Morphology and Mechanical Properties of Polyethylene Terephthalate/Ethylene Propylene Diene Monomer (PET/EPDM) in the Presence of Nanoclay

2020 ◽  
Vol 57 (3) ◽  
pp. 249-259
Author(s):  
Baifen Liu ◽  
Mohammad Mirjalili ◽  
Peiman Valipour ◽  
Sajad Porzal ◽  
shirin Nourbakhsh

This research deals with the mechanical properties, microstructure, and interrelations of triple nanocomposite based on PET/EPDM/Nanoclay. These properties were examined in different percentages of PET/EPDM blend with compatibilizer (Styrene-Ethylene/Butylene-Styrene)-G-(Maleic anhydrate) (SEBS-g-MAH). Results showed that the addition of 15% SEBS-g-MAH improved the toughness and impact strength of this nanocomposite. SEM micrographs indicated the most stable fuzzy microstructure in a 50/50 mixture of scattered phases of EPDM/SEBS-g-MAH. The effects of percentages of 1, 3, 5, 7 nanoclay Cloisite 30B (C30B) on the improvement of the properties were evaluated. With the addition of nano clay, the toughness and impact strength was reduced. Thermal destruction of nanoclay in processing temperature led to the decreasing dispersion of clay plates in the matrix and a reduction in the distances of nano clay plates in the composite compared to pure nano clay. XRD and TEM analysis was used to demonstrate the results. By adding 1% of nanoclay to the optimal sample, maximum stiffness, and Impact strength, among other nanocomposites, was achieved.

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Chern Chiet Eng ◽  
Nor Azowa Ibrahim ◽  
Norhazlin Zainuddin ◽  
Hidayah Ariffin ◽  
Wan Md. Zin Wan Yunus

Natural fiber as reinforcement filler in polymer composites is an attractive approach due to being fully biodegradable and cheap. However, incompatibility between hydrophilic natural fiber and hydrophobic polymer matrix restricts the application. The current studies focus on the effects of incorporation of silane treated OPMF into polylactic acid (PLA)/polycaprolactone (PCL)/nanoclay/OPMF hybrid composites. The composites were prepared by melt blending technique and characterize the composites with Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). FTIR spectra indicated that peak shifting occurs when silane treated OPMF was incorporated into hybrid composites. Based on mechanical properties results, incorporation of silane treated OPMF enhances the mechanical properties of unmodified OPMF hybrid composites with the enhancement of flexural and impact strength being 17.60% and 48.43%, respectively, at 10% fiber loading. TGA thermogram shows that incorporation of silane treated OPMF did not show increment in thermal properties of hybrid composites. SEM micrographs revealed that silane treated OPMF hybrid composites show good fiber/matrix adhesion as fiber is still embedded in the matrix and no cavity is present on the surface. Water absorption test shows that addition of less hydrophilic silane treated OPMF successfully reduces the water uptake of hybrid composites.


2013 ◽  
Vol 681 ◽  
pp. 252-255
Author(s):  
Xiu Qi Liu ◽  
He Qin Xing ◽  
Li Li Zhao ◽  
Dan Wang

In our study, a new kind of material was prepared by melt blending with PVC as the matrix and carbon black (CB) as the filler. With the amount of CB increasing, the notched impact strength of composite increased greatly, however the tensile strength declined. When the amount of CB was 30%, the notched impact strength of composite was 9.66 KJ/m2, the tensile strength dropped from 48.3MPa to 33.2MPa. The distribution of CB in the PVC matrix is relatively uniform and no large agglomeration in the PVC matrix.


Author(s):  
Gangadhara H S

Abstract: According to the environmental aspects, the combinations of natural and synthetic fibers has been used for making eco-friendly products. The present investigation has been made develop and characterize a new class of composites with a polymer called epoxy-resin as the matrix and Hemp and synthetic fibers (Carbon, E-glass, Kevlar) are the reinforcing material. These materials are fabricated using hand layup technique to frame a fallowing hybrid composite, 1) Hemp/Carbon/Epoxy 2) Hemp/E-glass/Epoxy 3) Hemp/Kevlar/epoxy composites of 3mm thickness to find the various mechanical properties (wear, hardness and impact strength) of produced samples as per ASTM Standards. For defining relative significance of measured norms pairwise comparison was done. Wear, Hardness and Impact properties are carried out. The effect of fiber loading and length on mechanical properties like wear, hardness and impact strength of composites is studied. In these fallowing conditions shows a better property. The result on this study indicated that Hemp/Kevlar/Epoxy composite shows better impact mechanical properties compare to another two hybrid composites. Hemp/E-Glass/Epoxy composite shows better wear and hardness properties compare to another two hybrid composites. Hemp/Carbon/Epoxy composite shows intermediate properties compare to Hemp/E-Glass/Epoxy and Hemp/Kevlar/Epoxy composite. Keywords: Hemp, Carbon, Glass, Kevlar, Epoxy, Wear, Hardness, Impact test


