scholarly journals Effect of Al2TiO5 Content and Sintering Temperature on the Microstructure and Residual Stress of Al2O3–Al2TiO5 Ceramic Composites

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7624
Author(s):  
Kunyang Fan ◽  
Wenhuang Jiang ◽  
Jesús Ruiz-Hervias ◽  
Carmen Baudín ◽  
Wei Feng ◽  
...  
Keyword(s):  
Residual Stress ◽  
Residual Stresses ◽  
Sintering Temperature ◽  
Rietveld Analysis ◽  
Ceramic Composites ◽  
Lattice Parameter ◽  
X Ray Diffraction ◽  
The Mean ◽  
The Individual ◽  
Al2o3 Matrix

A series of Al2O3–Al2TiO5 ceramic composites with different Al2TiO5 contents (10 and 40 vol.%) fabricated at different sintering temperatures (1450 and 1550 °C) was studied in the present work. The microstructure, crystallite structure, and through-thickness residual stress of these composites were investigated by scanning electron microscopy, X-ray diffraction, time-of-flight neutron diffraction, and Rietveld analysis. Lattice parameter variations and individual peak shifts were analyzed to calculate the mean phase stresses in the Al2O3 matrix and Al2TiO5 particulates as well as the peak-specific residual stresses for different hkl reflections of each phase. The results showed that the microstructure of the composites was affected by the Al2TiO5 content and sintering temperature. Moreover, as the Al2TiO5 grain size increased, microcracking occurred, resulting in decreased flexure strength. The sintering temperatures at 1450 and 1550 °C ensured the complete formation of Al2TiO5 during the reaction sintering and the subsequent cooling of Al2O3–Al2TiO5 composites. Some decomposition of AT occurred at the sintering temperature of 1550 °C. The mean phase residual stresses in Al2TiO5 particulates are tensile, and those in the Al2O3 matrix are compressive, with virtually flat through-thickness residual stress profiles in bulk samples. Owing to the thermal expansion anisotropy in the individual phase, the sign and magnitude of peak-specific residual stress values highly depend on individual hkl reflection. Both mean phase and peak-specific residual stresses were found to be dependent on the Al2TiO5 content and sintering temperature of Al2O3–Al2TiO5 composites, since the different developed microstructures can produce stress-relief microcracks. The present work is beneficial for developing Al2O3–Al2TiO5 composites with controlled microstructure and residual stress, which are crucial for achieving the desired thermal and mechanical properties.

scholarly journals Evaluation of Weld Filler Alloying Concepts for Residual Stress Engineering by Means of Neutron and X-Ray Diffraction

2014 ◽  
Vol 996 ◽  
pp. 469-474 ◽  
Author(s):  
Arne Kromm
Keyword(s):  
Residual Stress ◽  
Residual Stresses ◽  
Stress Reduction ◽  
Maximum Stress ◽  
Lattice Parameter ◽  
Filler Materials ◽  
X Ray Diffraction ◽  
X Ray ◽  
Stress Control ◽  
Surface Areas

Novel Low Transformation Temperature (LTT-) filler materials are specially designed for controlling residual stresses by means of adjusted martensite formation already during welding. Different alloying concepts compete for maximum stress reduction. Two newly developed LTT-alloys were evaluated concerning their potential for residual stress control. For this purpose residual stresses were determined in the surface and also in sub-surface areas of welded joints using X-ray diffraction and Neutron diffraction taking into account local variations of the unstrained lattice parameter.

