scholarly journals ASSESMENT OF HEAVY METALS IN MANIHOT ESCULENTA (CASSAVA) IN SELECTED FARMS IN LAGOS STATE, NIGERIA

2018 ◽  
Vol 5 (1) ◽  
Author(s):  
Abosede A. Adu ◽  
Bamidele I. John ◽  
Anthony B. Ojekale ◽  
O.J. Aderinola
Keyword(s):  
Heavy Metals ◽  
Manihot Esculenta ◽  
Anthropogenic Activities ◽  
High Concentration ◽  
Lagos State ◽  
Iron Nickel ◽  
Lead Zinc ◽  
Aas Method ◽  
Sodium And Potassium ◽  
Recommended Level

Introduction: Anthropogenic activities by man in Nigeria especially Lagos State have induced accumulation of heavy metals in soils which invariably have resulted in the disturbance of living organism’s biochemical and physiological functions. Aim: This study assessed the level of heavy metals concentration in cassava (Manihot esculenta) harvested in selected farms in Lagos state. Materials and Methods: Leaves, stems, tubers of cassava were obtained from Morogbo, Badagry area and Odogunyan, Ikorodu area; and the concentrations of heavy metals content were determined using Atomic Absorption Spectrophotometric (AAS) method. Results: The results in mg/kg showed that heavy metals concentration [Nickel (3559.67 ± 5794.16), Manganese (120.33 ± 5.51), Copper (52.10 ± 2.85 and so on] were highly bioaccumulated in leafy part of the cassava. Conversely, Sodium (11620.00 ± 820.18) and Potassium (15133.33 ± 508.46) were highly bio-accumulated in the cassava’s stem while Calcium (3996.67 + 35.12) was found in high concentration in the cassava’s tuber. Lead (0.03 ± 0.05) and Cadmium (0.08 ± 0.08) were of significant values in the soil of Ikorodu and lower in the soil of Badagry. Heavy metal (Ni, Mn, Cd, Mg and Na) bio-accumulation in the two different location were higher in Badagry than Ikorodu, while Zn, Fe and K were higher in Ikorodu than in Badagry but Cobalt was not detected in both sites. Conclusion: Copper, Lead, Zinc, Manganese, Iron, Nickel, Calcium, Sodium and Potassium were above the recommended level of W.H.O. Therefore, consumption of leafy and tuber part of the cassava in both Ikorodu and Badagry areas could pose threat to animals.

ASSESSMENT OF HEAVY METAL CONCENTRATION IN COCONUT WATER

1970 ◽  
pp. 07-10
Author(s):  
MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Concentration ◽  
Coconut Water ◽  
Toxic Heavy Metals ◽  
High Concentration ◽  
Toxic Heavy Metal ◽  
Low Concentration ◽  
Wet Ashing ◽  
Aas Method

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples. 

scholarly journals Seasonal assessment, treatment and removal of heavy metal concentrations in a tropical drinking water reservoir

2016 ◽  
Vol 35 (2) ◽  
pp. 103-113 ◽  
Author(s):  
Moshood Keke Mustapha ◽  
Joy Chinenye Ewulum
Keyword(s):  
Heavy Metals ◽  
Drinking Water ◽  
Best Management Practices ◽  
Management Practices ◽  
Anthropogenic Activities ◽  
Health Hazard ◽  
Water Reservoir ◽  
Industrial Effluents ◽  
High Concentration ◽  
Agricultural Materials

