scholarly journals Characterization of Carbonaceous Deposits on an End-of-Life Engines for Effective Cleaning for Remanufacturing

2021 ◽  
Vol 13 (2) ◽  
pp. 950
Author(s):  
Xing Wang ◽  
Jianfeng Li ◽  
Xiujie Jia ◽  
Mingliang Ma ◽  
Yuan Ren
Keyword(s):  
End Of Life ◽  
Sustainable Manufacturing ◽  
Hybrid Structure ◽  
Nuclear Magnetic Resonance Study ◽  
Carbonaceous Deposit ◽  
X Ray ◽  
Cleaning Method ◽  
Carbonaceous Deposits ◽  
Strong Adhesion

Remanufacturing is one of the most effective strategies to achieve sustainable manufacturing and restore the performance of end-of-life products. However, the lack of an effective cleaning method to clean carbonaceous deposits severely hampers the remanufacturing of end-of-life engines. To explore an appropriate cleaning method, it is necessary to first study the characterization of the carbonaceous deposits. A broad range of analyses including X-ray fluorescence spectrometry, thermogravimetric analysis, 1H-nuclear magnetic resonance study, X-ray diffraction analysis, and scanning electron microscopy were performed to conduct an in-depth characterization of the carbonaceous deposits. The results showed that a hybrid structure composed of organics and inorganics is the most distinguishing feature of the carbonaceous deposit in end-of-life engines. The inorganics form the skeleton on which organics get attached, thereby resulting in a strong adhesion of the deposit and increasing the difficulty of cleaning. Therefore, a method in which several cleaning forces can be simultaneously applied is more suitable for the present purpose. Molten salt cleaning was chosen to verify the feasibility of this proposal. This method was shown to have the potential to effectively clean the carbonaceous deposit. This finding could contribute towards promoting the effective remanufacturing of end-of-life engines.

Preliminary characterization of a new hybrid structure with CdTe: x-ray imaging capabilities

1994 ◽  
Author(s):  
Marc Cuzin ◽  
Francis Glasser ◽  
R. Mermet ◽  
N. Meunier ◽  
Olivier C. Peyret ◽  
...  
Keyword(s):  
Hybrid Structure ◽  
X Ray ◽  
Preliminary Characterization ◽  
X Ray Imaging

scholarly journals Formation and Evolution Mechanism for Carbonaceous Deposits on the Surface of a Coking Chamber

Processes ◽  
2019 ◽  
Vol 7 (8) ◽  
pp. 508 ◽  
Author(s):  
Hao Wang ◽  
Baosheng Jin ◽  
Xiaojia Wang ◽  
Gang Tang
Keyword(s):  
Photoelectron Spectroscopy ◽  
Oxidation Process ◽  
Diffraction Spectrum ◽  
Carbonyl Groups ◽  
X Ray Diffraction ◽  
Carbonaceous Deposit ◽  
X Ray ◽  
Carbonaceous Deposits ◽  
Infrared Spectrometer ◽  
Formation And Evolution

This work aimed to investigate the carbonaceous deposits on the surface of the coking chamber. Scanning electron microscopy (SEM), X-ray fluorescence spectrum (XRF), Fourier transform infrared spectrometer (FTIR), Raman spectroscopy, X-ray diffraction spectrum (XRD), and X-ray photoelectron spectroscopy (XPS) were applied to investigate the carbonaceous deposits. FTIR revealed the existence of carboxyl, hydroxyl, and carbonyl groups in the carbonaceous deposits. SEM showed that different carbonaceous deposit layers presented significant differences in morphology. XRF and XPS revealed that the carbonaceous deposits mainly contained C, O, and N elements, with smaller amounts of Al, Si, and Ca elements. It was found that in the formation of carbonaceous deposits, the C content gradually increased while the O and N elements gradually decreased. It was also found that the absorbed O2 and H2O took part in the oxidation process of the carbon skeleton to form the =O and –O– structure. The oxidation and elimination reaction resulted in change in the bonding state of the O element, and finally formed compact carbonaceous deposits on the surface of the coking chamber. Based on the analysis, the formation and evolution mechanisms of carbonaceous deposits were discussed.

