scholarly journals Organic Contaminant-Triggered Self-Healing Soil Mix Cut-Off Wall Materials Incorporating Oil Sorbents

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5802
Author(s):  
Benyi Cao ◽  
Livia Ribeiro de Souza ◽  
Abir Al-Tabbaa
Keyword(s):  
Organic Contaminants ◽  
Liquid Paraffin ◽  
Self Healing ◽  
Novel Approach ◽  
Oil Sorbent ◽  
Oil Sorbents ◽  
The Matrix ◽  
Order Of Magnitude ◽  
Wall Materials ◽  
Soil Mix

Soil mix cut-off walls have been increasingly used for containment of organic contaminants in polluted land. However, the mixed soil is susceptible to deterioration due to aggressive environmental and mechanical stresses, leading to crack-originated damage and requiring costly maintenance. This paper proposed a novel approach to achieve self-healing properties of soil mix cut-off wall materials triggered by the ingress of organic contaminants. Oil sorbent polymers with high absorption and swelling capacities were incorporated in a cementitious grout and mixed with soil using a laboratory-scale auger setup. The self-healing performance results showed that 500 µm-wide cracks could be bridged and blocked by the swollen oil sorbents, and that the permeability was reduced by almost an order of magnitude after the permeation of liquid paraffin. It was shown by micro-CT scan tests that the network formed by the swollen oil sorbents acted as attachments and binder, preventing the cracked mixed soil sample from crumbling, and that the oil sorbents swelled three times in volume and therefore occupied the air space and blocked the cracks in the matrix. These promising results exhibit the potential for the oil sorbents to provide soil mix cut-off walls in organically-contaminated land with self-healing properties and enhanced durability.

Soil Mix Cutoff Wall Materials with Microcapsule-Based Self-Healing Grout

2021 ◽  
Vol 147 (11) ◽  
pp. 04021124
Author(s):  
Benyi Cao ◽  
Livia Souza ◽  
Jian Xu ◽  
Wenting Mao ◽  
Fei Wang ◽  
...  
Keyword(s):  
Self Healing ◽  
Cutoff Wall ◽  
Wall Materials ◽  
Soil Mix

scholarly journals Connectivity matrix model of quantum circuits and its application to distributed quantum circuit optimization

2021 ◽  
Vol 20 (7) ◽  
Author(s):  
Ismail Ghodsollahee ◽  
Zohreh Davarzani ◽  
Mariam Zomorodi ◽  
Paweł Pławiak ◽  
Monireh Houshmand ◽  
...  
Keyword(s):  
Quantum Computation ◽  
Quantum Computer ◽  
Quantum Circuit ◽  
Quantum Circuits ◽  
Connectivity Matrix ◽  
Circuit Optimization ◽  
Novel Approach ◽  
The Matrix ◽  
Minimum Number ◽  
Two Phases

AbstractAs quantum computation grows, the number of qubits involved in a given quantum computer increases. But due to the physical limitations in the number of qubits of a single quantum device, the computation should be performed in a distributed system. In this paper, a new model of quantum computation based on the matrix representation of quantum circuits is proposed. Then, using this model, we propose a novel approach for reducing the number of teleportations in a distributed quantum circuit. The proposed method consists of two phases: the pre-processing phase and the optimization phase. In the pre-processing phase, it considers the bi-partitioning of quantum circuits by Non-Dominated Sorting Genetic Algorithm (NSGA-III) to minimize the number of global gates and to distribute the quantum circuit into two balanced parts with equal number of qubits and minimum number of global gates. In the optimization phase, two heuristics named Heuristic I and Heuristic II are proposed to optimize the number of teleportations according to the partitioning obtained from the pre-processing phase. Finally, the proposed approach is evaluated on many benchmark quantum circuits. The results of these evaluations show an average of 22.16% improvement in the teleportation cost of the proposed approach compared to the existing works in the literature.

Mechanical responses of microencapsulated self-healing cementitious composites under compressive loading based on a micromechanical damage-healing model

2021 ◽  
pp. 105678952110112
Author(s):  
Kaihang Han ◽  
Jiann-Wen Woody Ju ◽  
Yinghui Zhu ◽  
Hao Zhang ◽  
Tien-Shu Chang ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Compressive Strength ◽  
Micromechanical Model ◽  
Cementitious Composites ◽  
Self Healing ◽  
Damage Degree ◽  
Healing Efficiency ◽  
The Matrix ◽  
Healing Agent ◽  
Damage Healing

