scholarly journals Introducing Deep Eutectic Solvents as a Water-Free Dyeing Medium for Poly (1,4-cYclohexane Dimethylene Isosorbide Terephthalate) PICT Nanofibers

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2594
Author(s):  
Nadir Hussain ◽  
Sadam Hussain ◽  
Mujahid Mehdi ◽  
Muzamil Khatri ◽  
Sana Ullah ◽  
...  

Water, one of the most priceless sources of life, is becoming dangerously threatened and contaminated due to population growth, industrial development, and climatic variations. The drainage of industrial, farming, and municipal sewage into drinking water sources pollutes the water. The textile processing industry is one of the major consumers of water. Herein, the idea of water-free dyeing of electrospun poly (1, 4-cyclohexane dimethylene isosorbide terephthalate) PICT nanofibers is proposed. For this, two different deep eutectic solvents (DE solvents) were introduced as an alternative to water for the dyeing of PICT nanofibers in order to develop a water-free dyeing medium. For this, C.I. disperse red 167 was used as a model dye to improve the aesthetic properties of PICT nanofibers. PICT nanofibers were dyed by conventional batch dyeing and ultrasonic dyeing methods to investigate the effect of the dyeing technique on color buildup characteristics. Dyeing conditions such as dyeing time, temperature and, dye-concentration were optimized. Morphological and chemical characterization observations revealed a smooth morphology of dyed and undyed PICT nanofibers. The ultrasonically dyed nanofibers showed higher color strength and increased tensile strength compared to conventionally dyed nanofibers. Further, the consumption of electrical and thermal energy was also calculated for both processes. The results confirmed that the ultrasonic dyeing method can save 58% on electrical energy and 25% on thermal energy as compared to conventional dyeing.

Author(s):  
Я.М. КАШИН ◽  
Л.Е. КОПЕЛЕВИЧ ◽  
А.В. САМОРОДОВ ◽  
Ч. ПЭН

Описаны конструктивные особенности трехвходовой аксиальной генераторной установки (ТАГУ), преобразующей кинетическую энергию ветра и световую энергию солнца и суммирующей механическую, световую и тепловую энергию с одновременным преобразованием полученной суммарной энергии в электрическую. Показаны преимущества ТАГУ перед двухвходовыми генераторными установками. Дополнительное включение стабилизатора напряжения в схему ТАГУ позволило расширить область применения стабилизированной трехвходовой аксиальной генераторной установки за счет стабилизации ее выходного напряжения. The design features of the three-input axial generating installation (TAGI), which converts the kinetic energy of wind and light energy of the sun and sums the mechanical, light and thermal energy with the simultaneous conversion of the total energy into electrical energy, are described. The benefits of TAGI in front of the two-input generating installation shown. The additional introduction of a voltage regulator into the TAGI scheme allowed to expand the scope of the stabilized three-input axial generating installation by stabilizing its output voltage.


Cotton leaves have been used to extract natural dye for dyeing of Egyptian cotton variety Giza 86 fabric and its blend with polyester 50:50, using different mordants such as iron (II) sulfate, copper (II) sulfate, and alum. The exhaust dyeing method was utilized using the pre-mordant technique. It is observed that both fabric samples can be dyed in different colors and depth of shades with Cotton leaves dye. Iron (II) sulfate ensures the best light fastness. Improved light fastness is obtained using abovementioned lower amounts of iron (II) sulfate and copper (II) sulfate. Alum is found to be less effective than iron (II) sulfate and copper (II) sulfate on the light fastness. As a novel alternative and potential natural dye, Cotton leaves extract solution can be used to get various colors and shades with satisfactory fastness properties. The mordanted and un-mordanted fabric samples were tested for their dyeing performance in terms of color parameters K/S, (L*), a*, b*, (C*) and (H*), and fastness properties (wash, perspiration, light and rubbing fastness) were studied. The samples showed high color strength, and high fastness properties. These results are very important for industrial application and with the production of a natural dye as an inexpensive source from cotton leaves as a by-product. Another objective is to increase the production of eco-textile garments with a good price for the Egyptian customers.


