Determination of Physicochemical Properties and Emissions for Different Blends of Biodiesel from Watermelon(Citrullus lanatus L.) Seeds and Diesel Fuel

2018 ◽  
Vol 68 (12) ◽  
pp. 2771-2775
Author(s):  
Mihaela Gabriela Dumitru ◽  
Delia Nica Badea ◽  
Dragos Tutunea
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Fossil Fuels ◽  
Citrullus Lanatus ◽  
Methyl Esters ◽  
Oxidation Stability ◽  
Chemical Properties ◽  
Raw Material ◽  
Alternative Source ◽  
Material Sources

Across the world the fossil fuels are depleting and countries are forced to find an alternative source to reduce green house gases and replace petroleum fuels. Depending of the raw material sources, vegetable oils, animal fats or algae, biodiesel offers a solution for a clean-burning diesel fuel. Watermelon (Citrullus lanatus L.) seed were collected and the oil was extracted. The oil was transformed into fatty acid methyl esters through a transesterification process and blended in various proportions with diesel fuel. The physico-chemical properties of fuels were determined. Results obtained showed that the biodiesel has a density (0.870 g/cm3), kinematic viscosity 40�C (3.1 mm2/s), flash point (128�C), saponification index (150 mgKOH/g), iodine index (108 mgI2/100g), peroxide index (3.7 mEqO2/Kg) and oxidation stability (6 hours) in the range of UE specifications. The engine tests were conducted on a Deutz F4L912 diesel engine, 51 kW, 4-stroke, air cooled, direct injection diesel engine. From the test performed was observed that the CO and HC emissions were reduced due to high content of oxygen in biodiesel blends.

scholarly journals ANALYSIS OF THE ECOLOGICAL PARAMETERS OF THE DIESEL ENGINE POWERED WITH BIODIESEL FUEL CONTAINING METHYL ESTERS FROM CAMELINA SATIVA OIL

Transport ◽  
2010 ◽  
Vol 25 (1) ◽  
pp. 22-28 ◽  
Author(s):  
Sergejus Lebedevas ◽  
Galina Lebedeva ◽  
Violeta Makarevičienė ◽  
Irina Kazanceva ◽  
Kiril Kazancev
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Methyl Esters ◽  
Chemical Properties ◽  
Acid Methyl Ester ◽  
Fuel Mixture ◽  
Camelina Sativa ◽  
Biodiesel Fuel ◽  
Load Range ◽  
Acid Methyl

The article explores the possibilities of using fatty acid methyl esters derived from the oil of a new species of oily plant Camelina sativa not demanding on soil. The performed research on the physical and chemical properties of pure methyl esters from Camelina sativa show that biofuels do not meet requirements for the biodiesel fuel standard (LST EN 14214:2009) of a high iodine value and high content of linoleic acid methyl ester, so they must be mixed with methyl esters produced from pork lard the content of which in the mixture must be not less than 32%. This article presents the results of tests on combustion emission obtained when three‐cylinder diesel engine VALMET 320 DMG was fuelled with a mixture containing 30% of this new kind of fuel with fossil diesel fuel comparing with emissions obtained when the engine was fuelled with a fuel mixture containing 30% of conventional biodiesel fuel (rapeseed oil methyl esters) with fossil diesel fuel. The obtained results show that using both types of fuel, no significant differences in CO and NOx concentrations were observed throughout the tested load range. When operating on fuels containing methyl esters from Camelina sativa, HC emissions decreased by 10 to 12% and the smokeness of exhaust gas by 12 to 25%.

Mango (Magnifera indica) seed oil grown in Dilla town as potential raw material for biodiesel production using NaOH- a homogeneous catalyst

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Diesel Engine ◽  
Physicochemical Properties ◽  
Seed Oil ◽  
Methyl Esters ◽  
Pollution Prevention ◽  
Raw Material ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Homogeneous Catalyst ◽  
Minimal Amount

Biodiesel produced by transesterification process from vegetable oils or animal fats is viewed as a promising renewable energy source. Now a day’s diminishing of petroleum reserves in the ground and increasing environmental pollution prevention and regulations have made searching for renewable oxygenated energy sources from biomasses. Biodiesel is non-toxic, renewable, biodegradable, environmentally benign, energy efficient and diesel substituent fuel used in diesel engine which contributes minimal amount of global warming gases such as CO, CO2, SO2, NOX, unburned hydrocarbons, and particulate matters. The chemical composition of the biodiesel was examined by help of GC-MS and five fatty acid methyl esters such as methyl palmitate, methyl stearate, methyl oleate, methyl linoleate and methyl linoleneate were identified. The variables that affect the amount of biodiesel such as methanol/oil molar ratio, mass weight of catalyst and temperature were studied. In addition to this the physicochemical properties of the biodiesel such as (density, kinematic viscosity, iodine value high heating value, flash point, acidic value, saponification value, carbon residue, peroxide value and ester content) were determined and its corresponding values were 87 Kg/m3, 5.63 Mm2/s, 39.56 g I/100g oil, 42.22 MJ/Kg, 132oC, 0.12 mgKOH/g, 209.72 mgKOH/g, 0.04%wt, 12.63 meq/kg, and 92.67 wt% respectively. The results of the present study showed that all physicochemical properties lie within the ASTM and EN biodiesel standards. Therefore, mango seed oil methyl ester could be used as an alternative to diesel engine.

