scholarly journals Dolomitization of Paleozoic Successions, Huron Domain of Southern Ontario, Canada: Fluid Flow and Dolomite Evolution

Water ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2449
Author(s):  
Ihsan S. Al-Aasm ◽  
Richard Crowe ◽  
Marco Tortola
Keyword(s):  
Regional Scale ◽  
Carbon Isotopic Composition ◽  
Warm Water ◽  
Geochemical Data ◽  
Fluid Composition ◽  
Rock Interaction ◽  
Near Surface ◽  
Southern Ontario ◽  
Ce Anomaly ◽  
Diagenetic Fluids

Integrated petrographic, isotopic, fluid inclusion microthermometry, and geochemical analyses of Paleozoic carbonate successions from multiple boreholes within the Huron Domain, southern Ontario were conducted to characterize the diagenetic history and fluid composition, on a regional scale, and evaluate the nature and origin of dolomitized beds. Multiple generations of non-stochiometric dolomite have been observed. These dolomites occur as both replacement (D1 and D2) and cement (saddle dolomite; SD) and formed either at near-surface to shallow burial zone (D1) or intermediate burial (D2 and SD). Petrographic and geochemical data of dolomite types and calcite cement suggest that these carbonates have experienced multiple fluid events that affected dolomite formation and other diagenetic processes. Cambrian and Ordovician strata have two possibly isolated diagenetic fluid systems; an earlier fluid system that is characterized by a pronounced negative shift in oxygen and carbon isotopic composition, more radiogenic Sr ratios, warm and saline signatures, higher average ∑REE compared to warm water marine brachiopods, negative La anomaly, and positive Ce anomaly; and a later Ordovician system, characterized by less negative shifts in oxygen and carbon isotopes, comparable Th, hypersaline, a less radiogenic, less negative La anomaly, and primarily positive Ce anomaly but also higher average ∑REE compared to warm water marine brachiopods. Ordovician, Silurian, and Devonian Sr isotopic ratios, however, show seawater composition of their respective age as the primary source of diagenetic fluids with minor rock/water interactions. In contrast, the isotopic data of the overlying Silurian and Devonian carbonates show overlaps between δ13C and δ18O values. However, δ18O values show evidence of dolomite recrystallization. D2 shows wide Th values and medium to high salinity values. Higher Th and salinity are observed in SD in the Silurian carbonates, which suggest the involvement of localized fluxes of hydrothermal fluids during its formation during Paleozoic orogenesis. Geochemical proxies suggest that in both age groups the diagenetic fluids were originally of coeval seawater composition, subsequently modified via water-rock interaction possibly related to brines, which were modified by the dissolution of Silurian evaporites from the Salina series. The integration of the obtained data in the present study demonstrates the linkage between fluid flux history, fluid compartmentalization, and related diagenesis during the regional tectonic evolution of the Michigan Basin.

scholarly journals Influence of the aerosol solar extinction on photochemistry during the 2010 Russian wildfires episode

2015 ◽  
Vol 15 (19) ◽  
pp. 10983-10998 ◽  
Author(s):  
J. C. Péré ◽  
B. Bessagnet ◽  
V. Pont ◽  
M. Mallet ◽  
F. Minvielle
Keyword(s):  
Transport Model ◽  
Regional Scale ◽  
Model Performance ◽  
Surface Concentration ◽  
Near Surface ◽  
Aerosol Mass ◽  
Aerosol Mass Concentration ◽  
Air Quality Measurements ◽  
Photolysis Rates ◽  
Optical Module

Abstract. In this work, impact of aerosol solar extinction on the photochemistry over eastern Europe during the 2010 wildfires episode is discussed for the period from 5 to 12 August 2010, which coincides to the peak of fire activity. The methodology is based on an online coupling between the chemistry-transport model CHIMERE (extended by an aerosol optical module) and the radiative transfer code TUV. Results of simulations indicate an important influence of the aerosol solar extinction, in terms of intensity and spatial extent, with a reduction of the photolysis rates of NO2 and O3 up to 50 % (in daytime average) along the aerosol plume transport. At a regional scale, these changes in photolysis rates lead to a 3–15 % increase in the NO2 daytime concentration and to an ozone reduction near the surface of 1–12 %. The ozone reduction is shown to occur over the entire boundary layer, where aerosols are located. Also, the total aerosol mass concentration (PM10) is shown to be decreased by 1–2 %, on average during the studied period, caused by a reduced formation of secondary aerosols such as sulfates and secondary organics (4–10 %) when aerosol impact on photolysis rates is included. In terms of model performance, comparisons of simulations with air quality measurements at Moscow indicate that an explicit representation of aerosols interaction with photolysis rates tend to improve the estimation of the near-surface concentration of ozone and nitrogen dioxide as well as the formation of inorganic aerosol species such as ammonium, nitrates and sulfates.

