scholarly journals Synergistic Study of Solid Lubricant Nano-Additives Incorporated in canola oil for Enhancing Energy Efficiency and Sustainability

2021 ◽  
Vol 14 (1) ◽  
pp. 290
Author(s):  
Soumya Sikdar ◽  
Md Hafizur Rahman ◽  
Pradeep L. Menezes
Keyword(s):  
Vegetable Oils ◽  
Canola Oil ◽  
Hexagonal Boron Nitride ◽  
Low Cost ◽  
Tribological Performance ◽  
Base Oil ◽  
The Coefficient Of Friction ◽  
Nano Lubricant ◽  
Interacting Surfaces ◽  
Disk Test

In recent years, with the development of eco-friendly lubricants, different vegetable oils have been studied and found to improve the overall tribological performance compared to petroleum-based oils. Being one of the commonly used vegetable oils, canola oil has become popular due to its non-toxicity and low cost. However, this bio-lubricant lacks tribological performance compared to petroleum-based oils. To improve its performance, sustainable solid additives such as graphene nanoplatelet (GNP) and hexagonal boron nitride (hBN) have recently gained the researcher’s attention. While incorporating nanomaterials in the oil as additives is a promising way to improve base oil’s performance, the excessive use of nanoparticles can introduce undesirable effects. This study investigated canola oil’s tribological performances with the addition of 0.5, 1.0, 1.5, and 2.0 wt.% GNP and 0.5, 1.0, and 1.5 wt.% hBN nanoparticles. The dynamic viscosities of these seven settings showed higher viscosity for GNP-incorporated oils compared to that with hBN. The boundary lubrication regime was targeted for the coefficient of friction (COF) and wear analyses during each pin on the disk test. It was observed that for the GNP, 1.5 wt.% provided the minimum COF (52% less than base oil), whereas, for the hBN, 1.0 wt.% provided the lowest (40% less than base oil) values. Based on these insights, three nano lubricant mixtures were formulated by incorporating both GNP and hBN settings in different ratios. These mixtures provided an optimum positive synergy by reducing 56% friction and 90% wear compared to the base oil. These percentage values were significantly more compared to both GNP and hBN based lubricants in their individual settings. These improvements in the mixture were due to a composite film formed which protected the interacting surfaces and also due to the polishing mechanisms. Therefore, incorporating both these nanoparticles in canola oil could reduce friction and wear and thus help in better energy conservation.

Effect of hBN/Al2O3 Nanoparticle Additives on the Tribological Performance of Engine Oil

2014 ◽  
Vol 66 (3) ◽  
Author(s):  
Muhammad Ilman Hakimi Chua Abdullah ◽  
Mohd Fadzli Abdollah ◽  
Hilmi Amiruddin ◽  
Noreffendy Tamaldin ◽  
Nur Rashid Mat Nuri
Keyword(s):  
Diesel Engine ◽  
Hexagonal Boron Nitride ◽  
Fuel Efficiency ◽  
Tribological Performance ◽  
Engine Oil ◽  
Wear Scar Diameter ◽  
Engine Wear ◽  
The Coefficient Of Friction ◽  
Al2o3 Nanoparticle ◽  
Nanoparticle Additives

Nanotechnology currently has an important role in reducing engine wear and improving fuel efficiency within engines using nanoparticle additives in engine oil. In this work, the effect of hexagonal boron nitride (hBN) and alumina (Al2O3) nanoparticle additives, on the tribological performance of SAE 15W40 diesel engine oil, was studied. A tribological test was conducted using a four-ball tribotester. The results show that the coefficient of friction (COF) and wear rate of the ball reduced significantly by dispersing hBN nanoparticle additives in SAE 15W40 diesel engine oil; compared to without or with Al2O3 nanoparticle additives. This is in accordance with the significant reduction of wear scar diameter and smoother worn surfaces observed on the balls.

scholarly journals Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1438
Author(s):  
Ankush Raina ◽  
Mir Irfan Ul Haq ◽  
Ankush Anand ◽  
Sanjay Mohan ◽  
Rajiv Kumar ◽  
...  
Keyword(s):  
Coefficient Of Friction ◽  
Hexagonal Boron Nitride ◽  
Normal Load ◽  
Lubricant Additive ◽  
Oil Lubrication ◽  
Volumetric Wear ◽  
Base Oil ◽  
Applied Normal Load ◽  
Lubrication Performance ◽  
The Coefficient Of Friction

