scholarly journals The effect of ultrafine detonation synthesized diamond powder on the properties and structure of PVC-based thermoplastic elastomer

2020 ◽  
pp. 30-32
Author(s):  
E. Yu. Lapkovskaya ◽  
P. O. Sukhodaev ◽  
V. E. Red’kin ◽  
A. I. Lyamkin ◽  
D. V. Ershov
Keyword(s):  
Uniform Distribution ◽  
Polyvinyl Chloride ◽  
Polymer Matrix ◽  
Thermoplastic Elastomer ◽  
Diamond Powder ◽  
Thermoplastic Elastomers ◽  
Strength Characteristics

Samples of thermoplastic elastomers based on polyvinyl chloride (PVC) modified with ultrafine detonation-synthesed (nano) diamonds were obtained. It was found that small additives of nanodiamonds improve the strength characteristics and arrange the structure of PVC. A method that allows obtaining a uniform distribution of nanoparticles in a polymer matrix is proposed.

scholarly journals Impact Modified Polyvinyl Chloride Based Thermoplastic Elastomers: Effect of Nitrile Butadiene Rubber and Graphene Oxide Loading

2021 ◽  
Vol 17 (1) ◽  
pp. 51-74
Author(s):  
Kuhanraj Vijayan ◽  
Mathialagan Muniyadi ◽  
Yamuna Munusamy
Keyword(s):  
Graphene Oxide ◽  
Impact Strength ◽  
Polyvinyl Chloride ◽  
Thermoplastic Elastomer ◽  
Thermoplastic Elastomers ◽  
Morphological Observation ◽  
Butadiene Rubber ◽  
Swelling Properties ◽  
Nitrile Butadiene Rubber ◽  
Micro Cracks

A new thermoplastic elastomer with improved impact and tensile properties was produced through melt blending of graphene oxide filled nitrile butadiene rubber (NBR-GO) and polyvinyl chloride (PVC) without the addition of plasticisers and thermal stabilisers. Nitrile butadiene rubber (NBR) compounds, with and without graphene oxide (GO) are prepared through latex compounding method and cured, prior to blending with PVC. The effect of NBR and NBR-GO loading on the process-ability and physico-mechanical properties of PVC blends were evaluated. The addition of NBR and NBR-GO improved tensile strength (TS), impact strength and swelling resistance of PVC. Addition of NBR also increased the stiffness of PVC due to higher elasticity of NBR as compared to PVC. Optimum impact strength, TS and swelling resistance was achieved with the addition of 10 wt. % NBR-GO. Good miscibility between NBR and PVC, and additional reinforcement by GO is responsible for enhancement of impact and TS. NBR-GO showed greater miscibility in PVC as compared to NBR as proven by morphological observation under scanning electron microscope. Morphological observation reveals that micro-cracks formation on PVC/30NBR surface which is responsible for low impact, tensile and swelling properties as compared to PVC/30NBR-GO composite.

scholarly journals Studies on PBFMO-b-PNMMO alternative block thermoplastic elastomers as potential binders for solid propellants

RSC Advances ◽  
2019 ◽  
Vol 9 (51) ◽  
pp. 29765-29771 ◽  
Author(s):  
Minghui Xu ◽  
Xianming Lu ◽  
Hongchang Mo ◽  
Ning Liu ◽  
Qian Zhang ◽  
...  
Keyword(s):  
Thermoplastic Elastomer ◽  
Thermoplastic Elastomers ◽  
Solid Propellants ◽  
Polymeric Binder

A novel energetic polymeric binder PBFMO-b-PNMMO alternative block thermoplastic elastomer was developed for metal-rich solid propellants.

scholarly journals Properties and Structure of Concretes Doped with Production Waste of Thermoplastic Elastomers from the Production of Car Floor Mats

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 872
Author(s):  
Malgorzata Ulewicz ◽  
Alina Pietrzak
Keyword(s):  
Tensile Strength ◽  
Production Process ◽  
Compression Strength ◽  
Physical And Mechanical Properties ◽  
Thermoplastic Elastomer ◽  
Thermoplastic Elastomers ◽  
Production Waste ◽  
Fine Aggregate ◽  
Freezing And Thawing ◽  
Average Decrease