scholarly journals Formation environments and mechanisms of multistage paleokarst of Ordovician carbonates in Southern North China Basin

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Haitao Zhang ◽  
Guangquan Xu ◽  
Mancai Liu ◽  
Minhua Wang
Keyword(s):  
Carbonate Rocks ◽  
North China ◽  
Oil And Gas ◽  
Carbonate Reservoir ◽  
Carbonate Reservoirs ◽  
Geochemical Data ◽  
Near Surface ◽  
Oil And Gas Exploration ◽  
Pore Types ◽  
North China Basin

AbstractWith the reduction of oil and gas reserves and the increase of mining difficulty in Northern China, the carbonate rocks in Southern North China Basin are becoming a significant exploration target for carbonate reservoirs. However, the development characteristics, formation stages, formation environments and mechanisms of the carbonate reservoirs in Southern North China Basin are still unclear, which caused the failures of many oil and gas exploration wells. This study focused on addressing this unsolved issue from the Ordovician carbonate paleokarst in the Huai-Fu Basin, which is located in the southeast of Southern North China Basin and one of the key areas for oil and gas exploration. Based on petrology, mineralogy and geochemical data, pore types, distribution characteristics, and formation stages of the Ordovician paleokarst were analyzed. Then, in attempt to define the origins of porosity development, the formation environments and mechanisms were illustrated. The results of this study showed that pore types of the Ordovician carbonates in the Huai-Fu Basin are mainly composed of intragranular pores, intercrystalline (intergranular) pores, dissolution pores (vugs), fractures, channels, and caves, which are usually in fault and fold zones and paleoweathering crust. Furthermore, five stages and five formation environments of the Ordovician paleokarst were identified. Syngenetic karst, eogenetic karst, and paleoweathering crust karst were all developed in a relatively open near-surface environment, and their formations are mainly related to meteoric water dissolution. Mesogenetic karst was developed in a closed buried environment, and its formation is mainly related to the diagenesis of organic matters and thermochemical sulfate reduction in the Permian-Carboniferous strata. Hydrothermal (water) karst was developed in a deep-buried and high-temperature environment, where hydrothermal fluids (waters) migrated upward through structures such as faults and fractures to dissolve carbonate rocks and simultaneously deposited hydrothermal minerals and calcites. Lastly, a paleokarst evolution model, combined with the related porosity evolution processes, nicely revealed the Ordovician carbonate reservoir development. This study provides insights and guidance for further oil and gas exploration in the Southern North China Basin, and also advances our understanding of the genesis of carbonate paleokarst around the world.

Regional characterisation of soil properties by combining soil science and hyperspectral and thermal remote sensing: A technical overview of lab and field remote sensing methods

2021 ◽  
Author(s):  
Richard Mommertz ◽  
Lars Konen ◽  
Martin Schodlok
Keyword(s):  
Remote Sensing ◽  
Soil Properties ◽  
Regional Scale ◽  
Arable Land ◽  
Soil Mapping ◽  
Soil Science ◽  
Near Surface ◽  
Soil Parameter ◽  
The Impact ◽  
Parameter Retrieval

