scholarly journals Waste-Based Pigments for Application in Ceramic Glazes and Stoneware Bodies

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3396 ◽  
Author(s):  
Jorge Carneiro ◽  
David Maria Tobaldi ◽  
Marinélia Neto Capela ◽  
Maria Paula Seabra ◽  
João António Labrincha

The use of wastes, some of them hazards, as raw materials of ceramic pigments has been a way to diminish their environmental impact, to economically valorize them, and to face the depletion of virgin raw materials. In this work were prepared pigments having in their composition only industrial wastes: Cr/Ni electroplating (ES), and sludges from the cutting of natural stones—marble (MS) and granite (GS). The prepared mixtures were calcined at three temperatures (1100, 1200, and 1300 °C) and the obtained powders were characterized by XRD and UV-vis. Their coloring strength and thermal stability were assessed by adding them to different ceramic substrates: glazes (transparent bright and opaque matte) and a stoneware paste. The CIEL*a*b* coordinates of the fired materials were measured. The developed pigments are thermally stable and exhibit good tinting power, originating nicely colored and defect-free ceramic materials.

2015 ◽  
Vol 663 ◽  
pp. 34-41 ◽  
Author(s):  
Fernanda Andreola ◽  
Isabella Lancellotti ◽  
Rosa Taurino ◽  
Cristina Leonelli ◽  
Luisa Barbieri

Virgin raw materials can be partially replaced by glass waste in order to reduce the environmental impact being its recycling a significant problem for municipalities worldwide. In Italy in 2013, approximately 1,600,000 tons of container glass have been collected but it was not possible to recycle all of them in the glass melting process.This work is focused on the valorization of glass waste as raw material in new cement and ceramic products, to convert it from an environmental and economic burden to a profitable, added-value resource in the formulation of new mixes. Several parameters, such as grinding, forming, firing, etc. have been studied.It has been optimized the grinding and the reclaiming step of waste to obtain an alternative raw material for hot and cold consolidation processes. Chemical, physical and mechanical properties of products were carried out. The results show new real possibilities to use high amounts of glass waste as an alternative raw material in products consolidated either by hot or cold techniques, reducing the management problems of the glass waste.


Materials ◽  
2019 ◽  
Vol 12 (2) ◽  
pp. 208 ◽  
Author(s):  
Mónica Rodríguez-Galán ◽  
Bernabé Alonso-Fariñas ◽  
Francisco Baena-Moreno ◽  
Carlos Leiva ◽  
Benito Navarrete ◽  
...  

Herein an innovative process to develop a potential vitreous material with cementing properties is proposed. This process paves a production path through melting industrial waste and subsequently cooling the casting in water. The idea erases the need to reduce the environmental impact of the cement industry in terms of natural resources consumption as well as the re-utilization of abandoned wastes from other industries. The recycled industrial wastes were selected according to the amount of waste produced in the industrial field and its suitable chemical composition, such as construction and demolition waste and/or shells from shellfish. As a main result, the mechanical properties showed by our novel material were worse than those reported by blast furnace slag (25–28 MPa for two different proportions) for seven days and better (43–52 MPa for two different proportions) for 28 days. The rest of the properties evaluated were in agreement with the standards’ requirements. Hence, this novel process would help to minimize the environmental impact of these wastes at the same time that their use in the cement industry would reduce the consumption of raw materials.


2015 ◽  
Vol 663 ◽  
pp. 11-22 ◽  
Author(s):  
Jesús Ma Rincón

Since last decades both processes for the production of glass and ceramic materials (known by the generic name of "vitrification") and the processing of the usual ceramic materials ("sintering") are being investigated as a possible way to isolate, inmobilize and even recycling of industrial wastes as a source of "secondary raw materials". Starting from this point of view, the basis for the processing of some of wastes investigated by the author in the last decades are exposed, namely: metallurgy (muds or sludges...), residues from the production of energy (generation power plants, incinerators, nuclear power plants ...) wastes coming from the treatment of minerals and rocks (dumps, mine tailings, muds and machining of natural stone ...), as well as electrical wastes, demolition wastes and finally biomass residues which have been investigated in the recent years. This type of waste and mixtures give rise to synthetic materials with wide uses in construction and public works. Indeed, these are the only industries able to management of high volumes which may be suitable for absorbing a new range of glass, ceramic and glass-ceramic materials from all type of wastes. Experimental results obtained in last decades allow to conclude that both sintering processes as well as vitrification can be considered as an actual and useful, at least partially, for solving the environmental problems generated by all type of wastes.


2021 ◽  
Author(s):  
Vsevolod Mymrin ◽  
Kirill Alekseev ◽  
Walderson Klitzke ◽  
Monica A. Avanci ◽  
Paulo H.B. Rolim ◽  
...  

Abstract This paper reports the development and characterization of some new ceramic materials from hazardous bauxite red mud (50 to 100 wt.%) and blast furnace slag (10 and 50%). This research aimed to demonstrate the possibility of expanding the raw material base for ceramics production, completely replacing the traditional natural raw materials (clay and sand) by hazardous industrial wastes composites with increasing local and global sustainability. Studies on the physicochemical processes of the ceramic structure’s formation were conducted by the XRF, XRD, AAS, SEM with EDS, and LAMMA methods. Changes in flexural strength, linear shrinkage, water absorption, and density were determined during the sintering process at 1000°, 1050°, 1100°, 1150°, 1200°, and 1225°C. The ceramics` flexural strength after sintering at 1225°C reached 19.78 MPa due to the syntheses of the mainly glass-like structure formation, confirmed by SEM, EDS and isotopes LAMMA methods with the complete binding of the heavy metals.


