scholarly journals Structural Identification between Phthalazine-1,4-Diones and N-Aminophthalimides via Vilsmeier Reaction: Nitrogen Cyclization and Tautomerization Study

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2907
Author(s):  
Cheng-Yen Chung ◽  
Ching-Chun Tseng ◽  
Sin-Min Li ◽  
Shuo-En Tsai ◽  
Hui-Yi Lin ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Structural Identification ◽  
Experimental Results ◽  
The Other ◽  
Vilsmeier Reaction ◽  
Cyclization Reactions ◽  
Reaction Conditions ◽  
Other Hand ◽  
Structural Divergence ◽  
Selective Formation

N-aminophthalimides and phthalazine 1,4-diones were synthesized from isobenzofuran-1,3-dione, isoindoline-1,3-dione, furo [3,4-b] pyrazine-5,7-dione, or 1H-pyrrolo [3,4-c] pyridine-1,3-dione with monohydrate hydrazine to carry out the 5-exo or 6-endo nitrogen cyclization under the different reaction conditions. Based on the control experimental results, 6-endo thermodynamic hydrohydrazination and kinetical 5-exo cyclization reactions were individually selective formation. Subsequently, Vilsmeier amidination derivatization was successfully developed to probe the structural divergence between N-aminophthalimide 2 and phthalazine 1,4-dione 3. On the other hand, the best tautomerization of N-aminophthalimide to diazinone was also determined under acetic acid mediated solution.

scholarly journals Synthesis of spiro[dihydropyridine-oxindoles] via three-component reaction of arylamine, isatin and cyclopentane-1,3-dione

2013 ◽  
Vol 9 ◽  
pp. 8-14 ◽  
Author(s):  
Yan Sun ◽  
Jing Sun ◽  
Chao-Guo Yan
Keyword(s):  
Acetic Acid ◽  
Reaction Mechanism ◽  
Room Temperature ◽  
The Other ◽  
Other Hand ◽  
Three Component Reaction ◽  
High Yields

A fast and convenient protocol for the synthesis of novel spiro[dihydropyridine-oxindole] derivatives in satisfactory yields was developed by the three-component reactions of arylamine, isatin and cyclopentane-1,3-dione in acetic acid at room temperature. On the other hand the condensation of isatin with two equivalents of cyclopentane-1,3-dione gave 3,3-bis(2-hydroxy-5-oxo-cyclopent-1-enyl)oxindole in high yields. The reaction mechanism and substrate scope of this novel reaction is briefly discussed.

Natural Vulcanization Accelerators in Hevea Latex

1948 ◽  
Vol 21 (4) ◽  
pp. 853-859
Author(s):  
R. F. A. Altman
Keyword(s):  
Amino Acids ◽  
Experimental Results ◽  
The Other ◽  
Active Nitrogen ◽  
Nitrogen Bases ◽  
Other Hand ◽  
Decomposition Processes ◽  
Volatile Products ◽  
Nitrogenous Substances ◽  
The One

Abstract As numerous investigators have shown, some of the nonrubber components of Hevea latex have a decided accelerating action on the process of vulcanization. A survey of the literature on this subject points to the validity of certain general facts. 1. Among the nonrubber components of latex which have been investigated, certain nitrogenous bases appear to be most important for accelerating the rate of vulcanization. 2. These nitrogen bases apparently occur partly naturally in fresh latex, and partly as the result of putrefaction, heating, and other decomposition processes. 3. The nitrogen bases naturally present in fresh latex at later stages have been identified by Altman to be trigonelline, stachhydrine, betonicine, choline, methylamine, trimethylamine, and ammonia. These bases are markedly active in vulcanization, as will be seen in the section on experimental results. 4. The nitrogenous substances formed by the decomposition processes have only partly been identified, on the one hand as tetra- and pentamethylene diamine and some amino acids, on the other hand as alkaloids, proline, diamino acids, etc. 5. It has been generally accepted that these nitrogenous substances are derived from the proteins of the latex. 6. Decomposition appears to be connected with the formation of a considerable amount of acids. 7. The production of volatile nitrogen bases as a rule accompanies the decomposition processes. These volatile products have not been identified. 8. The active nitrogen bases, either already formed or derived from complex nitrogenous substances, seem to be soluble in water but only slightly soluble in acetone.

scholarly journals Comparison of the Fungicidal Properties of Different Humectants in a Tobacco Blend / Vergleich der fungistatischen Wirkung verschiedener Feuchthaltemittel bei einer ungesoßten Tabakmischung

1966 ◽  
Vol 3 (7) ◽  
Author(s):  
H. van Nooy
Keyword(s):  
Experimental Results ◽  
The Other ◽  
Other Hand ◽  
Tobacco Treatment

AbstractThe experimental results indicated in the present paper reveal that among all humectants admitted 1,3-butyleneglycol alone has marked fungicidal properties satisfying the requirements of practical tobacco treatment, and that, on the other hand, diethyleneglycol and glycerine practically do not have such qualities

scholarly journals Elastic Properties of Magnetorheological Elastomers in a Heterogeneous Uniaxial Magnetic Field