Saxs Characterization of Pyrolytic Carbon Blacks

1995 ◽  
Vol 407 ◽  
Author(s):  
B. Sahouli ◽  
S. Blacher ◽  
F. Brouers ◽  
R. Sobry ◽  
G. van den Bossche ◽  
...  
Keyword(s):  
Fractal Dimension ◽  
Pyrolysis Temperature ◽  
Pyrolytic Carbon ◽  
X Ray ◽  
Carbon Blacks ◽  
Carbonaceous Deposits ◽  
X Ray Scattering ◽  
Vacuum Pyrolysis ◽  
Different Temperatures

ABSTRACTThe surface fractal dimension (Ds) of pyrolytic carbon blacks (CBp) was determined using small angle X-ray scattering (SAXS). The CBp were produced by vacuum pyrolysis of used tires at different temperatures and pressures. For the CBp a dependence of the pyrolysis conditions on the fractal dimension was observed. The fractal dimension decreases, suggesting a smother surface, with increasing pyrolysis pressure and to a lesser intent with increasing pyrolysis temperature. Earlier SIMS and ESCA investigations have indicated that an evident correlation exists between the surface morphology and the surface chemistry of the CBp. According to these investigations, the smoothing of the CBp surface is due to the formation of carbonaceous deposits from adsorbed hydrocarbons on the CBp.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

High Resolution Replication of Organoclay Surfaces

1982 ◽  
Vol 40 ◽  
pp. 576-577
Author(s):  
W. W. Barker ◽  
W. E. Rigsby ◽  
V. J. Hurst ◽  
W. J. Humphreys
Keyword(s):  
Clay Mineral ◽  
Organic Molecule ◽  
Organic Molecules ◽  
X Ray Diffraction ◽  
Xrd Pattern ◽  
X Ray ◽  
Naturally Occurring ◽  
Silicate Layers ◽  
Mineral Identification

Experimental clay mineral-organic molecule complexes long have been known and some of them have been extensively studied by X-ray diffraction methods. The organic molecules are adsorbed onto the surfaces of the clay minerals, or intercalated between the silicate layers. Natural organo-clays also are widely recognized but generally have not been well characterized. Widely used techniques for clay mineral identification involve treatment of the sample with H2 O2 or other oxidant to destroy any associated organics. This generally simplifies and intensifies the XRD pattern of the clay residue, but helps little with the characterization of the original organoclay. Adequate techniques for the direct observation of synthetic and naturally occurring organoclays are yet to be developed.

Digital x-ray mapping of nanometer-size supported bimetallic catalysts

1988 ◽  
Vol 46 ◽  
pp. 530-531
Author(s):  
L. T. Germinario
Keyword(s):  
Background Radiation ◽  
Metal Cluster ◽  
Single Element ◽  
Beam Diameter ◽  
X Rays ◽  
X Ray ◽  
Major Interest ◽  
Induced Changes

Understanding the role of metal cluster composition in determining catalytic selectivity and activity is of major interest in heterogeneous catalysis. The electron microscope is well established as a powerful tool for ultrastructural and compositional characterization of support and catalyst. Because the spatial resolution of x-ray microanalysis is defined by the smallest beam diameter into which the required number of electrons can be focused, the dedicated STEM with FEG is the instrument of choice. The main sources of errors in energy dispersive x-ray analysis (EDS) are: (1) beam-induced changes in specimen composition, (2) specimen drift, (3) instrumental factors which produce background radiation, and (4) basic statistical limitations which result in the detection of a finite number of x-ray photons. Digital beam techniques have been described for supported single-element metal clusters with spatial resolutions of about 10 nm. However, the detection of spurious characteristic x-rays away from catalyst particles produced images requiring several image processing steps.

Plant Pathology Diagnosed by X-Ray Microanalysis

1987 ◽  
Vol 45 ◽  
pp. 974-975
Author(s):  
J. H. Resau ◽  
N. Howell ◽  
S. H. Chang
Keyword(s):  
Electron Microscopy ◽  
Plant Pathology ◽  
Biochemical Characterization ◽  
Nutrient Deficiency ◽  
Green Leaf ◽  
Parasitic Infestation ◽  
X Ray

Spinach grown in Texas developed “yellow spotting” on the peripheral portions of the leaves. The exact cause of the discoloration could not be determined as there was no evidence of viral or parasitic infestation of the plants and biochemical characterization of the plants did not indicate any significant differences between the yellow and green leaf portions of the spinach. The present study was undertaken using electron microscopy (EM) to determine if a micro-nutrient deficiency was the cause for the discoloration.Green leaf spinach was collected from the field and sent by express mail to the EM laboratory. The yellow and equivalent green portions of the leaves were isolated and dried in a Denton evaporator at 10-5 Torr for 24 hrs. The leaf specimens were then examined using a JEOL 100 CX analytical microscope. TEM specimens were prepared according to the methods of Trump et al.