AbstractHeavy metals are present in low concentrations in reservoirs, but seasonal anthropogenic activities usually elevate the concentrations to a level that could become a health hazard. The dry season concentrations of cadmium, copper, iron, lead, mercury, nickel and zinc were assessed from three sites for 12 weeks in Oyun reservoir, Offa, Nigeria. Triplicate surface water samples were collected and analysed using atomic absorption spectrophotometry. The trend in the level of concentrations in the three sites is site C > B > A, while the trend in the levels of the concentrations in the reservoir is Ni > Fe > Zn > Pb > Cd > Cu > Hg. Ni, Cd, Pb and Hg were found to be higher than the WHO guidelines for the metals in drinking water. The high concentration of these metals was from anthropogenic watershed run-off of industrial effluents, domestic sewages and agricultural materials into the reservoir coming from several human activities such as washing, bathing, fish smoking, especially in site C. The health effects of high concentration of these metals in the reservoir were highlighted. Methods for the treatment and removal of the heavy metals from the reservoir during water purification such as active carbon adsorption, coagulation-flocculation, oxidation-filtration, softening treatment and reverse osmosis process were highlighted. Other methods that could be used include phytoremediation, rhizofiltration, bisorption and bioremediation. Watershed best management practices (BMP) remains the best solution to reduce the intrusion of the heavy metals from the watershed into the reservoir.

scholarly journals Contamination Features and Source Apportionment of Heavy Metals in the River Sediments around a Lead-Zinc Mine: A Case Study in Danzhai, Guizhou, China

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Rongguo Sun ◽  
Yue Gao ◽  
Jing Xu ◽  
Yang Yang ◽  
Yutao Zhang
Keyword(s):  
Heavy Metals ◽  
Anthropogenic Activities ◽  
Risk Index ◽  
River Sediments ◽  
Careful Consideration ◽  
Ecological Risks ◽  
Lead Zinc ◽  
Zinc Mine ◽  
Mining And Smelting ◽  
Mining And Smelting Activities

The spatial patterns, ecological risks, and sources of heavy metals (HMs), including Pb, Zn, Mn, Cu, Cd, Hg, and As in river sediments, were identified around a lead-zinc mine of Danzhai, Guizhou, China. The concentrations of selected HMs and their coefficient variations indicated that the river sediments around this typical lead-zinc mine were obviously contaminated with HMs. Anthropogenic activities had further enhanced the accumulation of HMs. The higher contents of the most common selected HMs were mainly distributed in the area close to the lead-zinc mine. Based on the combined evaluations of the single factor pollution index, geo-accumulation index, and potential ecological risk index, it indicated that the ecological risks of Hg, Cd, Zn, and Pb were high or extremely high, and of Mn, Cu, and As were slight or none in the sediments around this lead-zinc mine. It was found that lead-zinc mining and smelting activities, coal mining activities, and agricultural activities (livestock and poultry breeding) are the primary sources of selected HMs, based on the results of correlation analysis together with principal component analysis (PCA) and positive matrix factorization (PMF) model. The pollution of HMs in the river sediments around a lead-zinc mine was predominantly caused by lead-zinc mining and smelting activities. Therefore, for environmental persistence, lead-zinc mining and smelting activities should be given careful consideration and under close surveillance.

scholarly journals Heavy Metals in Water, Soils and Sediments of La Villa River Basin- Panama

2021 ◽  
pp. 1-12
Author(s):  
José Villarreal Núñez ◽  
Adolfo Santo Pineda ◽  
Jhon Villalaz Pérez ◽  
Iván Ramos Zachrisson
Keyword(s):  
Heavy Metals ◽  
River Basin ◽  
Water Samples ◽  
Rainy Season ◽  
Anthropogenic Activities ◽  
Great Influence ◽  
Dry Season ◽  
High Concentration ◽  
South Central ◽  
Rectangular Area

