scholarly journals Durability of Sustainable Ceramics Produced by Alkaline Activation of Clay Brick Residue

2021 ◽  
Vol 13 (19) ◽  
pp. 10931
Author(s):  
Fabiana Pereira da Costa ◽  
Izabelle Marie Trindade Bezerra ◽  
Jucielle Veras Fernandes ◽  
Alisson Mendes Rodrigues ◽  
Romualdo Rodrigues Menezes ◽  
...  

Alkali-activated materials (AAMs) were produced using residues from the red ceramic industry as a precursor, and sodium hydroxide (NaOH), potassium hydroxide (KOH), and sodium silicate (Na2SiO3) as alkaline activators. The effect of activators and curing conditions on physical-mechanical properties and durability were evaluated. The processing parameters (amount of water and consistency index) and the activation conditions (the activator contents and curing temperature) were defined based on an experimental design getting the flexural rupture module as the response. The durability behavior was evaluated by natural aging, accelerated aging (simulated rain test), exposure to the marine environment (salt fog), and acidic environments (HCl and H2SO4). The results showed that the NaOH- and KOH-activated samples exhibited inferior mechanical behavior than those activated with Na2SiO3. In the durability studies, due to leaching, there was a decrease in mechanical strength when samples are subjected to aggressive exposure conditions. However, the strength values are still higher than the minimum indicated for traditional ceramic applications.

2014 ◽  
Vol 672-674 ◽  
pp. 1823-1827
Author(s):  
Xiao Wei Sun ◽  
Wan Yang Niu ◽  
Ling Ling Wang

These are many factors that can influence the properties of alkali-activated slag cementitious material, such as the modulus and content of water glass, water-cement ratio, curing conditions, and so forth. The rules that how these factors affect setting time and strength of the material are systematically discussed in the paper. It is found that the setting time of the material depends on the concentration of alkaline ions in solution; The material will have the best strength when the modulus and content of water glass are 1.4 and 8%, respectively. The curing temperature increase will be helpful to compressive strength increase.


2010 ◽  
Vol 452-453 ◽  
pp. 737-740
Author(s):  
Hyun Jin Kang ◽  
Gum Sung Ryu ◽  
Gyung Taek Koh ◽  
Su Tae Kang ◽  
Jung Jun Park

This paper evaluates the relationship between the compressive strength and microscopic structure of geopolymer mortar using 100% of fly ash instead of cement. The experimental variable is the curing temperature, which may influence the compressive strength of the geopolymer. The compressive strength, porosity, XRD, SEM and EDS are examined after 48 hours of curing at 30, 60 and 90°C. The resulting compressive strength at 60°C appeared to be the largest. In order to evaluate the voids produced during the polymerization, the porosity was measured and showed also the largest value after curing at 60°C during 48 hours. Furthermore, SEM and EDS analyses verified clear improvement of the microstructure after 48 hours of curing at 60°C. Such result can be explained by the variation of the Si-Al ratio according to the curing conditions, which revealed to be lower for curing at 30 and 90°C than at 60°C and demonstrated that the curing temperature has significantly effect on the compressive strength of the geopolymer.


2012 ◽  
Vol 560-561 ◽  
pp. 580-585
Author(s):  
Bogdan Iliev Bogdanov ◽  
Yancho Hristov ◽  
Dimitar Petrov Georgiev ◽  
Irena Markovska

A lightweight inorganic polymer is obtained using ash from thermal power plants, metakaolinite and lightweight aggregate. This inorganic material is activated using small amounts of sodium hydroxide and sodium silicate solution. Processing parameters and various curing conditions, such as curing temperature, curing time and moisture, are investigated. Compressive strength, rate of water absorption and density of each sample were measured.


Author(s):  
Tali H. Horst ◽  
Richard D. Smith ◽  
Antje Potthast ◽  
Martin A. Hubbe

AbstractThree copies of a book that had been optionally deacidified using two different procedures in 1967, and then subjected to accelerated aging, were tested again after 52 years of natural aging. Matched copies of the book Cooking the Greek Way, which had been printed in Czechoslovakia on acidic paper, were evaluated. Nonaqueous treatment of two of the copies with magnesium methoxide dissolved in chlorofluorocarbon solvent had been found in 1967 to have decreased the susceptibility to embrittlement, as evidenced by the results of the accelerated aging, followed by folding endurance tests. Retesting of the same books in 2019, after 52 years of room temperature storage, showed that the deacidification treatments had achieved the following benefits in comparison to the untreated book: (a) higher brightness; (b) higher folding endurance; (c) tensile breaking length higher in the cross-direction of the paper; (d) substantial alkaline reserve content, (e) an alkaline surface pH in the range 7.1–7.4, and (f) higher molecular mass of the cellulose. Remarkably, some of the folding endurance results matched those of unaged samples evaluated in 1967. Scanning electron micrographs showed no differences between the treated and untreated books.


2021 ◽  
Vol 11 (11) ◽  
pp. 4754
Author(s):  
Assia Aboubakar Mahamat ◽  
Moussa Mahamat Boukar ◽  
Nurudeen Mahmud Ibrahim ◽  
Tido Tiwa Stanislas ◽  
Numfor Linda Bih ◽  
...  

