scholarly journals Glycolysis of Polyurethanes Composites Containing Nanosilica

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1418
Author(s):  
Jesus del Amo ◽  
Ana Maria Borreguero ◽  
Maria Jesus Ramos ◽  
Juan Francisco Rodríguez
Keyword(s):  
Diethylene Glycol ◽  
Vacuum Distillation ◽  
Crude Glycerol ◽  
Single Phase ◽  
Chemical Recycling ◽  
Foam Properties ◽  
Polyurethane Composites ◽  
Pu Foams ◽  
Phase Process

Rigid polyurethane (RPU) foams have been successfully glycolyzed by using diethylene glycol (DEG) and crude glycerol (CG) as transesterification agents. However, DEG did not allow to achieve a split-phase process, obtaining a product with low polyol purity (61.7 wt %). On contrary, CG allowed to achieve a split-phase glycolysis improving the recovered polyol purity (76.5%). This is an important novelty since, up to now, RPUs were glycolyzed in single-phase processes giving products of low polyol concentration, which reduced the further applications. Moreover, the nanosilica used as filler of the glycolyzed foams was recovered completely pure. The recovered polyol successfully replaced up to 60% of the raw polyol in the synthesis of RPU foams and including the recovered nanosilica in the same concentration than in glycolyzed foam. Thus, the feasibility of the chemical recycling of this type of polyurethane composites has been demonstrated. Additionally, PU foams were synthesized employing fresh nanosilica to evaluate whether the recovered nanosilica has any influence on the RPU foam properties. These foams were characterized structurally, mechanically and thermally with the aim of proving that they met the specifications of commercial foams. Finally, the feasibility of recovering the of CG by vacuum distillation has been demonstrated.

Single-phase and well-dispersed Cu1.75S nanocrystals by ambient pressure diethylene glycol solution synthesis

2013 ◽  
Vol 266 ◽  
pp. 39-45 ◽  
Author(s):  
Xuerong Zheng ◽  
Zhengguo Jin ◽  
Hui Liu ◽  
Yueqiu Wang ◽  
Xin Wang ◽  
...  
Keyword(s):  
Diethylene Glycol ◽  
Single Phase ◽  
Ambient Pressure ◽  
Solution Synthesis ◽  
Glycol Solution

Evaluation of Semi-dry Mesophilic Anaerobic Co-digestion of Corn Stover and Vegetable Waste by a Single-Phase Process

2017 ◽  
Vol 10 (5) ◽  
pp. 1159-1166 ◽  
Author(s):  
Yunhua Zhang ◽  
Lu Xu ◽  
Yue-gan Liang ◽  
Shuyun Yang ◽  
Xiao-hong Liu
Keyword(s):  
Corn Stover ◽  
Single Phase ◽  
Vegetable Waste ◽  
Phase Process

Two-phase anaerobic treatment of cane-molasses alcohol stillage

1997 ◽  
Vol 36 (6-7) ◽  
pp. 441-448 ◽  
Author(s):  
B. G. Yeoh
Keyword(s):  
Single Phase ◽  
Anaerobic Treatment ◽  
Methane Yield ◽  
Phase System ◽  
Treatment Efficiency ◽  
Two Phase ◽  
Kinetic Evaluation ◽  
Cane Molasses ◽  
Loading Rates ◽  
Phase Process