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1066 ◽  
Author(s):  
Valentina Siracusa

Over the last ten years, the demand of biodegradable polymers has grown at an annual rate of 20–30%. However, the market share is about less than 0.1% of the total plastic production due to their lower performances, higher price and limited legislative attention in respect to the standard materials. The biodegradability as a functional added property is often not completely perceived from the final consumers. However, the opportunity to use renewable resources and to reduce the dependency from petroleum resources could become an incentive to accelerate their future growth. Renewable raw materials, coming from industrial wastes such as oilseed crops, starch from cereals and potatoes, cellulose from straw and wood, etc., can be converted into chemical intermediates and polymers, in order to substitute fossil fuel feedstock. The introduction of these new products could represent a significant contribution to sustainable development. However, the use of renewable resources and the production of the bioplastics are no longer a guarantee for a minimal environmental impact. The production process as well as their technical performances and their ultimate disposal has to be carefully considered. Bioplastics are generally biodegradable, but the diffusion of the composting technology is a prerequisite for their development. Efforts are required at industry level in order to develop less expensive and high performance products, with minimal environmental impact technologies.


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3564
Author(s):  
Arnas Majumder ◽  
Laura Canale ◽  
Costantino Carlo Mastino ◽  
Antonio Pacitto ◽  
Andrea Frattolillo ◽  
...  

The building sector is known to have a significant environmental impact, considering that it is the largest contributor to global greenhouse gas emissions of around 36% and is also responsible for about 40% of global energy consumption. Of this, about 50% takes place during the building operational phase, while around 10–20% is consumed in materials manufacturing, transport and building construction, maintenance, and demolition. Increasing the necessity of reducing the environmental impact of buildings has led to enhancing not only the thermal performances of building materials, but also the environmental sustainability of their production chains and waste prevention. As a consequence, novel thermo-insulating building materials or products have been developed by using both locally produced natural and waste/recycled materials that are able to provide good thermal performances while also having a lower environmental impact. In this context, the aim of this work is to provide a detailed analysis for the thermal characterization of recycled materials for building insulation. To this end, the thermal behavior of different materials representing industrial residual or wastes collected or recycled using Sardinian zero-km locally available raw materials was investigated, namely: (1) plasters with recycled materials; (2) plasters with natural fibers; and (3) building insulation materials with natural fibers. Results indicate that the investigated materials were able to improve not only the energy performances but also the environmental comfort in both new and in existing buildings. In particular, plasters and mortars with recycled materials and with natural fibers showed, respectively, values of thermal conductivity (at 20 °C) lower than 0.475 and 0.272 W/(m⋅K), while that of building materials with natural fibers was always lower than 0.162 W/(m⋅K) with lower values for compounds with recycled materials (0.107 W/(m⋅K)). Further developments are underway to analyze the mechanical properties of these materials.


Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3052
Author(s):  
Diego Cardoza ◽  
Inmaculada Romero ◽  
Teresa Martínez ◽  
Encarnación Ruiz ◽  
Francisco J. Gallego ◽  
...  

A biorefinery integrated process based on lignocellulosic feedstock is especially interesting in rural areas with a high density of agricultural and agro-industrial wastes, which is the case for olive crop areas and their associated industries. In the region of Andalusia, in the south of Spain, the provinces of Jaén, Córdoba and Seville accumulate more than 70% of the olive wastes generated in Spain. Therefore, the valorisation of these wastes is a matter of interest from both an environmental and a social point of view. The olive biorefinery involves a multi-product process from different raw materials: olive leaves, exhausted olive pomace, olive stones and olive tree pruning residues. Biorefinery processes associated with these wastes would allow their valorisation to produce bioenergy and high value-added renewable products. In this work, using geographic information system tools, the biomass from olive crop fields, mills and olive pomace-extracting industries, where these wastes are generated, was determined and quantified in the study area. In addition, the vulnerability of the territory was evaluated through an environmental and territorial analysis that allowed for the determination of the reception capacity of the study area. Then, information layers corresponding to the availability of the four biomass wastes, and layers corresponding to the environmental fragility of the study area were overlapped and they resulted in an overall map. This made it possible to identify the best areas for the implementation of the biorefineries based on olive-derived biomass. Finally, as an example, three zones were selected for this purpose. These locations corresponded to low fragility areas with a high availability of biomass (more than 300,000 tons/year) in a 30 km radius, which would ensure the biomass supply.


2021 ◽  
Vol 13 (8) ◽  
pp. 4394
Author(s):  
Margarita Ignatyeva ◽  
Vera Yurak ◽  
Alexey Dushin ◽  
Vladimir Strovsky ◽  
Sergey Zavyalov ◽  
...  

Nowadays, circular economy (CE) is on the agenda, however, this concept of closed supply chains originated in the 1960s. The current growing quantity of studies in this area accounts for different discourses except the holistic one, which mixes both approaches—contextual and operating (contextual approach utilizes the thorough examination of the CE theory, stricture of the policy, etc.; the operating one uses any kind of statistical data)—to assess the capacity of circular economy regulatory policy packages (CERPP) in operating raw materials and industrial wastes. This article demonstrates new guidelines for assessing the degree level of capacity (DLC) of CERPPs in the operation of raw materials and industrial wastes by utilizing the apparatus of the fuzzy set theory. It scrupulously surveys current CERPPs in three regions: the EU overall, Finland and Russia; and assesses for eight regions—the EU overall, Finland, Russia, China, Greece, France, the Netherlands and South Korea—the DLC of CERPPs in operating raw materials and industrial wastes. The results show that EU is the best in CE policy and its CERPP is 3R. The following are South Korea and China with the same type of CERPP. Finland, France and the Netherlands have worse results than EU with the type of CERPP called “integrated waste management” because of the absence of a waste hierarchy (reduce, recover, recycle). Russia closes the list with the type of CERPP “basic waste management”.


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