scholarly journals STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF CHEMICALLY DEPOSITED COPPER DOPED NICKEL HYDROXIDE

2021 ◽  
pp. 90-91
Author(s):  
D.B. Mane ◽  
L.D. Kadam ◽  
R.V. Dhekale ◽  
G. M. Lohar
Keyword(s):  
Specific Capacitance ◽  
Xrd Analysis ◽  
Charge Transfer Resistance ◽  
Stainless Steel Electrode ◽  
Hexagonal Crystal Structure ◽  
Hexagonal Crystal ◽  
Transfer Resistance ◽  
Steel Electrode ◽  
Ft Ir ◽  
Ir Study

Present work reported, copper doped Ni(OH) deposited successfully by chemical bath deposition method on 2 economical stainless steel electrode. The XRD analysis represent hexagonal crystal structure and presence of Ni and Cu confirm by FT-IR study. The surface morphology studied by SEM indicates nanopetals linked marigold like microflowers. -1 -1 The 0.2% Cu doped Ni(OH)2 shows specific capacitance 715 Fg at scan rate 10 mV s . EIS study interprets that electrode N-0.2% have least charge transfer resistance which improve value of specific capacitance. All results revels cupper is good dopant for improve the specific capacitance.

scholarly journals STUDY OF STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF 3-D MICROFLOWER-LIKE NICKEL HYDROXIDE

2021 ◽  
pp. 17-18
Author(s):  
D.B. Mane ◽  
L.D. Kadam ◽  
R.V. Dhekale ◽  
G. M. Lohar
Keyword(s):  
Nickel Hydroxide ◽  
Room Temperature ◽  
Deposition Time ◽  
Charge Transfer Resistance ◽  
Hexagonal Crystal ◽  
Galvanostatic Charge ◽  
Transfer Resistance ◽  
Ft Ir ◽  
Eis Analysis ◽  
Energy And Power Density

Recent work reported on nickel hydroxide chemically synthesized by simple cast effective chemical bath deposition method at room temperature. During reaction, nanoflakes developed and time enhance nanoflakes interlinked to form marigold like microflower which reveals from SEM. Structural properties analysis by XRD and FT-IR gives hexagonal crystal structure and presence of Ni-O bond to confirmation of deposition of Ni(OH) material. Highest value of specific 2 -1 capacitance of electrode at deposition time 90 min without aniline from Cyclic voltammetry is 553 Fg at scan rate 10 mV -1 -1 -2 -1 -1 s and from Galvanostatic charge discharge 215 Fg at current density 3 mA cm with 6.04 W h kg and 1687.5 W kg of energy and power density respectively. EIS analysis reveals least charge transfer resistance of 90min deposition time electrode.

LiMn1.5Ni0.25Fe0.2M0.05O4 Nanoparticles as a Cathode Material for Rechargeable Li-Ion Batteries

2020 ◽  
Vol 835 ◽  
pp. 149-154
Author(s):  
Haitham A. Abdellatif ◽  
Mostafa M.M. Sanad ◽  
Elsayed M. Elnaggar ◽  
Mohamed M. Rashad ◽  
Gamal M. El-Kady
Keyword(s):  
Annealing Temperature ◽  
Sol Gel ◽  
Combustion Method ◽  
Xrd Analysis ◽  
Charge Transfer Resistance ◽  
Li Ion Batteries ◽  
Transfer Resistance ◽  
Auto Combustion ◽  
Li Ion ◽  
Kinetic Diffusion

New series of spinel LiNi0.25Fe0.2Mˊ0.05Mn1.5O4 (Mˊ = Cu, Mg or Zn) cathode materials have been purposefully tailored using sol-gel auto-combustion method at low annealing temperature ~ 700°C for 3 h. The XRD analysis showed that all substituted (LNFMO-Mˊ) samples are comported with the main structure of undoped (LNFMO) with crystalline disordered spinel Fd-3m structure. TEM images revealed the octahedron-shape like morphology for the particles and the LNFMO-Zn sample has the widest particle size distribution. EIS spectra evidenced that a typical one semicircle (LNFMO-Mg) was revealed for each cell, suggesting the absence of ionic conductivity contribution. The values of charge transfer resistance (Rct) were equal to 9.3, 6.7, 6.0 and 4.4 kΩ for LNFMO, LNFMO-Cu, LNFMO-Mg indicating that the Zn-doped sample has the fastest kinetic diffusion rate and lowest activation energy of conduction.

