scholarly journals Efficiency of Different Superplasticizers and Retarders on Properties of ‘One-Part’ Fly Ash-Slag Blended Geopolymers with Different Activators

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3410 ◽  
Author(s):  
Shin Hau Bong ◽  
Behzad Nematollahi ◽  
Ali Nazari ◽  
Ming Xia ◽  
Jay Sanjayan
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Silicate ◽  
No Reduction ◽  
Setting Time ◽  
Sodium Metasilicate ◽  
Hardened Properties ◽  
The One ◽  
Positive Effect

Currently, there are a very limited number of studies on the effect of admixtures on properties of ‘one-part’ geopolymers. This paper reports the effects of different superplasticizers and retarders on fresh and hardened properties of one-part fly ash-slag blended geopolymers made by different solid activators. Two different grades of sodium silicate, namely anhydrous sodium metasilicate powder (nSiO2/nNa2O = 0.9) and GD Grade sodium silicate powder (nSiO2/nNa2O = 2.0) were used as the solid activators. Five different commercially available superplasticizers, including three modified polycarboxylate-based superplasticizers (denoted as PC1, PC2, and PC3) and two naphthalene-based superplasticizers (denoted as N1 and N2), as well as three different retarders, including sucrose, anhydrous borax and a commercially available retarder, were investigated. Workability, setting time and compressive strength of the mixtures without and with addition of each ‘individual’ admixture were measured. The results showed the effect of admixtures on the properties of the one-part geopolymers significantly depended on the type of solid activator and the type of admixture used. When GD Grade sodium silicate powder was used as the solid activator, all investigated admixtures not only had no positive effect on the workability and setting time, but also significantly reduced the compressive strength of the mixture. However, when anhydrous sodium metasilicate powder was used as the solid activator, the PC1 and sucrose were the best performing superplasticizer and retarder, respectively, causing no reduction in the compressive strength, but significant increase in the workability (up to + 72%) and setting time (up to + 111%), respectively as compared to the mixture with no admixture. In addition, the results also showed that addition of ‘combined’ admixtures (i.e., PC1 in the presence of sucrose) significantly increased the workability (up to + 39%) and setting time (up to + 141%), but slightly reduced the compressive strength (−16%) of the mixture activated by anhydrous sodium metasilicate powder, as compared to the mixture with no admixture.

scholarly journals Properties and Engineering Applications of a New Goaf Grouting Filling Material

Geofluids ◽  
2022 ◽  
Vol 2022 ◽  
pp. 1-14
Author(s):  
Xiao Feng ◽  
Chong Xia ◽  
Sifeng Zhang ◽  
Chuangui Li ◽  
Hongkui Zhao ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Silicate ◽  
Traffic Engineering ◽  
Setting Time ◽  
Microstructural Analysis ◽  
Volume Ratio ◽  
Skeletal Structure ◽  
Filling Material ◽  
Technical Problems

In the treatment of goafs in traffic engineering, technical problems such as those related to large-volume grouting and the precise control of material properties are often encountered. To address these issues, we developed a new composite material comprising cement-fly ash-modified sodium silicate (C-FA-MS). The setting time, fluidity, unconfined compressive strength, and microstructure were varied for different proportions of cement-sodium silicate (C-S) slurry, cement-fly ash-sodium silicate (C-FA-S) slurry, and C-FA-MS slurry, and their performances were compared and analysed. The experimental results showed that the initial setting time of the slurry was the shortest when both the original sodium silicate volume ratio ( V S ) and modified sodium silicate volume ratio ( V MS ) were 0.2. The final setting time of the C-S and C-FA-S slurries tended to decrease but then increased with decrease in V S , while that of the C-FA-MS slurry increased with lower V MS . The fluidity of the C-FA-S and C-FA-MS slurries decreased with decrease in V S or V MS at different fly ash admixture ratios. The consolidation compressive strength of C-S increased with decreasing V S , while that of C-FA-S showed a considerable increase only when V S decreased from 0.4 to 0.2. Meanwhile, the compressive strength of the C-FA-MS concretions first increased and then decreased with decrease in V MS . Microstructural analysis revealed that there were more cracks in the C-S agglomerate, the fly ash in the C-FA-S agglomerate reduced the relative density of the skeletal structure, and the stronger cross-linking in the C-FA-MS agglomerate improved the strength of the agglomerate. Under the condition of unit grouting volume, the cost of the C-FA-MS slurry was approximately 44.7% and 31.3% lower than that of the C-S and C-FA-S slurries, respectively. The new C-FA-MS material was applied for the treatment of the goaf in the Wu Sizhuang coal mine. Core drilling detection and audiofrequency magnetotelluric survey revealed that the goaf was sufficiently filled.