<p>Soil is one of the world’s most important natural resources for human livelihood as it provides food and clean water. Therefore, its preservation is of huge importance. For this purpose, a proficient regional database on soil properties is needed. The project “ReCharBo” (Regional Characterisation of Soil Properties) has the objective to combine remote sensing, geophysical and pedological methods to determine soil characteristics on a regional scale. Its aim is to characterise soils non-invasive, time and cost efficient and with a minimal number of soil samples to calibrate the measurements. Konen et al. (2021) give detailed information on the research concept and first field results in a presentation in the session “SSS10.3 Digital Soil Mapping and Assessment”. Hyperspectral remote sensing is a powerful and well known technique to characterise near surface soil properties. Depending on the sensor technology and the data quality, a wide variety of soil properties can be derived with remotely sensed data (Chabrillat et al. 2019, Stenberg et al. 2010). The project aims to investigate the effects of up and downscaling, namely which detail of information is preserved on a regional scale and how a change in scales affects the analysis algorithms and the possibility to retrieve valid soil parameter information. Thus, e.g. laboratory and field spectroscopy are applied to gain information of samples and fieldspots, respectively. Various UAV-based sensors, e.g. thermal & hyperspectral sensors, are applied to study soil properties of arable land in different study areas at field scale. Finally, airborne (helicopter) hyperspectral data will cover the regional scale. Additionally forthcoming spaceborne hyperspectral satellite data (e.g. Prisma, EnMAP, Sentinel-CHIME) are a promising outlook to gain detailed regional soil information. In this context it will be discussed how the multisensor data acquisition is best managed to optimise soil parameter retrieval. Sensor specific properties regarding time and date of acquisition as well as weather/atmospheric conditions are outlined. The presentation addresses and discusses the impact of a multisensor and multiscale remote sensing data collection regarding the results on soil parameter retrieval.</p><p> </p><p>References</p><p>Chabrillat, S., Ben-Dor, E. Cierniewski, J., Gomez, C., Schmid, T. & van Wesemael, B. (2019): Imaging Spectroscopy for Soil Mapping and Monitoring. Surveys in Geophysics 40:361–399. https://doi.org/10.1007/s10712-019-09524-0</p><p>Stenberg, B., Viscarra Rossel, R. A., Mounem Mouazen, A. & Wetterlind, J. (2010): Visible and Near Infrared Spectroscopy in Soil Science. In: Donald L. Sparks (editor): Advances in Agronomy. Vol. 107. Academic Press:163-215. http://dx.doi.org/10.1016/S0065-2113(10)07005-7</p>

scholarly journals Fluid Chemistry of Mid-Ocean Ridge Hydrothermal Vents: A Comparison between Numerical Modeling and Vent Geochemical Data

Geofluids ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-20 ◽  
Author(s):  
Samuel Pierre ◽  
Alexander P. Gysi ◽  
Thomas Monecke
Keyword(s):  
Numerical Modeling ◽  
Geochemical Data ◽  
Fluid Composition ◽  
Secondary Mineral ◽  
Ambient Seawater ◽  
Mineral Solution ◽  
Mid Ocean Ridge ◽  
Activity Ratios ◽  
Proton Activity ◽  
Ocean Ridge

Seawater-basalt interaction taking place at mid-ocean ridges was studied using numerical modeling to determine the compositional evolution of hydrothermal fluids and associated alteration mineralogy forming within newly emplaced crustal material. Geochemical modeling was carried out in a closed seawater-basalt system at discrete temperature intervals between 2 and 400°C at 500 bars, varying fluid/rock ratios, and secondary mineral assemblages representative of basalt alteration in natural systems. In addition to temperature, the fluid/rock ratio has a fundamental control on the resulting system chemistry. At rock-buffered conditions (low fluid/rock ratios), the mineral-solution equilibrium was characterized by high cation to proton activity ratios foraCa2+/(aH+)2andaNa+/aH+and very low dissolved Mg concentrations due to the precipitation of smectites and chlorite. A complex secondary mineral alteration assemblage dominated by Ca- and Na-bearing minerals including zeolites, calcite, epidote, prehnite, clinozoisite, and albite was predicted to form. The resulting fluid composition was alkaline and reduced relative to ambient seawater, with Eh values ranging between −0.2 and −0.6 V. In contrast, seawater-buffered conditions (high fluid/rock ratios) resulted in lower cation to proton activity ratios foraCa2+/(aH+)2andaNa+/aH+and higher dissolved Mg concentrations comparable to the value of this element in ambient seawater. A more simple mineral assemblage was predicted to form at these conditions with the predominance of Al-Si- and Mg-bearing minerals including kaolinite, quartz, and talc in addition to large amounts of anhydrite. The resulting fluid composition was mildly acidic and oxidized relative to seawater with Eh values ranging between −0.2 and 0 V. These modeling results were compared to a compilation of submarine hydrothermal vent fluid compositions from mid-ocean ridge settings and analogous basalt-dominated environments. The agreement obtained between the simulations and the compiled fluid data indicates that mid-ocean ridge hydrothermal processes can be closely reproduced by mineral-solution equilibria for a broad range of temperatures and fluid/rock ratios.

Coral microatolls and a probable Middle Ordovician example

1990 ◽  
Vol 64 (1) ◽  
pp. 39-43 ◽  
Author(s):  
David R. Kobluk ◽  
Iqbal Noor
Keyword(s):  
Coral Reefs ◽  
Fossil Record ◽  
Scleractinian Coral ◽  
Regional Scale ◽  
Southern Ontario ◽  
Middle Ordovician ◽  
Reef Environments ◽  
Maximum Water ◽  
Water Depths ◽  
Tabulate Corals