Anaerobic treatment of cane-molasses alcohol stillage was studied in a thermophilic two-phase system comprising two bioreactors for the acidogenic and methanogenic phases respectively in comparison with the single-phase process. The experiments were conducted with HRT ranging from 36.0 to 9.0 days for single-phase and from 32.7 to 5.6 days for two-phase, corresponding to organic loading rates of 3.452 to 14.487 and 4.646 to 20.022 kgCODm−3day−1 respectively. The treatment efficiency was essentially maintained at BOD5 and COD removal of over 85% and 65% respectively in the two-phase process even with higher substrate loading. The acidogenic phase provided satisfactory conversion of initial COD to VFA averaging 15.6% in the degree of acidification. The methanogenic culture pH of both systems was maintained in a range of 7.4 to 7.8 through self regulation. The methane content of the biogas generated from the two-phase process was significantly higher by about 17% than that from the single-phase process, both decreasing with increasing substrate loading and shorter HRT. The mean overall methane yield was found to be 0.168 m3CH4(STP)kg−1 CODadded or 0.292 m3CH4(STP)kg−1 VSadded from two-phase methanogenesis, compared to 0.055 m3CH4(STP)kg−1CODadded or 0.082 m3CH4(STP)kg−1VSadded from single-phase fermentation. However, methane yield in the two-phase process was enhanced only at COD loading rates higher than 2.9 kgm−3day−1 or VS loading rates higher than 1.8 kgm−3day−1. The ultimate methane yield was evaluated graphically to be 0.216 m3CH4(STP)kg−1CODadded, or 0.401 m3CH4(STP)kg−1 VSadded. This indicated a methane yield efficiency of 73-78% for the two-phase anaerobic digestion of cane-molasses alcohol stillage, which was composed of 24.2% and 28.2% of non-biodegradable COD and VS respectively. Kinetic evaluation of the experimental data provided θm (minumum SRT) and K (kinetic constant) values as 6.6 days and 0.166 respectively based on COD, or 7.0 days and 0.160 respectively based on VS. Application of the two-phase anaerobic process on full scale at an industrial treatment plant for alcohol stillage showed mean treatment efficiency in terms of BOD5 and COD reduction of 84.3% and 63.2% respectively at an average loading rate of 5.1 kgCODm−3day−1, which was in good agreement with the bench-scale studies, considering the great variation in the raw wastewater characteristics typical of an industrial operation.

Magnetic Parameters of R2Fe14B Compounds with Nanograin Structure

2008 ◽  
Vol 584-586 ◽  
pp. 950-954 ◽  
Author(s):  
Irina S. Tereshina ◽  
Gennady S. Burkhanov ◽  
Sergey V. Dobatkin ◽  
O.D. Chistyakov ◽  
Evgeniya A. Tereshina ◽  
...  
Keyword(s):  
Quantitative Data ◽  
Remanent Magnetization ◽  
Vacuum Distillation ◽  
Room Temperature ◽  
Single Phase ◽  
Rare Earth Metals ◽  
Nanocrystalline Structure ◽  
Exchange Interactions ◽  
Magnetic Parameters ◽  
Arc Melting

High-purity compounds R2Fe14B (R = Y, Gd, Tb, Dy, Ho and Er) were prepared by arc melting using rare-earth metals purified by vacuum distillation-sublimation. The compounds R2Fe14B are single-phase and have well-defined directional structure. Nanocrystalline structure was formed by severe plastic deformation of the samples by means of torsion for 5 turns on the Bridgeman anvil under the pressure of 4 GPa at room temperature. The performed investigations of magnetic properties of these compounds allowed us to obtain reliable quantitative data on the intrinsic magnetic parameters, such as saturation magnetization, Curie temperature, the remanent magnetization and coercive force. The enhancement of the remanent magnetization was observed for R2Fe14B in nanocrystalline states compared with the crystalline samples due to the intercrystalline exchange interactions.

scholarly journals Lignin as a Partial Polyol Replacement in Polyurethane Flexible Foam

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2302
Author(s):  
Akash Gondaliya ◽  
Mojgan Nejad
Keyword(s):  
Thermal Properties ◽  
Gel Permeation Chromatography ◽  
31P Nmr Spectroscopy ◽  
Mechanical And Thermal Properties ◽  
Scanning Calorimetry ◽  
Hydroxyl Content ◽  
Wide Range ◽  
Foam Properties ◽  
High Flexibility ◽  
Pu Foams

