scholarly journals Investigation of the Pigments and Glassy Matrix of Painted Enamelled Qing Dynasty Chinese Porcelains by Noninvasive On-Site Raman Microspectrometry

Heritage ◽  
2020 ◽  
Vol 3 (3) ◽  
pp. 915-940
Author(s):  
Philippe Colomban ◽  
Burcu Kırmızı ◽  
Bing Zhao ◽  
Jean-Baptiste Clais ◽  
Yong Yang ◽  
...  
Keyword(s):  
Qing Dynasty ◽  
Au Nanoparticles ◽  
18Th Century ◽  
Glassy Matrix ◽  
Lead Arsenate ◽  
Alkali Glass ◽  
Different Types ◽  
Yellow Pigments ◽  
Raman Microspectrometry ◽  
Selection Of

A selection of 15 Chinese painted enameled porcelains from the 18th century (Qing dynasty) was analyzed on-site by mobile Raman and XRF microspectroscopy. The highly prized artifacts are present in the collections of the Musée du Louvre in Paris and Musée Chinois at Fontainebleau Castle in France. In the painted enamels, pigments such as Naples yellow lead pyrochlore, hematite, manganese oxide and carbon and opacifiers such as lead arsenates were detected. The glassy matrices of the enamels mainly belonged to lead-rich and lead-alkali glass types according to the Raman spectra obtained. The glaze and body phases of the porcelain artifacts were also analyzed. The detection of lead arsenate apatite in some of the blue enamels was significant, indicating the use of arsenic-rich European cobalt ores (smalt) and possibly mixing with Asian cobalt. This characteristic phase has also been identified in French soft-paste porcelains and glass decor and high-quality Limoges enamels from the same period. Based on the shape of the Raman scattering background, the presence of colloidal gold (Au° nanoparticles) was identified in red, orange and pink enamels. Different types of Naples yellow pigments were also detected with Sb-rich, Sn-rich and mixed Sb–Sn–(Zn, Fe?) compositions in the yellow enamels. The results were compared to previous data obtained on Chinese cloisonné and painted enameled metalware and Limoges enamels as well as French enameled watches.

scholarly journals Non-Invasive On-Site Raman Study of Pigments and Glassy Matrix of 17th–18th Century Painted Enamelled Chinese Metal Wares: Comparison with French Enamelling Technology

Coatings ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 471 ◽  
Author(s):  
Philippe Colomban ◽  
Burcu Kırmızı ◽  
Bing Zhao ◽  
Jean-Baptiste Clais ◽  
Yong Yang ◽  
...  
Keyword(s):  
Qing Dynasty ◽  
Au Nanoparticles ◽  
18Th Century ◽  
Glassy Matrix ◽  
X Ray ◽  
The Qing Dynasty ◽  
Non Invasive ◽  
Lead Arsenate ◽  
Raman Study ◽  
Selection Of

A selection of 10 Chinese enamelled metal wares dating from the 17th–18th centuries (Qing Dynasty) was analysed on-site by mobile Raman microspectroscopy. These wares display cloisonné and/or painted enamels and belong to the collections of Musée du Louvre in Paris and Musée Chinois at the Fontainebleau Castle in France. Pigments (Naples yellow lead pyrochlore, hematite, manganese oxide etc.), opacifiers (fluorite, lead arsenates) and corresponding lead-based glassy matrices were identified. One artefact was also analysed by portable X-ray fluorescence spectrometry (pXRF) in order to confirm the Raman data. In some of these metal wares, it is suggested that cassiterite was unpredictably used as an opacifier in some parts of the decor. The results are compared to previous data obtained on Chinese cloisonné and Limoges enamels as well as recent data recorded on painted enamelled porcelains of the Qing Dynasty. Lead arsenate apatite detected in some of the 17th–18th century blue enamelled decors is related to the use of arsenic-rich European cobalt ores, as also characterized in French soft-paste porcelain and glass decors and high-quality Limoges enamels for the same period. However, lead arsenate could then also have been deliberately used for white opacification. The specific Raman signature displaying the shape of the Raman scattering background indicates the presence of colloidal gold (Au° nanoparticles) in red to violet enamelled and cloisonné areas. At least three types of Naples yellow lead pyrochlore pigments identified with Sb-rich, Sn-rich and mixed Sb–Sn–(Zn, Fe?) compositions prove the use of European pigments/recipes.