The cementitious composites with microencapsulated healing agents have become a class of hotspots in the field of construction materials, and they have very broad application prospects and research values. The in-depth study on multi-scale mechanical behaviors of microencapsulated self-healing cementitious composites is critical to quantitatively account for the mechanical response during the damage-healing process. This paper proposes a three-dimensional evolutionary micromechanical model to quantitatively explain the self-healing effects of microencapsulated healing agents on the damage induced by microcracks. By virtue of the proposed 3 D micromechanical model, the evolutionary domains of microcrack growth (DMG) and corresponding compliances of the initial, extended and repaired phases are obtained. Moreover, the elaborate studies are conducted to inspect the effects of various system parameters involving the healing efficiency, fracture toughness and preloading-induced damage degrees on the compliances and stress-strain relations. The results indicate that relatively significant healing efficiency, preloading-induced damage degree and the fracture toughness of polymerized healing agent with the matrix will lead to a higher compressive strength and stiffness. However, the specimen will break owing to the nucleated microcracks rather than the repaired kinked microcracks. Further, excessive higher values of healing efficiency, preloading-induced damage degree and the fracture toughness of polymerized healing agent with the matrix will not affect the compressive strength of the cementitious composites. Therefore, a stronger matrix is required. To achieve the desired healing effects, the specific parameters of both the matrix and microcapsules should be selected prudently.

scholarly journals A novel approach to quantify and locate potential microrefugia using topoclimate, climate stability, and isolation from the matrix

2012 ◽  
Vol 18 (6) ◽  
pp. 1866-1879 ◽  
Author(s):  
Michael B. Ashcroft ◽  
John R. Gollan ◽  
David I. Warton ◽  
Daniel Ramp
Keyword(s):  
Climate Stability ◽  
Novel Approach ◽  
The Matrix

scholarly journals Method for the Microstructural Characterisation of Unidirectional Composite Tapes

2021 ◽  
Vol 5 (10) ◽  
pp. 275
Author(s):  
Nico Katuin ◽  
Daniël M. J. Peeters ◽  
Clemens A. Dransfeld
Keyword(s):  
Voronoi Tessellation ◽  
Unidirectional Composite ◽  
Fibre Volume ◽  
Cross Sectional ◽  
Reinforced Polymer ◽  
Novel Approach ◽  
The Matrix ◽  
Carbon Fibre Reinforced Polymer ◽  
Fibre Reinforced Polymer ◽  
Microstructural Characterisation

The outstanding properties of carbon fibre-reinforced polymer composites are affected by the development of its microstructure during processing. This work presents a novel approach to identify microstructural features both along the tape thickness and through the thickness. Voronoi tessellation-based evaluation of the fibre volume content on cross-sectional micrographs, with consideration of the matrix boundary, is performed. The method is shown to be robust and is suitable to be automated. It has the potential to discriminate specific microstructural features and to relate them to processing behaviour removing the need for manufacturing trials.

scholarly journals Estimation of hepatitis B virus cccDNA persistence in chronic infection using within-host evolutionary rates

2020 ◽  
Author(s):  
Katrina A. Lythgoe ◽  
Sheila F. Lumley ◽  
Jane A. McKeating ◽  
Philippa C. Matthews
Keyword(s):  
Hepatitis B Virus ◽  
Hepatitis B ◽  
Chronic Infection ◽  
Standard Of Care ◽  
Evolutionary Rates ◽  
Mathematical Framework ◽  
Novel Approach ◽  
B Virus ◽  
Order Of Magnitude ◽  
Progressive Liver Disease

AbstractHepatitis B virus (HBV) infection is a major global health problem with over 240 million infected individuals at risk of developing progressive liver disease and hepatocellular carcinoma. HBV is an enveloped DNA virus that establishes its genome as an episomal, covalently closed circular DNA (cccDNA) in the nucleus of infected hepatocytes. Currently available standard-of-care treatments for chronic hepatitis B (CHB) include nucleos(t)ide analogues (NA) that suppress HBV replication but do not target the cccDNA and hence rarely cure infection. There is considerable interest in determining the lifespan of cccDNA molecules to design and evaluate new curative treatments. We took a novel approach to this problem by developing a new mathematical framework to model changes in evolutionary rates during infection which, combined with previously determined within-host evolutionary rates of HBV, we used to determine the lifespan of cccDNA. We estimate that during HBe-antigen positive (HBeAgPOS) infection the cccDNA lifespan is 61 (36-236) days, whereas during the HBeAgNEG phase of infection it is only 26 (16-81) days. We found that cccDNA replicative capacity declined by an order of magnitude between HBeAgPOS and HBeAgNEG phases of infection. Our estimated lifespan of cccDNA is too short to explain the long durations of chronic infection observed in patients on NA treatment, suggesting that either a sub-population of long-lived hepatocytes harbouring cccDNA molecules persists during therapy, or that NA therapy does not suppress all viral replication. These results provide a greater understanding of the biology of the cccDNA reservoir and can aid the development of new curative therapeutic strategies for treating CHB.