This study was focused on evaluating the suitability of a wide range of lignins, a natural polymer isolated from different plant sources and chemical extractions, in replacing 20 wt.% of petroleum-based polyol in the formulation of PU flexible foams. The main goal was to investigate the effect of unmodified lignin incorporation on the foam’s structural, mechanical, and thermal properties. The hydroxyl contents of the commercial lignins were measured using phosphorus nuclear magnetic resonance (31P NMR) spectroscopy, molar mass distributions with gel permeation chromatography (GPC), and thermal properties with differential scanning calorimetry (DSC) techniques. The results showed that incorporating 20 wt.% lignin increased tensile, compression, tear propagation strengths, thermal stability, and the support factor of the developed PU flexible foams. Additionally, statistical analysis of the results showed that foam properties such as density and compression force deflection were positively correlated with lignin’s total hydroxyl content. Studying correlations between lignin properties and the performance of the developed lignin-based PU foams showed that lignins with low hydroxyl content, high flexibility (low Tg), and high solubility in the co-polyol are better candidates for partially substituting petroleum-based polyols in the formulation of flexible PU foams intended for the automotive applications.

Influence of Heat Treatments on Microstructures in an Fe-Co-V Alloy

1974 ◽  
Vol 32 ◽  
pp. 512-513
Author(s):  
S. Mahajan ◽  
M. R. Pinnel ◽  
J. E. Bennett
Keyword(s):  
Single Phase ◽  
Alloy Composition ◽  
Supersaturated Solid Solution ◽  
Cell Formation ◽  
Heat Treatments ◽  
Air Cooling ◽  
Iced Brine ◽  
Transmission Electron ◽  
The Matrix ◽  
Bcc Structure

The microstructural changes in an Fe-Co-V alloy (composition by wt.%: 2.97 V, 48.70 Co, 47.34 Fe and balance impurities, such as C, P and Ni) resulting from different heat treatments have been evaluated by optical metallography and transmission electron microscopy. Results indicate that, on air cooling or quenching into iced-brine from the high temperature single phase ϒ (fcc) field, vanadium can be retained in a supersaturated solid solution (α2) which has bcc structure. For the range of cooling rates employed, a portion of the material appears to undergo the γ-α2 transformation massively and the remainder martensitically. Figure 1 shows dislocation topology in a region that may have transformed martensitically. Dislocations are homogeneously distributed throughout the matrix, and there is no evidence for cell formation. The majority of the dislocations project along the projections of <111> vectors onto the (111) plane, implying that they are predominantly of screw character.

Raman And Fluorescence Spectra Observed in Laser Microprobe Measurements of Several Compositions in the Ln-Ba-Cu-O System

1990 ◽  
Vol 48 (2) ◽  
pp. 278-279
Author(s):  
Edgar S. Etz ◽  
Thomas D. Schroeder ◽  
Winnie Wong-Ng
Keyword(s):  
Fluorescence Spectra ◽  
Single Phase ◽  
X Ray Diffraction ◽  
Ceramic Powders ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Raman Microprobe ◽  
Methods Of Synthesis ◽  
Compositional Homogeneity ◽  
Processing Techniques

We are investigating by Raman microprobe measurements the superconducting and related phases in the LnBa2Cu3O7-x (for x=0 to 1) system where yttrium has been replaced by several of the lanthanide (Ln = Nd,Sm,Eu,Ho,Er) elements. The aim is to relate the observed optical spectra (Raman and fluorescence) to the compositional and structural properties of these solids as part of comprehensive materials characterization. The results are correlated with the methods of synthesis, the processing techniques of these materials, and their superconducting properties. Of relevance is the substitutional chemistry of these isostructural systems, the differences in the spectra, and their microanalytical usefulness for the detection of impurity phases, and the assessment of compositional homogeneity. The Raman spectra of most of these compounds are well understood from accounts in the literature.The materials examined here are mostly ceramic powders prepared by conventional solid state reaction techniques. The bulk samples are of nominally single-phase composition as determined by x-ray diffraction.