2018 ◽  
Vol 19 (10) ◽  
pp. 3045 ◽  
Author(s):  
Takehito Kikuchi ◽  
Yusuke Kobayashi ◽  
Mika Kawai ◽  
Tetsu Mitsumata
Keyword(s):  
Magnetic Field ◽  
Elastic Properties ◽  
Uniform Magnetic Field ◽  
Large Strain ◽  
Small Strain ◽  
Experimental Results ◽  
The Other ◽  
Magnetorheological Elastomers ◽  
Other Hand ◽  
Strain Model

Magnetorheological elastomers (MREs) are stimulus-responsive soft materials that consist of polymeric matrices and magnetic particles. In this study, large-strain response of MREs with 5 vol % of carbonyl iron (CI) particles is experimentally characterized for two different conditions: (1) shear deformation in a uniform magnetic field; and (2), compression in a heterogeneous uniaxial magnetic field. For condition (1), dynamic viscoelastic measurements were performed using a rheometer with a rotor disc and an electric magnet that generated a uniform magnetic field on disc-like material samples. For condition (2), on the other hand, three permanent magnets with different surface flux densities were used to generate a heterogeneous uniaxial magnetic field under cylindrical material samples. The experimental results were mathematically modeled, and the relationship between them was investigated. We also used finite-element method (FEM) software to estimate the uniaxial distributions of the magnetic field in the analyzed MREs for condition (2), and developed mathematical models to describe these phenomena. By using these practicable techniques, we established a simple macroscale model of the elastic properties of MREs under simple compression. We estimated the elastic properties of MREs in the small-strain regime (neo–Hookean model) and in the large-strain regime (Mooney–Rivlin model). The small-strain model explains the experimental results for strains under 5%. On the other hand, the large-strain model explains the experimental results for strains above 10%.

Effect of Manganese Addition on Strength and Fracture Toughness in Mg-6Al-1Zn Alloy

2006 ◽  
Vol 306-308 ◽  
pp. 857-862 ◽  
Author(s):  
Taisuke Sasaki ◽  
Tokuteru Uesugi ◽  
Yorinobu Takigawa ◽  
Kenji Higashi
Keyword(s):  
Fracture Toughness ◽  
Magnesium Alloy ◽  
Yield Strength ◽  
Ductile Fracture ◽  
Manganese Content ◽  
Experimental Results ◽  
The Other ◽  
Excessive Amount ◽  
Void Coalescence ◽  
Other Hand

The effect of manganese on strength and fracture toughness was investigated using five kinds of Mg-6Al-1Zn alloys. From the experimental results, the yield strength increased with increasing in manganese content until manganese content reached 0.14 wt. %. On the other hand, further increase in yield strength was not observed in case larger than 0.14 % of manganese was added. In addition, fracture toughness decreases with increasing manganese content. Fracture of magnesium alloy was ductile fracture by void coalescence. Adding excessive amount of manganese caused the increase in the presence of inclusions. This kind of particle easily became the nucleus of microvoid. As a conclusion, manganese should be added so that coarse manganese-bearing particle is not formed. Thus, 0.14 wt. % of manganese should be added to Mg-6Al-1Zn alloy in order to develop the alloy with well-balanced relationship between strength and fracture toughness.

Effects of Mandarin Cultivar on Quality of Mandarin Juice

2008 ◽  
Vol 14 (4) ◽  
pp. 307-313 ◽  
Author(s):  
F. Beltrán ◽  
A.J. Perez-López ◽  
J.M. López-Nicolás ◽  
A.A. Carbonell-Barrachina
Keyword(s):  
Vitamin C ◽  
Volatile Compounds ◽  
Experimental Results ◽  
The Other ◽  
Total Volatile ◽  
Color Coordinates ◽  
Juice Processing ◽  
Other Hand ◽  
Cielab Color

Eight mandarin cultivars have been analyzed for their content of vitamin C, minerals (Ca, Mg, K, Na, Fe, Cu, Mn, and Zn), CIELab color coordinates (L*, a*, b*, C*, and h ab), total volatile compounds content and sensory aroma intensity of juice. Experimental results proved that no important enough differences were found in the minerals contents to decide which mandarin cultivar was of higher quality. Clemenules provided the darkest juice with the highest vitamin C content and with the most intense mandarin aroma. On the other hand, Nova and Hernandina mandarin could be considered as the worst cultivars for juice production. Finally if Clemenules mandarins were not available for juice processing, Orogrande, Clemenpons, Ellendale, and Marisol could also be good options.