A disk-shaped massive colony of Tetradium, from the Middle Ordovician Bobcaygeon Formation in southern Ontario, displays features of a coral microatoll. This is the first pre-Holocene coral microatoll yet described, indicating that some tabulate corals in level-bottom communities were growing as microatolls as do many modern colonial skeleton-secreting organisms.The microatoll therefore is not strictly a Quaternary or even Cenozoic phenomenon, but has a fossil record that may span most of the Phanerozoic. This indicates that the special conditions necessary for microatoll growth have existed outside of reef environments, and were present before the advent of scleractinian coral reefs. It may be possible to use ancient microatolls to estimate absolute water depths at low tide, thereby providing a means for estimating maximum water depths on a local and regional scale.

scholarly journals HFSE‐REE Transfer Mechanisms During Metasomatism of a Late Miocene Peraluminous Granite Intruding a Carbonate Host (Campiglia Marittima, Tuscany)

Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 682
Author(s):  
Paoli ◽  
Dini ◽  
Petrelli ◽  
Rocchi
Keyword(s):  
External Source ◽  
Magmatic Fluid ◽  
Chemical Components ◽  
Fluid Composition ◽  
Peraluminous Granite ◽  
Rock Interaction ◽  
Complete Replacement ◽  
Element Mobilization ◽  
Geochemical Models ◽  
Metasomatic Event

The different generations of calc‐silicate assemblages formed during sequential metasomatic events make the Campiglia Marittima magmatic–hydrothermal system a prominent case study to investigate the mobility of rare earth element (REE) and other trace elements. These mineralogical assemblages also provide information about the nature and source of metasomatizing fluids. Petrographic and geochemical investigations of granite, endoskarn, and exoskarn bodies provide evidence for the contribution of metasomatizing fluids from an external source. The granitic pluton underwent intense metasomatism during post‐magmatic fluid–rock interaction processes. The system was initially affected by a metasomatic event characterized by circulation of K‐rich and Ca(‐Mg)‐rich fluids. A potassic metasomatic event led to the complete replacement of magmatic biotite, plagioclase, and ilmenite, promoting major element mobilization and crystallization of K‐feldspar, phlogopite, chlorite, titanite, and rutile. The process resulted in significant gain of K, Rb, Ba, and Sr, accompanied by loss of Fe and Na, with metals such as Cu, Zn, Sn, W, and Tl showing significant mobility. Concurrently, the increasing fluid acidity, due to interaction with Ca‐rich fluids, resulted in a diffuse Ca‐metasomatism. During this stage, a wide variety of calc‐silicates formed (diopside, titanite, vesuvianite, garnet, and allanite), throughout the granite body, along granite joints, and at the carbonate–granite contact. In the following stage, Ca‐F‐rich fluids triggered the acidic metasomatism of accessory minerals and the mobilization of high-field-strength elements (HFSE) and REE. This stage is characterized by the exchange of major elements (Ti, Ca, Fe, Al) with HFSE and REE in the forming metasomatic minerals (i.e., titanite, vesuvianite) and the crystallization of HFSE‐REE minerals. Moreover, the observed textural disequilibrium of newly formed minerals (pseudomorphs, patchy zoning, dissolution/reprecipitation textures) suggests the evolution of metasomatizing fluids towards more acidic conditions at lower temperatures. In summary, the selective mobilization of chemical components was related to a shift in fluid composition, pH, and temperature. This study emphasizes the importance of relating field studies and petrographic observations to detailed mineral compositions, leading to the construction of litho‐geochemical models for element mobilization in crustal magmatic‐hydrothermal settings.

scholarly journals Simulations of Black Carbon Over Indian Region: Improvements and Implications of Diurnality in Emissions

2019 ◽  
Author(s):  
Gaurav Govardhan ◽  
Sreedharan Krishnakumari Satheesh ◽  
Krishnaswamy Krishna Moorthy ◽  
Ravi Nanjundiah
Keyword(s):  
Boundary Layer ◽  
Black Carbon ◽  
Radiative Forcing ◽  
Regional Scale ◽  
Early Morning ◽  
Temporal Variations ◽  
Indian Region ◽  
Near Surface ◽  
Aerosol Radiative Forcing ◽  
Convective Mixing