scholarly journals The Technology Transfer from Europe to China in the 17th–18th Centuries: Non-Invasive On-Site XRF and Raman Analyses of Chinese Qing Dynasty Enameled Masterpieces Made Using European Ingredients/Recipes

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7434
Author(s):  
Philippe Colomban ◽  
Michele Gironda ◽  
Divine Vangu ◽  
Burcu Kırmızı ◽  
Bing Zhao ◽  
...  
Keyword(s):  
Qing Dynasty ◽  
18Th Century ◽  
Raman Microspectroscopy ◽  
The Other ◽  
The Qing Dynasty ◽  
Lead Arsenate ◽  
Napoleon Iii ◽  
Dark Green ◽  
High Level ◽  
Incense Burner

Two masterpieces of the Qing Dynasty (1644–1912 CE), one in gilded brass (incense burner) decorated with cloisonné enamels stylistically attributed to the end of the Kangxi Emperor’s reign, the other in gold (ewer offered by Napoleon III to the Empress as a birthday present), decorated with both cloisonné and painted enamels bearing the mark of the Qianlong Emperor, were non-invasively studied by optical microscopy, Raman microspectroscopy and X-ray microfluorescence spectroscopy (point measurements and mapping) implemented on-site with mobile instruments. The elemental compositions of the metal substrates and enamels are compared. XRF point measurements and mappings support the identification of the coloring phases and elements obtained by Raman microspectroscopy. Attention was paid to the white (opacifier), blue, yellow, green, and red areas. The demonstration of arsenic-based phases (e.g., lead arsenate apatite) in the blue areas of the ewer, free of manganese, proves the use of cobalt imported from Europe. The high level of potassium confirms the use of smalt as the cobalt source. On the other hand, the significant manganese level indicates the use of Asian cobalt ores for the enamels of the incense burner. The very limited use of the lead pyrochlore pigment (European Naples yellow recipes) in the yellow and soft green cloisonné enamels of the Kangxi incense burner, as well as the use of traditional Chinese recipes for other colors (white, turquoise, dark green, red), reinforces the pioneering character of this object in technical terms at the 17th–18th century turn. The low level of lead in the cloisonné enamels of the incense burner may also be related to the use of European recipes. On the contrary, the Qianlong ewer displays all the enameling techniques imported from Europe to obtain a painted decoration of exceptional quality with the use of complex lead pyrochlore pigments, with or without addition of zinc, as well as cassiterite opacifier.

Waldentwicklung als Politikfeld. Das südwestliche Rheinland (Deutschland) im 18. Jahrhundert | Political dimension of forest development. Southwest Rhineland (Germany) in the 18th century

2001 ◽  
Vol 152 (12) ◽  
pp. 484-489
Author(s):  
Christoph Ernst
Keyword(s):  
18Th Century ◽  
Wood Production ◽  
Political Issue ◽  
Political Dimension ◽  
Mutual Dependence ◽  
New Knowledge ◽  
Different Types ◽  
Production Agriculture ◽  
Landed Gentry ◽  
Archive Material

Evaluation of archive material from southwest Rhineland, Germany,has provided new knowledge on the development of forests in the 18th century. The society of those times had three different main requirements, which called for three different types of forest; for wood production, agriculture and hunting. But both landed gentry and the community as a whole were interested in maximising the use of the forest. It is therefore not accurate to conclude that wood production was only in the interest of the landowners and agriculture in the interest of the rest of the community. In addition, the different types of forest were subject to mutual dependence because changing one parameter meant that the balance governing wood production,grazing and arable areas, as well as habitat for game,also shifted. These interests, both divergent and common, of the population as a whole lead to the conclusion that forestry development was a highly political issue, and that the influence of the non-owning part of the population was greater than previously thought.

scholarly journals Multi-Criteria Selection of Additives in Porous Asphalt Mixtures Using Mechanical, Hydraulic, Economic, and Environmental Indicators