2017 ◽  
Vol 51 (24) ◽  
pp. 3425-3439 ◽  
Author(s):  
Zhengyang Yu ◽  
Xiaodong Wang ◽  
Dezhen Wu

The present study focuses on the mechanical properties, impact behaviors, and morphology of a new long-fiber-reinforced composite system based on poly(butylene terephthalate) and polyimide fiber prepared by melt pultrusion. Mechanical characterization revealed that the obtained composites achieved significant improvements not only in tensile and flexural strength but also in impact toughness. It is highlighted that the Izod impact strength was improved by a factor of 5 when 12 wt% PI fiber was incorporated into the matrix. Morphological investigation indicated that the fiber pullout was the dominant mechanism for tensile failure, whereas the enhancement of impact toughness was attributed to the energy dissipation by both the fiber pullout and fiber strain. In this case, a simple fiber strain energy model was used to predict the impact strength of this composite system. The theoretical results showed a good fit with the experimental data of impact energy due to the fiber strain energy absorption involved in the major dissipation of impact energy. In addition, the incorporation of polyimide fiber not only enhanced the crystallinity of poly(butylene terephthalate) due to the heterogeneous nucleating effect but also improved the thermal stability of composites by promoting the carbonization of the matrix. As a result of this study, the high-performance composites based on a thermoplastic matrix and an organic reinforcing fiber were created for the engineering and structural applications.


2013 ◽  
Vol 747 ◽  
pp. 355-358 ◽  
Author(s):  
Pornsri Pakeyangkoon ◽  
Benjawan Ploydee

Mechanical properties of wood plastic composite, prepared from acrylate-styrene-acrylonitrile (ASA) and bagasse, were investigated. In this study, 10 to 50 phr of bagasse were used in order to obtain the wood plastic composite with superior mechanical properties. The wood plastic composites in the study were prepared by melt-blending technique. All materials were mixed by using a two-roll-mill, shaped into sheets by a compression molding machine and the specimens were cut with a cutting machine. Youngs modulus, flexural strength, flexural modulus, impact strength and hardness of the wood plastic composites were investigated and found to improve with increasing bagasse content. However, some composite properties, i.e., impact strength, was decreased by adding the bagasse and then become steady when the amount of bagasse added was more than 30 phr. It was concluded that wood plastic composites with the desirable mechanical properties can be formulated using ASA as the matrix polymer and 50 phr of bagasse.


2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
M. P. Luda ◽  
V. Brunella ◽  
D. Guaratto

Three used PP-based car bumpers are characterized by many techniques (fractionation, IR, TGA, DSC, DMTA, and SEM). They show different impact and static and dynamic mechanical properties depending on their composition and morphology. It appears that block copolymer compatibilizers constituted by polyethylene-polypropylene sequences allow a better compatibility between the rubber domains and the PP matrix leading to relatively high impact resistance. Indeed if the ethylene sequences of the copolymer are large enough to crystallize, the decreased mobility of the whole system impairs the impact resistance. In addition, a higher amount of rubber in domains regular in shape and of greater dimension (1–3 μm) promotes a more homogeneous dispersion of external force inside the material, decreasing the risk of fracture. The amount of mineral fillers regulates the elastic modulus (the higher the load, the higher the modulus); however, a fairly good interfacial adhesion is required for satisfactory impact strength. All PP-based bumpers have been mechanically recycled in an internal mixer to redistribute oxidized species and to reestablish phase compatibilization. Recycling improves mechanical properties in slow speed test but fails to increase impact strength particularly in filled bumper, in which the quality of the matrix/filler interphase is hard to improve by simple remixing.


