scholarly journals Hyperbranched Liquid Crystals Modified with Sisal Cellulose Fibers for Reinforcement of Epoxy Composites

Polymers ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1024 ◽  
Author(s):  
Qiyun Luo ◽  
Yuqi Li ◽  
Li Ren ◽  
Xu Xu ◽  
Shaorong Lu
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Material ◽  
Liquid Crystals ◽  
Natural Fiber ◽  
Cellulose Fibers ◽  
Epoxy Composites ◽  
Mechanical And Thermal Properties ◽  
Polymer Adhesion ◽  
The Poor

Well-defined functionalized sisal cellulose fibers (SCFs) grafted on hyperbranched liquid crystals (HLP) were synthesized to improve the compatibility between SCFs and epoxy resin (EP). The influence of SCFs-HLP on the mechanical and thermal properties of SCFs-HLP/EP composites was studied. The results show that the mechanical properties of SCFs-HLP/EP composites were enhanced distinctly. Particularly, compared with EP, impact strength, tensile strength, and flexural strength of composites with 4.0 wt % SCFs-HLP were 38.3 KJ·m−2, 86.2 MPa, and 150.7 MPa, increasing by 118.7%, 55.6%, and 89.6%, respectively. As well, the glass transition temperature of the composite material increased by 25 °C. It is hope that this work will inform ongoing efforts to exploit more efficient methods to overcome the poor natural fiber/polymer adhesion in the interface region.

Degradation Behaviour of Nanosilica Enhanced Oil Palm Empty Fruit Bunch Fiber Epoxy Composites

2020 ◽  
Vol 305 ◽  
pp. 28-35
Author(s):  
Anslem Wong Tsu An ◽  
Sujan Debnath ◽  
Vincent Lee Chieng Chen ◽  
Moola Mohan Reddy ◽  
Alokesh Pramanik
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Oil Palm ◽  
Environmental Conditions ◽  
Natural Fiber ◽  
Fiber Composites ◽  
Epoxy Composites ◽  
Empty Fruit Bunch ◽  
Degradation Behaviour ◽  
Brine Solution

In recent years, studies regarding natural fiber reinforced composites have been increased as they are biodegradable with good mechanical performance therefore can help to overcome the environmental issue. As the natural fibers are easy to obtain, many industries have started to make use of natural fiber composites which are light in weight and possess good mechanical properties. However, the natural fiber composites also possess certain limitations most importantly their high moisture absorption ability which makes them incompatible at degradable environment. The fiber constituents of natural fiber composite may have different type of interactions at different environmental conditions. In addition, the involvement of nanoparticles in the composite may be the solution to overcome the deficiencies. In this research, the degradation behaviour of Oil palm empty fruit bunch (OPEFB) fibers reinforced epoxy composites upon exposure to degradable environmental conditions and the effect of adding nanoparticles have been studied. The tensile tests were conducted before and after the exposure to different environmental conditions including plain water, moist soil, brine solution, and cooking oil. Results shows that the addition of 10wt% of OPEFB fiber to the epoxy composites had improved the mechanical tensile strength up to 15.97% and composites exposed to brine solution have the most prominent sign of degradation in mechanical properties in both composites with and without nanosilica. Nevertheless, the composites with nanosilica have shown up to 24.28% improvement in tensile strength after exposure to different environmental conditions. The improvement were attributed due to filling the voids of the composites with nanosilica and good interfacial adhesion between the nanofiller, fiber, and matrix.

