The Influence of Zinc on the Hydration and Compressive Strength of Portland Cement

2014 ◽  
Vol 1000 ◽  
pp. 43-46
Author(s):  
Iva Kolářová ◽  
Pavel Šiler ◽  
František Šoukal

The aim of this work was to investigate the effect of addition of elements present in secondary raw materials on the hydration and compressive strength of Portland cement. Ordinary Portland cement (OPC) has been used to solidify hazardous waste for about 25 years and the effect of waste components on the hydraulic activity is an interesting object for the research. In this study Zn nitrate, chloride and oxide were added to Portland cement. The concentrations of 0.1 and 1.0 weight percent of zinc in cement were tested. After 1, 7 and 28 days the compressive strength was reduced or similar by the addition of zinc in comparison with pure cement. This difference is probably due to a delay in tricalcium silicate hydration as shown by isothermal calorimetry.

2013 ◽  
Vol 327 ◽  
pp. 40-43
Author(s):  
Xiao Long Li ◽  
Guo Zhong Li

The ordinary portland cement was used to prepare foamed cement insulation materials by physical foaming method. The influence of different process of fiber added to the foamed cement insulation materials on its performance was studied and the optimum mix ratio of raw materials was determined. The results showed that the glass fire could be evenly dispersed in the slurry by dry adding technology and got better enhanced effect. When the dosage of glass fire was 0.9%, the performance of the foamed cement material as follows: dry density of 318 kg/m3, 3d flexural strength of 0.61MPa, 3d compressive strength of 1.05MPa, thermal conductivity of 0.065W/(m·k). The reinforce mechanism of glass fire was explored.


2021 ◽  
Vol 904 ◽  
pp. 435-440
Author(s):  
Thunthanut Inyai ◽  
Phongthorn Julphunthong ◽  
Panuwat Joyklad

The present study evaluated the engineering properties and microstructure of an alternative binder composed of calcium carbide residue and silica fume. The cementitious mechanisms of this alternative binder based on the pozzolanic reaction in raw materials. The ratio of calcium carbide residue and silica fume was decided based on the chemical composition of raw materials and their chemical reaction. The calcium carbide residue-silica fume mortar was prepared and tested for its compressive strength at several curing periods, with results then compared to conventional mortar made with ordinary Portland cement. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to investigate the microstructure of hardened mortars. The test results suggest that the compressive strength of calcium carbide residue-silica fume mortar continuously developed throughout the curing period. The relative compressive strength of calcium carbide residue-silica fume mortar reached 72.78% of the ordinary Portland cement mortar strength at 28 days curing age.


2016 ◽  
Vol 865 ◽  
pp. 67-71 ◽  
Author(s):  
Olesia Mikhailova ◽  
Pavel Rovnaník

Geopolymers are presented in many studies as binders alternative to ordinary Portland cement. Several inorganic materials have been used as raw materials for the production of geopolymers. One of them is metakaolin which is produced by dehydroxylation of kaolin. Metakaolin has a much larger surface area than cement, resulting in an increase in water demand to maintain workability. Polymer admixtures may contribute to reduction of this demand. However, another problem should be considered: plasticizers which improve rheological properties in cement technology are not effective for geopolymers. The aim of this study was to analyze the effect of different polymer admixtures on the compressive and flexural strength, pore size distribution and microstructure of alkali-activated metakaolin material. The results revealed that a maximum compressive strength of 18.6 MPa was achieved by adding 1.5% of VINNAPAS 7016 F, and a maximum flexural strength of 2.2 MPa when adding 0.5 or 1% of the same polymer admixture.


2012 ◽  
Vol 476-478 ◽  
pp. 1585-1588
Author(s):  
Hong Pan ◽  
Guo Zhong Li

The comprehensively modified effect of cement, VAE emulsion and self-made acrylic varnish on mechanical and water-resistant properties of gypsum sample was investigated and microstructure of gypsum sample was analyzed. Experimental results exhibit that absolutely dry flexural strength, absolutely dry compressive strength, water absorption and softening coefficient of gypsum specimen with admixture of 10% ordinary Portland cement and 6% VAE emulsion and acrylic varnish coated on its surface can respectively reach to 5.11MPa , 10.49 MPa, 8.32% and 0.63, respectively.


Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 1015 ◽  
Author(s):  
Emy Aizat Azimi ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Petrica Vizureanu ◽  
Mohd Arif Anuar Mohd Salleh ◽  
Andrei Victor Sandu ◽  
...  

A geopolymer has been reckoned as a rising technology with huge potential for application across the globe. Dolomite refers to a material that can be used raw in producing geopolymers. Nevertheless, dolomite has slow strength development due to its low reactivity as a geopolymer. In this study, dolomite/fly ash (DFA) geopolymer composites were produced with dolomite, fly ash, sodium hydroxide, and liquid sodium silicate. A compression test was carried out on DFA geopolymers to determine the strength of the composite, while a synchrotron Micro-Xray Fluorescence (Micro-XRF) test was performed to assess the elemental distribution in the geopolymer composite. The temperature applied in this study generated promising properties of DFA geopolymers, especially in strength, which displayed increments up to 74.48 MPa as the optimum value. Heat seemed to enhance the strength development of DFA geopolymer composites. The elemental distribution analysis revealed exceptional outcomes for the composites, particularly exposure up to 400 °C, which signified the homogeneity of the DFA composites. Temperatures exceeding 400 °C accelerated the strength development, thus increasing the strength of the DFA composites. This appears to be unique because the strength of ordinary Portland Cement (OPC) and other geopolymers composed of other raw materials is typically either maintained or decreases due to increased heat.


