Microstructure Evolution of Al/Fe Liquid/Solid Interface

2012 ◽  
Vol 268-270 ◽  
pp. 417-421
Author(s):  
Shu Ying Jiang ◽  
Shi Chun Li
Keyword(s):  
Diffusion Couple ◽  
Microstructure Evolution ◽  
Single Phase ◽  
Solid Phase ◽  
Great Influence ◽  
Diffusion Reaction ◽  
Phase Layer ◽  
Solid Interface ◽  
Solid Diffusion ◽  
Wide Range

The liquid/solid composite technology has wide range of applications in the preparation of Fe-Al composite materials and structures. The diffusion-reaction zone (DRZ) formed in the liquid/solid interface has a great influence on their properties. The Al-Fe diffusion couple was prepared by using the insert technology and treated at 700°C-900°C. The microstructure evolution and growth mechanism of the DRZ in the Al/Fe liquid /solid interface were investigated. The result shows that the microstructure of Al/Fe liquid/solid diffusion couple after heat treatment (HT) is (Al+FeAl3)/FeAl3/Fe2Al5/Fe; Fe2Al5 is the only new phase during the heat preservation process, FeAl3 is formed by desolventizing during the cooling process. The growth of the Fe2Al5 is controlled by the chemical reaction of the Al atoms and Fe atoms before the Fe2Al5 continuous single-phase layer is formed; Once the continuous Fe2Al5 single-phase layer is formed, the growth of the Fe2Al5 mainly depends on the diffusion of Al atoms in the solid phase Fe2Al5 layer, and the reaction occurs in the solid/solid interface of the Fe2Al5 layer and iron. Precipitate is not found in the iron while the needlelike and strip FeAl3 precipitates appear in the aluminum; the density and size of the FeAl3 precipitates decrease gradually from the vicinity of interface to the distant.

scholarly journals Reaction Behavior of Porous TiAl3 Intermetallics Fabricated by Thermal Explosion with Different Particle Sizes

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7417
Author(s):  
Kaiyang Li ◽  
Tiance Zhang ◽  
Yuanzhi Zhu
Keyword(s):  
Particle Size ◽  
Thermal Explosion ◽  
Solid Phase ◽  
Raw Materials ◽  
Diffusion Reaction ◽  
Particle Sizes ◽  
Reaction Behavior ◽  
Liquid Diffusion ◽  
Solid Diffusion ◽  
Solid Liquid

Porous TiAl3 intermetallics were prepared by the thermal explosion (TE) and space holder method with different particle sizes of Ti and Al powders, and their reaction behaviors were investigated. The results showed that with the increase in the particle size of the Ti and Al powders, the interfacial contact between the particles decreased, resulting in low interfacial energy and reaction activity, making the process difficult to initiate. Meanwhile, the heat flow rose from 358.37 J/g to 730.17 J/g and 566.74 J/g due to the extension of the solid–liquid diffusion time. The TiAl3 structures obviously expanded, and the formation of connected pore channels promoted the porosity. Only when the Ti and Al particle sizes were both small did the solid–solid diffusion significantly appear. At the same time, the TE reaction weakened, so the product particles had no time to fully grow. This indicates that the particle size of the raw materials controlled the TE reaction process by changing the solid–liquid diffusion reaction time and the degree of solid-phase diffusion.

Analysis of Aromatic Amines in Industrial Wastewater by Capillary Gas Chromatography-Mass Spectrometry

2000 ◽  
Vol 35 (2) ◽  
pp. 245-262 ◽  
Author(s):  
Francis I. Onuska ◽  
Ken A. Terry ◽  
R. James Maguire
Keyword(s):  
Gas Chromatography ◽  
Aromatic Amines ◽  
Methylene Chloride ◽  
Solid Phase ◽  
Stationary Phases ◽  
Gas Chromatography Mass Spectrometry ◽  
Substituted Anilines ◽  
Environmental Media ◽  
Solid Phase Extraction Cartridge ◽  
Wide Range

Abstract The analysis of aromatic amines, particularly benzidines, at trace levels in environmental media has been difficult because of the lack of suitable deactivated capillary column stationary phases for gas chromatography. This report describes the use of an improved type of column as well as a method for the analysis of anilines and benzidines in water, wastewater and sewage samples. Extraction procedures are applicable to a wide range of compounds that are effectively partitioned from an aqueous matrix into methylene chloride, or onto a solid-phase extraction cartridge. The extracted analytes are also amenable to separation on a capillary gas chromatographic column and transferable to the mass spectrometer. These contaminants are converted to their N-trifluoroacetyl derivatives. Aniline and some substituted anilines, and 3,3’-dichlorobenzidine and benzidine were determined in 24-h composite industrial water, wastewater, primary sludge and final effluent samples at concentrations from 0.03 up to 2760 µg/L.