Nanodiamond (ND) particles are effective lubricant additives. Attention of research has shifted towards investigating the particles as secondary additives. ND particles provide more benefits as secondary additives than as the sole lubricant additive for steel–steel contacts. In this work, the influence of ND particles as secondary additives on oil lubrication of steel–aluminium tribopair (hard–soft contact) was examined. AISI 52100 steel balls were slid against AA2024 aluminium alloy discs, in the presence of polyalphaolefin (PAO) base oil, in boundary lubrication regime (applied normal load: 10 N to 50 N). Primary additives were copper oxide (CuO) and hexagonal boron nitride (h-BN) nanoparticles. The addition of ND particles to PAO, with CuO and h-BN as primary additives, at the lowest applied normal load of 10 N: (i) decreased the volumetric wear of the aluminium discs by 28% and 63%, respectively, and (ii) decreased the coefficient of friction by 15% and 33%, respectively. At the highest applied normal load of 50 N, it: (i) decreased the volumetric wear of the aluminium discs by 20% and 38%, respectively, and (ii) decreased the coefficient of friction by 5.4% and 8%, respectively. ND particles as secondary additives significantly reduce energy loss and power loss as a consequence of an effective reduction in friction during sliding. Unique characteristics of ND particles—such as their (a) physicochemical and thermal properties, (b) ball bearing and polishing effects and (c) synergistic interaction with primary additives to form stable tribofilms—enhance the lubrication performance of steel–aluminium contact. ND particles in combination with h-BN nanoparticles showed the best performance, due to better synergy between the primary additive and the secondary additive. Results from the investigation indicate that ND particles taken as secondary additives in small amount (0.2 wt%) can improve oil lubrication performance of hard–soft contacts in engineering systems.

scholarly journals Modified graphene as novel lubricating additive with high dispersion stability in oil

Friction ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 143-154 ◽  
Author(s):  
Pu Wu ◽  
Xinchun Chen ◽  
Chenhui Zhang ◽  
Jiping Zhang ◽  
Jianbin Luo ◽  
...  
Keyword(s):  
Friction And Wear ◽  
Wear Track ◽  
Normal Load ◽  
Lubricant Additive ◽  
Tribological Performance ◽  
Dispersion Stability ◽  
High Dispersion ◽  
Base Oil ◽  
The Coefficient Of Friction ◽  
Modified Graphene

Abstract Graphene is a promising material as a lubricant additive for reducing friction and wear. Here, a dispersing method which combines chemical modification of graphene by octadecylamine and dicyclohexylcarbodiimide with a kind of effective dispersant has been successfully developed to achieve the remarkable dispersion stability of graphene in base oil. The stable dispersion time of modified graphene (0.5 wt%) with dispersant (1 wt%) in PAO-6 could be up to about 120 days, which was the longest time reported so far. At the same time, the lubricant exhibits a significant improvement of tribological performance for a steel ball to plate tribo-system with a normal load of 2 N. The coefficient of friction between sliding surfaces was ~0.10 and the depth of wear track on plate was ~21 nm, which decreased by about 44% and 90% when compared to pure PAO-6, respectively. Furthermore, the analysis of the lubricating mechanisms in regard to the sliding-induced formation of nanostructured tribo-film has been contacted by using Raman spectra and TEM.

Modifications Required for Palm Oil to be Qualified as a Mechanical Lubricant

2019 ◽  
Vol 9 (1) ◽  
pp. 50-66
Author(s):  
Muhammad Sharil Yahayaa ◽  
Nurliyana Abdul Raof ◽  
Zulkifli Ibrahim ◽  
Azniza Ahmad ◽  
Chandima Gomes
Keyword(s):  
Palm Oil ◽  
Carbon Materials ◽  
Hexagonal Boron Nitride ◽  
Mineral Oil ◽  
Tribological Performance ◽  
Chemical Modifications ◽  
Environmental Friendly ◽  
Metal Metal ◽  
Nano Additives ◽  
Dialkyl Dithiophosphate

Adaptation of apt chemical modifications and incorporation of suitable additives, especially, nano-additives, could improve the properties of bio-lubricants derived from palm oil. This makes it one of the best alternatives to mineral oil lubricants. Possible chemical modifications are hydrogenation, esterification/ transesterification, epoxidation and metathesis. Feasible additives and nano-additives available in the market for minimizing the drawbacks of palm oil as a lubricant are ionic liquids, phosphorus, sulphur, zinc dialkyl dithiophosphate, metal, metal oxides, metal sulphides, carbonates, borates, carbon materials, organic materials, hexagonal boron nitride, alumina, CaO, CuO, ZnO, TiO2 and lanthanum borates. Few of them may not be environmental friendly. In line with market potentials and demand, it could be predicted that ROI of funding for the research and development of palm oil as a bio-lubricant may be significantly high. The study addresses tribological performance and properties, chemical modifications and formulation with additives of palm oil as a bio-lubricant.

scholarly journals Inorganic nanomaterial lubricant additives for base fluids, to improve tribological performance: Recent developments

Friction ◽  
2021 ◽  
Author(s):  
Junhai Wang ◽  
Weipeng Zhuang ◽  
Wenfeng Liang ◽  
Tingting Yan ◽  
Ting Li ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Metallic Nanoparticles ◽  
Carbon Nanomaterials ◽  
Hexagonal Boron Nitride ◽  
Tribological Performance ◽  
Inorganic Nanoparticles ◽  
Future Research ◽  
Graphene Oxides ◽  
Practical Applications ◽  
Nano Additives