Extraction and Determination of Physico-chemical Properties of Oil from Watermelon Seeds (Citrullus lanatus L) to Use in Internal Combustion Engines

2017 ◽  
Vol 68 (11) ◽  
pp. 2676-2681
Author(s):  
Mihaela Gabriela Dumitru ◽  
Dragos Tutunea
Keyword(s):  
Fatty Acid ◽  
Internal Combustion Engines ◽  
Fossil Fuels ◽  
Citrullus Lanatus ◽  
Combustion Process ◽  
Chemical Properties ◽  
Physico Chemical ◽  
Mean Diameter ◽  
Geometrical Mean ◽  
Reduction Of Nox

The purpose of this work was to investigate the physicochemical properties of watermelon seeds and oil and to find out if this oil is suitable and compatible with diesel engines. The results showed that the watermelon seeds had the maximum length (9.08 mm), width (5.71mm), thickness (2.0 mm), arithmetic mean diameter (5.59 mm), geometrical mean diameter (4.69 mm), sphericity (51.6%), surface area (69.07), volume 0.17 cm3 and moisture content 5.4%. The oil was liquid at room temperature, with a density and refractive index of 0.945 and 1.4731 respectively acidity value (1.9 mgNaOH/g), free fatty acid (0.95 mgNaOH), iodine value (120 mgI2/100g), saponification value (180 mgKOH/g), antiradical activity (46%), peroxide value (7.5 mEqO2/Kg), induction period (6.2 h), fatty acid: palmitic acid (13.1%), stearic acid (9.5 %), oleic acid (15.2 %) and linoleic acid (61.3%). Straight non food vegetable oils can offer a solution to fossil fuels by a cleaner burning with minimal adaptation of the engine. A single cylinder air cooled diesel engine Ruggerini RY 50 was used to measure emissions of various blends of watermelon oil (WO) and diesel fuel (WO10D90, WO20D80, WO30D70 and WO75D25). The physic-chemical properties of the oil influence the combustion process and emissions leading to the reduction of NOX and the increase in CO, CO2 and HC.

scholarly journals RAPE SEED OIL TETRAHYDROFURFURYLESTERS

2015 ◽  
Vol 1 ◽  
pp. 46
Author(s):  
K. Malins ◽  
V. Kampars ◽  
R. Kampare ◽  
T. Rusakova
Keyword(s):  
Rapeseed Oil ◽  
Fossil Fuels ◽  
Raw Materials ◽  
Methyl Esters ◽  
Cetane Number ◽  
Food Prices ◽  
Raw Material ◽  
Biodiesel Production ◽  
Cold Filter Plugging Point ◽  
Mineral Oils

The transesterification of vegetable oil using various kinds of alcohols is a simple and efficient renewable fuel synthesis technique. Products obtained by modifying natural triglycerides in transesterification reaction substitute fossil fuels and mineral oils. Currently the most significant is the biodiesel, a mixture of fatty acid methyl esters, which is obtained in a reaction with methanol, which in turn is obtained from fossil raw materials. In biodiesel production it would be more appropriate to use alcohols which can be obtained from renewable local raw materials. Ethanol rouses interest as a possible reagent, however, its production locally is based on the use of grain and therefore competes with food production so it would implicitly cause increase in food prices. Another raw material option is alcohols that can be obtained from furfurole. Furfurole is obtained in dehydration process from pentose sugars which can be extracted from crop straw, husk and other residues of agricultural production. From furfurole the tetrahydrofurfuryl alcohol (THFA), a raw material for biodiesel, can be produced. By transesterifying rapeseed oil with THFA it would be possible to obtain completely renewable biodiesel with properties very close to diesel [2-4]. With the purpose of developing the synthesis of such fuel, in this work a three-stage synthesis of rapeseed oil tetrahydrofurfurylesters (ROTHFE) in sulphuric acid presence has been performed, achieving product with purity over 98%. The most important qualitative factors of ROTHFE have been determined - cold filter plugging point, cetane number, water content, Iodine value, phosphorus content, density, viscosity and oxidative stability.

scholarly journals An investigation of effect of biodiesel and aviation fuel jeta-1 mixtures performance and emissions on diesel engine

