scholarly journals Aggregates Obtained by Alkali Activation of Fly Ash: The Effect of Granulation, Pelletization Methods and Curing Regimes

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 776 ◽  
Author(s):  
Ognjen Rudić ◽  
Vilma Ducman ◽  
Mirjana Malešev ◽  
Vlastimir Radonjanin ◽  
Suzana Draganić ◽  
...  
Keyword(s):  
Fly Ash ◽  
Energy Dispersive Spectrometer ◽  
Textural Properties ◽  
Alkali Activation ◽  
X Ray Diffraction ◽  
Scattered Electron ◽  
Curing Regime ◽  
Class F Fly Ash ◽  
Curing Regimes ◽  
Alkali Activated

This paper presents results regarding the phase composition, microstructure and textural properties of two types of aggregates, which were prepared via crushing or pelletization of alkali-activated Class F fly ash and cured under different conditions. The alkali activator was the same for aggregate products, containing an alkaline solution consisting of 8 M NaOH and Na-silicate (8 M NaOH/Na-silicate = 1:2.5 mass ratio). The aforementioned properties were influenced by two different preparation procedures combined with varying curing regimes (under normal conditions at 20 °C, RH 40–60% for 28 and 120 days and under an accelerated regime, at 65 °C for 5 days). Aggregates were characterized using X-ray diffraction (XRD), Fourier-transform transmission infrared spectroscopy (FTIR), back scattered electron microscopy with energy dispersive spectrometer (BSE-EDS) analyses and mercury intrusion porosimetry (MIP). The results showed noteworthy structural and textural diversities between the two types of aggregate. The method of preparation and curing regime affected the formation of the N-A-S-H structure and the texture of the alkali-activated fly ash product, with the crushing method giving an advantage.

Influence of water, alkali activators, and curing regime on the workability and compressive strength of the alkali activated mortar

2019 ◽  
Author(s):  
Eslam Gomaa ◽  
Simon Sargon ◽  
Cedric Kashosi ◽  
Ahmed Gheni ◽  
Mohamed ElGawady
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Calcium Content ◽  
Chemical Compositions ◽  
Heat Curing ◽  
High Calcium ◽  
Influence Of Water ◽  
Curing Regime ◽  
Curing Regimes ◽  
Alkali Activated

<p>The effect of the water to fly ash (W/FA), alkali activators to fly ash (Alk/FA), and curing regimes on the workability and compressive strength of the alkali-activated mortar (AAM) was studied. Three high calcium fly ashes (FAs) having different chemical compositions were used. Sodium hydroxide (SH) and sodium silicate (SS) were used as the alkali activators. The two alkali activators were mixed together at ratio of 1.0. Two curing regimes, elevated heat curing in an electric oven at 70°C for 24 hr and ambient curing at 23 ± 2°C, were applied. The water to fly ash (W/FA) ratios were 0.350, 0.375, and 0.400. However, the alkali activators to fly ash (Alk/FA) ratios were 0.250, 0.275 and 0.300. The results revealed that the workability and the compressive strength of the oven cured specimens were decreased with increasing the calcium content of FA in the mixture. However, the compressive strength of the specimens that cured under the ambient temperature increased with increasing the calcium content. The workability increased with increasing the W/FA and decreasing the Alk/FA. The compressive strength based on both curing regimes decreased with increasing the W/FA. The optimum Alk/FA was 0.275 with W/FA of 0.400.</p>

scholarly journals Effect of CaSO4 Incorporation on Pore Structure and Drying Shrinkage of Alkali-Activated Binders

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1673 ◽  
Author(s):  
Hyeongmin Son ◽  
Sol Moi Park ◽  
Joon Ho Seo ◽  
Haeng Ki Lee
Keyword(s):  
Fly Ash ◽  
Pore Structure ◽  
Drying Shrinkage ◽  
Phase Changes ◽  
X Ray Diffraction ◽  
Activated Slag ◽  
Capillary Tension ◽  
Alkali Activated Binders ◽  
Internal Pore Structure ◽  
Alkali Activated