Influence of Electromagnetic Treatment on Corrosion Behavior of Carbon Steel and 316L Stainless Steel in Simulated Cooling Water

2011 ◽  
Vol 347-353 ◽  
pp. 3135-3138
Author(s):  
Hong Hua Ge ◽  
Jie Ting Tao ◽  
Xiao Ming Gong ◽  
Cheng Jun Wei ◽  
Xue Min Xu
Keyword(s):  
Stainless Steel ◽  
Carbon Steel ◽  
Corrosion Behavior ◽  
316L Stainless Steel ◽  
Cooling Water ◽  
Stainless Steel Electrode ◽  
Transfer Resistance ◽  
Steel Electrode ◽  
Pitting Potential ◽  
Electromagnetic Treatment

Abstract: The effect of electromagnetic treatment on corrosion behavior of carbon steel and stainless steel in simulated cooling water was investigated by electrochemical impedance spectroscopy, potentiodynamic polarization techniques and water analysis. It was found that the charge transfer resistance decreased and the corrosion current density increased after electromagnetic treatment for carbon steel electrode, which shows that such treatment promotes corrosion of carbon steel in simulated cooling water. In contrast, the pitting potential of 316L stainless steel electrode rose which revealed that electromagnetic treatment of the experimental water exhibited corrosion inhibition to 316L stainless steel. Reasons for different corrosion behavior of the two metals were discussed.

Facile Preparation of NiO/Ni Nanocomposite and its Electrochemical Capacitive Behaviors

2011 ◽  
Vol 306-307 ◽  
pp. 134-138 ◽  
Author(s):  
Wei Dong Yin ◽  
Gui Lian Li ◽  
Xian Ming Liu
Keyword(s):  
Specific Capacitance ◽  
Oxidation Process ◽  
Aqueous Electrolyte ◽  
High Specific Capacitance ◽  
Cycling Performance ◽  
Charge Transfer Resistance ◽  
Electrochemical Performances ◽  
Composite Electrodes ◽  
Galvanostatic Charge ◽  
Transfer Resistance

NiO/Ni nanocomposites were prepared by chemically reduction-oxidation process in tetra-ethylene glycol (TEG) solution. The structure and morphology of the samples were examined by XRD and SEM. The results indicated the composite consisted of NiO and Ni and exhibited spherical morphology with diameter of 50-200 nm. The electrochemical performances of composite electrodes used in electrochemical capacitors were studied. The electrochemical measurements were carried out using cyclic voltammetry, galvanostatic charge/discharge and impedance spectroscopy in 6M KOH aqueous electrolyte using three-electrode Swagelok systems. The results showed that the composite had a high specific capacitance and excellent capacitive behavior. The specific capacitance of the composite decreased to 192F/g after 500 cycles. Due to the existance of Ni, the charge transfer resistance is lower than 1Ω. It revealed that the composite exhibited good cycling performance.

scholarly journals Facilely Synthesized NiCo2O4/NiCo2O4 Nanofile Arrays Supported on Nickel Foam by a Hydrothermal Method and Their Excellent Performance for High-Rate Supercapacitance

Energies ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1308 ◽  
Author(s):  
Anil Yedluri ◽  
Eswar Araveeti ◽  
Hee-Je Kim
Keyword(s):  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Nickel Foam ◽  
Rate Capability ◽  
Charge Transfer Resistance ◽  
High Rate ◽  
Transfer Resistance ◽  
Electrons And Ions ◽  
Binary Metal Oxides ◽  
Hydrothermal Approach

NiCo2O4 nanoleaf arrays (NCO NLAs) and NiCo2O4/NiCO2O4 nanofile arrays (NCO/NCO NFAs) material was fabricated on flexible nickel foam (NF) using a facile hydrothermal approach. The electrochemical performance, including the specific capacitance, charge/discharge cycles, and lifecycle of the material after the hydrothermal treatment, was assessed. The morphological and structural behaviors of the NF@NCO NLAs and NF@NCO/NCO NFAs electrodes were analyzed using a range of analysis techniques. The as-obtained nanocomposite of the NF@NCO/NCO NFAs material delivered outstanding electrochemical performance, including an ultrahigh specific capacitance (Cs) of 2312 F g−1 at a current density of 2 mA cm−2, along with excellent cycling stability (98.7% capacitance retention after 5000 cycles at 5 mA cm−2). These values were higher than those of NF@NCO NLAs (Cs of 1950 F g−1 and 96.3% retention). The enhanced specific capacitance was attributed to the large electrochemical surface area, which allows for higher electrical conductivity and rapid transport between the electrons and ions as well as a much lower charge-transfer resistance and superior rate capability. These results clearly show that a combination of two types of binary metal oxides could be favorable for improving electrochemical performance and is expected to play a major role in the future development of nanofile-like composites (NF@NCO/NCO NFAs) for supercapacitor applications.