2014 ◽  
Vol 18 (1) ◽  
pp. 239-247 ◽  
Author(s):  
Hasan Yamik
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Chemical Properties ◽  
Engine Performance ◽  
Combustion Efficiency ◽  
Aviation Fuel ◽  
Aviation Industry ◽  
Performance And Emission ◽  
Performance And Emissions ◽  
Biodiesel Fuels

Biodiesel is an alternative fuel for diesel engines which doesn?t contain pollutants and sulfur; on the contrary it contains oxygen. In addition, both physical and chemical properties of sunflower oil methyl ester (SME) are identical to diesel fuel. Conversely, diesel and biodiesel fuels are widely used with some additives to reduce viscosity, increase the amount of cetane, and improve combustion efficiency. This study uses diesel fuel, SME and its mixture with aviation fuel JetA-1 which are widely used in the aviation industry. . Fuel mixtures were used in 1-cylinder, 4-stroke diesel engine under full load and variable engine speeds. In this experiment, engine performance and emission level are investigated. As a conclusion, as the JetA-1 ratio increases in the mixture, lower nitrogen oxide (NOx) emission is measured. Also, specific fuel consumption is lowered.

scholarly journals Eucalyptus Biodiesel as an Alternative to Diesel Fuel: Preparation and Tests on DI Diesel Engine

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Lyes Tarabet ◽  
Khaled Loubar ◽  
Mohand Said Lounici ◽  
Samir Hanchi ◽  
Mohand Tazerout
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Fossil Fuels ◽  
Pressure Rise ◽  
Operating Conditions ◽  
Second Phase ◽  
Oil Consumption ◽  
Unburned Hydrocarbon ◽  
Engine Combustion ◽  
Di Diesel Engine

Nowadays, the increasing oil consumption throughout the world induces crucial economical, security, and environmental problems. As a result, intensive researches are undertaken to find appropriate substitution to fossil fuels. In view of the large amount of eucalyptus trees present in arid areas, we focus in this study on the investigation of using eucalyptus biodiesel as fuel in diesel engine. Eucalyptus oil is converted by transesterification into biodiesel. Eucalyptus biodiesel characterization shows that the physicochemical properties are comparable to those of diesel fuel. In the second phase, a single cylinder air-cooled, DI diesel engine was used to test neat eucalyptus biodiesel and its blends with diesel fuel in various ratios (75, 50, and 25 by v%) at several engine loads. The engine combustion parameters such as peak pressure, rate of pressure rise, and heat release rate are determined. Performances and exhaust emissions are also evaluated at all operating conditions. Results show that neat eucalyptus biodiesel and its blends present significant improvements of carbon monoxide, unburned hydrocarbon, and particulates emissions especially at high loads with equivalent performances to those of diesel fuel. However, the NOx emissions are slightly increased when the biodiesel content is increased in the blend.

Comparison of Performance and Emission Characteristic of Tamanu, Mahua and Pongamia Biodiesel in a Di Diesel Engine

2013 ◽  
Vol 768 ◽  
pp. 218-225 ◽  
Author(s):  
M. Parthasarathy ◽  
J. Isaac Joshua Ramesh Lalvani ◽  
B. Parthiban ◽  
K. Annamalai
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Alternative Fuels ◽  
Fossil Fuels ◽  
Operating Conditions ◽  
Emission Characteristic ◽  
Performance And Emission ◽  
Di Diesel Engine ◽  
Alternative Sources ◽  
Petroleum Reserves

Random extraction and consumption of fossil fuels have leads to a reduction in petroleum reserves. As for as developing countries like India is connected the need to search for alternative fuels is most urgent as India is heavily dependent upon the import of petroleum to meet its demands for automotive and power sectors. This has inspired curiously in alternative sources for petroleum based fuels. An alternative fuel must be economically competitive and environmentally acceptable. India has great potential for production of biofuels like Biodiesel from vegetable seeds. In the quest to find an alternative to the existing diesel and petrol fuels various Biodiesel and alcohol has been tried and tested in the Internal Compression engine. In this direction, an attempt has been made to investigate the performance and emission characteristic of Biodiesels and compare it with diesel. The Biodiesels considered are Tamanu, Mahua and Pongamia were tested with four stroke diesel engine. A drastic improvement in reduction of Hydrocarbon (HC) and Carbon monoxide (CO) were found for Biodiesels at high engine loads. Smoke and Nitrogen oxides (NOx) were slightly higher for Biodiesels. Biodiesels exposed similar combustion stages to diesel fuel. Therefore use of transesterified vegetable oils can be partially substituted for the diesel fuel at most operating conditions in term of the performance parameters and emissions without any engine modification.

