scholarly journals Nonwoven Materials Produced by Melt Electrospinning of Polypropylene Filled with Calcium Carbonate

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2981
Author(s):  
Sergey N. Malakhov ◽  
Petr V. Dmitryakov ◽  
Evgeny B. Pichkur ◽  
Sergey N. Chvalun
Keyword(s):  
Calcium Carbonate ◽  
Composite Films ◽  
Sodium Stearate ◽  
Average Diameter ◽  
X Ray Diffraction ◽  
Melt Electrospinning ◽  
Nonwoven Materials ◽  
Smectic Mesophase ◽  
High Degree ◽  
Degree Of Filling

Nowadays, polypropylene-based nonwovens are used in many areas, from filtration to medicine. One of the methods for obtaining such materials is melt electrospinning. In some cases, it is especially interesting to produce composite fibers with a high degree of filling. In this work, the influence of the filling degree of isotactic polypropylene with calcium carbonate on the structure and properties of nonwoven materials obtained by melt electrospinning was studied. It was shown that electrospinning is possible, even at a filler content of 50%, while the average diameter of the fibers increases with the growth in the content of calcium carbonate. The addition of sodium stearate significantly reduces the diameter of the fibers (from 10–65 to 2–10 microns) due to reducing viscosity and increasing the electrical conductivity of the melt. Wide-angle X-ray diffraction analysis and IR spectroscopy reveal that the initial polymer and composites are characterized by the presence of stable α-form crystals, while nonwovens show a predominance of smectic mesophase. The addition of calcium carbonate leads to an increase in the hydrophobicity of the composite films, the addition of sodium stearate results in a decrease of hydrophobicity, while all nonwovens demonstrate superhydrophobic properties.

scholarly journals Structural characterization of Yba2Cu3O7–δ/Y2O3 composite films

1998 ◽  
Vol 13 (4) ◽  
pp. 954-958 ◽  
Author(s):  
P. R. Broussard ◽  
M. A. Wall ◽  
J. Talvacchio
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Coincidence Site Lattice ◽  
Composite Films ◽  
X Ray Diffraction ◽  
Plane Orientation ◽  
Transmission Electron ◽  
Two Phases ◽  
High Degree

Using 4-circle x-ray diffraction and transmission electron microscopy, we have studied the microstructure and in-plane orientation of the phases present in thin film composite mixtures of Yba2Cu3O7–δ and Y2O3. We see a high degree of in-plane orientation and have verified a previous prediction for the in-plane order of Y2BaCuO5 on (110) MgO. Transmission electron microscopy shows the composite films to be a mixture of two phases, with YBCO grain sizes of ≈1 μm. We have also compared our observations of the in-plane order to the predictions of a modified near coincidence site lattice model.

Performance of Polypropylene Composites Filled by Calcium Carbonate Whiskers

2011 ◽  
Vol 399-401 ◽  
pp. 415-418
Author(s):  
Qiu Ju Sun ◽  
Gui Zhen Zhao ◽  
Shi Gang Xin ◽  
Shi Wei Wu ◽  
Jie Lu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Calcium Carbonate ◽  
Sodium Stearate ◽  
X Ray Diffraction ◽  
Screw Extruder ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Polypropylene Composites ◽  
Twin Screw ◽  
Scanning Electron

Calcium carbonate (CaCO3) whiskers were firstly treated by sodium stearate, and then blended with polypropylene (PP) to prepare the composites by a closely intermeshing co-rotating twin-screw extruder at 200°C. The performance of the composites, such as thermal behavior, microstructure and mechanical properties, were analyzed with differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and mechanical testing. The results showed that CaCO3 whisker influenced the crystalline behavior of PP phase in the blends because of its intervening. Moreover, thermo-decomposing temperature, tensile and bending strengths of the blends all increased with increasing whisker content. CaCO3 whiskers had good reinforcing and toughening effects on PP.

Solvothermal Synthesis and Characterization of Hierarchical Calcium Carbonate Spheres

2014 ◽  
Vol 912-914 ◽  
pp. 318-320 ◽  
Author(s):  
Yin Xia Chen ◽  
Xian Bing Ji ◽  
Yu Lian Quan
Keyword(s):  
Calcium Carbonate ◽  
Solvothermal Synthesis ◽  
Mixed Solvents ◽  
Average Diameter ◽  
Synthesis And Characterization ◽  
Solvothermal Process ◽  
X Ray Diffraction ◽  
X Ray ◽  
Experimental Parameters

Hierarchical calcium carbonate spheres composed of nanoparticles has been successfully synthesized via a solvothermal process. The structures are fabricated by the reaction of Ca (CH3COO)2with (CO(NH2)2) at 110 °C in diethylene glycolwater mixed solvents in the presence of polyvinylpyrrolidone. The as-prepared products were characterized by field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD). The characterization results revealed that the average diameter of the hierarchical calcium carbonate spheres is about 5 μm, and the size of the nanoparticals range from 50 to 100 nm. In addition, a small amount of bundle-like aragonite calcium carbonate is also obtained in the experimental parameters.