This present study investigates the effects of CaSO4 incorporation on the pore structure and drying shrinkage of alkali-activated slag and fly ash. The slag and fly ash were activated at a 5:5 ratio by weighing with a sodium silicate. Thereafter, 0%, 5%, 10%, and 15% of CaSO4 were incorporated to investigate the changes in phase formation and internal pore structure. X-Ray Diffraction (XRD), thermogravimetry (TG)/derivative thermogravimetry (DTG), mercury intrusion porosimetry (MIP), nuclear magnetic resonance (NMR), and drying shrinkage tests were carried out to find the correlation between the pore structure and drying shrinkage of the specimens. The results showed that CaSO4 incorporation increased the formation of thenardite, and these phase changes affected the pore structure of the activated fly ash and slag. The increase in the CaSO4 content increased the pore distribution in the mesopore. As a result, the capillary tension and drying shrinkage decreased.

scholarly journals Mechanical Properties of Alkali Activated Material Based on Red Clay and Silica Gel Precursor

2021 ◽  
Vol 25 (1) ◽  
pp. 931-943
Author(s):  
Girts Bumanis ◽  
Danute Vaiciukyniene
Keyword(s):  
Silica Gel ◽  
Raw Materials ◽  
Raw Material ◽  
Alkali Activation ◽  
Production Plant ◽  
X Ray Diffraction ◽  
Red Clay ◽  
Significant Strength ◽  
Naoh Solution ◽  
Alkali Activated

Abstract The search for alternative alumosilicates source for production of alkali activated materials (AAM) is intensively researched. Wide spread of natural materials such as clays and waste materials are one of potential alternatives. In this research AAM was made from local waste brick made of red clay and calcined low-carbonate illite clay precursor and its properties evaluated. Waste silica gel containing amorphous silica from fertilizer production plant was proposed as additional raw material. 6 M and 7 M NaOH alkali activation solutions were used to obtain AAM. Raw materials were characterized by X-ray diffraction, laser particle size analyser, DTA/TG. Raw illite clay was calcined at a temperature of 700 to 800 °C. Waste brick was ground similar as raw clay and powder was obtained. Replacement of red clay with silica gel from 2–50 wt.% in mixture composition was evaluated. Results indicate that the most effective activator was 6 M NaOH solution and AAM with strength up to 13 MPa was obtained. Ground brick had the highest strength results and compressive strength of AAM reached 25 MPa. Silica gel in small quantities had little effect of AAM strength while significant strength reduction was observed with the increase silica gel content. The efflorescence was observed for samples with silica gel.

scholarly journals Pressure-Induced Geopolymerization in Alkali-Activated Fly Ash

2018 ◽  
Vol 10 (10) ◽  
pp. 3538 ◽  
Author(s):  
Sol Park ◽  
Hammad Khalid ◽  
Joon Seo ◽  
Hyun Yoon ◽  
Hyeong Son ◽  
...  
Keyword(s):  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Elevated Pressure ◽  
X Ray Diffraction ◽  
27Al Mas Nmr ◽  
Alkali Activated

The present study investigated geopolymerization in alkali-activated fly ash under elevated pressure conditions. The fly ash was activated using either sodium hydroxide or a combination of sodium silicate solution and sodium hydroxide, and was cured at 120 °C at a pressure of 0.22 MPa for the first 24 h. The pressure-induced evolution of the binder gel in the alkali-activated fly ash was investigated by employing synchrotron X-ray diffraction and solid-state 29Si and 27Al MAS NMR spectroscopy. The results showed that the reactivity of the raw fly ash and the growth of the zeolite crystals were significantly enhanced in the samples activated with sodium hydroxide. In contrast, the effects of the elevated pressure conditions were found to be less apparent in the samples activated with the sodium silicate solution. These results may have important implications for the binder design of geopolymers, since the crystallization of geopolymers relates highly to its long-term properties and functionality.

