Development of an Alternative Cementitious Materials Based on Calcium Carbide Residue and Silica Fume

2021 ◽  
Vol 904 ◽  
pp. 435-440
Author(s):  
Thunthanut Inyai ◽  
Phongthorn Julphunthong ◽  
Panuwat Joyklad
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Silica Fume ◽  
Ordinary Portland Cement ◽  
Raw Materials ◽  
Calcium Carbide ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Engineering Properties ◽  
Calcium Carbide Residue

The present study evaluated the engineering properties and microstructure of an alternative binder composed of calcium carbide residue and silica fume. The cementitious mechanisms of this alternative binder based on the pozzolanic reaction in raw materials. The ratio of calcium carbide residue and silica fume was decided based on the chemical composition of raw materials and their chemical reaction. The calcium carbide residue-silica fume mortar was prepared and tested for its compressive strength at several curing periods, with results then compared to conventional mortar made with ordinary Portland cement. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to investigate the microstructure of hardened mortars. The test results suggest that the compressive strength of calcium carbide residue-silica fume mortar continuously developed throughout the curing period. The relative compressive strength of calcium carbide residue-silica fume mortar reached 72.78% of the ordinary Portland cement mortar strength at 28 days curing age.

Strength Development and Microstructural Investigation of Calcium Carbide Residue and Fly Ash Prepared with Optimized Alternative Green Binders

2021 ◽  
Vol 904 ◽  
pp. 429-434
Author(s):  
Papantasorn Manprom ◽  
Phongthorn Julphunthong ◽  
Pithiwat Tiantong ◽  
Tawat Suriwong
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Raw Materials ◽  
Extended Period ◽  
Calcium Carbide ◽  
Pozzolanic Reaction ◽  
Strength Development ◽  
Chemical Compositions ◽  
Microstructural Investigation ◽  
Calcium Carbide Residue

The development of new environmentally friendly binder from calcium carbide residue and fly ash wastes were investigated in this study. The key point of this work is difference to several previous investigations in that the optimized mixture proportion of the raw materials were calculated based on their chemical composition and their reaction. The compressive strength development over the curing age was also compared with reference mortar created with OPC binder. Mortar cubes were cast from the mix containing the calcium carbide residue and fly ash, at the optimized ratio. The compressive strength of the mortar was then monitored over an extended period: at 56 days it was 10.66 MPa, which is approximately 47% of the reference mortar. The morphologies and chemical compositions of the developed mortar showed the presence of spherically shaped of unreacted fly ash powder particles embedded in a cement C–S–H gel resulting from the pozzolanic reaction of raw materials.

scholarly journals Study of Hydration and Microstructure of Mortar Containing Coral Sand Powder Blended with SCMs

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4248
Author(s):  
Xingxing Li ◽  
Ying Ma ◽  
Xiaodong Shen ◽  
Ya Zhong ◽  
Yuwei Li
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Silica Fume ◽  
Dilution Effect ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Limestone Powder ◽  
Chemical Effect ◽  
Granulated Blast Furnace Slag ◽  
Coral Sand

The utilization of coral waste is an economical way of using concrete in coastal and offshore constructions. Coral waste with more than 96% CaCO3 can be ground to fines and combined with supplementary cementitious materials (SCMs) such as fly ash, silica fume, granulated blast furnace slag in replacing Portland cement to promote the properties of cement concrete. The effects of coral sand powder (CSP) compared to limestone powder (LSP) blended with SCMs on hydration and microstructure of mortar were investigated. The result shows CSP has higher activity than LSP when participating in the chemical reaction. The chemical effect among CSP, SCMs, and ordinary Portland cement (OPC) results in the appearance of the third hydration peak, facilitating the production of carboaluminate. CSP-SCMs mortar has smaller interconnected pores on account of the porous character of CSP as well as the filler and chemical effect. The dilution effect of CSP leads to the reduction of compressive strength of OPC-CSP and OPC-CSP-SCMs mortars. The synergic effects of CSP with slag and silica fume facilitate the development of compressive strength and lead to a compacted isolation and transfer zone (ITZ) in mortar.

Study on the Preparation and Properties of Fiber Reinforced Foamed Cement Material

2013 ◽  
Vol 327 ◽  
pp. 40-43
Author(s):  
Xiao Long Li ◽  
Guo Zhong Li
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Raw Materials ◽  
Dry Density ◽  
Fiber Reinforced ◽  
Cement Material ◽  
Insulation Materials

The ordinary portland cement was used to prepare foamed cement insulation materials by physical foaming method. The influence of different process of fiber added to the foamed cement insulation materials on its performance was studied and the optimum mix ratio of raw materials was determined. The results showed that the glass fire could be evenly dispersed in the slurry by dry adding technology and got better enhanced effect. When the dosage of glass fire was 0.9%, the performance of the foamed cement material as follows: dry density of 318 kg/m3, 3d flexural strength of 0.61MPa, 3d compressive strength of 1.05MPa, thermal conductivity of 0.065W/(m·k). The reinforce mechanism of glass fire was explored.