A Comparison of X-Ray and Neutron Diffraction Measurement of Lattice Parameters for the Determination of Residual Stress and Chemical Composition in Zirconium Alloy Tubes

1991 ◽  
Vol 35 (A) ◽  
pp. 475-480
Author(s):  
M. Griffiths ◽  
J.E. Winegar ◽  
J.F. Mecke ◽  
T.M. Holden ◽  
R.A. Holt
Keyword(s):  
Residual Stress ◽  
Neutron Diffraction ◽  
Residual Stresses ◽  
Zirconium Alloys ◽  
Lattice Parameter ◽  
Lattice Parameters ◽  
Surface Relaxation ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
X Ray

AbstractIntergranular residual stresses can exist in zirconium alloys, especially when there is a large distribution of grain orientations. The stresses result from the anisotropic plasticity and thermal expansion of the hexagonal close-packed crystal structure of α-zirconium. Apart from complicating the characterisation of materials using lattice parameter measurements, the intergranular stresses can significantly affect material behaviour, especially in nuclear reactor environments, and there is therefore a great deal of interest in their measurement.The effects of specimen preparation and surface relaxation on X-ray diffraction measurements of lattice parameters of zirconium alloys have been investigated by comparing bulk neutron diffraction with X-ray diffraction on identical materials. The results show that: (i) intergranular or interphase residual stresses exist in dual-phase Zr-2.5Nb pressure tubes; (ii) the stresses normal to the surface of an X-ray diffraction specimen are not relieved completely when there are intergranular residual stresses in the material. One can conclude that intergranular stresses have to be considered when determining chemical compositions from lattice parameter measurements and also when measuring macroscopic residual stress using X-ray diffraction.

Residual Stresses in Ultrathin Metal Sublayers Within Au/Ni Multilayers

1997 ◽  
Vol 475 ◽  
Author(s):  
S. Labat ◽  
P. Gergaud ◽  
O. Thomas ◽  
B. Gilles ◽  
A. Marty ◽  
...  
Keyword(s):  
Residual Stress ◽  
Residual Stresses ◽  
Residual Strain ◽  
Strain State ◽  
Lattice Parameter ◽  
Metallic Multilayers ◽  
X Ray Diffraction ◽  
X Ray ◽  
Residual Strains ◽  
Far From Equilibrium

ABSTRACTMetallic Multilayers (MLs) have attracted a considerable interest during these last years because of their unusual properties. In small periods ML's (a few nm) the high density of interfaces give rise to structures very far from equilibrium. Au/Ni multilayers have been grown in the (111) orientation by M.B.E. on Si(100) via a Cu(100) buffer layer. Two different parameters have been studied: the Au:Ni ratio at constant (4 nm) superperiod and the superperiod at constant (1:1) Au:Ni ratio. The full strain state of Au and of Ni has been determined via x-ray diffraction measurements. The high lattice parameter misfit beween Au and Ni (14%) implies that all the layers are partially relaxed. Residual strains as high as several % are encountered. The residual strain in the Au layers is clearly correlated with their thickness. A residual stress as high as 3.9 GPa is determined in the thinner layers.

Problems Associated with Kα Doublet in Residual Stress Measurements

1979 ◽  
Vol 23 ◽  
pp. 333-339
Author(s):  
S. K. Gupta ◽  
B. D. Cullity
Keyword(s):  
Residual Stress ◽  
Silicon Powder ◽  
Lattice Parameter ◽  
Diffraction Peak ◽  
Parameter Determination ◽  
X Ray Diffraction ◽  
X Ray ◽  
Analysis Techniques ◽  
The Difference ◽  
Similar Accuracy

Since the measurement of residual stress by X-ray diffraction techniques is dependent on the difference in angle of a diffraction peak maximum when the sample is examined consecutively with its surface at two different angles to the diffracting planes, it is important that these diffraction angles be obtained precisely, preferably with an accuracy of ± 0.01 deg. 2θ. Similar accuracy is desired in precise lattice parameter determination. In such measurements, it is imperative that the diffractometer be well-aligned. It is in the context of diffractometer alignment with the aid of a silicon powder standard free of residual stress that the diffraction peak analysis techniques described here have been developed, preparatory to residual stress determinations.