2021 ◽  
pp. 009524432098816
Author(s):  
Sajjad Daneshpayeh ◽  
Faramarz Ashenai Ghasemi ◽  
Ismail Ghasemi

In this research, mechanical properties of poly lactic acid (PLA)-based nanocomposites were investigated. The nanocomposites were fabricated by adding of three types of nano-materials including multi-walled carbon nanotubes (MWCNT), carbon black (CB) nanoparticles and graphene nano-platelets (GnPs) in four levels from 0 to 3 wt.% to PLA matrix by an internal mixer. Tensile and impact tests were performed to obtain the mechanical properties of nanocomposites. Moreover, field-emission scanning electron microscopy (FESEM) was used to observe the state of nano-fillers dispersion. The FESEM images showed that CB nanoparticles and MWCNT are well distributed in the matrix, but that GnPs are agglomerated. The results of the tensile tests showed that the addition of MWCNT and CB nanoparticles increased the tensile strength by 36% and 76% and the elastic modulus by 10% and 68%, respectively. Also, the presence of all three types of carbon fillers at low loading increased the elongation at break of PLA matrix, and this increase was more significant for GnPs by 55% in the 1 wt.% loading. Finally, the PLA polymer become more brittle with the addition of nanotubes and nano-platelets, and its impact strength was reduced. While, the CB nanoparticles increased the absorbing energy and impact strength.


2022 ◽  
Vol 2022 ◽  
pp. 1-9
Author(s):  
R. Rangaraj ◽  
S. Sathish ◽  
T. L. D. Mansadevi ◽  
R. Supriya ◽  
Raviteja Surakasi ◽  
...  

The aim of the present work is to develop novel hybrid composites using areca, kenaf, and snake grass fibers as reinforcement and epoxy as the matrix. The areca, kenaf, and snake grass fibers were extracted from Catechu Linnaeus, Hibiscus cannabinus, and Sansevieria Ehrenbergii plants, respectively, and treated with 5% NaOH to improve the interfacial adhesion between the hydrophilic fiber and the hydrophobic matrix. Hybrid composites were developed by the compression molding technique and formulated based on the weight fraction of fibers. Tensile, flexural, and impact strength and hardness samples were prepared as per ASTM D 3039, ASTM D 790, ASTM D 256, and ASTM D 2240, respectively. The effects of alkaline treatment on developed hybrid composites were investigated. The developed hybrid composites with 20% wt. snake grass and 10% wt. areca fiber present interesting mechanical properties with a tensile strength of 58 MPa, flexural strength of 124 MPa, impact strength of 5.24 kJ/m2, and hardness of 88. The results indicate that maximum mechanical properties were obtained for alkaline-treated fiber composites with 20% wt. snake grass fiber compared to untreated fiber composites owing to better adhesion between the treated fiber and the matrix. The effect of alkaline treatment was analyzed by Fourier transform infrared. The fractured surfaces of tested samples were analyzed by scanning electron microscopy.


2016 ◽  
Vol 36 (2) ◽  
pp. 157-163 ◽  
Author(s):  
Ayyanar Athijayamani ◽  
Balasubramaniam Stalin ◽  
Susaiyappan Sidhardhan ◽  
Azeez Batcha Alavudeen

Abstract The present study describes the preparation of aligned unidirectional bagasse fiber-reinforced vinyl ester (BFRVE) composites and their mechanical properties such as tensile, flexural, shear and impact strength. Composites were prepared by a hand lay-up technique developed in our laboratory with the help of a hot press. Mechanical properties were obtained for different fiber contents by varying the number of layers. The obtained tensile property values were compared with the theoretical results. The results show that the tensile strength increased linearly up to 44 wt% and then dropped. However, the tensile modulus increased linearly from 17 wt% to 60 wt%. In the case of flexural properties, the flexural strength increased up to 53 wt% and started to decrease. However, the flexural modulus also increased linearly up to 60 wt%. The impact strength values were higher than the matrix materials for all the specimens. The short beam shear strength values were also increased up to 53 wt% and then dropped. The modified Bowyer and Bader (MBB) model followed by the Hirsch model shows a very good agreement with experimental results in both tensile strength and modulus.


2010 ◽  
Vol 150-151 ◽  
pp. 379-385
Author(s):  
Qun Lü ◽  
Qing Feng Zhang ◽  
Hai Ke Feng ◽  
Guo Qiao Lai

The wood-plastic composites (WPC) were prepared via compress molding by using the blends of high density polyethylene (HDPE) and modified polyethylene (MAPE) as the matrix and wood flour (WF) as filler. The effect of MAPE content in the matrix on the mechanical properties of the matrix and WPC was investigated. It was shown that the change of MAPE content in the matrix had no influence on the tensile strength of the matrix, but markedly reduced the impact strength of the matrix. Additionally, it had significant influence on the strength of WPC. When the content of wood flour and the content of the matrix remained fixed, with increasing the content of MAPE in the matrix, the tensile strength and the flexural strength of WPC tended to increase rapidly initially and then become steady. Moreover, with the increasing of MAPE concentration, the impact strength of WPC decreased when the low content of wood flour (30%) was filled, but increased at high wood flour loading (70%).


Sign in / Sign up

Export Citation Format

Share Document