The Synergistic Effect of Flame Retardants on Flammability, Thermal and Mechanical Properties of Natural Fiber Reinforced Epoxy Composite

2016 ◽  
Vol 701 ◽  
pp. 281-285 ◽  
Author(s):  
Pooria Khalili ◽  
Kim Yeow Tshai ◽  
Ing Kong ◽  
Jun Hui Lee ◽  
Farzad Arefi Mostafa
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Mass Loss ◽  
Heat Release ◽  
Natural Fiber ◽  
Synergistic Effects ◽  
Epoxy Composites ◽  
Zinc Borate ◽  
Thermal And Mechanical Properties ◽  
Combustion Heat

Epoxy was effectively resin infused with 15 %wt intumescing Alumina Trihydrate (ATH) flame retardant (FR) formulations into a 10 %wt palm EFB natural fiber (NF) mat. The effects of ATH and its intumescing blend with Zinc Borate (ZB) and Ammonium Polyphosphate (APP) on flammability, thermal and mechanical properties of the composites were investigated. Compared to neat NF filled epoxy composites, specimens loaded with intumescing blend of FR formulations demonstrated an improved thermal properties, showing greater mass residual which can be attributed to the formation of cross-linked network amongst the NF, FRs and epoxy matrix upon combustion at elevated temperature tested within a TGA instrument. Incorporation of fibers drastically enhanced the mass residue and lowered the heat release compare to the pure epoxy. Addition of the intumescing blend of FR formulations also drastically reduces the combustion heat release, total mass loss and zero drip flame in the NF composites. The optimum FRs formulation with 5 %wt ATH and 10 %wt APP exhibited self-extinguishing property, achieved lowest mass loss and no drip flame under Bunsen burner tests, signifying the synergistic effects between ATH and APP within the NF epoxy composites. APP reacts with the carbonaceous network of NF throughout the ignition period, such interaction formed a thick char layer acting as gas and thermal barrier against the fire mechanism. This reaction does not take place in NF composite specimens without APP. In terms of mechanical properties, NF composites loaded with FRs broadly showed poorer tensile strength, mainly due to the existence of FRs, which acted as a nucleating agent affected the physico-mechanical characteristics of the composites. Amongst the FR rich formulations, specimens with APP or ZB blends seem to possess a more superior tensile strength compared with the neat ATH filled formulation. In addition, composites loaded with FRs showed enhanced Young’s modulus relative to those without addition of FRs.

Graphite/Bio-Based Epoxy Composites: The Mechanical Properties Interface

2015 ◽  
Vol 799-800 ◽  
pp. 115-119 ◽  
Author(s):  
Anika Zafiah M. Rus ◽  
Nur Munirah Abdullah ◽  
M.F.L. Abdullah ◽  
M. Izzul Faiz Idris
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Filler Content ◽  
Weight Percent ◽  
Epoxy Composites ◽  
Elongation At Break ◽  
Graphite Content ◽  
Dispersion Condition ◽  
Strong Interfacial Bonding

Graphite reinforced bio-based epoxy composites with different particulate fractions of graphite were investigated for mechanical properties such as tensile strength, elastic modulus and elongation at break. The graphite content was varied from 5 wt.%, 10 wt.%, 15 wt.%, 20 wt.%, 25 wt.%, 30 wt.% by weight percent in the composites. The results showed that the mechanical properties of the composites mainly depend on dispersion condition of the treated graphite filler, aggregate structure and strong interfacial bonding between treated graphite in the bio-based epoxy matrix. The composites showed improved tensile strength and elastic modulus with increase treated graphite weight loading. This also revealed the composites with increasing filler content was decreasing the elongation at break.

Thermoplastic polyurethane/CNT nanocomposites with low electromagnetic resistance property

2021 ◽  
pp. 002199832110370
Author(s):  
Chia-Fang Lee ◽  
Chin-Wen Chen ◽  
Fu-Sheng Chuang ◽  
Syang-Peng Rwei
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Thermoplastic Polyurethane ◽  
Conductive Polymer ◽  
Resistance Coefficient ◽  
Equal Weight ◽  
Mechanical And Thermal Properties ◽  
Multi Wall Carbon Nanotubes ◽  
Twin Screw ◽  
Acrylic Ester