AbstractIn this paper, we review recent research developments regarding the tribological performances of a series of inorganic nano-additives in lubricating fluids. First, we examine several basic types of inorganic nanomaterials, including metallic nanoparticles, metal oxides, carbon nanomaterials, and “other” nanomaterials. More specifically, the metallic nanoparticles we examine include silver, copper, nickel, molybdenum, and tungsten nanoparticles; the metal oxides include CuO, ZnO, Fe3O4, TiO2, ZrO2, Al2O3, and several double-metal oxides; the carbon nanomaterials include fullerene, carbon quantum dots, carbon nanotubes, graphene, graphene oxides, graphite, and diamond; and the “other” nanomaterials include metal sulfides, rare-earth compounds, layered double hydroxides, clay minerals, hexagonal boron nitride, black phosphorus, and nanocomposites. Second, we summarize the lubrication mechanisms of these nano-additives and identify the factors affecting their tribological performance. Finally, we briefly discuss the challenges faced by inorganic nanoparticles in lubrication applications and discuss future research directions. This review offers new perspectives to improve our understanding of inorganic nano-additives in tribology, as well as several new approaches to expand their practical applications.

A review on tribological performance of ionic liquids as additives to bio lubricants

2020 ◽  
pp. 135065012097380
Author(s):  
Tehreem Naveed ◽  
Rehan Zahid ◽  
Riaz Ahmad Mufti ◽  
Muhammad Waqas ◽  
Muhammad Talha Hanif
Keyword(s):  
Ionic Liquids ◽  
Friction And Wear ◽  
Combustion Engine ◽  
Tribological Performance ◽  
Environmental Concerns ◽  
Published Data ◽  
Oil Reserves ◽  
Mineral Oils ◽  
The Past ◽  
Interacting Surfaces

All the moving components in an internal combustion engine require a lubricant that allows smooth sliding and/or rolling of interacting surfaces. Lubricant not only minimizes the friction and wear but also dissipates the heat generated due to friction and removes debris from the area of contact. Environmental concerns, decreasing mineral oil reserves and difficult disposal of nonbiodegradable conventional lubricants have urged the researchers to shift towards environmental-friendly lubricants. Number of tribological studies carried out in the past have proved that ionic liquid-based bio-lubricants are sustainable and biodegradable alternative to mineral oils. This paper presents a brief review of properties of ionic liquids and their ability to reduce friction and wear between the interacting surfaces. Tribological performance and compatibility of ionic liquids with various base-oils have been compared under boundary lubrication. The results reveal that phosphonium-based ionic liquids namely tetra-decyl tri-hexyl phosphonium bis(2,4,4-trimethylpentyl) phosphinate (P66614)i(C8)2PO2 and tri-hexyl tetra-decyl phosphonium bis(2-ethylhexyl) phosphate (P-DEHP) are more suitable for tribological applications. Since, ionic liquids can be tailored according to the application and millions of combinations are possible therefore, there is a need to summarize the published data in a more systematic and logical way.

Tribological Investigation of Copper (Cu) and Copper Oxide (CuO) Nanoparticles Based Nanolubricants for Machine Tool Slideways

2014 ◽  
Author(s):  
Saravanakumar Nesappan ◽  
Nallasamy Palanisamy ◽  
Mahesh Chandran
Keyword(s):  
Electron Microscope ◽  
Machine Tool ◽  
Copper Oxide ◽  
Elevated Temperatures ◽  
Stick Slip ◽  
Base Oil ◽  
Weight Composition ◽  
The Coefficient Of Friction ◽  
Oxide Particles ◽  
Mineral Lubricant

The present study intends to evaluate the tribological characteristics of Copper (Cu) and Copper oxide (CuO) based nanolubricant for its use in machine tool slideways. Different sizes of copper and copper oxide particles were chosen and physical characterisation were carried out using scanning electron microscope (SEM) and transmission electron microscope (TEM). The nanolubricants were prepared by adding various proportions (0.1%, 0.25%, 0.4% wt) of the particles in Polyalphaolefin (PAO) base oil with lecithin and oleic acid surfactants. Friction and stick-slip characteristics of the nanolubricants were assessed using pin-on-block reciprocating friction monitor simulating the actual loading conditions prevailing in machine tool slideways. Studies were also conducted under elevated temperatures to ascertain the performance of particles at higher temperatures. Extreme pressure properties of the lubricants were studied using Four Ball Tester. The results of the experiments were compared with ISO VG 32 oil, a conventional mineral lubricant meant for machine tool slideways and it was found that the tribological properties nanolubricants using both the nanoparticles were considerably better. The coefficient of friction found to be decreased by 2.5% and 17.5% for copper particles with 0.1% weight composition in ambient temperature and elevated temperature respectively. Whereas for copper oxide particles with 0.1% weight composition a reduction of 14.25% and 10% were obtained.

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