The Influence of Mechanical Activation of Fly Ash on the Toxic Metals Immobilization by Fly Ash-Based Geopolymers

2018 ◽  
Vol 761 ◽  
pp. 3-6 ◽  
Author(s):  
Violeta Nikolić ◽  
Miroslav Komljenović ◽  
Nataša Džunuzović ◽  
Tijana Ivanovic
Keyword(s):  
Fly Ash ◽  
Mechanical Activation ◽  
Toxic Metals ◽  
Structural Changes ◽  
Gas Adsorption ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Water Soluble ◽  
Alkali Activation ◽  
Alkali Activated

This paper investigates the influence of mechanical activation of fly ash on the toxic metals immobilization by fly ash-based geopolymers. Fly ash was firstly mechanically and then alkali-activated. Mechanical activation of fly ash was conducted in a planetary ball mill. Alkali activation of fly ash was carried out at room temperature by use of sodium silicate solution as an activator. Toxic metals (Pb and Cr) were added in the form of water soluble salts during the synthesis of geopolymers. The immobilization process was assessed via investigation of the mechanical and leaching properties of geopolymers. Structural changes of geopolymers during the toxic metals immobilization were assessed by means of gas adsorption and SEM analyses. Mechanical activation of fly ash led to a significant increase in geopolymer strength and to a reduced leaching of toxic metals from geopolymers.

scholarly journals Compressive Strength Performance of Alkali Activated Concretes under Different Curing Conditions

2021 ◽  
Author(s):  
Anıl Niş ◽  
İlhan Altındal
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Strength Performance ◽  
Curing Conditions ◽  
Standardization Process ◽  
Water Curing ◽  
Curing Regimes ◽  
Alkali Activated Concrete ◽  
Alkali Activated ◽  
Ambient Curing

This study investigated the influence of different curing conditions on the compressive strength (CS) of the different alkali activated concrete (AAC) specimens at the ages of 2, 28, and 90 days for the structural utilization and standardization process of AAC instead of OPC concrete. For this aim, 100% slag (S100), 75% slag and 25% fly ash (S75FA25), and 50% slag and 50% fly ash based (S50FA50) AAC specimens were produced. Based on the oven-curing (O), water-curing (W), and ambient-curing (A) methods, the influence of 2O for 2 days, 26A2O, 2O26A, 28A, 28W, 26W2O, and 2O26W for 28 days, and 88A2O, 2O88A, 90A, 88W2O, 2O88W, 90W for 90 days on the CS of the AAC were examined in details. In addition, the influence of delayed oven-curing conditions on CS development was also investigated. The results indicated that curing conditions significantly affected on the CS and the water-curing condition could provide a better CS for those of AAC at 90 days. Although, the oven-curing enhanced CS of the S100 specimens at initial ages (first oven-curing applied), delayed oven-curing (oven-curing applied later) was found significant for S75FA25 and S50FA50 specimens. The delayed oven-curing affected more on the CS of the AAC when fly ash content increased. The most of AAC specimens with oven-curing had significantly enhanced the CS at 28 days, but S50FA50 at the age of 90 days decreased. Different curing regimes were proposed for the superior compressive strength values for each AAC specimens at the ages of 28 and 90 days.

scholarly journals Influence of Concrete Sludge Addition in the Properties of Alkali-Activated and Non-Alkali-Activated Fly Ash-Based Mortars

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Fotini Kesikidou ◽  
Stavroula Konopisi ◽  
Eleftherios K. Anastasiou
Keyword(s):  
Fly Ash ◽  
Silicon Oxide ◽  
Strength Development ◽  
Alkali Activation ◽  
Early Age ◽  
Fly Ash Concrete ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Potential Synergy ◽  
Alkali Activated