Effect of Sintering Temperature on Microstructure and Mechanical Properties of Al2O3-TiC-ZrO2 Ceramic Composites

2012 ◽  
Vol 476-478 ◽  
pp. 1031-1035
Author(s):  
Wei Min Liu ◽  
Xing Ai ◽  
Jun Zhao ◽  
Yong Hui Zhou
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Fracture Toughness ◽  
Flexural Strength ◽  
Relative Density ◽  
Sintering Temperature ◽  
Ceramic Composites ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

Al2O3-TiC-ZrO2ceramic composites (ATZ) were fabricated by hot-pressed sintering. The phases and microstructure of the composites were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The relative density and mechanical properties (flexural strength, fracture toughness and Vicker’s hardness) of the composites were tested. The results show that the microstructure of the composites was the gray core-white rim. With the increase of sintering temperature, the relative density and mechanical properties of the composites increased first and then decreased. The composite sintered at 1705°C has the highest synthetical properties, and its relative density, flexural strength, fracture toughness and Vickers hardness are 98.3%,970MPa,6.0 MPa•m1/2and 20.5GPa, respectively.

Characterization of bulk crystals of transition metal doped ZnO for spintronic applications

2003 ◽  
Vol 799 ◽  
Author(s):  
M. H. Kane ◽  
R. Varatharajan ◽  
Z. C. Feng ◽  
S. Kandoor ◽  
J. Nause ◽  
...  
Keyword(s):  
Transition Metal ◽  
Lattice Parameter ◽  
X Ray Diffraction ◽  
Absorption Bands ◽  
Growth Technique ◽  
Undoped Material ◽  
Doped Zno ◽  
Metal Doped ◽  
The Individual

ABSTRACTIn this work, we report on the material properties of ZnO doped with Mn, Co, and Fe grown by a modified melt growth technique. X-ray diffraction measurements show that transition metals can be incorporated on Zn sites; an increase in the lattice parameter is apparent with increasing doping level. UV-visible transmission and reflectance measurements have also been performed. Absorption bands in the visible regime are distinctive to the individual transition metal dopants. A noticeable shift in the optical band edge has been observed from these Mn/Co/Fe-doped ZnO crystals in comparison with the undoped material. ZnO may also provide a suitable platform for the incorporation of transition metal elements through high temperature near equilibrium growth processes; however, further work is required in order to employ these materials for spintronic applications.

Elaboration, Structure and Mössbauer Spectroscopy of Nanostructured Fe100−xSix Powders Elaborated by Mechanical Alloying

SPIN ◽  
2017 ◽  
Vol 07 (02) ◽  
pp. 1750002 ◽  
Author(s):  
M. Hemmous ◽  
A. Guittoum
Keyword(s):  
Magnetic Field ◽  
Solid Solution ◽  
Mechanical Alloying ◽  
Hyperfine Magnetic Field ◽  
Lattice Parameter ◽  
X Ray Diffraction ◽  
X Ray ◽  
Grain Sizes ◽  
The Mean ◽  
Xrd Studies

We have studied the effect of the silicon concentration on the structural and hyperfine properties of nanostructured Fe[Formula: see text]Six powders ([Formula: see text], 20, 25 and 30[Formula: see text]at.%) prepared by mechanical alloying. The X-ray diffraction (XRD) studies indicated that after 72[Formula: see text]h of milling, the solid solution bcc-[Formula: see text]-Fe(Si) is formed. The grain sizes, [Formula: see text]D[Formula: see text] (nm), decreases with increasing Si concentration and reaches a minimum value of 11[Formula: see text]nm. We have found that the lattice parameter decreases with increasing Si concentration. The changes in values are attributed to the substitutional dissolution of Si in Fe matrix. From the adjustment of Mössbauer spectra, we have shown that the mean hyperfine magnetic field, [Formula: see text]H[Formula: see text] (T), decreases with increasing Si concentration. The substitutional dependence of [Formula: see text]H[Formula: see text] (T) can be attributed to the effect of p electrons Si influencing electrons d of Fe.

