20, v/v) of seeds displayed significant in vitro antioxidant activity which was determined by DPPH free radical scavenging assay.


2017 ◽  
Vol 2017 ◽  
pp. 1-3
Author(s):  
Ashutosh K. Mittal ◽  
Shishir Tandon

Seed oils have been used for centuries by communities as food, medicine, cosmetic applications, and fuel. Recently, there has been a renewed interest in these nontimber forest products specifically for use in cosmetic formulations. The fatty acid compositions of kernel oil of Heynea trijuga was analyzed by GC-FID. The results showed that the oil content was 37.61 percent (w/w) in seed. Seed oil was rich in unsaturated fatty acids. Important fatty acids present were palmitic acid (22.12%), stearic acid (7.51%), oleic acid (25.20%), and linoleic acid (11.65%).


1946 ◽  
Vol 24b (5) ◽  
pp. 211-220 ◽  
Author(s):  
C. Y. Hopkins

The fatty oil of hare's-ear mustard seed (Conringia orientalis L.) was examined. Constants of the oil were determined and a partial separation of the fatty acids was carried out by the methyl ester fractionation method. Palmitic, oleic, linoleic, eicosenoic, erucic, and lignoceric acids were identified. Erucic acid was found to be present in largest amount. The oil resembles rapeseed and other Cruciferae seed oils in this respect. The content of eicosenoic acid is estimated to be not more than 12% of the total fatty acids.


Author(s):  
Jie Li, Zai-Hua Wang

Wild Paeonia ludlowii is considered as a traditional ornamental plant, but its flowers and seed oils are edible with important economic values, and the variation of nutrients, fatty acid composition in wild populations is scarcely known. Flowers and seeds of P. ludlowii were collected from two wild populations for evaluating the nutrients in flowers, composition of fatty acids in seed oils and the antioxidant activity. The flowers contained high composition of proteins, carbohydrates, amino acids, total flavonoids, phenolic compounds and essential minerals. Seed oil yield reached up to 21.95% using supercritical CO2 fluid extraction, and it contained 14 fatty acids (up to 93.35 g/100g seed oil), especially the unsaturated fatty acids (oleic acid, linoleic acid and α-linolenic acid) was up to 88.69% with low ω6/ω3 ratios of 0.58. The antioxidant capacity can be arranged in the order of trolox > flower extracts > seed oil according to the DPPH and ABTS free radical assay. Contents of nutrient in flowers and fatty acids in seed oils were significantly different between two wild populations due to the impact of different growing environments. These results indicate that flowers and seed oils of P. ludlowii are potential food resources in human diets.


2014 ◽  
Vol 9 (12) ◽  
pp. 1934578X1400901 ◽  
Author(s):  
Mustapha Boukouada ◽  
Zineb Ghiaba ◽  
Nadhir Gourine ◽  
Isabelle Bombarda ◽  
Mokhtar Saidi ◽  
...  

The fatty acid composition of date seed oil from two different date palm ( Phoenix dactylifera L.) cultivars, locally known as Degla-Baïdha and Tafezouine, were investigated. GC analysis revealed the presence of five dominant fatty acids: oleic C18:1 (46.51; 39.15%), lauric C12:0 (22.1; 28.5%), myristic C14:0 (10.7; 11.4%), palmitic C16:0 (9.6; 8.7%) and linoleic C18:2 (6.9; 6.1%). The oils was characterised by a low content of tocopherols (0.53; 1.41 μg/g). The antioxidant activity of the oils was investigated using the DPPH•(1,1-di-phenyl-2-picryl-hydrazyl) scavenging assay. The oils had a weak bleaching effect on DPPH• free radicals. This study showed that the qualities of the tested oils are highly comparable with those of some commercial seed oils of other plants. Furthermore, a statistical analysis using the hierarchy ascendant classification method was conducted in order to highlight the similarities and/or the differences regarding the contents of the main fatty acids found in some common plants and in the five most famous cultivars of Phoenix dactylifera of south eastern Algeria (Tafezouine, Degla-Baïdha, Deglet-Nour, Ghars, Tamdjouhert).


2018 ◽  
Vol 7 (1) ◽  
pp. 56
Author(s):  
Xinchu Weng ◽  
Zhuoting Yun ◽  
Chenxiao Zhang

Physicochemical properties, fatty acid composition, antioxidant compounds and oxidative stability of oil-tea seed oil (Camellia oleifera Abel.) and green-tea seed oil (Camellia sinensis O. Ktze.) were investigated. The refractive index, saponification value, iodine value, acid value, peroxide value, unsaponifiables were determined to assess the quality of the oils. The major fatty acids of green-tea seed oil and oil-tea seed oil were oleic acid, linoleic acid and palmitic acid. Green-tea seed oil was typical oleic-linoleic-oil with 52.13% oleic acid and 24.32% linoleic acid level, whereas oil-tea seed oil was typical oleic-oil with very high oleic acid level (73.67%). The amount of total phenols, α-tocopherol and β-carotene of green-tea seed oil were 8.68 mg/kg, 160.33 mg/kg, 3.20 mg/kg, respectively, whereas they were 17.90 mg/kg, 85.66 mg/kg, 1.18 mg/kg in oil-tea seed oil, respectively. Green-tea seed oil contained high amounts of α-tocopherol which was nearly twice that of oil-tea seed oil. The initial induction period (IP) values of green-tea seed oil and oil-tea seed oil were 6.55h and 6.08h at 110 oC by OSI method, respectively, which shows the oxidative stability of two kinds of tea seed oils were preferable. Therefore, oil-tea seed oil could be a good dietary supplement with high level of monounsaturated fatty acids and similar fatty acid composition of olive oil. Green-tea seed oil was a new oil resource which is rich in α-tocopherol in China.


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