Determine the concentration of heavy metals in water, sediments, and crops within the La Villa river basin, Herrera and Los Santos provinces, republic of Panama. La Villa river Basin, south central of Panama, in the rainy season of 2016 (May to November) and in the dry season of 2017 (December to April). Twenty two sediments and water samples were taken using the systematic method which consists of selecting sampling points at uniform distances and crops in upper, middle and lower basin. The selected sampling was confined to a preferably rectangular area of 10.0 m x 30.0 m, on which the sub-samples were taken with a number of 15 on each grid, at 0.20m depth. For collecting the water samples, a rod with a clean plastic bottle was introduced against the current of the river. The digestion of sediments and crops to determine the concentration of heavy metals (As, Pb, Cr, Ni, Cu, Mn, Zn and Cd) was carried out according to USEPA (25) method (3051A) (SW-846). In the sediments, in the rainy season, Cu (upper and lower basin) and Mn (all levels) values were found above the USEPA Standards. In the dry season, high values of Mn were found in the middle and lower basin, Cr in the upper and lower basin and As in all areas of the basin. In the rainy and dry seasons, high levels of Mn, Zn, Cr, Cd and Pb were found in the waters of the rivers that make up the basin. The main crops at each height of the basin were analyzed, determining high levels of As and Cr in the upper basin, in the middle and lower basin Cr and Cd. It is necessary to monitor the concentration of heavy metals in sediments of La Villa river basin because 90% of the agrochemicals that enter the country is destined for agriculture. Each Panamanian consumes (does not ingest) 3 kg of agrochemicals annually, exceeding six times the amount used in Central America.  Due to their geological origin, these soils are rich in copper, manganese and arsenic, latter being associated with iron oxides and sulfides but there is also great influence of anthropogenic activities, agriculture and industries. Some metals such as lead and arsenic showed low solubility in water but showed high concentration in sediments. Chromium and cadmium present in crops come from water.

Contamination and environmental risk assessment of heavy metals in marine sediments from Tahaddart estuary (NW of Morocco)

2020 ◽  
Vol 26 (1) ◽  
pp. 87-102
Author(s):  
Meryem El Barjy ◽  
Mehdi Maanan ◽  
Mohamed Maanan ◽  
Fouad Salhi ◽  
Ali Tnoumi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Anthropogenic Activities ◽  
Risk Index ◽  
Thermal Power ◽  
Sediment Cores ◽  
Aquatic Organisms ◽  
Size Composition ◽  
Potential Ecological Risk ◽  
High Concentration ◽  
Environmental Indices

The distribution, contamination status, and ecological risks of heavy metals in Tahaddart estuary were investigated. 24 surface sediment samples and two cores were collected and analyzed for major (Al and Fe), heavy metals (As, Cd, Cr, Cu, Ni, Pb, and Zn), and grain size composition. The heavy metals assessment was carried out using different environmental indices. The results indicated that the spatial distribution patterns of Al, Fe, and Zn were mainly determined by the distribution of the finer grained fraction (<63 μm) in the sediment. In contrast, As, Cd, Cr, Cu, Ni, and Pb concentrations were controlled by anthropogenic activities (vehicular traffic from Highway Bridge and thermal power plant). The distribution of heavy metals in sediment cores showed an upward enrichment in heavy metals with high concentration found in the uppermost may related to the increasing in human activities. The pollution indexes confirmed that the Tahaddart estuary sediment was considerably to high contaminated by heavy metals near to different anthropogenic inputs. Similarly, the potential ecological risk index and the biological risk index present 21% probability of toxicity posing potential risk to the aquatic organisms. These results provide basic information that can be used to protect and improve the quality of this ecosystem.

SPATIAL DISTRIBUTION AND HEALTH RISK ASSESSMENT OF HEAVY METALS IN URBAN PARKS AND GARDENS SOILS IN LAGOS STATE, NIGERIA

2019 ◽  
Vol 18 (1) ◽  
pp. 16-35
Author(s):  
O. H. ADEDEJI ◽  
O. O. OLAYINKA ◽  
O. O. TOPE-AJAYI ◽  
D. A. AWOSIKA
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Health Risk ◽  
Health Risk Assessment ◽  
Risk Model ◽  
Anthropogenic Activities ◽  
Risk Index ◽  
Urban Parks ◽  
Motor Vehicles ◽  
Lagos State