Interply Behavior Exhibited in Compliant Filamentary Composite Laminates

1982 ◽  
Vol 55 (4) ◽  
pp. 1078-1094 ◽  
Author(s):  
J. L. Turner ◽  
J. L. Ford
Keyword(s):  
Shear Strain ◽  
Composite Laminates ◽  
Matrix Material ◽  
Matrix Composites ◽  
Efficient Manner ◽  
Strain Behavior ◽  
The Matrix ◽  
Order Of Magnitude ◽  
Extensional Strain ◽  
Interlaminar Shear

Abstract Cord-rubber composite systems allow a visualization of interply shear strain effects because of the compliant nature of the matrix material. A technique termed the pin test was developed to aid this visualization of interply shear strain. The pin test performed on both flat pads and radial tires shows that interlaminar shear strain behavior in both types of specimens is similar, most of the shear strain being confined to a region approximately 10 interly rubber thicknesses from the edge. The observed shear strain is approximately an order of magnitude greater than the applied extensional strain. A simplified mathematical model, called the Kelsey strip, for describing such behavior for a two-ply (±θ) cord-rubber strip has been formulated and demonstrated to be qualitatively correct. Furthermore, this model is capable of predicting trends in both compliant and rigid matrix composites and allows for simplified idealizations. A finite-element code for dealing with such interply effects in a simple but efficient manner predicts qualitatively correct results.

Degradation of recalcitrant organic contaminants by solar photocatalysis

2007 ◽  
Vol 55 (12) ◽  
pp. 119-125 ◽  
Author(s):  
L. Mansouri ◽  
L. Bousselmi ◽  
A. Ghrabi
Keyword(s):  
Organic Contaminants ◽  
Order Kinetic ◽  
Biological Degradation ◽  
Solar Photocatalysis ◽  
Photocatalytic Reactor ◽  
Operational Conditions ◽  
Toc Removal ◽  
The Matrix ◽  
Pre Treatment ◽  
Refractory Organic Pollutants

Biological pre-treated landfill leachates of Djebel Chakir contains some macromolecular organic substances that are resistant to biological degradation. The aim of the present work is to assess the feasibility of removing refractory organic pollutants in biological pre-treated landfill leachate by solar photocatalyse process. Leachate pollutant contents are studied to assess their contribution to leachate pollution and their treatability by solar photocatalyse process. Phenol is chosen as model of pollutants, to evaluate its removal and the efficiency of the photocatalytic system. The experiments were carried out in suspended photocatalytic reactor, using TiO2 Degussa P25, under sunlight illumination (UV-A: 15–31 W/cm2). Under optimum operational conditions, applied to single reactant (phenol), the system presents a TOC removal of 90% (the degradation follows a first-order kinetic). Based on the TOC removal, the results shows that the degradation of biological pre-treated leachate follows a zero-order kinetic. After 5 h of sunlight exposure, 74% of COT is removed. The TOC removal is the best without any correction of the pH and at the TiO2 concentration of 2.5 g/L. The photocatalytic degradation of organic contaminants as well as the formation and disappearance of the by-products were followed by GC/MS. The solar photocatalysis processes induce several modifications of the matrix leading to more biodegradable forms: all the remaining and new compounds generated after the biological pre-treatment of leachate are degraded and other types of organics appear, mainly carboxylic acid, aliphatic hydrocarbons and phtalic acids.

Self-healing organic coatings based on microcapsules – A patent-based review

2021 ◽  
Vol 04 ◽  
Author(s):  
Diego Moreira Schlemper ◽  
Sérgio Henrique Pezzin
Keyword(s):  
Corrosion Protection ◽  
State Of The Art ◽  
Review Article ◽  
The State ◽  
Organic Coatings ◽  
Self Healing ◽  
Future Challenges ◽  
The Matrix ◽  
Healing Agent

: Self-healing coatings are intended to increase long-term durability and reliability and can be enabled by the presence of microcapsules containing a self-healing agent capable of interacting with the matrix and regenerating the system. This review article provides an overview of the state-of-the-art, focusing on the patents published in the field of microcapsule-based self-healing organic coatings, since the early 2000’s. A discussion about coatings for corrosion protection and the different self-healing approaches and mechanisms are also addressed, as well as future challenges and expectations for this kind of coatings.

scholarly journals Efficiently self-healing boronic ester crystals

2020 ◽  
Vol 11 (10) ◽  
pp. 2606-2613 ◽  
Author(s):  
Patrick Commins ◽  
Marieh B. Al-Handawi ◽  
Durga Prasad Karothu ◽  
Gijo Raj ◽  
Panče Naumov
Keyword(s):  
Organic Crystal ◽  
Self Healing ◽  
Boronic Ester ◽  
Order Of Magnitude

Organic crystal is described that can be bent plastically and twisted elastically, and can self-heal to 67%, an efficiency that is an order-of-magnitude higher compared to the only previously reported example.

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