This article presents physical and mechanical properties of concrete composites that include waste thermoplastic elastomer (TPE) from the production process of car floor mats. Waste elastomer (2–8 mm fraction) was used as a substitute for fine aggregate in quantities of 2.5, 5.0, 7.5, and 10% of the cement weight. For all series of concrete, the following tests were carried out: compression strength, bending tensile strength, splitting tensile strength, absorbability, density, resistance to water penetration under pressure, frost resistance, and abrasion resistance, according to applicable standards. Moreover, SEM/EDS analysis was carried out on the surface microstructure of synthesized concrete composites. It was proven that the use of production waste from the production process of car floor mats in the quantity of 2.5% does not influence the change of the concrete microstructure and it does not result in the decrease of the mechanical parameters of concrete modified with waste. All concrete modified with the addition of waste meet standards requirements after carrying out 15 cycles of freezing and thawing, and the average decrease in compression strength did not exceed 20%. Adding waste in the quantity of 2.5% allows for limiting the use of aggregate by about 5%, which is beneficial for the natural environment.

scholarly journals Effect of Acetylated SEBS/PP for Potential HVDC Cable Insulation

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1596
Author(s):  
Peng Zhang ◽  
Yongqi Zhang ◽  
Xuan Wang ◽  
Jiaming Yang ◽  
Wenbin Han
Keyword(s):  
Mechanical Properties ◽  
Field Strength ◽  
Thermoplastic Elastomer ◽  
High Energy ◽  
Thermoplastic Elastomers ◽  
Electrical Strength ◽  
Voltage Stabilizer ◽  
Breakdown Field ◽  
Cable Insulation ◽  
Breakdown Field Strength

Blending thermoplastic elastomers into polypropylene (PP) can make it have great potential for high-voltage direct current (HVDC) cable insulation by improving its toughness. However, when a large amount of thermoplastic elastomer is blended, the electrical strength of PP will be decreased consequently, which cannot meet the electrical requirements of HVDC cables. To solve this problem, in this paper, the inherent structure of thermoplastic elastomer SEBS was used to construct acetophenone structural units on its benzene ring through Friedel–Crafts acylation, making it a voltage stabilizer that can enhance the electrical strength of the polymer. The DC electrical insulation properties and mechanical properties of acetylated SEBS (Ac-SEBS)/PP were investigated in this paper. The results showed that by doping 30% Ac-SEBS into PP, the acetophenone structural unit on Ac-SEBS remarkably increased the DC breakdown field strength of SEBS/PP by absorbing high-energy electrons. When the degree of acetylation reached 4.6%, the DC breakdown field strength of Ac-SEBS/ PP increased by 22.4% and was a little higher than that of PP. Ac-SEBS, with high electron affinity, is also able to reduce carrier mobility through electron capture, resulting in lower conductivity currents in SEBS/PP and suppressing space charge accumulation to a certain extent, which enhances the insulation properties. Besides, the highly flexible Ac-SEBS can maintain the toughening effect of SEBS, resulting in a remarkable increase in the tensile strength and elongation at the break of PP. Therefore, Ac-SEBS/PP blends possess excellent insulation properties and mechanical properties simultaneously, which are promising as insulation materials for HVDC cables.

Thermoplastic Elastomer Compounds from Sulfonated EPDM Ionomers

1988 ◽  
Vol 61 (2) ◽  
pp. 223-237 ◽  
Author(s):  
A. U. Paeglis ◽  
F. X. O'Shea
Keyword(s):  
High Performance ◽  
High Strength ◽  
Thermoplastic Elastomer ◽  
Cost Effective ◽  
Thermoplastic Elastomers ◽  
Hot Air ◽  
Low Temperature Flexibility ◽  
High Performance Application ◽  
And Control ◽  
Thermal Reversibility