Recent Application of Polystyrene-supported Triphenylphosphine in Solid-Phase Organic Synthesis

2019 ◽  
Vol 23 (6) ◽  
pp. 643-678
Author(s):  
Lalthazuala Rokhum ◽  
Ghanashyam Bez
Keyword(s):  
Organic Synthesis ◽  
Combinatorial Chemistry ◽  
Solid Phase ◽  
Recent Application ◽  
Organic Transformations ◽  
Solid Phase Organic Synthesis ◽  
Wide Range ◽  
Fast Development ◽  
Polymer Supported

Recent years have witnessed a fast development of solid phase synthetic pathways, a variety of solid-supported reagent and its applications in diverse synthetic strategies and pharmaceutical applicability’s. Polymer-supported triphenylphosphine is getting a lot of applications owing to the speed and simplicity in the process. Furthermore, ease of recyclability and reuse of polymer-supported triphenylphosphine added its advantages. This review covers a wide range of useful organic transformations which are accomplished using cross-linked polystyrene-supported triphenylphosphine with the aim of giving renewed interest in the field of organic and medicinal-combinatorial chemistry.

scholarly journals Recent Developments in the Determination of Biomarkers of Tobacco Smoke Exposure in Biological Specimens: A Review

2021 ◽  
Vol 18 (4) ◽  
pp. 1768
Author(s):  
Hernâni Marques ◽  
Pedro Cruz-Vicente ◽  
Tiago Rosado ◽  
Mário Barroso ◽  
Luís A. Passarinha ◽  
...  
Keyword(s):  
Tobacco Smoke ◽  
Solid Phase ◽  
Smoke Exposure ◽  
Tobacco Smoke Exposure ◽  
World Health ◽  
Second Hand Smoke ◽  
Tobacco Exposure ◽  
Wide Range ◽  
Recent Developments

Environmental tobacco smoke exposure (ETS) and smoking have been described as the most prevalent factors in the development of certain diseases worldwide. According to the World Health Organization, more than 8 million people die every year due to exposure to tobacco, around 7 million due to direct ETS and the remaining due to exposure to second-hand smoke. Both active and second-hand exposure can be measured and controlled using specific biomarkers of tobacco and its derivatives, allowing the development of more efficient public health policies. Exposure to these compounds can be measured using different methods (involving for instance liquid- or gas-chromatographic procedures) in a wide range of biological specimens to estimate the type and degree of tobacco exposure. In recent years, a lot of research has been carried out using different extraction methods and different analytical equipment; this way, liquid–liquid extraction, solid-phase extraction or even miniaturized procedures have been used, followed by chromatographic analysis coupled mainly to mass spectrometric detection. Through this type of methodologies, second-hand smokers can be distinguished from active smokers, and this is also valid for e-cigarettes and vapers, among others, using their specific biomarkers. This review will focus on recent developments in the determination of tobacco smoke biomarkers, including nicotine and other tobacco alkaloids, specific nitrosamines, polycyclic aromatic hydrocarbons, etc. The methods for their detection will be discussed in detail, as well as the potential use of threshold values to distinguish between types of exposure.

Solid Phase Synthesis and Sintering Properties of Yttrium Iron Garnet

2008 ◽  
Vol 368-372 ◽  
pp. 588-590 ◽  
Author(s):  
Ming Hao Fang ◽  
Jun Tong Huang ◽  
Zhao Hui Huang ◽  
Yan Gai Liu ◽  
Bin Jiang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Single Phase ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Volume Density ◽  
Phase Synthesis ◽  
Fe2o3 Content ◽  
Sintering Properties ◽  
Iron Garnet

Single phase YIG powders were synthesized successfully using Fe2O3 and Y2O3 as starting materials by solid state reaction, and YIG ceramics were prepared by pressureless sintering. The influence of synthesizing temperature and Fe2O3 content on the final production were studied The effect of Fe2O3 content on volume density and microstructure of the sintered YIG was also investigated. The results showed that single phase YIG powders were synthesized by solid state reaction at 1400°C for 3h. When Fe2O3 content was excessive 3 wt%, YIG ceramics with a density of 5.294g·cm-3 was fabricated by sintering at 1480°C for 2.5h.

scholarly journals A high-throughput and sensitive methodology for the quantification of urinary 8-hydroxy-2′-deoxyguanosine: measurement with gas chromatography-mass spectrometry after single solid-phase extraction