Distribution and health risk assessment of heavy metals in urban parks and gardens Gani Fawehinmi Park, Ojota, (GFP), Oshodi Heritage Park Oshodi (OHP), Ikorodu/Ipado Garden (IIG), MKO Abiola Gardens, Ojota (MKO), and MOE Garden, Alausa (MOE) soils in Lagos Metropolis, Nigeria were examined using Index of Geo-accumulation (Igeo), Potential Ecological Risk Index (RI) and health risk model. Urban parks and gardens soils were substantially polluted by Cu and Pb due closeness to highways where heavy metals emitted from motor vehicles are deposited.  Geoaccumulation index (Igeo) values for Pb were 10.616, 10.060, 9.027, 8.862 and 8.665 for GFP, OHP, IIG, MKO and MOE respectively. RI values for all the sites showed high pollution as they were all above 200. Health risk assessment revealed that children who visit the urban parks and garden in Lagos State are more exposed to cancer risk from Pb especially through ingestion. Results from this study provided valuable information on the pollution levels of urban parks in Lagos, Nigeria as a result of traffic related emissions and calls for proper monitoring of anthropogenic activities in the metropolis and reduce the human health impacts. The planting of hedge plants and erection of low walls could serve as shield against traffic pollution for the roadside parks      

Assessment of micro and macro nutrients in poultry feeds available in Dhaka city, Bangladesh.

2017 ◽  
Vol 1 ◽  
pp. 264
Author(s):  
Md Didarul Islam ◽  
Ashiqur Rahaman ◽  
Fahmida Jannat
Keyword(s):  
Heavy Metals ◽  
Adverse Effect ◽  
The Other ◽  
Nutrient Level ◽  
Dhaka City ◽  
Toxic Heavy Metals ◽  
High Concentration ◽  
Low Concentration ◽  
Feed Formulation ◽  
Macro Nutrients

This study was based on to determine the concentration of macro and micro nutrients as well as toxic and nontoxic heavy metals present in the chicken feed available in Dhaka city of Bangladesh. All macro nutrients, if present in the feed at high concentration have some adverse effect, at the same time if this nutrient present in the feed at low concentration this have some adverse effect too. So that this nutrient level should be maintained at a marginal level. On the other side toxic heavy metals if present in the feed at very low concentration those can contaminate the total environment of the ecosystem. In this study six brand samples (starter, grower, finisher and layer) which was collected from different renowned chicken feed formulation industry in Bangladesh. Those samples were prepared for analysis by wet ashing and then metals were determined by Atomic Absorption Spectroscopy. It was found that 27.7 to 68.4, 57.3 to 121.9, 0.21 to 4.1, 0.32 to 2.1, 0.11 to 1.58, 0.28 to 2.11 and 0.28 to 1.78 for zinc, iron, copper, mercury, cadmium, nickel and cobalt respectively. It was found that essential macro and micro nutrients were present in the feed in low concentration on the other side mercury was present in high concentration in the feed samples.

Chemical Composition and Metal Speciation in Porewaters from the Upper Qu’Appelle River Basin, Saskatchewan

1993 ◽  
Vol 28 (1) ◽  
pp. 83-110 ◽  
Author(s):  
Richard E. Farrell ◽  
Jae E. Yang ◽  
P. Ming Huang ◽  
Wen K. Liaw
Keyword(s):  
Amino Acids ◽  
Trace Metal ◽  
River Basin ◽  
Drainage Basin ◽  
Metal Speciation ◽  
Anthropogenic Activities ◽  
High Concentration ◽  
Metal Concentrations ◽  
Carbonate Equilibria ◽  
The Impact

Abstract Porewater samples from the upper Qu’Appelle River basin in Saskatchewan, Canada, were analyzed to obtain metal, inorganic ligand and amino add profiles. These data were used to compute the aqueous speciation of the metals in each porewater using the computer program GEOCHEM-PC. The porewaters were classified as slightly to moderately saline. Metal concentrations reflected both the geology of the drainage basin and the impact of anthropogenic activities. Whereas K and Na were present almost entirely as the free aquo ions, carbonate equilibria dominated the speciation of Ca. Mg and Mn (the predominant metal ligand species were of the type MCO3 (s). MCO30. and MHCO3+). Trace metal concentrations were generally within the ranges reported for non-polluted freshwater systems. Whereas the speciation of the trace metals Cr(III) and Co(II) was dominated by carbonate equilibria, Hg(II)-, Zn(II)- and Fe(II)-speciation was dominated by hydroxy-metal complexes of the type M(OH)+ and M(OH)2°. The speciation of Fe(III) was dominated by Fe(OH)3 (s). In porewaters with high chloride concentrations (&gt; 2 mM), however, significant amounts of Hg(II) were bound as HgCl20 and HgClOH0. The aqueous speciation of Al was dominated by Al(OH)4− and Al2Si2O4(OH)6 (s). Total concentrations of dissolved free amino acids varied from 15.21 to 25.17 umole L−1. The most important metal scavenging amino acids were histidine (due to high stability constants for the metal-histidine complexes) and tryptophan (due to its relatively high concentration in the porewaters. i.e., 5.96 to 7.73 umole L−1). Secondary concentrations of various trace metal-amino add complexes were computed for all the porewaters, but metal-amino acid complexes dominated the speciation of Cu(II) in all the porewaters and Ni(II) in two of the porewaters.

