scholarly journals Al-1.5Fe-xLa Alloys for Lithium-Ion Battery Package

Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 890 ◽  
Author(s):  
Rong Zhang ◽  
Dongyan Ding ◽  
Wenlong Zhang ◽  
Yongjin Gao ◽  
Zhanlin Wu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Corrosion Resistance ◽  
Lithium Ion Battery ◽  
Annealing Temperature ◽  
Electrochemical Impedance ◽  
Annealing Treatment ◽  
Lithium Ion ◽  
Second Phase ◽  
High Fraction ◽  
Mechanical Properties And Corrosion

Al foil with high formability and corrosion resistance is highly desired for lithium-ion battery soft packaging. Annealing treatment has a significant impact on the performance of soft packaging Al foil. The effects of both La content and the annealing temperature on the microstructure, mechanical properties, and corrosion behavior of Al-1.5Fe-La alloy was investigated through optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), tensile testing, potentiodynamic polarization testing, and electrochemical impedance spectroscopy (EIS) testing. A higher addition of La resulted in the formation of AlFeLa particles and a refinement of the Fe-rich second phase. The Al-1.5Fe-0.25La alloy had a higher formability and corrosion resistance than the Al-1.5Fe-0.1La alloy. Microstructure analysis indicated that recovery, recrystallization, and grain growth successively occurred in the Al-Fe-La alloy with the increase of the annealing temperature from 200 °C to 250 and 380 °C. After annealing at 250 °C, the Al-Fe-La alloys had the highest corrosion resistance due to refined grain and a high fraction of small-angle grain boundaries.

scholarly journals Effect of Al Element on the Microstructure and Properties of Cu-Ni-Fe-Mn Alloys

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1777 ◽  
Author(s):  
Ran Yang ◽  
Jiuba Wen ◽  
Yanjun Zhou ◽  
Kexing Song ◽  
Zhengcheng Song
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Corrosion Property ◽  
Artificial Seawater ◽  
Second Phase ◽  
Corrosion Properties ◽  
Transmission Electron ◽  
Mechanical And Corrosion Properties ◽  
Mechanical Properties And Corrosion ◽  
Peak Value

The effects of aluminum on the mechanical properties and corrosion behavior in artificial seawater of Cu-Ni-Fe-Mn alloys were investigated. Cu-7Ni-xAl-1Fe-1Mn samples, consisting of 0, 1, 3, 5, and 7 wt % aluminum along with the same contents of other alloying elements (Ni, Fe, and Mn), were prepared. The microstructure of Cu-7Ni-xAl-1Fe-1Mn alloy was analyzed by Transmission Electron Microscopy (TEM), and its corrosion property was tested by an electrochemical system. The results show that the mechanical and corrosion properties of Cu-7Ni-xAl-1Fe-1Mn alloy have an obvious change with the aluminum content. The tensile strength has a peak value of 395 MPa by adding 3 wt % aluminum in the alloy. Moreover, the corrosion rate in artificial seawater of Cu-7Ni-3Al-1Fe-1Mn alloy is 0.0215 mm/a which exhibits a better corrosion resistance than the commercially used UNS C70600. It is confirmed that the second-phase transformation of Cu-7Ni-xAl-1Fe-1Mn alloy follows the sequence of α solid solution → Ni3Al → Ni3Al + NiAl → Ni3Al + NiAl3. The electrochemical impedance spectroscopy (EIS) shows that the adding element aluminum in the Cupronickel can improve the corrosion resistance of Cu-7Ni-xAl-1Fe-1Mn alloy.

scholarly journals Characterization of the Compressive Load on a Lithium-Ion Battery for Electric Vehicle Application

Machines ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 71
Author(s):  
Seyed Saeed Madani ◽  
Erik Schaltz ◽  
Søren Knudsen Kær
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Electric Vehicles ◽  
Large Scale ◽  
Electrochemical Impedance ◽  
Applied Pressure ◽  
Lithium Ion ◽  
Battery Cells

Lithium-ion batteries are being implemented in different large-scale applications, including aerospace and electric vehicles. For these utilizations, it is essential to improve battery cells with a great life cycle because a battery substitute is costly. For their implementation in real applications, lithium-ion battery cells undergo extension during the course of discharging and charging. To avoid disconnection among battery pack ingredients and deformity during cycling, compacting force is exerted to battery packs in electric vehicles. This research used a mechanical design feature that can address these issues. This investigation exhibits a comprehensive description of the experimental setup that can be used for battery testing under pressure to consider lithium-ion batteries’ safety, which could be employed in electrified transportation. Besides, this investigation strives to demonstrate how exterior force affects a lithium-ion battery cell’s performance and behavior corresponding to static exterior force by monitoring the applied pressure at the dissimilar state of charge. Electrochemical impedance spectroscopy was used as the primary technique for this research. It was concluded that the profiles of the achieved spectrums from the experiments seem entirely dissimilar in comparison with the cases without external pressure. By employing electrochemical impedance spectroscopy, it was noticed that the pure ohmic resistance, which is related to ion transport resistance of the separator, could substantially result in the corresponding resistance increase.

scholarly journals Effect of Mn Content and Solution Annealing Temperature on the Corrosion Resistance of Stainless Steel Alloys