2004 ◽  
Vol 380 (2) ◽  
pp. 541-548 ◽  
Author(s):  
Hai-Shu LIN ◽  
Andrew M. JENNER ◽  
Choon Nam ONG ◽  
Shan Hong HUANG ◽  
Matthew WHITEMAN ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Solid Phase Extraction ◽  
Healthy Subjects ◽  
Solid Phase ◽  
Large Population ◽  
Urine Samples ◽  
Gas Chromatography Mass Spectrometry ◽  
Phase Extraction ◽  
Freeze Dried ◽  
Wide Range

8-Hydroxy-2´-deoxyguanosine (8OHdG) is a widely used biomarker for the measurement of endogenous oxidative DNA damage. A sensitive method for the quantification of 8OHdG in urine by single solid-phase extraction and GC-MS (gas chromatography with MS detection) using selective ion monitoring is described in the present study. After solid-phase extraction, samples are freeze-dried, derivatized by trimethylsilylation and analysed by GC-MS. The urinary 8OHdG was quantified using heavy isotope dilution with [18O]8OHdG. The recovery of 8OHdG after the solid-phase extraction ranged from 70 to 80% for a wide range of urinary 8OHdG levels. Using 1 ml of urine, the limit of quantification was >2.5 nM (2.5 pmol/ml) and the calibration curve was linear in the range 2.5–200 nM. This method was applied to measure 8OHdG in urine samples from 12 healthy subjects. The intra- and inter-day variations were <9%. Urinary 8OHdG levels in spot urine samples from four healthy subjects were also measured for 1 week and, again, the variation was small. The presence of H2O2 in urine did not cause artifactual formation of 8OHdG. Since this assay is simple, rapid, sensitive and reproducible, it seems suitable to be used as a routine methodology for the measurement of urinary excretion of 8OHdG in large population studies.

Simulation of Fabrication for Al2O3 Ceramic Tool Materials

2012 ◽  
Vol 500 ◽  
pp. 537-543 ◽  
Author(s):  
Bin Fang ◽  
Chuan Zhen Huang ◽  
Hong Tao Zhu ◽  
Chong Hai Xu
Keyword(s):  
Grain Size ◽  
Monte Carlo ◽  
Microstructure Evolution ◽  
Potts Model ◽  
Single Phase ◽  
Ceramic Tool ◽  
Tool Materials ◽  
Fabrication Parameters

The new Monte Carlo Potts model that couples with fabrication parameters and considers pores and additives has been developed in order to simulate the fabrication of single-phase ceramics tool materials. The microstructure evolution for single-phase Al2O3 ceramic tool materials is simulated with the different technology parameters. At the same time, the single-phase Al2O3 ceramic tool materials are fabricated with the corresponding technology parameters. The errors of grain size between the simulated and the experimental is 12.1 and18.2%.

Residual shear strength of fine-grained soils and soil–solid interfaces at low effective normal stresses

2015 ◽  
Vol 52 (2) ◽  
pp. 198-210 ◽  
Author(s):  
Hisham T. Eid ◽  
Ruslan S. Amarasinghe ◽  
Khaled H. Rabie ◽  
Dharma Wijewickreme
Keyword(s):  
Shear Strength ◽  
Large Strain ◽  
Laboratory Research ◽  
Normal Stresses ◽  
Interface Shear ◽  
Residual Shear Strength ◽  
Fine Grained ◽  
Solid Interface ◽  
Wide Range ◽  
Shear Area

A laboratory research program was undertaken to study the large-strain shear strength characteristics of fine-grained soils under low effective normal stresses (∼3–7 kPa). Soils that cover a wide range of plasticity and composition were utilized in the program. The interface shear strength of these soils against a number of solid surfaces having different roughness was also investigated at similar low effective normal stress levels. The findings contribute to advancing the knowledge of the parameters needed for the design of pipelines placed on sea beds and the stability analysis of shallow soil slopes. A Bromhead-type torsional ring-shear apparatus was modified to suit measuring soil–soil and soil–solid interface residual shear strengths at the low effective normal stresses. In consideration of increasing the accuracy of assessment and depicting the full-scale field behavior, the interface residual shear strengths were also measured using a macroscale interface direct shear device with a plan interface shear area of ∼3.0 m2. Correlations are developed to estimate the soil–soil and soil–solid interface residual shear strengths at low effective normal stresses. The correlations are compared with soil–soil and soil–solid interface drained residual shear strengths and correlations presented in the literature.

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