scholarly journals Iron Sulfide Materials: Catalysts for Electrochemical Hydrogen Evolution

Inorganics ◽  
2019 ◽  
Vol 7 (6) ◽  
pp. 75 ◽  
Author(s):  
Dominikus Heift

The chemical challenge of economically splitting water into molecular hydrogen and oxygen requires continuous development of more efficient, less-toxic, and cheaper catalyst materials. This review article highlights the potential of iron sulfide-based nanomaterials as electrocatalysts for water-splitting and predominantly as catalysts for the hydrogen evolution reaction (HER). Besides new synthetic techniques leading to phase-pure iron sulfide nano objects and thin-films, the article reviews three new material classes: (a) FeS2-TiO2 hybrid structures; (b) iron sulfide-2D carbon support composites; and (c) metal-doped (e.g., cobalt and nickel) iron sulfide materials. In recent years, immense progress has been made in the development of these materials, which exhibit enormous potential as hydrogen evolution catalysts and may represent a genuine alternative to more traditional, noble metal-based catalysts. First developments in this comparably new research area are summarized in this article and discussed together with theoretical studies on hydrogen evolution reactions involving iron sulfide electrocatalysts.

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Panlong Zhai ◽  
Mingyue Xia ◽  
Yunzhen Wu ◽  
Guanghui Zhang ◽  
Junfeng Gao ◽  
...  

AbstractRational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nanosheets (Ru1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru1/D-NiFe LDH delivers an ultralow overpotential of 18 mV at 10 mA cm−2 for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O–O coupling at a Ru–O active site for oxygen evolution reaction. The Ru1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts.


Leonardo ◽  
2009 ◽  
Vol 42 (5) ◽  
pp. 439-442 ◽  
Author(s):  
Eduardo R. Miranda ◽  
John Matthias

Music neurotechnology is a new research area emerging at the crossroads of neurobiology, engineering sciences and music. Examples of ongoing research into this new area include the development of brain-computer interfaces to control music systems and systems for automatic classification of sounds informed by the neurobiology of the human auditory apparatus. The authors introduce neurogranular sampling, a new sound synthesis technique based on spiking neuronal networks (SNN). They have implemented a neurogranular sampler using the SNN model developed by Izhikevich, which reproduces the spiking and bursting behavior of known types of cortical neurons. The neurogranular sampler works by taking short segments (or sound grains) from sound files and triggering them when any of the neurons fire.


2003 ◽  
Vol 12 (3) ◽  
pp. 311-325 ◽  
Author(s):  
Martin R. Stytz ◽  
Sheila B. Banks

The development of computer-generated synthetic environments, also calleddistributed virtual environments, for military simulation relies heavily upon computer-generated actors (CGAs) to provide accurate behaviors at reasonable cost so that the synthetic environments are useful, affordable, complex, and realistic. Unfortunately, the pace of synthetic environment development and the level of desired CGA performance continue to rise at a much faster rate than CGA capability improvements. This insatiable demand for realism in CGAs for synthetic environments arises from the growing understanding of the significant role that modeling and simulation can play in a variety of venues. These uses include training, analysis, procurement decisions, mission rehearsal, doctrine development, force-level and task-level training, information assurance, cyberwarfare, force structure analysis, sustainability analysis, life cycle costs analysis, material management, infrastructure analysis, and many others. In these and other uses of military synthetic environments, computer-generated actors play a central role because they have the potential to increase the realism of the environment while also reducing the cost of operating the environment. The progress made in addressing the technical challenges that must be overcome to realize effective and realistic CGAs for military simulation environments and the technical areas that should be the focus of future work are the subject of this series of papers, which survey the technologies and progress made in the construction and use of CGAs. In this, the first installment in the series of three papers, we introduce the topic of computer-generated actors and issues related to their performance and fidelity and other background information for this research area as related to military simulation. We also discuss CGA reasoning system techniques and architectures.


Nano Research ◽  
2021 ◽  
Author(s):  
Qikang Wu ◽  
Songrui Wang ◽  
Jiahui Guo ◽  
Xueqing Feng ◽  
Han Li ◽  
...  

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Kamrul Ahsan ◽  
Shams Rahman

PurposeThis study conducts a systematic literature review of e-tail product returns research. E-tail product returns are essentially acquisition of products that have been sold through purely online or brick-and-click channels and then returned by consumer to business.Design/methodology/approachUsing a systematic literature review protocol, we identified 75 peer-reviewed articles on e-tail product returns, conducted bibliometric analysis and content analysis of the articles and summarised our findings.FindingsThe findings reveal that the subject of e-tail returns is a new research area; academics have started to investigate several aspects of e-tail returns through different research methodologies and theoretical foundations. Further research is required in leading e-commerce countries and on key areas such as omni-channel returns management, customer satisfaction and service, the impact of resources such as people skills, the benefits of technology and IT systems in managing e-tail returns.Practical implicationsThe study offers a summative account of current e-tail knowledge areas, which can serve as a reference guide for e-tailers to develop strategies for more efficient and competitive product returns.Originality/valueThis study contributes theoretically by developing clusters of key themes or knowledge areas about e-tail returns. It also provides a conceptual framework for e-tail returns management, which can be used as a springboard for further empirical research.