EXELFS Studies of Carbon Fibers

1990 ◽  
Vol 48 (2) ◽  
pp. 72-73
Author(s):  
V. Serin ◽  
K. Hssein ◽  
G. Zanchi ◽  
J. Sévely
Keyword(s):  
Carbon Fibers ◽  
Energy Analysis ◽  
Electron Excitation ◽  
Complex Structures ◽  
High Modulus ◽  
Promising Technique ◽  
X Ray ◽  
Fine Structures ◽  
X Ray Absorption

The present developments of electron energy analysis in the microscopes by E.E.L.S. allow an accurate recording of the spectra and of their different complex structures associated with the inner shell electron excitation by the incident electrons (1). Among these structures, the Extended Energy Loss Fine Structures (EXELFS) are of particular interest. They are equivalent to the well known EXAFS oscillations in X-ray absorption spectroscopy. Due to the EELS characteristic, the Fourier analysis of EXELFS oscillations appears as a promising technique for the characterization of composite materials, the major constituents of which are low Z elements. Using EXELFS, we have developed a microstructural study of carbon fibers. This analysis concerns the carbon K edge, which appears in the spectra at 285 eV. The purpose of the paper is to compare the local short range order, determined by this way in the case of Courtauld HTS and P100 ex-polyacrylonitrile carbon fibers, which are high tensile strength (HTS) and high modulus (HM) fibers respectively.

Characterization of defects in tabular silver halide grains

1990 ◽  
Vol 48 (4) ◽  
pp. 1046-1047
Author(s):  
C. Goessens ◽  
D. Schryvers ◽  
J. Van Landuyt ◽  
A. Verbeeck ◽  
R. De Keyzer
Keyword(s):  
Radiation Damage ◽  
Silver Halide ◽  
Chemical Characteristics ◽  
X Ray ◽  
Free Region ◽  
Central Defect ◽  
Crystallographic Defects ◽  
Physical And Chemical ◽  
Two Sides

Silver halide grains (AgX, X=Cl,Br,I) are commonly recognized as important entities in photographic applications. Depending on the preparation specifications one can grow cubic, octahedral, tabular a.o. morphologies, each with its own physical and chemical characteristics. In the present study crystallographic defects introduced by the mixing of 5-20% iodide in a growing AgBr tabular grain are investigated. X-ray diffractometry reveals the existence of a homogeneous Ag(Br1-xIx) region, expected to be formed around the AgBr kernel. In fig. 1 a two-beam BF image, taken at T≈100 K to diminish radiation damage, of a triangular tabular grain is presented, clearly showing defect contrast fringes along four of the six directions; the remaining two sides show similar contrast under relevant diffraction conditions. The width of the central defect free region corresponds with the pure AgBr kernel grown before the mixing with I. The thickness of a given grain lies between 0.15 and 0.3 μm: as indicated in fig. 2 triangular (resp. hexagonal) grains exhibit an uneven (resp. even) number of twin interfaces (i.e., between + and - twin variants) parallel with the (111) surfaces. The thickness of the grains and the existence of the twin variants was confirmed from CTEM images of perpendicular cuts.

Synthesis and characterization of TiN / Ti / AISI 410 coatings

2018 ◽  
Vol 2 (1) ◽  
pp. 7
Author(s):  
S Chirino ◽  
Jaime Diaz ◽  
N Monteblanco ◽  
E Valderrama
Keyword(s):  
Synthesis And Characterization ◽  
Photoemission Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Columnar Grains ◽  
Tin Thin Films ◽  
Steel Aisi ◽  
Interacting Surfaces ◽  
Stainless Steel Aisi

The synthesis and characterization of Ti and TiN thin films of different thicknesses was carried out on a martensitic stainless steel AISI 410 substrate used for tool manufacturing. The mechanical parameters between the interacting surfaces such as thickness, adhesion and hardness were measured. By means of the scanning electron microscope (SEM) the superficial morphology of the Ti/TiN interface was observed, finding that the growth was of columnar grains and by means of EDAX the existence of titanium was verified.  Using X-ray diffraction (XRD) it was possible to observe the presence of residual stresses (~ -3.1 GPa) due to the different crystalline phases in the coating. Under X-ray photoemission spectroscopy (XPS) it was possible to observe the molecular chemical composition of the coating surface, being Ti-N, Ti-N-O and Ti-O the predominant ones.

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