scholarly journals Physical and chemical bases of decarburization of high-carbon ferromanganese melt

2020 ◽  
Vol 1,2020 (1,2020 (124)) ◽  
pp. 30-35
Author(s):  
Velychko O ◽  
Yunshen Du ◽  
Mianovska Ya ◽  
Kamkina L ◽  
Ankuninov R
Keyword(s):  
Manganese Oxides ◽  
Low Carbon ◽  
High Carbon ◽  
Mixing Processes ◽  
Metallic Manganese ◽  
Low Phosphorus ◽  
High Carbon Ferromanganese ◽  
Patterns Of Behavior ◽  
Manganese Ferroalloys ◽  
Physical And Chemical

The aim of the work is to establish physicochemical patterns of behavior of carbon, silicon, manganese when using the method of oxygen purge of high-carbon ferromanganese. Method. The process of blowing red metal to sour is neglected. With the fusion of fused acid, it is more important to oxidize silicon. Its presence in metal is practical in the block of oxidized manganese. Because oxygen is an assimilation gas, the mixing processes of the converter bath components and the reduction of manganese oxides at the metal-slag interface do not develop properly during purging. The smelters of the medium-carbonaceous ferromanganese in the converter are characterized by a stable chemical warehouse and even a higher number of vimogs for this type of alloy. The low concentration of silicon in metal over a number of swimming trunks can be easily shoved with a hat of pre-purge bathtub with sour at the final stage of refining. The behavior of phosphorus in these smelts is not controlled. The content of P2O5 in the final slag is 0.1%. To achieve acceptable concentrations of phosphorus in the metal, it is necessary to use starting materials with a low phosphorus content. Scientific novelty.Taking into consideration the high affinity of silicon for oxygen, the physical and chemical basis for the production of medium-carbon ferromanganese, as well as metallic manganese and low-carbon ferromanganese, is the process of the interaction of manganese oxides of a certain basicity slag melt with silicon dissolved in ferromanganese (manganese), that is, as combined reduction -refining process to produce manganese ferroalloys with a given silicon content standard

scholarly journals Recycling of Waste Slag Upon Production of Manganese Ferroalloys

2020 ◽  
Author(s):  
Veniamin Ya. Dashevskii ◽  
Aleksandr A. Aleksandrov ◽  
Vladimir I. Zhuchkov ◽  
Leopold I. Leontˋev ◽  
Akim G. Kanevskii
Keyword(s):  
Raw Materials ◽  
Mineral Resources ◽  
Phosphorus Concentration ◽  
Hot Metal ◽  
High Carbon ◽  
Manganese Ores ◽  
Optimum Variant ◽  
High Carbon Ferromanganese ◽  
Mining Capacity ◽  
Manganese Ferroalloys

The mineral resources base of manganese ores is sufficiently large in Russia. However, their mining capacity is almost absent. This is due to the low quality of domestic manganese ores and the high content of phosphorus. To date, Russia has been obliged to import the commercial manganese ore, manganese-containing ferroalloys, metallic manganese, and manganese dioxide. To produce the high-carbon ferromanganese the composition of charge was developed. The optimum variant was that where 10–15% of manganese-containing raw materials were changed for waste slag. In this case, the phosphorus content in the high-carbon ferromanganese is lower by approximately 20 rel. % in comparison with the production of ferromanganese only from the manganese-containing raw materials. About 50–60 rel. % of manganese can be extracted from the waste slag of silicon-thermal production. To produce the hot metal, the composition of iron-bearing burden material was developed. The optimum variant was that where 100% of manganese raw materials were changed for the waste slag. In this case, upon production of hot metal, the specific consumptions of manganese raw materials and limestone were decreased by 100 and 20%, respectively. The phosphorus concentration in metal was lower by about 10 rel. % as compared to the production of hot metal only from the manganese raw materials. Up to 55% of manganese can be extracted from the waste slag of silicothermic production, which is irretrievably lost at present. Keywords: manganese ferroalloys, manganese-containing raw materials, waste slag, hot metal

scholarly journals Novel process for producing hierarchical carbide derived carbon monolith and low carbon ferromanganese from high carbon ferromanganese

RSC Advances ◽  
2017 ◽  
Vol 7 (54) ◽  
pp. 33875-33882 ◽  
Author(s):  
Wei Liu ◽  
Guolong Liu ◽  
Qian Kou ◽  
Saijun Xiao
Keyword(s):  
Molten Salt ◽  
Porous Carbon ◽  
Low Carbon ◽  
High Carbon ◽  
Molten Salt Electrolysis ◽  
Carbon Monolith ◽  
High Carbon Ferromanganese ◽  
Carbide Derived Carbon

In this work, remelted high carbon ferromanganese was chosen as a consumable anode to produce porous carbon monolith and low carbon ferromanganese at the same time by molten salt electrolysis.