Abstract. With a view to improving the performance of WRF-Chem over the Indian region in simulating BC (black Carbon) mass concentrations as well as its short-term variations, especially on diurnal scale, a region-specific diurnal variation scheme has been introduced in the model emissios and the performance of the modified simulations has been evaluated against high-resolution measurements carried out over 8 ARFI (Aerosol Radiative Forcing over India) network observatories spread across India for distinct seasons; pre-monsoon (represented by May), post-monsoon (represented by October) and winter (represented by December). In addition to an overall improvement in the simulated concentrations and their temporal variations, it has also been found that the effects of prescribing diurnally varying emissions on the simulated near-surface concentrations largely depend on the boundary layer turbulence. The effects are perceived fast (within about 2–3 hours) during the evening–early morning hours when the atmospheric boundary layer is shallow and convective mixing is weak, while they are delayed, taking as much as about 5–6 hours, during periods when the boundary layer is deep and convective mixing is strong. This information would also serve as an important input for agencies concerned with urban planning and pollution mitigation. Despite these improvements in the near-surface concentrations, the simulated columnar aerosol optical depth (AOD) still remains largely underestimated vis-a-vis the satellite retrieved products. These modifications will serve as a guideline for further model-improvement initiatives at regional scale.

Examining the Discrepancy between Forecast and Observed Liquefaction from the 2015 Gorkha, Nepal, Earthquakes

2017 ◽  
Vol 33 (1_suppl) ◽  
pp. 73-83 ◽  
Author(s):  
Robb Eric S. Moss ◽  
Laurie G. Baise ◽  
Jing Zhu ◽  
Diwakar Kadkha
Keyword(s):  
Regional Scale ◽  
Groundwater Table ◽  
Earthquake Sequence ◽  
Hazard Mapping ◽  
Kathmandu Valley ◽  
Surface Shear ◽  
Near Surface ◽  
Global Database ◽  
Crust Layer ◽  
Liquefaction Hazard

Many ground failures resulted from the 2015 Nepal earthquake sequence, including landslides, rockfalls, liquefactions, and cyclic failures. And whereas the amount and extent of landsliding were relatively consistent with predictions for a Mw 7.8 main shock, the amount and extent of liquefaction were not. We present a summary of liquefaction field observations that we made as part of the Geotechnical Extreme Events Reconnaissance (GEER) investigations. The liquefaction that did occur in the Kathmandu Valley was limited in its spatial extent, and the postliquefaction deformations were small. Prior earthquakes in this region have been reported to have caused greater liquefaction-related failures, and liquefaction hazard–mapping studies predicted widespread liquefaction hazard from an event of this size. We explore two possible reasons at the regional scale for the limited liquefaction from this earthquake sequence: drawdown of the groundwater table and high near-surface shear wave velocity. Our study finds that pumping has depressed the groundwater table across the Kathmandu Valley by 13–40 m since 1980, thereby decreasing the amount of near-surface liquefiable material and increasing the nonliquefiable “crust” layer. The regional slope-based V S30 for the valley is on average higher than that for liquefaction sites in a global database of observed liquefaction. A global geospatial model for liquefaction occurrence shows low liquefaction potential in the Kathmandu Valley consistent with the observed patterns.

scholarly journals Simulations of black carbon over the Indian region: improvements and implications of diurnality in emissions

2019 ◽  
Vol 19 (12) ◽  
pp. 8229-8241 ◽  
Author(s):  
Gaurav Govardhan ◽  
Sreedharan Krishnakumari Satheesh ◽  
Krishnaswamy Krishna Moorthy ◽  
Ravi Nanjundiah
Keyword(s):  
Boundary Layer ◽  
Black Carbon ◽  
Radiative Forcing ◽  
Regional Scale ◽  
Early Morning ◽  
Temporal Variations ◽  
Indian Region ◽  
Near Surface ◽  
Aerosol Radiative Forcing ◽  
Convective Mixing

Abstract. With a view to improving the performance of WRF-Chem over the Indian region in simulating BC (black carbon) mass concentrations as well as its short-term variations, especially on a diurnal scale, a region-specific diurnal variation scheme has been introduced in the model emissions and the performance of the modified simulations has been evaluated against high-resolution measurements carried out over eight ARFI (Aerosol Radiative Forcing over India) network observatories spread across India for distinct seasons: pre-monsoon (represented by May), post-monsoon (represented by October) and winter (represented by December). In addition to an overall improvement in the simulated concentrations and their temporal variations, we have also found that the effects of prescribing diurnally varying emissions on the simulated near-surface concentrations largely depend on the boundary layer turbulence. The effects are perceived quickly (within about 2–3 h) during the evening–early morning hours when the atmospheric boundary layer is shallow and convective mixing is weak, while they are delayed, taking as much as about 5–6 h, during periods when the boundary layer is deep and convective mixing is strong. This information would also serve as an important input for agencies concerned with urban planning and pollution mitigation. Despite these improvements in the near-surface concentrations, the simulated columnar aerosol optical depth (AOD) still remains largely underestimated vis-à-vis the satellite-retrieved products. These modifications will serve as a guideline for further model-improvement initiatives at a regional scale.

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