Multi-wall carbon nanotubes (MWCNTs) at 0.5 wt% to 2 wt% proportions were added to thermoplastic polyurethane (TPU) synthesized with polycarbonatediol (PCDL), 4,4’-methylene diphenyl diisocyanate (MDI), and 1,3-butanediol(1,3-BDO). To formulate a new TPU-MWCNT nanocomposite, the composite was melt-blended with a twin-screw extruder. To ensure the even dispersion of MWCNTs, dispersant (ethylene acrylic ester terpolymer; Lotader AX8900) of equal weight proportion to the added MWCNTs was also added during the blending process. Studies on the mechanical and thermal properties, and melt flow experiments and phase analysis of TPU-MWCNT nanocomposites, these nanocomposites exhibit higher tensile strength and elongation at break than neat TPU. TPU-MWCNT nanocomposites with higher MWCNT content possess higher glass-transition temperature (Tg), a lower melt index, and greater hardness. Relative to neat TPU, TPU-MWCNT nanocomposites exhibit favorable mechanical properties. By adding MWCNTs, the tensile strength of the nanocomposites increased from 7.59 MPa to 21.52 MPa, and Shore A hardness increased from 65 to 81. Additionally, TPU-MWCNT nanocomposites with MWCNTs had lower resistance coefficients; the resistance coefficient decreased from 4.97 × 1011 Ω/sq to 2.53 × 104 Ω/sq after adding MWCNTs, indicating a conductive polymer material. Finally, the internal structure of the TPU-MWCNT nanocomposites was examined under transmission electron microscopy. When 1.5 wt% or 2 wt% of MWCNTs and dispersant were added to TPU, the MWCNTs were evenly dispersed, with increased electrical conductivity and mechanical properties. The new material is applicable in the electronics industry as a conductive polymer with high stiffness.

scholarly journals Tension mechanical properties of recycled glass-epoxy composite material

2012 ◽  
pp. 189-198 ◽  
Author(s):  
Jelena Petrovic ◽  
Darko Ljubic ◽  
Marina Stamenovic ◽  
Ivana Dimic ◽  
Slavisa Putic
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Material ◽  
Composite Materials ◽  
Modulus Of Elasticity ◽  
Epoxy Composite ◽  
Raw Materials ◽  
Mechanical Tests ◽  
Recycled Glass ◽  
Before And After

The significance of composite materials and their applications are mainly due to their good properties. This imposes the need for their recycling, thus extending their lifetime. Once used composite material will be disposed as a waste at the end of it service life. After recycling, this kind of waste can be used as raw materials for the production of same material, which raises their applicability. This indicates a great importance of recycling as a method of the renowal of composite materials. This study represents a contribution to the field of mechanical properties of the recycled composite materials. The tension mechanical properties (tensile strength and modulus of elasticity) of once used and disposed glass-epoxy composite material were compared before and after the recycling. The obtained results from mechanical tests confirmed that the applied recycling method was suitable for glass-epoxy composite materials. In respect to the tensile strength and modulus of elasticity it can be further assessed the possibility of use of recycled glass-epoxy composite materials.

scholarly journals Experimental and Numerical Study on the Effect of Creep Behavior on Epoxy Composites Reinforced with Yttrium Oxide Powder

2020 ◽  
Vol 25 (4) ◽  
pp. 203-213
Author(s):  
B.H. Abed ◽  
K.J. Jadee ◽  
A.A. Battawi
Keyword(s):  
Mechanical Properties ◽  
Composite Material ◽  
Elasticity Modulus ◽  
Epoxy Composite ◽  
Numerical Study ◽  
Creep Behaviour ◽  
Weight Ratio ◽  
Volume Ratio ◽  
Epoxy Composites ◽  
Creep Characteristics

AbstractThe creep test is one of the important approaches to determining some mechanical properties of composite materials. This study was carried out to investigate the creep behaviour of an epoxy composite material that was reinforced with Y2O3 powder at weight ratios of 2%, 7%, 12%, 17% and 22%. Each volume ratio was subjected to five loads over the range of 1N to5N at a constant temperature of 16 ± 2°C. In this work, creep behaviour, stress and elasticity modulus were studied through experimental and numerical analyses. Results showed that increasing the weight ratio of Y2O3 powder enhanced creep characteristics.