Residual stresses in Al2O3/Y-TZP Ceramic Laminates Fabricated by Tape and Slip Casting

2008 ◽  
Vol 571-572 ◽  
pp. 327-332 ◽  
Author(s):  
Jesus Ruiz-Hervias ◽  
Giovanni Bruno ◽  
Jonas Gurauskis ◽  
A.J. Sanchez-Herencia ◽  
C. Baudin
Keyword(s):  
Residual Stress ◽  
Neutron Diffraction ◽  
Residual Stresses ◽  
Volume Fraction ◽  
Tape Casting ◽  
Slip Casting ◽  
Ceramic Composites ◽  
Processing Route ◽  
Alumina Matrix ◽  
Stress Profiles

Residual stress profiles were measured by neutron diffraction in Al2O3/Y-TZP ceramic composites containing 5 and 40 vol.% Y-TZP fabricated by conventional slip casting and by a novel tape casting route. Residual stresses in the zirconia are tensile and increase as its volume fraction decreases. For the alumina matrix, residual stress is compressive and increases with the zirconia volume fraction. In the composite with 5 vol.% zirconia, the processing route does not have an influence on residual stresses. However, in the composite with 40 vol.% zirconia, residual stresses are different in the samples obtained by both processing routes.

Structure of Carbonated Hydroxyapatite Based on Rietveld Method

2008 ◽  
Vol 368-372 ◽  
pp. 1187-1189
Author(s):  
Xu Ran ◽  
Jun Guo Ran ◽  
Li Gou ◽  
Ji Yong Chen ◽  
Jiao Min Luo
Keyword(s):  
Crystal Structure ◽  
Sintering Temperature ◽  
Rietveld Method ◽  
Rietveld Analysis ◽  
Structure Parameters ◽  
X Ray Diffraction ◽  
Carbonated Hydroxyapatite ◽  
X Ray ◽  
Quantitative Results ◽  
Distortion Index

The crystalline structures of B-type carbonated hydroxyapatite (CHA) powders sintered at 700, 900 and 1100°C, respectively, were studied by Rietveld analysis of powder X-ray diffraction (XRD) data. A series of structure parameters, including lattice parameters (a and c), bond length and the distortion index of PO4 tetrahedron (Dind) were calculated by Rietveld method to characterize the fine structure of CHA. The broadening effect of XRD reflections was separated to calculate the micro-strain and crystalline size. The results showed that CHA become more stable with the increase of sintering temperature, but the CO3 2- is almost lost at temperature of 1100°C. The quantitative results about crystal structure of CHA based on crystalline structure simulated by Rietveld method are obtained.

scholarly journals Strategy of Residual Stress Determination on Selective Laser Melted Al Alloy Using XRD

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 451 ◽  
Author(s):  
Yujiong Chen ◽  
Hua Sun ◽  
Zechen Li ◽  
Yi Wu ◽  
Yakai Xiao ◽  
...  
Keyword(s):  
Residual Stress ◽  
Surface Roughness ◽  
Residual Stresses ◽  
High Surface ◽  
Al Alloy ◽  
X Ray Diffraction ◽  
Scanning Strategy ◽  
Surface Distribution ◽  
Finished Surface ◽  
Microstructural Morphology

Selective laser melting (SLM) is known to generate large and anisotropic residual stresses in the samples. Accurate measurement of residual stresses on SLM-produced samples is essential for understanding the residual stress build-up mechanism during SLM, while a dramatic fluctuation can be observed in the residual stress values reported in the literature. On the basis of studying the influence of surface roughness on residual stress measured using X-ray diffraction (XRD), we propose a procedure coupling XRD technique with pretreatment consisting of mechanical polishing and chemical etching. The results highlight that residual stresses measured using XRD on as-built SLM-produced samples with high surface roughness are significantly lower than those measured on samples with finished surface, which is due to the stress relaxation on the spiked surface of as-built samples. Surface distribution of residual stresses and the effect of scanning strategy were systematically investigated for SLM-produced AlSi10Mg samples. Microstructural morphology was observed at the interface between sample and building platform and was linked to the surface distribution of residual stresses. This procedure can help us accurately measure the residual stresses in SLM-produced samples and thus better understand its build-up mechanism during the SLM process.

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