On the Properties of an Ion Conductive System Incorporated in Hybrid Films

2000 ◽  
Vol 628 ◽  
Author(s):  
G. González ◽  
P. J. Retuert ◽  
S. Fuentes
Keyword(s):  
Electrochemical Impedance ◽  
Ternary Phase Diagram ◽  
Lithium Perchlorate ◽  
Molar Ratio ◽  
Ionic Conductors ◽  
X Ray Diffraction ◽  
Poly Ethylene Oxide ◽  
Ion Conducting ◽  
Poly Ethylene ◽  
High Degree

ABSTRACTBlending the biopolymer chitosan (CHI) with poly (aminopropilsiloxane) oligomers (pAPS), and poly (ethylene oxide) (PEO) in the presence of lithium perchlorate lead to ion conducting products whose conductivity depends on the composition of the mixture. A ternary phase diagram for mixtures containing 0.2 M LiClO4 shows a zone in which the physical properties of the products - transparent, flexible, mechanically robust films - indicate a high degree of molecular compatibilization of the components. Comparison of these films with binary CHI-pAPS nanocomposites as well as the microscopic aspect, thermal behavior, and X-ray diffraction pattern of the product with the composition PEO/CHI/pAPS/LiClO4 1:0.5:0.6:0.2 molar ratio indicates that these films may be described as a layered nanocomposite. In this composite, lithium species coordinated by PEO and pAPS should be inserted into chitosan layers. Electrochemical impedance spectroscopy measurements indicate the films are pure ionic conductors with a maximal bulk conductivity of 1.7*10-5 Scm-1 at 40 °C and a sample-electrode interface capacitance of about 1.2*10-9 F.

scholarly journals Ultrasonic-modified montmorillonite uniting ethylene glycol diglycidyl ether to reinforce protein-based composite films

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 433-442
Author(s):  
Hua He ◽  
Rui-jing Jia ◽  
Kai-qiang Dong ◽  
Jia-wen Huang ◽  
Zhi-yong Qin
Keyword(s):  
Ethylene Glycol ◽  
Soy Protein ◽  
Soy Protein Isolate ◽  
Composite Films ◽  
Barrier Properties ◽  
Protein Isolate ◽  
Diglycidyl Ether ◽  
X Ray Diffraction ◽  
Protein Film ◽  
Modified Montmorillonite

Abstract A novel biodegradable protein-based material (UMSPIE) that consists of natural polymer soy protein isolate (SPI), ultrasonic-modified montmorillonite (UMMT), and ethylene glycol diglycidyl ether (EGDE) was produced by solution casting. Fourier infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG), and scanning electron microscopy (SEM) were used to characterize the chemical structure and micro-morphologies of as-synthesized protein-based composite films. The results showed that the interlayer structure of MMT was destroyed by ultrasonic treatment, and the hydrogen bonding between SPI chains and the ultrasound-treated MMT plates was enhanced. The synergistic effect of UMMT and EGDE on SPI molecules made the network structure of the UMSPIE film denser. In addition, the mechanical and barrier properties of the as-synthesized films were explored. Compared with pure soy protein film, the tensile strength of the UMSPIE film has an increase of 266.82% (increasing from 4.4 to 16.14 MPa). From the above, the modified strategy of layered silicates filling combining crosslinking agents is considered as an effective method to improve the functional properties of bio-based polymer composites.

scholarly journals Types of Void Space in the Bazhenov Reservoir Rocks

Geosciences ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 269
Author(s):  
Olga V. Postnikova ◽  
Alexander V. Postnikov ◽  
Olga A. Zueva ◽  
Artem E. Kozionov ◽  
Ekaterina V. Milovanova ◽  
...  
Keyword(s):  
Western Siberia ◽  
Distribution Patterns ◽  
Void Space ◽  
X Ray Diffraction ◽  
Bazhenov Formation ◽  
Reservoir Rocks ◽  
Oil Reserves ◽  
Light Oil ◽  
Clay Rocks ◽  
High Degree

The deposits of the Bazhenov formation are a unique reservoir of unconventional oil reserves in Western Siberia. They contain both solid organic matter (kerogen) and liquid light oil. The successful development of these hydrocarbons is largely determined by the adequacy of the void space models. The aim of the study is to identify the types of void space in the sediments of the Bazhenov formation and to identify the distribution patterns across the section of the researched wells. The void space was studied by electron and optical microscopy, and the mineral composition of the rocks was determined by X-ray diffraction analysis. The deposits of the Bazhenov productive formation in the territory of Western Siberia are represented by a wide complex of lithotypes, including various kinds of silicites, carbonate, clay rocks, and mixtites. The reservoir space in the reservoir rocks of the Bazhenov formation is a complex and hierarchically subordinated system, which includes voids and fractures of various sizes, configurations, and genesis. The void space of the Bazhenov formation is characterized by a fairly high degree of spatial heterogeneity, which is controlled by lithological, facies, and tectonic factors, as well as the direction of catagenetic processes.

