scholarly journals Electrical, Piezoresistive and Electromagnetic Properties of Graphene Reinforced Cement Composites: A Review

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3220
Author(s):  
Shengchang Mu ◽  
Jianguang Yue ◽  
Yu Wang ◽  
Chuang Feng

Due to their excellent combination of mechanical and physical properties, graphene and its derivatives as reinforcements have been drawing tremendous attention to the development of high-performance and multifunctional cement-based composites. This paper is mainly focused on reviewing existing studies on the three material properties (electrical, piezoresistive and electromagnetic) correlated to the multifunction of graphene reinforced cement composite materials (GRCCMs). Graphene fillers have demonstrated better reinforcing effects on the three material properties involved when compared to the other fillers, such as carbon fiber (CF), carbon nanotube (CNT) and glass fiber (GF). This can be attributed to the large specific surface area of graphene fillers, leading to improved hydration process, microstructures and interactions between the fillers and the cement matrix in the composites. Therefore, studies on using some widely adopted methods/techniques to characterize and investigate the hydration and microstructures of GRCCMs are reviewed and discussed. Since the types of graphene fillers and cement matrices and the preparation methods affect the filler dispersion and material properties, studies on these aspects are also briefly summarized and discussed. Based on the review, some challenges and research gaps for future research are identified. This review is envisaged to provide a comprehensive literature review and more insightful perspectives for research on developing multifunctional GRCCMs.

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 518 ◽  
Author(s):  
Ana Balea ◽  
Elena Fuente ◽  
Angeles Blanco ◽  
Carlos Negro

Nanocelluloses (NCs) are bio-based nano-structurated products that open up new solutions for natural material sciences. Although a high number of papers have described their production, properties, and potential applications in multiple industrial sectors, no review to date has focused on their possible use in cementitious composites, which is the aim of this review. It describes how they could be applied in the manufacturing process as a raw material or an additive. NCs improve mechanical properties (internal bonding strength, modulus of elasticity (MOE), and modulus of rupture (MOR)), alter the rheology of the cement paste, and affect the physical properties of cements/cementitious composites. Additionally, the interactions between NCs and the other components of the fiber cement matrix are analyzed. The final result depends on many factors, such as the NC type, the dosage addition mode, the dispersion, the matrix type, and the curing process. However, all of these factors have not been studied in full so far. This review has also identified a number of unexplored areas of great potential for future research in relation to NC applications for fiber-reinforced cement composites, which will include their use as a surface treatment agent, an anionic flocculant, or an additive for wastewater treatment. Although NCs remain expensive, the market perspective is very promising.


2014 ◽  
Vol 629-630 ◽  
pp. 487-493
Author(s):  
Bao Min Wang ◽  
Shuai Liu ◽  
Yu Han

For their remarkable properties, carbon nanotubes (CNTs) are considered as promising candidate for next generation of high performance and functional cement-based composites in 21st century. The paper focuses on the dispersibility, mechanical property, durability, conductivity and piezoresistivity properties of CNTs reinforced cement-based materials. A homogenous CNTs-suspension was obtained using the method which combined ultrasonic processing with mechanical stirring, electric-field introduction and surfactant decoration. The low weight fraction of CNTs improved the mechanical properties of CNTs/cement composites. The compressive strength and toughness were correspondingly improved. The added CNTs improved the sulfate attack resistance and impermeability properties of the prepared CNTs/cement mixes. Meanwhile, the added CNTs improved the pressure-sensitive, conductivity and electromagnetic absorption properties of the prepared mixes, which laid a foundation of multi-functional concrete and structure. It concludes that the key issue for CNTs/cement composites is the dispersibility and the compatibility of CNTs in cement matrix. The solving solutions are put forward. In the meantime, the further research prospects in this research field are forecasted.


2010 ◽  
Vol 163-167 ◽  
pp. 2549-2552
Author(s):  
Sang Hyun Nam ◽  
Young Jae Song ◽  
Sun Woo Kim ◽  
Hyun Do Yun

High performance fiber-reinforced cement composites (HPFRCCs) show multiple cracks and a limited damage tolerance capability due to the debonding of the fibers of the cement matrix. For practical applications, it is necessary to investigate the fractural behavior of HPFRCCs to understand the mechanism of the microbehavior of a cement matrix containing reinforcing fibers. We have investigated the acoustic emission (AE) signals in HPFRCCs under monotonic and cyclic uniaxial compressive loads. Four types of specimen were tested. The experimental parameters studied were: the type of fiber (polyethylene or polyvinyl alcohol), the hybrid type (with steel cord), and the loading pattern. The data shows that the progress of the damage in HPFRCCs in the compressive mode is characteristic of the type of hybrid fiber and its volume fraction. From the AE data, the second and third compressive load cycles resulted in a successive decrease in the amplitude compared to the first compressive load cycle. In addition, an AE Kaiser effect was observed in HPFRCCs specimens up to 80% of their ultimate strength. These observations suggest that the AE Kaiser effect has potential for use as a new tool to monitor the loading history of HPFRCCs.