Development of Non-Autoclaved Aerated Concrete by Alkali Activated Phosphorus Slag

2011 ◽  
Vol 250-253 ◽  
pp. 1147-1152 ◽  
Author(s):  
Xiao Jun Jiang ◽  
Yan Yun ◽  
Zhi Hua Hu
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Bulk Density ◽  
Sodium Silicate ◽  
Setting Time ◽  
Liquid Sodium ◽  
Molar Ratio ◽  
Autoclaved Aerated Concrete ◽  
Aerated Concrete ◽  
Alkali Activated

The feasibility of manufacturing non-autoclaved aerated concrete using alkali activated phosphorus slag as a cementitious material was investigated in this paper. Liquid sodium silicate with various modules (the molar ratio between SiO2 and Na2O) was used as alkali activator and a part of phosphorus slag was replaced with fly ash which was used to control the setting time of aerated concrete. The influences of the fly ash, curing procedure, modulus of sodium silicate solution and concentration of alkalis on the compressive strength and bulk density of non-autoclaved aerated concrete have been studied. Moreover, the types of the hydration products were investigated using XRD and SEM. The results indicate that: the compressive strength of aerated concrete was influenced by concentration of alkalis obviously. The compressive strength of 11.9MPa and the bulk density of 806kg/m3 were obtained with an activator of 1.2 modulus of sodium silicate and 6% concentration of alkalis under the circumstance of 60°C curing for 28 days.

scholarly journals Proportion optimization of grouting materials for roadways with soft surrounding mass

2020 ◽  
Author(s):  
Guorui Feng ◽  
Chenliang Hao ◽  
Pengfei Wang
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Silicate ◽  
Raw Materials ◽  
Setting Time ◽  
Reducing Agent ◽  
Mixture Ratio ◽  
Cement Ratio ◽  
Performance Indexes ◽  
Grouting Material

Abstract Severe deformation and failure frequently occur in roadways with soft or weak surrounding rock and have greatly influenced safe and efficient mining of coal in many coal mines. Using portland cement, emery and fly ash as main raw materials, through laboratory tests, effect of water/binder ratio, cement/sand ratio, water/sodium silicate ratio, water reducing agent, fly ash/cement ratio and various performance indexes of grout of fluidity, viscosity, setting time, bleeding rate, compressive strength, concretion rate and various performance indexes were systematically analyzed. An optimized mixture ratio of the main raw materials added in the grouting material proportion was determined through uniform design method, an optimal mixture ratio was determined by regression analysis. The results show that: 1) The flow performance is significantly affected by change of sodium silicate and water reducer, the compressive strength of grouting material increases significantly with increase in emery content, and decreases significantly with increase in water reducer. 2) An optimized mixture ratio among water cement ratio, cement sand ratio, water/sodium silicate ratio, water reducing agent, fly ash/cement ratio in the grouting material is 0.75, 1.2, 8%, 3% and 0.18, respectively. Field test demonstrated that the material has better performance in reinforcing weak and broken rock mass.

scholarly journals Effect of the Sodium Silicate Modulus and Slag Content on Fresh and Hardened Properties of Alkali-Activated Fly Ash/Slag

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 15 ◽  
Author(s):  
Xiaowei Ouyang ◽  
Yuwei Ma ◽  
Ziyang Liu ◽  
Jianjun Liang ◽  
Guang Ye
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Pore Structure ◽  
Heat Release ◽  
Setting Time ◽  
Heat Evolution ◽  
Reaction Products ◽  
Hardened Properties ◽  
Alkali Activated ◽  
Slag Content