scholarly journals MICROSTRUCTURE RESEARCH OF THE UNIDIRECTIONAL ORGANOPLASTIC BASED ON RUSAR-NT ARAMID FIBERS AND EPOXY-POLYSULFONE BINDER

2020 ◽  
pp. 19-26
Author(s):  
E.N. Kablov ◽  
◽  
G.S. Kulagina ◽  
G.F. Zhelezina ◽  
S.L. Lonskii ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Material ◽  
Polymer Matrix ◽  
Packing Density ◽  
Tensile Tests ◽  
Polymer Composite Material ◽  
Aramid Fibers ◽  
Before And After ◽  
Binder Structure

This paper studies a polymer composite material - a unidirectional organoplastic based on Rusar-NT aramid fiber and a melt epoxy-polysulfone binder. Organoplastic has the following mechanical properties: tensile strength 2060 MPa, Young's modulus 101 GPa. The microstructure of the fiber and the polymer matrix in the organoplastic samples was studied before and after tensile tests. The features of the formation of the binder structure depending on the packing density of the fibers in organoplastics have been determined. The nature of the destruction of fibers and polymer matrix caused by the uniaxial tension has been studied.

The influence of functionalization time of carbon nanotube on the mechanical properties of the epoxy composites

2017 ◽  
Vol 51 (12) ◽  
pp. 1693-1701 ◽  
Author(s):  
EA Zakharychev ◽  
EN Razov ◽  
Yu D Semchikov ◽  
NS Zakharycheva ◽  
MA Kabina
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Carbon Nanotube ◽  
Composite Materials ◽  
Polymer Composites ◽  
Epoxy Composites ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

This paper investigates the structure, length, and percentage of functional groups of multi-walled carbon nanotubes (CNT) depending on the time taken for functionalization in HNO3 and H2SO4 mixture. The carbon nanotube content and influence of functionalization time on mechanical properties of polymer composite materials based on epoxy matrix are studied. The extreme dependencies of mechanical properties of carbon nanotube functionalization time of polymer composites were established. The rise in tensile strength of obtained composites reaches 102% and elastic modulus reaches 227% as compared to that of unfilled polymer. The composites exhibited best mechanical properties by including carbon nanotube with 0.5 h functionalization time.

scholarly journals Performance of lightweight mortar reinforced with doum palm fiber

2020 ◽  
pp. 002199832097519
Author(s):  
Fatma Naiiri ◽  
Allègue Lamis ◽  
Salem Mehdi ◽  
Zitoune Redouane ◽  
Zidi Mondher
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Natural Fiber ◽  
Cement Mortar ◽  
Low Cost ◽  
Natural Fibers ◽  
Construction Materials ◽  
Mechanical And Thermal Properties ◽  
Palm Fiber ◽  
And Control

Natural fibers are increasingly used in composites because of their low cost and good mechanical properties. Cement reinforced with natural fibersis contemplates as a new generation of construction materials with superior mechanical and thermal performance. This study of three sizes’effect of Doum palm fiber explores the mortar’s behavior reinforced with different fiber ratio. The aim is to determine the optimal addition to improve mechanical and thermal properties of natural fiber reinforced cements. Physical, mechanical and thermal properties of composite are examined. Tensile properties of Doum fibers are verified to determine their potential as reinforced material. Findings prove that the use of alkali-treated Doum fiber as reinforcement in cement mortar composite leads to the upgrading of the mechanical properties including thermo-physical properties against composites reinforced with raw fibers and control cement mortars. While, the compression and flexural strength of the cement mortar reinforced with alkali-treated Doum fiber with diameter 0.3 mm (CT3) are metered to be 11.11 MPa, 5.22 MPa, respectively for fiber content 0.5%. Additionally, based on thermo-physical tests, it is assessed that the thermal conductivity and diffusivity decrease for cement mortar reinforced with Doum fiber with diameter 0.2 mm (CT2).

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