Earth-based materials have shown promise in the development of ecofriendly and sustainable construction materials. However, their unconventional usage in the construction field makes the estimation of their properties difficult and inaccurate. Often, the determination of their properties is conducted based on a conventional materials procedure. Hence, there is inaccuracy in understanding the properties of the unconventional materials. To obtain more accurate properties, a support vector machine (SVM), artificial neural network (ANN) and linear regression (LR) were used to predict the compressive strength of the alkali-activated termite soil. In this study, factors such as activator concentration, Si/Al, initial curing temperature, water absorption, weight and curing regime were used as input parameters due to their significant effect in the compressive strength. The experimental results depict that SVM outperforms ANN and LR in terms of R2 score and root mean square error (RMSE).


Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 714 ◽  
Author(s):  
Evangelos Petrakis ◽  
Vasiliki Karmali ◽  
Georgios Bartzas ◽  
Konstantinos Komnitsas

This study aims to model grinding of a Polish ferronickel slag and evaluate the particle size distributions (PSDs) of the products obtained after different grinding times. Then, selected products were alkali activated in order to investigate the effect of particle size on the compressive strength of the produced alkali activated materials (AAMs). Other parameters affecting alkali activation, i.e., temperature, curing, and ageing time were also examined. Among the different mathematical models used to simulate the particle size distribution, Rosin–Rammler (RR) was found to be the most suitable. When piecewise regression analysis was applied to experimental data it was found that the particle size distribution of the slag products exhibits multifractal character. In addition, grinding of slag exhibits non-first-order behavior and the reduction rate of each size is time dependent. The grinding rate and consequently the grinding efficiency increases when the particle size increases, but drops sharply near zero after prolonged grinding periods. Regarding alkali activation, it is deduced that among the parameters studied, particle size (and the respective specific surface area) of the raw slag product and curing temperature have the most noticeable impact on the compressive strength of the produced AAMs.


Author(s):  
Abdel-Hamid I. Mourad ◽  
Mouza S. Al Mansoori ◽  
Lamia A. Al Marzooqi ◽  
Farah A. Genena ◽  
Nizamudeen Cherupurakal

Kevlar composite materials are getting scientific interest in repairing of oil and gas pipelines in both offshore and onshore due to their unique properties. Curing is one of the major factor in deciding the final mechanical performance of laminated Kevlar/epoxy nanocomposites. The parameters such as curing time, temperature and applied pressure during the hot pressing will affect chemistry of crosslinking of the epoxy matrix and interaction of epoxy with the Kevlar fiber. The present study is carried out to evaluate the optimal curing conditions of the Kevlar/epoxy nanocomposites. Three different nanofillers (namely Multi walled Carbon nanotubes (MWCNT), Silicon Carbide (SiC) and Aluminum Oxide (Al2O3)) are incorporated in different weight percentage. Differential Scanning Calorimetry (DSC) and Thermo-Gravimetric Analysis (TGA) tests are carried out to determine the thermal stability and optimal curing conditions. Mechanical performance is investigated by conducting flexure, and drop weight tests. The results show that, the optimal curing temperature for maximizing the mechanical properties is at 170°C. Peeling off the Kevlar layers are observed for nanocomposite samples cured under 100°C. Mechanical strength of the composites is enhanced by optimizing the curing conditions and nanofiller contents.


2021 ◽  
Vol 233 ◽  
pp. 03047
Author(s):  
Yu Fang ◽  
Li Yongchao

In order to further promote the research and application of MgO expansion agent in concrete field, this paper carried out the effect of different humidity and temperature conditions on the expansion properties of mortar and mortar specimens mixed with MgO expansion agent. In addition, the mechanism of the factors affecting the sensitivity of the MgO expansion agent is revealed by combining microscopic technology. The results show that the higher the curing temperature and the greater the curing humidity, the greater the expansion efficiency of the MgO expansion agent. The temperature of 20~40°C has no obvious effect on the efficiency of the MgO expansion agent, but the expansion value of the specimen doubles as the temperature rises to 40~80°C. Besides, the higher the curing humidity, the better the expansion efficiency of the MgO expansion agent, but the MgO expansion agent is more sensitive to the low humidity environment, and the specimen shrinks in the lower humidity environment (RH=60%).


Alkali-activated concrete (AAC) is mounting as a feasible alternative to OPC assimilated to reduce greenhouse gas emanated during the production of OPC. Use of pozzolana results in gel over-strengthening and fabricate less quantity of Ca(OH)2 which provide confrontation to concrete against hostile environment. (AAC) is potential due to inheriting the property of disbursing CO2 instantly from the composition. Contrastingly an option to ordinary Portland cement (OPC), keeping this fact in mind the goal to evacuate CO2 emits and beneficiate industrial by-products into building material have been taken into consideration. Production of alkali-activated cement emanates CO2 nearly 50-80% less than OPC. This paper is the general assessment of current report on the fresh and hardened properties of alkali-activated fly ash (AAF), alkali-activated slag (AAS), and alkali activated slag and fly ash (AASF) concrete. In the recent epoch, there has been a progression to blend slag with fly ash to fabricate ambient cured alkali-activated concrete. Along with that the factors like environmental friendliness, advanced studies and investigation are also mandatorily required on the alkali activated slag and fly ash concrete. In this way, the slag to fly ash proportion impacts the essential properties and practical design of AAC. This discusses and reports the issue in an intensive manner in the following sections. This will entail providing a good considerate of the following virtues like workability, compressive strength, tensile strength, durability issues, ambient and elevated-temperature curing of AAC which will improve further investigation to elaborate the correct test methods and to commercialize it.


Sign in / Sign up

Export Citation Format

Share Document