2020 ◽  
Vol 161 ◽  
pp. 1155-1175
Author(s):  
Roberto Valente de Souza ◽  
Elisa Helena Leão Fernandes ◽  
José Luiz Lima de Azevedo ◽  
Mariana dos Santos Passos ◽  
Rafaela Martins Corrêa

2020 ◽  
Vol 11 (1) ◽  
pp. 37-42
Author(s):  
Md Abdullah Al Mamun ◽  
Mohammad Mamun Hossain ◽  
Mubarak Ahmad Khan

Polyester fabric is usually dyed with disperse dyes which has severe limitations specially toxicity and environmental issues. The aim of the present research is to introduce an ecofriendly dyeing process for polyester fabric with natural dyes. The natural colorants were extracted from mahogany seed pods using the simple acid boiling method. The spectroscopic analysis of the crude extract was carried out by UV and IR spectra of the extracted dyes and illuminated the presence of natural tannins as coloring materials in the crude extract. 10g fabric was dyed in 200cc extracted solution at 130⁰C for 60 minutes in exhaust dyeing method followed by neutralization and soaping. Finally, a light brown dyed fabric was obtained. The dyed fabric exhibited color strength in terms of k/s value of 0.63 (λmax 360nm), lightness of 80.565 and chromaticity value of 12.002 CIE units. Different samples were dyed by fluctuating the dyeing period. The dyeing traits of the dyed materials were judged in terms of their color strength and fatness properties. All testes were carried out following the ISO standards. From the results, it is lucid that the dyed fabric showed acceptable color fastness properties in case of all fastness except color fastness to light. It is observed that dyeing time had profound influence on the color strength (k/s value) of the dyed material. The k/s value increases with the increase of dyeing period up to 120 minutes. The maximum color strength (0.76) was noted for the fabric. The shorter dyeing time produces lighter samples and the longer dyeing time produced colorful samples. Journal of Engineering Science 11(1), 2020, 37-42


2019 ◽  
Vol 41 (1) ◽  
pp. 86-107 ◽  
Author(s):  
Ahmad Riaz ◽  
Ruobing Liang ◽  
Chao Zhou ◽  
Jili Zhang

The hybrid photovoltaic-thermal system has shown great progress. Electrical energy is produced from PV panels while thermal energy is produced via a working fluid carried through the panels. In this paper, the vertical PV/T is introduced using working fluids such as air and liquid, which serve to control the excess temperature of the PV panels as well as to collect heat to be made available as thermal energy. Installations of PV/T systems on building façades, as well as integration with other technologies such as heat pipe and heat pump are also discussed. Current studies of such building integration technologies are also explored, including the scale of application. This study aims to provide constructive information which can be used in future development of building facades for large-scale applications, to contribute to future sustainable development. Practical application: This study helps researchers and engineers who are considering photovoltaic thermal systems for building façades to have better understanding of its effect on electrical and thermal energy – for space heating, fresh air supply and hot water supply – using an active building envelope.


1997 ◽  
Vol 35 (5) ◽  
pp. 55-62 ◽  
Author(s):  
Ian D. Smith ◽  
George N. Bis ◽  
Edgar R. Lemon ◽  
Lloyd R. Rozema

Since November of 1991, an experimental constructed wetland has successfully treated municipal sewage effluent on a year round basis in a cool climate. The sub-surface, vertically pulsed flow system is located at a latitude of approximately 43 degrees, 15 minutes north latitude in south-central Canada. The 5 metre long by 5 metre wide by 1.2 metre deep constructed wetland cells were designed to operate through extended freezing periods via a number of specific features. The most important features being the allowance of thatch accumulation atop the system, ice accretion within the upper cell strata both acting as insulating layers, and the transfer of thermal energy to the system from warmer deep soils. The cells were hydraulically loaded below this frozen layer of granular matrix six times a day. A dense three dimensional array of thermocouples was planted within the first of the three constructed wetland cells in a series to allow for the assessment of thermal data at a high level of temporal and spatial resolution. Thermal data were sampled every five minutes and averaged and stored every hour over a two year period (1994 and 1995). The data were reviewed statistically to determine the operating envelope experienced at the Niagara-On-The-Lake experimental constructed wetland site. A detailed review of winter thermal data was made to provide parameters for the use of the HEATFLOW density-dependent ground water flow and thermal energy transport numerical model (Molson and Frind, 1995). The use of this coupled Darcy flux, thermal transport model has allowed for a better understanding of the importance of various thermal design considerations, and has allowed for the undertaking of sensitivity analyses for design assessment and optimization. The sensitivity analyses indicate that the retention of deep soil heat and top insulation from plant thatch are the most important thermal features. It is likely that this technology can be used in areas colder than Niagara-On-The-Lake.


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