This paper presents the results of an experimental study performed to investigate the effect of activator modulus (SiO2/Na2O) and slag addition on the fresh and hardened properties of alkali-activated fly ash/slag (AAFS) pastes. Four activator moduli (SiO2/Na2O), i.e., 0.0, 1.0, 1.5, and 2.0, and five slag-to-binder ratios, i.e., 0, 0.3, 0.5, 0.7, 1.0, were used to prepare AAFS mixtures. The setting time, flowability, heat evolution, compressive strength, microstructure, and reaction products of AAFS pastes were studied. The results showed that the activator modulus and slag content had a combined effect on the setting behavior and workability of AAFS mixtures. Both the activator modulus and slag content affected the types of reaction products formed in AAFS. The coexistence of N–A–S–H gel and C–A–S–H gel was identified in AAFS activated with high pH but low SiO2 content (low modulus). C–A–S–H gel had a higher space-filling ability than N–A–S–H gel. Thus, AAFS with higher slag content had a finer pore structure and higher heat release (degree of reaction), corresponding to a higher compressive strength. The dissolution of slag was more pronounced when NaOH (modulus of 0.0) was applied as the activator. The use of Na2SiO3 as activator significantly refined the pores in AAFS by incorporating soluble Si in the activator, while further increasing the modulus from 1.5 to 2.0 prohibited the reaction process of AAFS, resulting in a lower heat release, coarser pore structure, and reduced compressive strength. Therefore, in view of the strength and microstructure, the optimum modulus is 1.5.

scholarly journals The Use of Borax in Deterring Flash Setting of High Calcium Fly Ash Based Geopolymer

2016 ◽  
Vol 857 ◽  
pp. 416-420 ◽  
Author(s):  
Antoni ◽  
Stephen Wibiatma Wijaya ◽  
Juan Satria ◽  
Agung Sugiarto ◽  
Djwantoro Hardjito
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
Fly Ash ◽  
Chemical Composition ◽  
Setting Time ◽  
Chemical Properties ◽  
Physico Chemical ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Positive Effect

Geopolymer that was made with high CaO content fly ash was found to have higher compressive strength than the low CaO fly ash, using the same mixture composition. This effect could be due to the physico-chemical properties of the fly ash, in respect to its particle size or the chemical composition. Although it was not widely published, the occurrence of flash setting of geopolymer was known to occur when using high CaO content fly ash as the precursor. Geopolymer paste may solidify within minutes after the addition of alkali activators, making it very difficult to cast in big volume. This paper investigate the effect of borax addition to the high calcium fly ash-based geopolymer mixture to reduce the occurrence of flash setting. It was found that the setting time can be extended significantly, with the addition of 5% borax, by mass, of fly ash. The addition of borax also have positive effect on increasing the compressive strength of geopolymer.

Effect of Plasticizers and Water on Properties of HCFA Geopolymers

2017 ◽  
Vol 733 ◽  
pp. 76-79 ◽  
Author(s):  
Ahmad B. Malkawi ◽  
Mohd Fadhil Nuruddin ◽  
Amir Fauzi ◽  
Hashem Al-Mattarneh ◽  
Bashar S. Mohammed
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Tap Water ◽  
Setting Time ◽  
Water Addition ◽  
Final Setting Time ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Different Types ◽  
Hardened Properties

In this study, different types of plasticizers were used to investigate their effects on the fresh and hardened properties of high calcium fly ash geopolymers (HCFA). Modified polycarboxylate polymers (G3) and lignin-based polymers (G1) were used as plasticizing admixtures and the results were compared to the effect of tap water addition. The results showed that all the admixtures used are effective in increasing the workability of the HCFA geopolymers mixtures and the workability increased by 25-48% compared to the control mixtures. However, the use of G3 has adversely affected the strength by a reduction of 20%. While the use of G1 reduced the final setting time by 7% which is critical in the case of HCFA geopolymers where the final setting time occurs within 70 minutes. Water can be considered as the best admixture in terms of cost, setting time, and effect on compressive strength and it can be used where medium workability enhancement is required.

scholarly journals Study on Setting & Strength Characteristic of GGBS based Geopolymer Concrete by Blending of Fly Ash and Metakaoline

2020 ◽  
Vol 13 (1) ◽  
pp. 117-122
Author(s):  
Addepalli Mallinadh Kashyap ◽  
Tanimki Chandra Sekhar Rao ◽  
N.V. Ramana Rao
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Setting Time ◽  
Engineering Properties ◽  
Geopolymer Concrete ◽  
Conventional Concrete ◽  
New Material