2011 ◽  
Vol 675-677 ◽  
pp. 529-535 ◽  
Author(s):  
Jian Qiang Wei ◽  
Ming Li Cao

Whisker pull-out, which indicates that the interfacial bond strength of whiskers/cement is not high enough, is dominant in the microstructure of whisker-reinforced cement fractured surfaces. The weak interfacial bond of whiskers in cement matrix severely restrained the further improvement of properties. Superfine slag powder was used to modify and improve the strength and bond behavior of whisker-reinforced cement. Crystal structures, microcosmic appearances and characterizations of Slag Micro powder and the composite were studied by X-ray diffraction (XRD), and scan electron microscope (SEM/EDS), etc. Effect and mechanisms of different Slag powder content on the micro-structure and macro-properties of cement composite were investigated. The results show that Slag Micropowder can modify and improve the microstructure, interfacial and mechanical properties of whisker-reinforced cement.


2014 ◽  
Vol 7 (6) ◽  
pp. 965-975 ◽  
Author(s):  
V. J. Ferrari ◽  
A. P. Arquez ◽  
J. B. de Hanai ◽  
R. A. de Souza

This study presents the development and behavior analysis of high performance fiber reinforced cement composites (HPFRCC). The describedmaterials were specifically developed for application as a transition layer: a repair layer that constitutes the stressed chord of reinforcedconcrete beams strengthened in flexure with carbon fiber reinforced polymers (CFRP). Nineteen different composites were produced by thehybridization process, varying the conventional short steel fiber and steel microfiber (manufactured exclusively for this research) contentsto modify the microstructure of the material, thus enhancing the stress transfer process from the cement matrix to the fibers. To analyze theresponse to flexural loading, the composites underwent three point bending tests in notched prism specimens. The response of the materialwas obtained considering strength and tenacity parameters (flexural and fracture). There was evidence of high performance by the composites with a pseudo-hardening behavior.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4304
Author(s):  
Markssuel Teixeira Marvila ◽  
Afonso Rangel Garcez de de Azevedo ◽  
Paulo R. de de Matos ◽  
Sergio Neves Monteiro ◽  
Carlos Maurício Fontes Vieira

This review article proposes the identification and basic concepts of materials that might be used for the production of high-performance concrete (HPC) and ultra-high-performance concrete (UHPC). Although other reviews have addressed this topic, the present work differs by presenting relevant aspects on possible materials applied in the production of HPC and UHPC. The main innovation of this review article is to identify the perspectives for new materials that can be considered in the production of novel special concretes. After consulting different bibliographic databases, some information related to ordinary Portland cement (OPC), mineral additions, aggregates, and chemical additives used for the production of HPC and UHPC were highlighted. Relevant information on the application of synthetic and natural fibers is also highlighted in association with a cement matrix of HPC and UHPC, forming composites with properties superior to conventional concrete used in civil construction. The article also presents some relevant characteristics for the application of HPC and UHPC produced with alkali-activated cement, an alternative binder to OPC produced through the reaction between two essential components: precursors and activators. Some information about the main types of precursors, subdivided into materials rich in aluminosilicates and rich in calcium, were also highlighted. Finally, suggestions for future work related to the application of HPC and UHPC are highlighted, guiding future research on this topic.


Author(s):  
Genadijs Sahmenko ◽  
Sandis Aispurs ◽  
Aleksandrs Korjakins

Traditionally, sculptural and decorative elements of building facades are created from mortar mixes based on lime, gypsum or Portland cement. Generally these materials have porous and permeable structure, which determines their accelerated degradation, especially in the aggressive environment of modern cities. High performance cement composites (HPCC) have been considered for production and restoration of sculptural elements in historical buildings. For this purpose, fine-graded, multi-component and highly workable mixes were elaborated. Mix compositions were modified with micro-fillers, plasticizing and stabilizing admixtures, as well as fibers to improve material ductility and control shrinkage cracking. Basic mechanical properties and durability (such as water absorption, frost resistance) were determined and two types of HPCC were compared (>50 MPa: HPCC and >120 MPa: UHPCC). It has been confirmed that cement composite mixes are characterized by self-consolidating effect, high compressive strength, extremely high resistance versus freezing and thawing cycles and low water absorption. Surface quality was evaluated and initial water absorption (tube tests) were performed for laboratory samples and real sculptural elements after 5 years of exploitation. The results confirmed good potential for using HPCC for creating more attractive and durable architectural shapes and façade elements compared to elements made using traditional cement and lime mortar.


2018 ◽  
Vol 34 (1) ◽  
pp. 77-98 ◽  
Author(s):  
Sang Whan Han ◽  
Jin Wook Kang ◽  
Chang Seok Lee

The objective of this study was to investigate the seismic behavior of slender concrete diagonally-reinforced coupling beams (DRCBs) with an aspect ratio of 3.5 and to explore the possibility of alleviating the reinforcement detail for DRCBs using high-performance fiber-reinforced cement composites (HPFRCCs). For this purpose, slender HPFRCCs and conventional concrete DRCBs with transverse reinforcement spacing of 110 mm, 250 mm, and 500 mm were made and tested. One HPFRCC DRCB specimen was made without transverse reinforcement for comparison purposes. This experimental study shows that the slender HPFRRCC DRCBs with transverse reinforcement spacing of 250 mm have almost the same strength and drift capacity as those of the conventional concrete DRCB with transverse reinforcement spacing of 110 mm, satisfying the requirement of American Concrete Institute ACI 318-14 (2014) building code.


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