Synthesen von Heterocyclen, CCIV1 Reaktionen mit cyclischen Oxalylverbindungen, XIX2 Eine einfache Synthese von 5-Benzoyl-6-phenyl-1.3-dioxin-4-onen / Syntheses of Heterocycles, CCIV1 Reactions of Cyclic Oxalyl Compounds, XIX 2 A Simple Synthesis of 5 Benzoyl-6-phenyl-1,3-dioxin-4-ones

1977 ◽  
Vol 32 (6) ◽  
pp. 701-704 ◽  
Author(s):  
Gert Kollenz ◽  
Erich Ziegler ◽  
Walter Ott ◽  
Gert Kriwetz
Keyword(s):  
Acetic Acid ◽  
Methyl Ester ◽  
Acrylic Acid ◽  
Acid Methyl Ester ◽  
The Other ◽  
Simple Synthesis ◽  
Acid Methyl ◽  
Other Hand

4-Benzoyl-5-phenyl-2,3-dihydrofuran-2,3-dione (1) reacts with aldehydes or ketones via the acylketene-intermediate (2) yielding the 1,3-dioxin-4-ones (3). The aldehyde derivatives (3 a-e) can be converted into the anilino-chalcone (5) or the anilino acrylic acid (6) by treating with aniline at 20 °C. 6 and diazomethane combine to the acrylic acid methyl ester (7), which by heating (200 °C) is cyclisized to the quinolin-4-ole (8). On the other hand, the keto derivatives 3f-h and aniline give the dibenzoyl acetic acid anilide (9).

scholarly journals Modeling of Rate-Independent and Symmetric Hysteresis Based on Madelung’s Rules

Sensors ◽  
2019 ◽  
Vol 19 (2) ◽  
pp. 352 ◽  
Author(s):  
Kairui Cao ◽  
Rui Li
Keyword(s):  
Phenomenological Models ◽  
Turning Points ◽  
Modeling Method ◽  
Experimental Results ◽  
The Other ◽  
Other Hand ◽  
The Relationship ◽  
With Memory

Hysteresis is a kind of nonlinearity with memory, which is usually unwanted in practice. Many phenomenological models have been proposed to describe the observed hysteresis. For instance, the Prandtl-Ishlinskii (PI) model, which consists of several backlash operators, is the most widely used. On the other hand, the well-known Madelung’s rules are always used to validate hysteresis models. It is worth pointing out that the PI model obeys Madelung’s rules. In this paper, instead of considering these rules as criteria, we propose a modeling method for symmetric hysteresis by directly constructing the trajectory based on Madelung’s rules. In the proposed method, turning points are recorded and wiped out according to the input value. After the implementation of the recording and wiping-out mechanisms, the curve which the current trajectory moves along can be determined and then the trajectory can be described. Furthermore, the relationship between the proposed method and the PI model is also investigated. The effectiveness of the presented method is validated by simulation and experimental results.

scholarly journals Protection of lead in an environment containing acetic acid vapour by using adsorbents and their characterization

2019 ◽  
Vol 7 (1) ◽  
Author(s):  
Sarka Msallamova ◽  
Milan Kouril ◽  
Kristyna Charlotte Strachotova ◽  
Jan Stoulil ◽  
Kateryna Popova ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Activated Carbon ◽  
The Other ◽  
Historical Documents ◽  
Atmospheric Conditions ◽  
Activated Alumina ◽  
Historical Museums ◽  
Lead Corrosion ◽  
Other Hand ◽  
Sorption Ability

Abstract Historical museums and depositories contain collections with a number of lead objects or historical documents with lead seals. Lead is a metal which has good corrosion resistance under atmospheric conditions. On the other hand, lead corrodes in an activity in an environment which contains volatile organic compounds (mainly acetic acid and formic acid). In a depository environment, sources of volatile compounds can be the historical documents themselves, wood, plastics (those made from cellulose acetate), polyvinyl acetate adhesives, varnishes, oil or emulsion paints, etc. The aim of this work was to compare the efficiency of commercial adsorbents (activated carbon, activated alumina, zeolite, and bentonite) in the acetic acid vapours. The lead corrosion rates were determined by using lead resistometric probes. Activated alumina and activated carbon were found to be the most effective adsorbents of acetic acid vapours. On the other hand, the available zeolite had the worst sorption ability compared with the other tested substances.

The Separation of Light Gaseous Isotopes by Mass Diffusion Columns II

1964 ◽  
Vol 19 (6) ◽  
pp. 747-755
Author(s):  
W. J. De Wet ◽  
J. Los
Keyword(s):  
Theoretical Analysis ◽  
Mass Diffusion ◽  
Experimental Results ◽  
The Other ◽  
Countercurrent Flow ◽  
Gas Solubility ◽  
Flow Rates ◽  
Mixing Effects ◽  
Other Hand ◽  
Good Agreement

The design of mass diffusion columns operated with partition membranes, for the separation of light gaseous isotopes, is discussed. A theoretical analysis of experimental results obtained indicates that a good agreement between experimental results and theory is only obtained at low column pressures and moderate countercurrent flow rates. At fairly low countercurrent flow rates mixing effects due to viscous dragging and gas solubility by the condensate appear to be considerable whereas excessively high countercurrent flow rates, on the other hand, also seem undesirable. Some suggestions are proposed to obviate impairing effects at least to some extent.

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