Abiotic reduction of 2,4-dinitrotoluene in the presence of sulfide minerals under anoxic conditions

1996 ◽  
Vol 34 (10) ◽  
pp. 25-33 ◽  
Author(s):  
Cheng Jiayang ◽  
Makram T. Suidan ◽  
Albert D. Venosa
Keyword(s):  
Electron Donor ◽  
Chemical Reduction ◽  
Sulfide Minerals ◽  
Sulfide Concentration ◽  
Magnesium Ions ◽  
High Concentration ◽  
Anoxic Conditions ◽  
High Affinity ◽  
Iron Nickel ◽  
Abiotic Reduction

Abiotic reduction of 2,4-dinitrotoluene (DNT) in the presence of sulfide minerals has been investigated under anoxic conditions at 35°C. 2,4-DNT was abiotically reduced to 4-amino-2-nitrotoluene (4-A-2-NT) and 2-amino-4-nitrotoluene (2-A-4-NT) in the presence of high concentration of sulfide (0.84 mM). No abiotic reduction of 2,4-DNT was observed in the presence of low sulfide concentration (0.42 mM). The rate and the extent of the abiotic reduction of 2,4-DNT were increased with an increase in sulfide concentration. Sulfide served as an electron donor for the reduction of 2,4-DNT. The 2-nitro group was preferentially reduced, making the 2-A-4-NT:4-A-2-NT ratio in the final products 2:1. The addition of iron, nickel, and cobalt minerals significantly enhanced the abiotic reduction. The FeS, NiS, and CoS solids formed in the serum bottles catalyzed the reduction of 2,4-DNT preferentially to 4-A-2-NT. MnS and CuS solids also catalyzed the reduction of 2,4-DNT to 4-A-2-NT, but did not change the overall reduction of 2,4-DNT. However, the presence of calcium, zinc, and magnesium minerals impeded 2,4-DNT reduction. The calcium, zinc, and magnesium ions have a high affinity to sulfide, inactivating sulfide as an electron donor for the chemical reduction of 2,4-DNT.

Pollution retention capabilities of roadside soils

1999 ◽  
Vol 39 (2) ◽  
pp. 201-208 ◽  
Author(s):  
C. Dierkes ◽  
W. F. Geiger
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Drinking Water ◽  
Groundwater Recharge ◽  
Drinking Water Quality ◽  
Traffic Density ◽  
Roadside Soils ◽  
Highway Runoff ◽  
Lead And Cadmium ◽  
Lead Zinc

Runoff from highways contains significant loads of heavy metals and hydrocarbons. According to German regulations, it should be infiltrated over embankments to support groundwater-recharge. To investigate the decontaminating effect of greened embankments, soil-monoliths from highways with high traffic densities were taken. Soils were analyzed to characterize the contamination in relation to distance and depth for lead, zinc, copper, cadmium, PAH and MOTH. Lysimeters were charged in the field and laboratory with highway runoff to study the effluents under defined conditions. Concentrations of pollutants in roadside soils depend on the age of embankments and traffic density. Highest concentrations were found in the upper 5 cm of the soil and within a distance of up to two metres from the street. Concentrations of most pollutants decreased rapidly with depth and distance. Lead and cadmium could not be detected in lysimeter effluent. Zinc and copper were found in concentrations that did not exceed drinking water quality limits.

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