Carbon dioxide is liberated in huge amounts by the manufacturing of Portland Pozzolana Cement. Normally, conventional concrete is manufactured with Portland cement, which acts as a binder. The production of cement emits CO2 into the atmosphere, which is a green house gas and causes the environmental pollution. Considering this as a serious environmental problem, there is a need to develop sustainable alternatives to Portland cement utilizing the industrial byproducts such as fly ash, ground granulated blast furnace slag and Metakaoline which are pozzolonic in nature. It has been established that fly ash can replace cement partially. In this context, a new material was developed known as ‖Geopolymer‖. In this study, the various parameters on the short term engineering properties of fresh and hardened properties of Geopolymer Mortar were studied. In the present investigation, cement is replaced by geopolymer source material and water is replaced by alkaline activator consisting of Sodium Silicate and Sodium Hydroxide of molarity (12M). The ratio of sodium silicate to sodium hydroxide adopted was 2.5. The test results showed that final setting time decreases as the GGBS content in the mix increases and also increase in compressive strength. Where as in the case of metakaoline, as the content increases, there is a decrease in compressive strength and setting times of the geopolymer concrete.

The Effect of Dry Mix Sodium Hydroxide onto Workability and Compressive Strength of Geopolymer Paste

2020 ◽  
Vol 12 (9) ◽  
Author(s):  
A. Z. Mohd Ali ◽  
◽  
N. A. Jalaluddin ◽  
N. Zulkiflee ◽  
◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Alkaline Solution ◽  
High Emission ◽  
New Material ◽  
Curing Regime ◽  
Solid Form ◽  
Geopolymer Paste

The production of ordinary Portland cement (OPC) consumes considerable amount of natural resources, energy and at the same time contribute in high emission of CO2 to the atmosphere. A new material replacing cement as binder called geopolymer is alkali-activated concrete which are made from fly ash, sodium silicate and sodium hydroxide (NaOH). The alkaline solution mixed with fly ash producing alternative binder to OPC binder in concrete named geopolymer paste. In the process, NaOH was fully dissolved in water and cooled to room temperature. This study aims to eliminate this process by using NaOH in solid form together with fly ash before sodium silicate liquid and water poured into the mixture. The amount of NaOH solids were based on 10M concentration. The workability test is in accordance to ASTM C230. Fifty cubic mm of the geopolymer paste were prepared which consists of fly ash to alkaline solution ratio of 1: 0.5 and the curing regime of 80℃ for 24 hours with 100% humidity were implemented. From laboratory test, the workability of dry method geopolymer paste were decreased. The compressive strength of the dry mix of NaOH showed 55% and the workability has dropped to 58.4%, it showed strength reduction compared to the wet mix method.

Effect of Chopped Basalt Fiber on the Fresh and Hardened Properties of Fly Ash High Strength Concrete

2014 ◽  
Vol 567 ◽  
pp. 381-386 ◽  
Author(s):  
Nasir Shafiq ◽  
Muhd Fadhil Nuruddin ◽  
Ali Elheber Ahmed Elshekh ◽  
Ahmed Fathi Mohamed Salih
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
High Strength Concrete ◽  
Basalt Fiber ◽  
High Strength ◽  
Progressive Increase ◽  
Test Results ◽  
Strength Concrete ◽  
Hardened Properties ◽  
Chopped Basalt Fiber

In order to improve the mechanical properties of high strength concrete, HSC, several studies have been conducted using fly ash, FA. Researchers have made it possible to achieve 100-150MPa high strength concrete. Despite the popularity of this FAHSC, there is a major shortcoming in that it becomes more brittle, resulting in less than 0.1% tensile strain. The main objective of this work was to evaluate the fresh and hardened properties of FAHSC utilizing chopped basalt fiber stands, CBFS, as an internal strengthening addition material. This was achieved through a series of experimental works using a 20% replacement of cement by FA together with various contents of CBFS. Test results of concrete mixes in the fresh state showed no segregation, homogeneousness during the mixing period and workability ranging from 60 to 110 mm. Early and long terms of compressive strength did not show any improvement by using CBFS; in fact, it decreased. This was partially substituted by the effect of FA. Whereas, the split and flexural strengths of FASHC were significantly improved with increasing the content of CBFS as well as the percentage of the split and flexural tensile strength to the compressive strength. Also, test results showed a progressive increase in the areas under the stress-strain curves of the FAHSC strains after the CBFS addition. Therefore, the brittleness and toughness of the FAHSC were enhanced and the pattern of failure moved from brittle failure to ductile collapse using CBFS. It can be considered that the CBFS is a suitable strengthening material to produce ductile FAHSC.

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