Abstract The zinc sulfonate of EPDM, an ionic elastomer polymer, can be readily formulated into useful thermoplastic elastomer compounds having beneficial properties and processing characteristics. The thermoplastic processing characteristics of these ionic elastomers are uniquely controlled by “ionolyzers,” preferential ionic plasticizers. These additives induce thermal reversibility in the ionic crosslink and control the response of the ionic associations to temperature. Ionic elastomer compounds maintain many of the performance features characteristic of vulcanized EPDM, such as low-temperature flexibility, thermal stability, and weatherability, while providing the added advantages of heat weldability and elimination of vulcanization. We have developed a cost-effective ionic elastomer formulation that meets or exceeds the RMA recommendations for black EPDM in a demanding, high performance application, single-ply roofing membrane. High-strength lap seams can be rapidly fabricated using portable hot air welders, a technique unavailable to conventional vulcanized EPDM sheet. Other applications have been investigated for these polymers, such as hose, footwear, mechanical goods, adhesives, impact modifiers, and asphalt modifiers both as thermoplastic elastomers and as modifiers for other materials. These applications have taken advantage of the unique rheological and solubility properties of these polymers. In addition, a new polymer grade offers an advance in the ability to formulate higher strength and more highly filled and extended ionic elastomer compositions.

scholarly journals Thermoplastic elastomers containing 2D nanofillers: montmorillonite, graphene nanoplatelets and oxidized graphene platelets

2015 ◽  
Vol 17 (4) ◽  
pp. 74-81 ◽  
Author(s):  
Sandra Paszkiewicz ◽  
Iwona Pawelec ◽  
Anna Szymczyk ◽  
Zbigniew Rosłaniec
Keyword(s):  
Tensile Modulus ◽  
Thermoplastic Elastomer ◽  
Tensile Tests ◽  
Thermoplastic Elastomers ◽  
Graphene Nanoplatelets ◽  
Soft Phase ◽  
Permanent Set ◽  
Transmission Electron ◽  
Tetramethylene Oxide

Abstract This paper presents a comparative study on which type of platelets nanofiller, organic or inorganic, will affect the properties of thermoplastic elastomer matrix in the stronger manner. Therefore, poly(trimethylene terephthalate-block-poly(tetramethylene oxide) copolymer (PTT-PTMO) based nanocomposites with 0.5 wt.% of clay (MMT), graphene nanoplatelets (GNP) and graphene oxide (GO) have been prepared by in situ polymerization. The structure of the nanocomposites was characterized by transmission electron microscopy (TEM) in order to present good dispersion without large aggregates. It was indicated that PTT-PTMO/GNP composite shows the highest crystallization temperature. Unlike the addition of GNP and GO, the introduction of MMT does not have great effect on the glass transition temperature of PTMO-rich soft phase. An addition of all three types of nanoplatelets in the nanocomposites caused the enhancement in tensile modulus and yield stress. Additionally, the cyclic tensile tests showed that prepared nanocomposites have values of permanent set slightly higher than neat PTT-PTMO.

Effect of stabilizing additives on the strength characteristics of rigid polyvinyl chloride

1975 ◽  
Vol 9 (3) ◽  
pp. 486-488
Author(s):  
G. S. Baronin ◽  
E. V. Minkin ◽  
K. S. Kazaryan
Keyword(s):  
Polyvinyl Chloride ◽  
Strength Characteristics

scholarly journals High-throughput prediction of stress–strain curves of thermoplastic elastomer model block copolymers by combining hierarchical simulation and deep learning

MRS Advances ◽  
2021 ◽  
Author(s):  
Takeshi Aoyagi
Keyword(s):  
Deep Learning ◽  
High Throughput ◽  
High Throughput Screening ◽  
Thermoplastic Elastomer ◽  
Thermoplastic Elastomers ◽  
Coarse Grained ◽  
Stress Strain ◽  
Self Consistent Field ◽  
Self Consistent Field Theory ◽  
Dynamics Simulations

Abstract We achieved high-throughput prediction of the stress–strain (S–S) curves of thermoplastic elastomers by combining hierarchical simulation and deep learning. ABA triblock copolymer with a phase-separated structure was used as a thermoplastic elastomer model. The S–S curves of the ABA triblock copolymers were calculated from the hierarchical simulation of self-consistent field theory calculations and coarse-grained molecular dynamics simulations. Because such hierarchical simulations require considerable computational resources, we applied a deep learning technique to accelerate the prediction. Sets of phase-separated structures and the S–S curves obtained from the hierarchical simulation were used to train a 3D convolutional neural network. Using the trained network, we confirmed that the predicted S–S curves of the untrained structures accurately reproduced the simulation results. These results will enable us to design novel polymers and phase-separated structures with desired S–S curves by high-throughput screening of a wide variety of structures. Graphic abstract

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