scholarly journals High-carbon ferromanganese smelting on high-base slags

2020 ◽  
Vol 4 (315) ◽  
pp. 63-73
Author(s):  
O. R. Sariev ◽  
◽  
M. S. Dossekenov ◽  
B. S. Kelamanov ◽  
A. M. Abdirashit ◽  
...  
Keyword(s):  
Large Scale ◽  
Chemical Properties ◽  
Oxide Content ◽  
High Carbon ◽  
High Carbon Ferromanganese ◽  
High Base ◽  
Technical And Economic Indicators ◽  
Physical And Chemical ◽  
Positive Effect ◽  
Positive Results

The article presents the results of laboratory trials for the smelting of high-carbon ferromanganese on highly-basic slags. Laboratory trials have confirmed that an increase in the basicity of ferromanganese production slags has a positive effect on the reduction of manganese to the metal and a decrease in the concentration of silicon in it. However, the high basicity makes the slag high-melting and tough, leading to large losses of manganese with the slag. The use of on borate fluxes solves this problem by affecting the physical and chemical properties of the final slags, which allows the process to be carried out at high basicities with the achievement of optimal technological indicators. The obtained positive results of laboratory experiments served as the basis for approbation the developed technology on a semi-industrial scale with the smelting of high-carbon ferromanganese by the flux method from the manganese ore of the «Bogach» Deposit. As a result of studying the smelting of carbonaceous ferromanganese in large-scale laboratory conditions, the possibility of converting manganese ores on highly-basic slags with appropriate regulation of the transport properties of slag to a standard metal with high technical and economic indicators was established. The best results are achieved when the CaO/SiO2 ratio in the slag is 1.8 and the boron oxide content in the slag is 0.8%. It is established that under these conditions, the obtained boron-containing highly-basic slags of carbonaceous ferromanganese are not subject to slaking.

Precipitation at the transformation interface of pearlite in steel

1990 ◽  
Vol 48 (4) ◽  
pp. 912-913
Author(s):  
F. A. Khalid ◽  
D. V. Edmonds
Keyword(s):  
Thin Foil ◽  
Carbon Steels ◽  
Model Alloy ◽  
Low Carbon ◽  
High Carbon ◽  
Growth Interface ◽  
Medium Carbon ◽  
Interphase Precipitation ◽  
Solution Treated ◽  
Wide Range

The austenite/pearlite growth interface in a model alloy steel (Fe-1lMn-0.8C-0.5V nominal wt%) is being studied in an attempt to characterise the morphology and mechanism of VC precipitation at the growth interface. In this alloy pearlite nodules can be grown isothermally in austenite that remains stable at room temperature thus facilitating examination of the transformation interfaces. This study presents preliminary results of thin foil TEM of the precipitation of VC at the austenite/ferrite interface, which reaction, termed interphase precipitation, occurs in a number of low- carbon HSLA and microalloyed medium- and high- carbon steels. Some observations of interphase precipitation in microalloyed low- and medium- carbon commercial steels are also reported for comparison as this reaction can be responsible for a significant increase in strength in a wide range of commercial steels.The experimental alloy was made as 50 g argon arc melts using high purity materials and homogenised. Samples were solution treated at 1300 °C for 1 hr and WQ. Specimens were then solutionised at 1300 °C for 15 min. and isothermally transformed at 620 °C for 10-18hrs. and WQ. Specimens of microalloyed commercial steels were studied in either as-rolled or as- forged conditions. Detailed procedures of thin foil preparation for TEM are given elsewhere.

scholarly journals Interfacial Phenomena and Inclusion Formation Behavior at Early Melting Stages of HCFeCr and LCFeCr Alloys in Liquid Iron

2021 ◽  
Author(s):  
Yong Wang ◽  
Andrey Karasev ◽  
Joo Hyun Park ◽  
Wangzhong Mu ◽  
Pär G. Jönsson
Keyword(s):  
Liquid Iron ◽  
Diffusion Zone ◽  
Early Stage ◽  
Interfacial Phenomena ◽  
Solid Alloy ◽  
Low Carbon ◽  
High Carbon ◽  
Free Zone ◽  
Formation Behavior ◽  
Predetermined Time

AbstractChromium is normally added to liquid alloy in the form of different grades of ferrochromium (FeCr) alloys for the requirement of different alloy grades, such as stainless steels, high Cr cast iron, etc.. In this work, inclusions in two commercially produced alloys, i.e., high-carbon ferrochromium (HCFeCr) and low-carbon ferrochromium (LCFeCr) alloys, were investigated. The FeCr alloy/liquid iron interactions at an early stage were investigated by inserting solid alloy piece into contact with the liquid iron for a predetermined time using the liquid-metal-suction method. After quenching these samples, a diffusion zone between the alloys and the liquid Fe was studied based on the microstructural characterizations. It was observed that Cr-O-(Fe) inclusions were formed in the diffusion zone, FeOx inclusions were formed in the bulk Fe, and an “inclusion-free” zone was detected between them. Moreover, it was found that the HCFeCr was slowly dissolved, but LCFeCr alloy was rapidly melted during the experiment. The dissolution and melting behaviors of these two FeCr alloys were compared and the mechanism of the early-stage dissolution process of FeCr alloys in the liquid Fe was proposed.