X-ray diffraction study of the smectic mesophase of some azobenzene-containing polyacrylates

1993 ◽  
Vol 14 (4) ◽  
pp. 981-990 ◽  
Author(s):  
Oriano Francescangeli ◽  
Bin Yang ◽  
Emo Chiellini ◽  
Giancarlo Galli ◽  
Annino Sante Angeloni ◽  
...  
Keyword(s):  
Diffraction Study ◽  
X Ray Diffraction ◽  
X Ray ◽  
Smectic Mesophase

Particle Size, Structure and Powdering Process of Calcium Carbonate Nanoparticles Filled Powdered Styrene-Butadiene Rubber

2011 ◽  
Vol 415-417 ◽  
pp. 237-242
Author(s):  
Zhou Da Zhang ◽  
Xue Mei Chen ◽  
Guo Liang Qu
Keyword(s):  
Particle Size ◽  
Calcium Carbonate ◽  
Size Structure ◽  
Average Diameter ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Particle Structure ◽  
Styrene Butadiene ◽  
New Particles

Calcium carbonate nanoparticles (nano-CaCO3) filled powdered styrene-butadiene rubber (P(SBR/CaCO3) was prepared by adding nano-CaCO3 particles, encapsulant and coagulant to styrene-butadiene rubber (SBR) latex by coacervation, and the particle size distribution, structure were studied. Scanning electron microscopy (SEM) was used to investigate the (P(SBR/CaCO3) particle structure, and a powdering model was proposed to describe the powdering process. The process includes: (i) the latex particles associated with the dispersed nano-CaCO3 particles (adsorption process) to form “new particles” and (ii) the formation of P(SBR/CaCO3) by coagulating “new particles”. The SEM results also shown that the nano-CaCO3 and rubber matrix have formed a macroscopic homogenization in the (P(SBR/CaCO3) particles and nano-CaCO3 dispersed uniformly in the rubber matrix with an average diameter of approximately 50 nm.

The Preparation and Photocatalytic Activity of SWNTs Doped ZnO/TiO2 Compound Films

2010 ◽  
Vol 97-101 ◽  
pp. 1611-1615 ◽  
Author(s):  
Qing Wang ◽  
Xin Li Li ◽  
Wei Nie ◽  
Yong Mei Xia ◽  
Jian Feng Dai
Keyword(s):  
Photocatalytic Activity ◽  
Absorption Spectra ◽  
Sol Gel ◽  
Composite Films ◽  
Wavelength Region ◽  
Tio2 Films ◽  
X Ray Diffraction ◽  
Sol Gel Process ◽  
Doped Zno ◽  
Walled Carbon Nanotubes

The ZnO/TiO2 composite films were deposited over glass using spin coating technique by sol-gel process. Single-walled carbon nanotubes (SWNTs) were used to modify the ZnO/TiO2 films successfully in this paper. The structure and composition of the ZnO/TiO2 composite and SWNTs doped ZnO/TiO2 composite were characterized by X-ray diffraction (XRD). The morphology of samples was characterized by scanning electron microscopy (SEM). The photocatalytic activity was investigated by photocatalytic degradation of aqueous methyl orange under ultraviolet (UV) radiation. The UV-vis absorption spectra of the ZnO/TiO2 films and SWNTs doped ZnO/TiO2 films in the wavelength region 200~800 nm were obtained. The results indicate that the SWNTs addition can decrease the grain size of ZnO/TiO2, which can enhance the photocatalytic activity. UV-vis absorption spectra of SWNTs-ZnO/TiO2 showed obvious blue shifts compared with ZnO/TiO2. The optimal amount of doping SWNTs is 1% according to this research. The enhanced mechanism of the SWNTs for the photocatalytic activity in ZnO/TiO2 films was analyzed in this article.

Preparation of NiO Microspheres by Hydrothermal Method and its Electrochemical Capacitive Properties

2015 ◽  
Vol 814 ◽  
pp. 81-85 ◽  
Author(s):  
Qian Qian Li ◽  
Run Hua Fan ◽  
Ke Lan Yan ◽  
Kai Sun ◽  
Xu Ai Wang ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Electrochemical Impedance ◽  
Specific Capacity ◽  
Rate Capability ◽  
Average Diameter ◽  
Three Dimensions ◽  
Electrochemical Characteristics ◽  
X Ray Diffraction ◽  
High Specific Capacity ◽  
Capacitive Properties

The precursor Ni (OH)2 was synthesized by a simple hydrothermal method with hexamethylenetetramine ((CH2)6N4) as precipitant and template, and then NiO was gained after calcination. The phase and morphology of the synthesized product were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM), and the electrochemical capacitive characterization was performed using cyclic voltammetry (CV), chronopotentiometry and electrochemical impedance spectroscopy (EIS) in a 6mol/L KOH aqueous solution electrolyte. The result shows that spherical NiO without impurity was synthesized, the average diameter of the spheres is 5 um and these spheres were constructed by the interactive arrangement of many nanoflakes in three dimensions. This kind of NiO shows the typical electrochemical characteristics of pseudo capacitance with high specific capacity and excellent rate capability. The specific capacity can reach 515F/g at the current density of 1A/g

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