EFFECT OF TiO2 PARTICLES ON MICRO-HARDNESS, CORROSION, WEAR AND FRICTION OF Ni–P–TiO2 COMPOSITE COATINGS AT DIFFERENT ANNEALING TEMPERATURES

2016 ◽  
Vol 23 (01) ◽  
pp. 1550082 ◽  
Author(s):  
PRASANNA GADHARI ◽  
PRASANTA SAHOO
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Composite Coatings ◽  
Corrosion Current ◽  
Xrd Analysis ◽  
Charge Transfer Resistance ◽  
Micro Hardness ◽  
Transfer Resistance ◽  
X Ray ◽  
Annealing Temperatures

The present study investigates the effect of titania particles on the micro-hardness, wear resistance, corrosion resistance and friction of electroless Ni–P–TiO2 composite coatings deposited on mild steel substrates at different annealing temperatures. The experimental results confirmed that the amount of TiO2 particles incorporated in the coatings increases with increase in the concentration of particles in the electroless bath. In presence of TiO2 particles, hardness, wear resistance and corrosion resistance of the coating improve significantly. At higher annealing temperature, wear resistance increases due to formation of hard Ni3P phase and incorporation of titania particles in the coated layer. Charge transfer resistance and corrosion current density of the coatings reduce with an increase in TiO2 particles, whereas corrosion potential increases. Microstructure changes and composition of the composite coating due to heat treatment are studied with the help of scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA) and X-ray diffraction (XRD) analysis.

Effect of Magnetic Field on the Electropolymerization and Corrosion Properties of Polyaniline (PANI) Film

2012 ◽  
Vol 472-475 ◽  
pp. 198-205 ◽  
Author(s):  
Chao Fang Dong ◽  
Yang Yang ◽  
Hong Luo ◽  
Kui Xiao ◽  
Xiao Gang Li
Keyword(s):  
Magnetic Field ◽  
Aqueous Solution ◽  
304 Stainless Steel ◽  
Pani Film ◽  
Stainless Steel Electrode ◽  
X Ray Diffraction ◽  
Corrosion Properties ◽  
Steel Electrode ◽  
X Ray ◽  
Ft Ir

The polyaniline have been prepared in the absence and presence of magnetic field by the technique of cyclic voltammetry (CV) on 304-stainless steel electrode in H2SO4 aqueous solution of aniline (Ani). The influence of magnetic field on electropolymerization of PANI was investigated by electrochemical properties, FT-IR spectra, X-ray diffraction (XRD) and microstructure. The results indicate that the effect of magnetic field on the polyaniline is positive.

scholarly journals Magnetite-Functionalized Horse Dung Humic Acid (HDHA) for the Uptake of Toxic Lead(II) from Artificial Wastewater

2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Rahmat Basuki ◽  
Bambang Rusdiarso ◽  
Sri Juari Santosa ◽  
Dwi Siswanta
Keyword(s):  
Humic Acid ◽  
Xrd Analysis ◽  
Desorption Process ◽  
X Ray ◽  
Ft Ir ◽  
Magnetic Strength ◽  
The Stability ◽  
Ir Study ◽  
Average Size ◽  
Adsorption Rates