This study investigated the use of concrete sludge, a by-product of the ready-mix concrete industry, in combination with high-calcium fly ash in binary cementless binders. Concrete sludge was used in substitution rates ranging from 0% to 60% in test fly ash-based mortars to determine potential synergy. The mortars were tested for fresh and hardened properties; workability, viscosity, strength development, open porosity, early-age shrinkage, and analytical tests were carried out. A mortar with 50% fly ash and 50% limestone filler as binders was used for comparison purposes. Furthermore, a series of mortars with fly ash and concrete sludge were alkali-activated in order to determine potential strength gain. In the activated mortars, two fractions of concrete sludge were used, under 75 μm and 200 μm, due to different silicon oxide contents, while one mortar was cured at 40°C to investigate the effect of heating on alkali activation. Results show that sludge contributes to the formation of C-S-H and strength development when used in combination with high-calcium fly ash even at high replacement rates. The alkali activation of fly ash-concrete sludge system contributed to early-age strength development and to early-age shrinkage reduction.

scholarly journals STRENGTH AND DURABILITY PERFORMANCE OF FLY ASH BASED GEOPOLYMER CONCRETE USING NANO SILICA

2020 ◽  
Vol 4 (2) ◽  
pp. 1-12
Author(s):  
SAMEER VYAS ◽  
Sameer Mohammad ◽  
Shilpa Pal ◽  
Neetu Singh
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Geopolymer Concrete ◽  
Infrastructure Development ◽  
X Ray Diffraction ◽  
Nano Silica ◽  
Adverse Conditions ◽  
Concrete Production ◽  
Class F Fly Ash ◽  
Strength And Durability

With the increasing infrastructure development across the globe, the demand of cement  production increases day by day. However, the production of cement is associated with the emission of large amount of CO2 causing global warming. Scientist and engineers are in search of a green eco friendly alternative  for concrete production. Geopolymers are rapidly emerging as an alternative to Portland cement as the binder of structural concrete. In this respect, the fly ash based geopolymers  shows considerable prospect for application in concrete industry as an alternative binder to the Portland cement. Development of geopolymer concrete using class F fly ash brings many advantages like; enhancing workability, durability, better strength as well as lowering the price. There is not only a reduction in the greenhouse footprint but, also considerable increase in strength and resistivity to adverse conditions. In order to enhance the performance of Geopolymer concrete, the use of  Nano-silica is  found to be suitable and practiced by researchers.  Use of Nano materials as fillers in the concrete matrix has proven effective in increasing mechanical and durability properties. This research is based on performance evaluation of geopolymer concrete using different percentage of Nano-silica.. It was observed that Geopolymer concrete  with Nano-silica ( GPC-N)  shows good compressive strength as well as  durability under aggressive conditions. The materials performance were also investigated using X-Ray Diffraction technique. (XRD). Results show that the presence of nano silica  enhanced the performance of Geopolymer concrete with respect to strength and durability purposes.  

The Leachability of Heavy Metals from Alkali-Activated Fly Ash and Blast Furnace Slag Matrices

2016 ◽  
Vol 851 ◽  
pp. 141-146
Author(s):  
Jan Koplík ◽  
Miroslava Smolková ◽  
Jakub Tkacz
Keyword(s):  
Mechanical Properties ◽  
Heavy Metals ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Inductively Coupled Plasma ◽  
Emission Spectrometry ◽  
Alkali Activation ◽  
Furnace Slag ◽  
Alkali Activated

The ability of alkali-activated materials (AAMs) to fix and immobilize heavy metals was investigated. Two raw materials were used to prepare alkali-activated matrices – high-temperature fly ash and blast furnace slag (BFS). NaOH served as an alkaline activator. Two heavy metals (Mn, Ni) were added in different amounts to find out the influence of dosage of heavy metal on the mechanical properties of the matrices and the leachability. Leachability was measured as concentration of heavy metals in leachates (ČSN EN 12457-4) by inductively coupled plasma/optical emission spectrometry (ICP/OES). Structure of prepared matrices was characterized by scanning electron microscopy (SEM). Increasing of addition of heavy metals led to decrease of mechanical properties of matrices. The leaching tests showed, that both matrices can immobilize Mn and Ni in dosages of 0.1 – 2,5%. Higher dosages caused deterioration of the matrices and increased the leachability. After alkali activation both heavy metals were transformed into the form of insoluble salts.

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