2018 ◽  
Vol 283 ◽  
pp. 1525-1533 ◽  
Author(s):  
Arun Prasad Murthy ◽  
Durai Govindarajan ◽  
Jayaraman Theerthagiri ◽  
Jagannathan Madhavan ◽  
Kuppusami Parasuraman

1996 ◽  
Vol 6 (1) ◽  
pp. 63-87 ◽  
Author(s):  
Tony Lévy

This article analyzes new material on the history of the amicable numbers. It discusses Hebrew texts which throw new light on the diffusion in Medieval Europe of Ṯābit ibn Qurra's (9th century) work. We find Ṯābit's theorem on amicable numbers in a Hebrew translation, made in Saragossa in 1395, of an arithmetical commentary written by Abū al-Ṣalt al-Andalusī (ca. 1068–1134), and also in an original Hebrew text probably written by the Jewish Provençal scholar Qalonymos ben Qalonymos (1287 – after 1329). These texts lend strong support to the surmise that the Arabic tradition concerning amicable numbers could not have remained unknown to European mathematicians before the work of Descartes and Fermat in the 17th century.


2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Kongning Li ◽  
Deng Wu ◽  
Xi Chen ◽  
Ting Zhang ◽  
Lu Zhang ◽  
...  

Cell death is a critical biological process, serving many important functions within multicellular organisms. Aberrations in cell death can contribute to the pathology of human diseases. Significant progress made in the research area enormously speeds up our understanding of the biochemical and molecular mechanisms of cell death. According to the distinct morphological and biochemical characteristics, cell death can be triggered by extrinsic or intrinsic apoptosis, regulated necrosis, autophagic cell death, and mitotic catastrophe. Nevertheless, the realization that all of these efforts seek to pursue an effective treatment and cure for the disease has spurred a significant interest in the development of promising biomarkers of cell death to early diagnose disease and accurately predict disease progression and outcome. In this review, we summarize recent knowledge about cell death, survey current and emerging biomarkers of cell death, and discuss the relationship with human diseases.


Author(s):  
Francesca Rossi ◽  
Giada Magni ◽  
Francesca Tatini ◽  
Martina Banchelli ◽  
Federica Cherchi ◽  
...  

In recent years, photobiomodulation (PBM) has been recognized as a physical therapy in wound management. Despite several published research papers, the mechanism underlying photobiomodulation is still not completely understood. The investigation about application of blue light to improve wound healing is a relatively new research area. Tests in selected patients evidenced a stimulation of the healing process in superficial and chronic wounds treated with a blue LED light emitting at 420 nm; a study in animal model pointed out a faster healing process in superficial wound, with an important role of fibroblasts and myofibroblasts. Here we present a study aiming at evidencing the effects of blue light on the proliferation and metabolism in fibroblasts and keratinocytes. Different light doses were used to treat the cells, evidencing inhibitory and stimulatory effects. Electrophysiology was used to investigate the effects on membrane currents, while Raman spectroscopy revealed the mitochondrial Cytochrome C (Cyt C) oxidase dependence on blue light irradiation. In conclusion, we observed that the blue LED light can be used to modulate the activity of human fibroblasts, and the effects in wound healing are particularly evident when studying the fibroblasts and keratinocytes co-cultures.


PRIMO ASPECTU ◽  
2020 ◽  
pp. 56-64
Author(s):  
Julia DROZDOVA

In the modern globalized world migration shows a stable progressing nature which explains the academic interest in this complex, controversial phenomenon. The complexity of migration processes gives rise to new discourses, and a new research area where migration is studied as a social resource, a channel to replenish human resources in the declining regions of the Russian Federation. Data obtained in a complex sociological study performed within the framework of RFFI grant #19-411-340002 “Territorial communities in social transformation: a sociological and managerial analysis” permitted considering migration as a social resource. The research team of the Volgograd Institute of management, a branch of RANEPA, used a combined strategy that includes both quantitative (mass survey of citizens and rural residents) and qualitative methods of empirical study. The former were mass surveys of urban and country residents, the latter - in-depth interviews of experts and representatives of territorial local governing bodies, the academic community, urban and country activists, architects, leaders of property owner associations, long term residents of territorial communities. The obtained data allowed revealing the potential of migration in terms of partial compensation for the declining population of the Volgograd region, replenishing human resources and labor force, preservation and development of regional territories, building solidary ties between the local population and migrants. Migration has both positive and negative implications; the objective, inevitable nature of migration brings to the fore a need for optimal, effective methods of management at all levels of the social system. Social and ethnic agreement between migrants and the receiving population in territorial communities can be only possible when life in a region is well regulated, its municipal structures and local communities function properly, and the traditions and culture of all people residing here are respected.


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