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Ihsan-ul-Haq Toor
Keyword(s):  
Corrosion Resistance ◽  
Annealing Temperature ◽  
Electrochemical Impedance ◽  
Austenitic Stainless Steels ◽  
Electrochemical Tests ◽  
Linear Polarization Resistance ◽  
Ni Content ◽  
Different Temperatures ◽  
Acidic Chloride ◽  
Mn Content

The corrosion behavior of two specially designed austenitic stainless steels (SSs) having different Nickel (Ni) and Manganese (Mn) contents was investigated. Prior to electrochemical tests, SS alloys were solution-annealed at two different temperatures, that is, at 1030°C for 2 h and 1050°C for 0.5 h. Potentiodynamic polarization (PD) tests were carried out in chloride and acidic chloride, whereas linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) was performed in 0.5 M NaCl solution at room temperature. SEM/EDS investigations were carried out to study the microstructure and types of inclusions present in these alloys. Experimental results suggested that the alloy with highest Ni content and annealed at 1050°C/0.5 hr has the highest corrosion resistance.

Study of Corrosion Behavior of Conventional and Nanostructured WC-Co HVOF Sprayed Coats

2010 ◽  
Vol 64 ◽  
pp. 13-18 ◽  
Author(s):  
Shahin Khameneh Asl ◽  
Mohammad Reza Saghi Beyragh ◽  
Mahdi Ghassemi Kakroudi
Keyword(s):  
Electron Microscopy ◽  
Heat Treatment ◽  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Heat Treating ◽  
Crystalline Phases ◽  
Chemical Test ◽  
Transmission Electron ◽  
Hvof Spray ◽  
Wear And Corrosion Resistance

Interest in nanomaterials has increased in recent years. This is due to the potential of size reduction to nanometric scale to provide properties of materials such as hardness, toughness, wear, and corrosion resistance. The current study is focused on WC-Co cermet coats, materials that are extensively used in applications requiring wear resistance. In this work, WC-17Co powder was thermally sprayed onto mild steel using High Velocity Oxy Fuel (HVOF) spray technique. The nanostructured specimen was produced from sprayed sample by heat-treating at 1100°C in a vacuum chamber. Their structures were studied by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Polarization and electrochemical impedance spectroscopy (EIS) tests were performed on the both types of coated samples in 3.5% NaCl solution. The amorphous phase in WC-17Co coating was transformed to crystalline phases by heat treatment at high temperatures. The heat treatment of these coatings at high temperature also resulted in partially dissolution of WC particles and formation of new crystalline phases. Generation of these phases produced the nanostructured coating with better mechanical properties. Comparative electro chemical test results showed that, the heat treatment could improve corrosion resistance of the nanostructured WC-17Co coat than the as sprayed coats.

PM-02 Analysis of Lithium Ion Battery Materials Using Statistical Machine Learning and Image Processing of Electron Microscopy Data

Microscopy ◽  
2019 ◽  
Vol 68 (Supplement_1) ◽  
pp. i35-i35
Author(s):  
Hiromochi Tanaka ◽  
Tetsushi Watari ◽  
Takahiro Tsubouchi ◽  
Hisao Yamashige ◽  
Takashi Kato ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Machine Learning ◽  
Image Processing ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Statistical Machine Learning ◽  
Battery Materials ◽  
Electron Microscopy Data ◽  
Microscopy Data

scholarly journals Parameterization and Validation of an Electrochemical Thermal Model of a Lithium-Ion Battery

Batteries ◽  
2019 ◽  
Vol 5 (3) ◽  
pp. 62 ◽  
Author(s):  
Liebig ◽  
Gupta ◽  
Kirstein ◽  
Schuldt ◽  
Agert
Keyword(s):  
Lithium Ion Battery ◽  
Heat Dissipation ◽  
Electrochemical Impedance ◽  
Coupled Model ◽  
Lithium Ion ◽  
Open Circuit ◽  
Battery Cell ◽  
Model Parameterization ◽  
Parameterized Model ◽  
The Individual

The key challenge in developing a physico-chemical model is the model parameterization. The paper presents a strategic model parameterization procedure, parameter values, and a developed model that allows simulating electrochemical and thermal behavior of a commercial lithium-ion battery with high accuracy. Steps taken are the analysis of geometry details by opening a battery cell under argon atmosphere, building upon reference data of similar material compositions, incorporating cell balancing by a quasi-open-circuit-voltage experiment, and adapting the battery models reaction kinetics behavior by comparing experiment and simulation of an electrochemical impedance spectroscopy and hybrid pulse power characterization. The electrochemical-thermal coupled model is established based on COMSOL Multiphysics® platform (Stockholm, Sweden) and validated via experimental methods. The parameterized model was adopted to analyze the heat dissipation sources based on the internal states of the battery at different operation modes. Simulation in the field of thermal management for lithium-ion batteries highly depends on state of charge-related thermal issues of the incorporated cell composition. The electrode balancing is an essential step to be performed in order to address the internal battery states realistically. The individual contribution of the cell components heat dissipation has significant influence on the temperature distribution pattern based on the kinetic and thermodynamic properties.

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