2021 ◽  
Vol 13 (4) ◽  
pp. 2146
Author(s):  
Anik Gupta ◽  
Carlos J. Slebi-Acevedo ◽  
Esther Lizasoain-Arteaga ◽  
Jorge Rodriguez-Hernandez ◽  
Daniel Castro-Fresno
Keyword(s):  
Cellulose Fiber ◽  
Environmental Indicators ◽  
Asphalt Mixtures ◽  
Environmental Benefits ◽  
Modified Bitumen ◽  
Porous Asphalt ◽  
Different Types ◽  
Product Assessment ◽  
Polymer Modified Bitumen ◽  
Selection Of

Porous asphalt (PA) mixtures are more environmentally friendly but have lower durability than dense-graded mixtures. Additives can be incorporated into PA mixtures to enhance their mechanical strength; however, they may compromise the hydraulic characteristics, increase the total cost of pavement, and negatively affect the environment. In this paper, PA mixtures were produced with 5 different types of additives including 4 fibers and 1 filler. Their performances were compared with the reference mixtures containing virgin bitumen and polymer-modified bitumen. The performance of all mixes was assessed using: mechanical, hydraulic, economic, and environmental indicators. Then, the Delphi method was applied to compute the relative weights for the parameters in multi-criteria decision-making methods. Evaluation based on distance from average solution (EDAS), technique for order of the preference by similarity to ideal solution (TOPSIS), and weighted aggregated sum product assessment (WASPAS) were employed to rank the additives. According to the results obtained, aramid pulp displayed comparable and, for some parameters such as abrasion resistance, even better performance than polymer-modified bitumen, whereas cellulose fiber demonstrated the best performance regarding sustainability, due to economic and environmental benefits.

scholarly journals Methods for Preventing Visual Attacks in Convolutional Neural Networks Based on Data Discard and Dimensionality Reduction

2021 ◽  
Vol 11 (11) ◽  
pp. 5235
Author(s):  
Nikita Andriyanov
Keyword(s):  
Neural Network ◽  
Convolutional Neural Network ◽  
Network Inference ◽  
Recognition Accuracy ◽  
Network Architectures ◽  
Reduced Dimensions ◽  
Different Types ◽  
Rectangular Area ◽  
Noise Impulse ◽  
Selection Of

The article is devoted to the study of convolutional neural network inference in the task of image processing under the influence of visual attacks. Attacks of four different types were considered: simple, involving the addition of white Gaussian noise, impulse action on one pixel of an image, and attacks that change brightness values within a rectangular area. MNIST and Kaggle dogs vs. cats datasets were chosen. Recognition characteristics were obtained for the accuracy, depending on the number of images subjected to attacks and the types of attacks used in the training. The study was based on well-known convolutional neural network architectures used in pattern recognition tasks, such as VGG-16 and Inception_v3. The dependencies of the recognition accuracy on the parameters of visual attacks were obtained. Original methods were proposed to prevent visual attacks. Such methods are based on the selection of “incomprehensible” classes for the recognizer, and their subsequent correction based on neural network inference with reduced image sizes. As a result of applying these methods, gains in the accuracy metric by a factor of 1.3 were obtained after iteration by discarding incomprehensible images, and reducing the amount of uncertainty by 4–5% after iteration by applying the integration of the results of image analyses in reduced dimensions.

An algebraic approach to N-soft sets with application in decision-making using TOPSIS

2021 ◽  
pp. 1-21
Author(s):  
Muhammad Shabir ◽  
Rimsha Mushtaq ◽  
Munazza Naz
Keyword(s):  
Decision Making ◽  
Mathematical Models ◽  
Real World ◽  
Algebraic Approach ◽  
Multi Criteria Decision Making ◽  
Commutative Monoids ◽  
Soft Sets ◽  
Algebraic Properties ◽  
Different Types ◽  
Selection Of

In this paper, we focus on two main objectives. Firstly, we define some binary and unary operations on N-soft sets and study their algebraic properties. In unary operations, three different types of complements are studied. We prove De Morgan’s laws concerning top complements and for bottom complements for N-soft sets where N is fixed and provide a counterexample to show that De Morgan’s laws do not hold if we take different N. Then, we study different collections of N-soft sets which become idempotent commutative monoids and consequently show, that, these monoids give rise to hemirings of N-soft sets. Some of these hemirings are turned out as lattices. Finally, we show that the collection of all N-soft sets with full parameter set E and collection of all N-soft sets with parameter subset A are Stone Algebras. The second objective is to integrate the well-known technique of TOPSIS and N-soft set-based mathematical models from the real world. We discuss a hybrid model of multi-criteria decision-making combining the TOPSIS and N-soft sets and present an algorithm with implementation on the selection of the best model of laptop.