2010 ◽  
Vol 93 (1) ◽  
pp. 279-287 ◽  
Author(s):  
Linghong Zhang ◽  
Lionel J. J. Catalan ◽  
Raymond J. Balec ◽  
Andrew C. Larsen ◽  
Hassan Haji Esmaeili ◽  
...  

2013 ◽  
Vol 6 (1) ◽  
pp. 50-61
Author(s):  
Amer M. Ibrahem ◽  
Shakir A. Al-Mishhadani ◽  
Zeinab H.Naji

This investigation aimed to study the effect of nano metakaolin ( NMK ) on some properties (compressive strength ,splitting tensile strength & water absorption ) of concrete. The nano metakaolin (NMK) was prepared by thermal activation of kaolin clay for 2 hours at 750 Ċ. The cement used in this investigation consists of ordinary Portland cement (OPC). The OPC was partially substituted by NMK of ( 3, 5 & 10%) by weight of cement. The C45 concrete was prepared , using water/cement ratio ( W/c) of (0.53) .The Water absorption was tested at 28 days while the tests (compressive strength ,splitting tensile strength) were tested at ages of (7, 28, 60,& 90) days . The compressive strength and splitting tensile strength of concrete with NMK were higher than that of reference concrete with the same W/c ratio.The improvement in the compressive strength when using NMK was (42.2, 55.8 , 63.1% ) at age 28 days for ( 3%, 5%, &10% ) replacement of NMK respectively whereas the improvement in the splitting tensile strength was (0% , 36% & 46.8 %) at age of 28 days when using (3%, 5%, &10% ) NMK respectively. The improvement in the water absorption was (16.6%, 21.79%, &25.6 ) when using (3, 5, &10% )NMK.


Author(s):  
Safiki Ainomugisha ◽  
Bisaso Edwin ◽  
Bazairwe Annet

Concrete has been the world’s most consumed construction material, with over 10 billion tons of concrete annually. This is mainly due to its excellent mechanical and durability properties plus high mouldability. However, one of its major constituents; Ordinary Portland Cement is reported to be expensive and unaffordable by most low-income earners. Its production contributes about 5%–8% of global CO2 greenhouse emissions. This is most likely to increase exponentially with the demand of Ordinary Portland Cement estimated to rise by 200%, reaching 6000 million tons/year by 2050.  Therefore, different countries are aiming at finding alternative sustainable construction materials that are more affordable and offer greener options reducing reliance on non-renewable sources. Therefore, this study aimed at assessing the possibility of utilizing sugarcane bagasse ash from co-generation in sugar factories as supplementary material in concrete. Physical and chemical properties of this sugarcane bagasse ash were obtained plus physical and mechanical properties of fresh and hardened concrete made with partial replacement of Ordinary Portland Cement. Cost-benefit analysis of concrete was also assessed. The study was carried using 63 concrete cubes of size 150cm3 with water absorption studied as per BS 1881-122; slump test to BS 1881-102; and compressive strength and density of concrete according to BS 1881-116. The cement binder was replaced with sugarcane bagasse ash 0%, 5%, 10%, 15%, 20%, 25% and 30% by proportion of weight. Results showed the bulk density of sugarcane bagasse ash at 474.33kg/m3, the specific gravity of 1.81, and 65% of bagasse ash has a particle size of less than 0.28mm. Chemically, sugarcane bagasse ash contained SiO2, Fe2O3, and Al2O3 at 63.59%, 3.39%, and 5.66% respectively. A 10% replacement of cement gave optimum compressive strength of 26.17MPa. This 10% replacement demonstrated a cost saving of 5.65% compared with conventional concrete. 


2021 ◽  
Vol 4 (2) ◽  
pp. 12-18
Author(s):  
D.A. Tolypin ◽  
N. Tolypina

the article proposes a rational method for processing 3D printing concrete scrap using vibration equipment, which allows obtaining a multicomponent building material with minimal electricity consumption. As a crite-rion for the degree of grinding of concrete scrap, it is proposed to use the specific surface area of the finely dispersed part of concrete scrap, which should correspond to 400-500 m2/kg. The possibility of reusing the resulting product instead of the traditional fine aggregate of quartz sand is shown. It was found that the con-crete scrap without the addition of Portland cement hardens, reaching up to 48% of the compressive strength of the control samples by 28 days. When 10% of the binder CEM I 42.5 N was added to the concrete scrap processing product, the compressive strength of fine-grained concrete increased by 106.6%, and 20% of Portland cement - by 112.2 %, compared to the strength of control samples of a similar composition on tra-ditional quartz sand after 28 days of hardening. It is noted that this is primarily due to the weak contact zone of quartz sand and the cement matrix of concrete. The use of the product of processing concrete scrap al-lows obtaining building composites based on it with the complete exclusion of natural raw materials


Sign in / Sign up

Export Citation Format

Share Document