Tribological and emission characteristics of indirect ignition diesel engine fuelled with waste edible oil

2016 ◽  
Vol 68 (5) ◽  
pp. 554-560 ◽  
Author(s):  
De-Xing Peng
Keyword(s):  
Economic Growth ◽  
Diesel Engine ◽  
Diesel Fuel ◽  
Fossil Fuels ◽  
Fuel Injection ◽  
Engine Performance ◽  
Vital Role ◽  
Fuel Additive ◽  
Content Type ◽  
Lubricating Property

Purpose Energy is the prime mover of economic growth and is vital to the sustenance of a modern economy. Future economic growth depends heavily on the long-term availability of energy from sources that are affordable, accessible and environmentally friendly. Regulating the sulfur content in diesel fuel is expected to reduce the lubricity of these fuels, which may result in increased wear and damage of fuel injection systems in diesel engines. Design/methodology/approach The tribological properties of the biodiesels as additive in pure petro-diesel are studied by ball-on-ring wear tester to find optimal concentration, and the mechanism of the reduction of wear and friction will be investigated by optical microscopy. Findings Studies have shown that low concentrations of biodiesel blends are more effective as lubricants because of their superior polarity. Using biodiesel as a fuel additive in a pure petroleum diesel fuel improves engine performance and exhaust emissions. The high biodegradability and superior lubricating property of biodiesel when used in compression ignition engines renders it an excellent fuel. Originality/value This detailed experimental investigation confirms that biodiesel can substitute mineral diesel without any modification in the engine. The use of biofuels as diesel engine fuels can play a vital role in helping the developed and developing countries to reduce the environmental impact of fossil fuels.

scholarly journals Study on Particulate Matter of Diesel Engine Using Waste Cooking Oil

2015 ◽  
Vol 773-774 ◽  
pp. 420-424 ◽  
Author(s):  
Nur Fauziah Jaharudin ◽  
Nur Atiqah Ramlan ◽  
Mohd Herzwan Hamzah ◽  
Abdul Adam Abdullah ◽  
Rizalman Mamat
Keyword(s):  
Particulate Matter ◽  
Diesel Engine ◽  
Diesel Fuel ◽  
Alternative Fuels ◽  
Engine Speed ◽  
Direct Injection ◽  
Waste Cooking Oil ◽  
Manufacturing Cost ◽  
Alternative Source ◽  
Cooking Oil

Particulate matter (PM) is one of the major pollutants emitted by diesel engine which have adverse effects on human health. Accordingly, many researches have been done to find alternative fuels that are clean and efficient. Biodiesel is preferred as an alternative source for diesel engine which produces lower PM than diesel fuel. However, the manufacturing cost of biodiesel from vegetable oil is expensive. Therefore, using waste cooking oil (WCO) for biodiesel would be more economical and sustainable solution. The characteristics of direct injection diesel engine in term of the PM have been investigated experimentally in this study. The experiments were conducted using single cylinder diesel engine with different speed (1200 rpm, 1500 rpm, 1800 rpm, 2100 rpm, 2400 rpm) at constant load. PM emission of WCO B100 and diesel fuel was compared and the effect of PM components such as soluble organic fraction (SOF) and soot were studied. The result showed WCO B100 reduces the PM emission at all engine speed. Furthermore, both fuels showed highest reduction of PM concentration at moderate engine speed of 1500 rpm.

Impact of Using Biodiesels of Different Origin and Additives on the Performance of a Stationary Diesel Engine

2000 ◽  
Vol 122 (4) ◽  
pp. 624-631 ◽  
Author(s):  
A. Serdari ◽  
K. Fragioudakis ◽  
S. Kalligeros ◽  
S. Stournas ◽  
E. Lois
Keyword(s):  
Diesel Engine ◽  
Fatty Acid Methyl Esters ◽  
Corn Oil ◽  
Methyl Esters ◽  
Raw Material ◽  
Biodiesel Production ◽  
Exhaust Emission ◽  
Fuel Blends ◽  
Different Types ◽  
Particulate Matter Emissions

With the exception of rape seed oil which is the principal raw material for biodiesel Fatty Acid Methyl Esters, (FAME) production, sunflower oil, corn oil, and olive oil, which are abundant in Southern Europe, along with some wastes, such as used frying oils, appear to be attractive candidates for biodiesel production. In this paper fuel consumption and exhaust emission measurements from a single cylinder, stationary diesel engine are described. The engine was fueled with fuel blends containing four different types of biodiesel, at proportions up to 100 percent; the further impact of the usage of two specific additives was also investigated. The four types of biodiesel appeared to have equal performance and irrespective of the raw material used for their production, their addition to the traditional diesel fuel improved the particulate matter emissions. The results improve further when specific additive combinations are used. [S0742-4795(00)00604-9]

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