Observation of pseudo 10-fold symmetry in the ordered iron-zinc delta phase

1992 ◽  
Vol 50 (1) ◽  
pp. 36-37
Author(s):  
L. A. Giannuzzi ◽  
A. S. Ramani ◽  
P. R. Howell ◽  
H. W. Pickering ◽  
W. R. Bitler
Keyword(s):  
Single Phase ◽  
X Ray Diffraction ◽  
Rich Region ◽  
Average Cell ◽  
X Ray ◽  
Delta Phase ◽  
Cell Dimensions ◽  
Δ Phase ◽  
Morphological Differences ◽  
Concentration Discontinuity

The δ phase is a Zn-rich intermetallic, having a composition range of ∼ 86.5 - 92.0 atomic percent Zn, and is stable up to 665°C. The stoichiometry of the δ phase has been reported as FeZn7 and FeZn10 The deviation in stoichiometry can be attributed to variations in alloy composition used by each investigator. The structure of the δ phase, as determined by powder x-ray diffraction, is hexagonal (P63mc or P63/mmc) with cell dimensions a = 1.28 nm, c = 5.76 nm, and 555±8 atoms per unit cell. Later work suggested that the layer produced by hot-dip galvanizing should be considered as two distinct phases which are characterized by their morphological differences, namely: the iron-rich region with a compact appearance (δk) and the zinc-rich region with a columnar or palisade microstructure (δp). The sub-division of the δ phase was also based on differences in diffusion behavior, and a concentration discontinuity across the δp/δk boundary. However, work utilizing Weisenberg photographs on δ single crystals reported that the variation in lattice parameters with composition was small and hence, structurally, the δk phase and the δp phase were the same and should be thought of as a single phase, δ. Bastin et al. determined the average cell dimensions to be a = 1.28 nm and c = 5.71 nm, and suggested that perhaps some kind of ordering process, which would not be observed by x-ray diffraction, may be responsible for the morphological differences within the δ phase.

A TEM study of the influence of microstructure on the superplastic behavior of a U-5.8 wt.% Nb alloy

1986 ◽  
Vol 44 ◽  
pp. 568-569
Author(s):  
G. Mackiewicz Ludtka
Keyword(s):  
Grain Size ◽  
Heating Rate ◽  
Phase Field ◽  
Single Phase ◽  
Superplastic Behavior ◽  
Two Phase ◽  
Single Phase Field

Historically, metals exhibit superplasticity only while forming in a two-phase field because a two-phase microstructure helps ensure a fine, stable grain size. In the U-5.8 Nb alloy, superplastici ty exists for up to 2 h in the single phase field (γ1) at 670°C. This is above the equilibrium monotectoid temperature of 647°C. Utilizing dilatometry, the superplastic (SP) U-5.8 Nb alloy requires superheating to 658°C to initiate the α+γ2 → γ1 transformation at a heating rate of 1.5°C/s. Hence, the U-5.8 Nb alloy exhibits an anomolous superplastic behavior.

TEM investigations of surface residual stress relaxation in A12O3 and Al2O3-SiC nanocomposite

1994 ◽  
Vol 52 ◽  
pp. 628-629
Author(s):  
J. Fang ◽  
H. M. Chan ◽  
M. P. Harmer
Keyword(s):  
Residual Stress ◽  
Single Phase ◽  
Stress Relief ◽  
Stress Recovery ◽  
Surface Residual Stress ◽  
Microscopic Mechanism ◽  
Sic Particles ◽  
Annealing Procedure ◽  
The Difference ◽  
Nano Size

It was Niihara et al. who first discovered that the fracture strength of Al2O3 can be increased by incorporating as little as 5 vol.% of nano-size SiC particles (>1000 MPa), and that the strength would be improved further by a simple annealing procedure (>1500 MPa). This discovery has stimulated intense interest on Al2O3/SiC nanocomposites. Recent indentation studies by Fang et al. have shown that residual stress relief was more difficult in the nanocomposite than in pure Al2O3. In the present work, TEM was employed to investigate the microscopic mechanism(s) for the difference in the residual stress recovery in these two materials.Bulk samples of hot-pressed single phase Al2O3, and Al2O3 containing 5 vol.% 0.15 μm SiC particles were simultaneously polished with 15 μm diamond compound. Each sample was cut into two pieces, one of which was subsequently annealed at 1300° for 2 hours in flowing argon. Disks of 3 mm in diameter were cut from bulk samples.

Sign in / Sign up

Export Citation Format

Share Document