scholarly journals Carbon Emission Governance Zones at the County Level to Promote Sustainable Development

Land ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 197
Author(s):  
He Zhang ◽  
Jingyi Peng ◽  
Dahlia Yu ◽  
Lie You ◽  
Rui Wang
Keyword(s):  
Sustainable Development ◽  
Carbon Emission ◽  
Total Carbon ◽  
Small Scale ◽  
County Level ◽  
Low Carbon ◽  
High Carbon ◽  
Governance System ◽  
Medium Carbon ◽  
Indicator Evaluation

Low-carbon governance at the county level has been an important issue for sustainable development due to the large contributions to carbon emission. However, the experiences of carbon emission governance at the county level are lacking. This paper discusses 5 carbon emission governance zones for 1753 counties. The zoning is formed according to a differentiated zoning method based on a multi-indicator evaluation to judge if the governance had better focus and had formulated a differentiated carbon emission governance system. According to zoning results, there is 1 high-carbon governance zone, 2 medium-carbon governance zones, and 2 low-carbon zones. The extensive high-carbon governance zone and medium-carbon zones are key governance areas, in which the counties are mainly located in the northern plain areas and southeast coastal areas and have contributed 51.88% of total carbon emissions. This paper proposes differentiated governance standards for each indicator of the 5 zones. The differentiated zoning method mentioned in this paper can be applied to other governance issues of small-scale regions.

scholarly journals A Novel Decarburizing-Nitriding Treatment of Carburized/through-Hardened Bearing Steel towards Enhanced Nitriding Kinetics and Microstructure Refinement

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 112
Author(s):  
Fuyao Yan ◽  
Jiawei Yao ◽  
Baofeng Chen ◽  
Ying Yang ◽  
Yueming Xu ◽  
...  
Keyword(s):  
Surface Engineering ◽  
Plasma Nitriding ◽  
Nitrided Layer ◽  
Metallographic Analysis ◽  
Material Surface ◽  
Low Carbon ◽  
High Carbon ◽  
Softening Effect ◽  
Microstructure Refinement ◽  
Bearing Steels

Decarburization is generally avoided as it is reckoned to be a process detrimental to material surface properties. Based on the idea of duplex surface engineering, i.e., nitriding the case-hardened or through-hardened bearing steels for enhanced surface performance, this work deliberately applied decarburization prior to plasma nitriding to cancel the softening effect of decarburizing with nitriding and at the same time to significantly promote the nitriding kinetics. To manifest the applicability of this innovative duplex process, low-carbon M50NiL and high-carbon M50 bearing steels were adopted in this work. The influence of decarburization on microstructures and growth kinetics of the nitrided layer over the decarburized layer is investigated. The metallographic analysis of the nitrided layer thickness indicates that high carbon content can hinder the growth of the nitrided layer, but if a short decarburization is applied prior to nitriding, the thickness of the nitrided layer can be significantly promoted. The analysis of nitriding kinetics shows that decarburization reduces the activation energy for nitrogen diffusion and enhances nitrogen diffusivity. Moreover, the effect of decarburization in air can promote surface microstructure refinement via spinodal decomposition during plasma nitriding.

scholarly journals Laser Welding Dissimilar High-Strength Steel Alloys with Complex Geometries

Metals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 792 ◽  
Author(s):  
Panos Efthymiadis ◽  
Khalid Nor
Keyword(s):  
Carbon Steel ◽  
Laser Welding ◽  
Cross Sections ◽  
High Carbon Steel ◽  
High Strength Steels ◽  
High Strength ◽  
Low Carbon ◽  
High Carbon ◽  
Material Chemistry ◽  
Metallurgical Defects

Laser welding of dissimilar high-strength steels was performed in this study for two different geometries, flat and circular samples with material thicknesses of 5 and 8 mm. The material combinations were a low carbon to a medium or high carbon steel. Three different welding systems were employed: a Nd:YAG, a CO2 and a fiber laser. The process stability was evaluated for all the experiments. The resulting full penetration welds were inspected for their surface quality at the top and bottom of the specimens. Cross sections were taken to investigate the resulting microstructures and the metallurgical defects of the welds, such as cracks and pores. Significant hardening occurred in the weld region and the highest hardness values occurred in the Heat Affected Zone (HAZ) of the high carbon steel. The occurrence of weld defects depends strongly on the component geometry. The resulting microstructures within the weld were also predicted using neural network-simulated Continuous Cooling Transformation (CCT) diagrams and predicted the occurrence of a mixture of microstructures, such as bainite, martensite and pearlite, depending on the material chemistry. The thermal fields were measured with thermocouples and revealed the strong influence of component geometry on the cooling rate which in term defines the microstructures forming in the weld and the occurring hardness.

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