scholarly journals Outlier Detection at the Parcel-Level in Wheat and Rapeseed Crops Using Multispectral and SAR Time Series

2021 ◽  
Vol 13 (5) ◽  
pp. 956
Author(s):  
Florian Mouret ◽  
Mohanad Albughdadi ◽  
Sylvie Duthoit ◽  
Denis Kouamé ◽  
Guillaume Rieu ◽  
...  
Keyword(s):  
Outlier Detection ◽  
Experimental Validation ◽  
Vegetation Index ◽  
Normalized Difference Vegetation Index ◽  
Multispectral Images ◽  
Vegetation Indexes ◽  
Crop Development ◽  
Different Types ◽  
Selection Of ◽  
Sentinel 2

This paper studies the detection of anomalous crop development at the parcel-level based on an unsupervised outlier detection technique. The experimental validation is conducted on rapeseed and wheat parcels located in Beauce (France). The proposed methodology consists of four sequential steps: (1) preprocessing of synthetic aperture radar (SAR) and multispectral images acquired using Sentinel-1 and Sentinel-2 satellites, (2) extraction of SAR and multispectral pixel-level features, (3) computation of parcel-level features using zonal statistics and (4) outlier detection. The different types of anomalies that can affect the studied crops are analyzed and described. The different factors that can influence the outlier detection results are investigated with a particular attention devoted to the synergy between Sentinel-1 and Sentinel-2 data. Overall, the best performance is obtained when using jointly a selection of Sentinel-1 and Sentinel-2 features with the isolation forest algorithm. The selected features are co-polarized (VV) and cross-polarized (VH) backscattering coefficients for Sentinel-1 and five Vegetation Indexes for Sentinel-2 (among us, the Normalized Difference Vegetation Index and two variants of the Normalized Difference Water). When using these features with an outlier ratio of 10%, the percentage of detected true positives (i.e., crop anomalies) is equal to 94.1% for rapeseed parcels and 95.5% for wheat parcels.

scholarly journals Heterogeneity of mesenchymal stem cells in cartilage regeneration: from characterization to application

2021 ◽  
Vol 6 (1) ◽  
Author(s):  
Kangkang Zha ◽  
Xu Li ◽  
Zhen Yang ◽  
Guangzhao Tian ◽  
Zhiqiang Sun ◽  
...  
Keyword(s):  
Stem Cells ◽  
Mesenchymal Stem Cells ◽  
Articular Cartilage ◽  
Cartilage Repair ◽  
Cartilage Damage ◽  
Cartilage Regeneration ◽  
Great Promise ◽  
Traditional Treatment ◽  
Different Types ◽  
Selection Of

AbstractArticular cartilage is susceptible to damage but hard to self-repair due to its avascular nature. Traditional treatment methods are not able to produce satisfactory effects. Mesenchymal stem cells (MSCs) have shown great promise in cartilage repair. However, the therapeutic effect of MSCs is often unstable partly due to their heterogeneity. Understanding the heterogeneity of MSCs and the potential of different types of MSCs for cartilage regeneration will facilitate the selection of superior MSCs for treating cartilage damage. This review provides an overview of the heterogeneity of MSCs at the donor, tissue source and cell immunophenotype levels, including their cytological properties, such as their ability for proliferation, chondrogenic differentiation and immunoregulation, as well as their current applications in cartilage regeneration. This information will improve the precision of MSC-based therapeutic strategies, thus maximizing the efficiency of articular cartilage repair.

Features Extraction and Classification Methods for Automatic Selection of Two Different Types of Paint for Automotive Parts

2021 ◽  
Author(s):  
Deborah Martínez ◽  
Rafael Guzmán-Cabrera ◽  
Daniel A. May-Arrioja ◽  
Iván Hernández-Romano ◽  
Miguel Torres-Cisneros
Keyword(s):  
Features Extraction ◽  
Classification Methods ◽  
Automatic Selection ◽  
Different Types ◽  
Automotive Parts ◽  
Selection Of
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