Magnetite-functionalized horse dung humic acid (HDHA) has been successfully prepared by the coprecipitation method, and the as-prepared adsorbent (MHDHA) has been applied as an easy-handling adsorbent for toxic Pb(II) in artificial wastewater. The MHDHA was characterized by Fourier transform-infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), and vibrating sample magnetometer (VSM). The FT-IR study showed that the MHDHA had the characteristics peaks of HA and Fe-O stretching. The XRD analysis revealed that the MHDHA had the 2 θ characteristic for magnetite. The TEM image and EDX analysis exhibited that the MHDHA with an average size of ∼14 nm was partially aggregated and contained ( w / w ) 9.89% carbon, 2.89% nitrogen, and 32.74% oxygen based on functional groups of HDHA. The stability improvement of MHDHA was showed by decreasing HDHA dissolved from 95% to less than 30% at pH 12 after magnetite functionalization. The post-adsorption handling improvement was evidenced by easy and quick retraction by an external magnet with a 62.95 emu/g magnetic strength value. The adsorption capacities were influenced by the pH and ionic strength, whilst the adsorption rates were well simulated by the Ho pseudo-second-order model. The removal uptake of Pb(II) ions increased when the initial concentration was increased and fitted well with the Langmuir isotherm model when the monolayer adsorption capacity was 2.78 × 10 − 4   mol / g (equal to 57.64 mg/g). The value of Dubinin-Radushkevich adsorption energy ( E D − R ) found in this study was 14.78 kJ/mol, which implied that ion exchange is the main mechanism involved in the adsorption process. The regeneration studies of MHDHA show that there was no significant change in composition, morphology, crystallinity, and functional group after five consecutive cycles of the adsorption-desorption process.

Inhibitive Performance of 1,4/1,6-Bis(α-Alkyl Pyridinium ) Butane/Hexane Dibromide on A3 Steel

2011 ◽  
Vol 339 ◽  
pp. 96-102
Author(s):  
Xiao Hui Jiang ◽  
Li Mei Zhou ◽  
Shan Zhuo Yao ◽  
Ming Duan ◽  
Xing Qi Hu
Keyword(s):  
Self Assembly ◽  
Gemini Surfactants ◽  
Alkyl Chain ◽  
Charge Transfer Resistance ◽  
Inhibition Rate ◽  
Gravimetric Measurement ◽  
Transfer Resistance ◽  
Alkyl Chains ◽  
Ft Ir ◽  
Positively Charged

1,6-bis(α-alkyl pyridinium ) hexane dibromide was synthesized and confirmed by 1H NMR, 13C NMR, FT-IR and MS. The inhibitive effect of the gemini surfactants for A3 steel in 20% hydrochloric acid was evaluated by gravimetric measurement and electrochemical method. The results indicated that the inhibitive efficiency of the gemini surfactants was affected by the concentration, the length of alkyl chain and spacer in the gemini surfactants. The inhibition rate increased with concentration, the surfactants with four methylenes as spacer showed a slightly better anticorrosive performance than those with six methylenes, and the gemini surfactants with decyl chains exhibited the best inhibitive efficiency. The adsorption of these gemini surfactants on the surface of A3 steel was in accordance with Langmuir isotherm. The electrochemical experiment revealed that the gemini surfactants were mix-type inhibitors. The current density decreased noticeably with the concentration while the charge-transfer resistance increased. The pyridinium rings and positively charged nitrogen atoms in the gemini molecule adsorbed on A3 steel surface and the alkyl chains formed a hydrophobic layer by virtue of self-assembly property of surfactants. Therefore the corrosion of A3 steel was effectively inhibited by the gemini surfactants.

scholarly journals Nanoflake Manganese Oxide and Nickel-Manganese Oxide Synthesized by Electrodeposition for Electrochemical Capacitor

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Man Van Tran ◽  
An The Ha ◽  
Phung My Loan Le
Keyword(s):  
Manganese Oxide ◽  
Specific Capacitance ◽  
Deposition Time ◽  
Discharge Rate ◽  
Electrochemical Capacitor ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Structure Morphology ◽  
Highly Porous ◽  
Nickel Manganese

Nanoflake structures of electrochemical manganese oxide (EMD) and nickel mixed manganese oxide (NiMD) were directly deposited on a stainless steel by using Chronoamperometry and Cyclic Voltammetry (CV) techniques. The structure, morphology, and capacitive behavior of EMD or NIMD nanoflake were affected by the electrodeposition modes and deposition time. The highest specific capacitance (Csp) was obtained for only two-minute deposition by both methods. EMD nanoflakes electrodeposited by CV technique show higher specific capacitance values than those prepared by Chronoamperometry owing to its homogenous and highly porous surface. All EMD samples exhibited excellent cycle behavior, less than 5% capacitance loss after 1000 cycles. Ni mixed MnO2was prepared at different Mn2+/Ni2+ratios for 2 minutes of electrodeposition. The presence of Ni2+ion enhanced theCspvalue at high charge-discharge rate due to the decrease of the charge transfer resistance. The supercapacitor prototype of 2 cm × 2 cm was assembled using EMD and NiMD as electrode material and tested at 1 A·g−1.

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