Effect of Alkaline Solution to Fly Ash Ratio on Geopolymer Mortar Properties

2017 ◽  
Vol 733 ◽  
pp. 85-88 ◽  
Author(s):  
Amir Fauzi ◽  
Mohd Fadhil Nuruddin ◽  
Ahmad B. Malkawi ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Bashar S. Mohammed
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Alkaline Solution ◽  
Similar Pattern ◽  
Ordinary Portland Cement ◽  
Setting Time ◽  
Pozzolanic Reaction

Geopolymer system is new binding materials in concrete industry that is produced by the alkaline solution and materials rich in aluminosilicate such as fly ash. The effect of the alkaline solution to fly ash ratios of 0.3, 0.4 and 0.5 on mortar geopolymer properties was an issue in this study. The results showed that the higher alkaline solution to fly ash ratio improves the workability and brings a longer setting time, whereas the lower alkaline solution to fly ash ratio gains the significant compressive strength. It was a similar pattern with conventional mortar used ordinary Portland cement, which the compressive strength at 7 days was 85%-90% for 28 days compressive strength, whereas conventional mortar is only 65%-75%. This was due to the higher reactivity in geopolymer system that was faster than the pozzolanic reaction.

scholarly journals Composition and selected properties of low pH mortars and concretes for radioactive waste repositories

2020 ◽  
Vol 322 ◽  
pp. 01033
Author(s):  
An Cheng ◽  
Wei-Ting Lin ◽  
Sao-Jeng Chao ◽  
Hui-Mi Hsu
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Silica Fume ◽  
Spent Nuclear Fuel ◽  
Cementitious Materials ◽  
Low Ph ◽  
Engineering Properties ◽  
Filling Materials ◽  
Radioactive Waste Repositories ◽  
Waste Repositories

Conventional cementitious materials as tunnel supporting materials are utilised in the construction of the final repository for spent nuclear fuel. However, the use of cementitious material releases alkaline ions from pH12 to pH13 plumed into groundwater. Such a high pH is detrimental to the performance of the bentonite functioning, which may possibly enhance the dissolution and alteration of the fracture buffer and filling materials. Instead, low-pH cementitious materials are being developed for use in geological repositories. This study is aimed at evaluating the usability of low-pH cementitious materials containing 40% silica fume or composites blended with 20% silica fume and 40% fly ash. Engineering properties were analysed and verified through experimental research using the flow, compressive strength, pH measurement and hydraulic conductivity. Test results show that the replacement level with 40% of silica fume or 20% of silica fume and 40% of fly ash was suitable for the mixture of low-pH cementitious. Compared to the compressive strength and water permeability of ordinary cementitious, those of low-pH cementitious enhanced better engineered performances at the age of 91 days. The information is contributed us to establish the long-term durability and environmental requirements of disposal repositories in Taiwan.

scholarly journals Strength development of cement-treated sand using different cement types cured at different temperatures

2018 ◽  
Vol 195 ◽  
pp. 01006
Author(s):  
Lanh Si Ho ◽  
Kenichiro Nakarai ◽  
Kenta Eguchi ◽  
Takashi Sasaki ◽  
Minoru Morioka
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cement Content ◽  
Bound Water ◽  
Pozzolanic Reaction ◽  
Strength Development ◽  
Different Temperatures ◽  
Early Strength

This study aimed to investigate the strength development of cement-treated sand using different cement types: ordinary Portland cement (OPC), high early strength Portland cement (HPC), and moderate heat Portland cement (MPC) cured at different temperatures. The cementtreated sand specimens were prepared with 8% of cement content and cured under sealed conditions at 20οC and 40οC, and mortar specimens were also prepared for reference. The results showed that the compressive strength of cement-treated sand increased in order of MPC, OPC, and HPC under high curing temperatures. It was interesting that the compressive strength of the specimens using HPC was much larger than that of the specimen using OPC and MPC under 20οC due to the larger amount of chemically bound water. Additionally, it was revealed that under high curing temperatures, the pozzolanic reaction was accelerated in the cement-treated sand; this may be caused by the high proportions of sand in the mixtures.

scholarly journals Calcium Carbide Residue and Rice Husk Ash for improving the Compressive Strength of Compressed Earth Blocks

MRS Advances ◽  
2018 ◽  
Vol 3 (34-35) ◽  
pp. 2009-2014 ◽  
Author(s):  
Philbert Nshimiyimana ◽  
David Miraucourt ◽  
Adamah Messan ◽  
Luc Courard
Keyword(s):  
Compressive Strength ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Calcium Carbide ◽  
Pozzolanic Reaction ◽  
Compressed Earth Blocks ◽  
Calcium Carbide Residue ◽  
Earth Blocks ◽  
Wall Construction ◽  
By Products

ABSTRACTEarth stabilization, using two by-products available in Burkina Faso: Calcium Carbide Residue (CCR) and Rice Husk Ash (RHA), improved the performance of compressed earth blocks (CEBs). The effect of adding CCR or CCR: RHA (in various ratios) to the clayey earth was investigated. CEBs were molded by manually compressing moisturized mixtures of earthen materials and 0-15 % CCR or CCR: RHA (various ratios) with respect to the weight of earthen material. The results showed that, with 15 % CCR: RHA in 7: 3 ratio, the compressive strength of CEBs (6.6 MPa) is three times that of the CEBs containing 15 % CCR alone (2.2 MPa). This improvement was related to the pozzolanic reaction between CCR, clay and RHA. These CEBs comply with the requirement for wall construction of two-storey housing.

The Influence of Zinc on the Hydration and Compressive Strength of Portland Cement

2014 ◽  
Vol 1000 ◽  
pp. 43-46
Author(s):  
Iva Kolářová ◽  
Pavel Šiler ◽  
František Šoukal
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Hazardous Waste ◽  
Ordinary Portland Cement ◽  
Raw Materials ◽  
Isothermal Calorimetry ◽  
Weight Percent ◽  
Tricalcium Silicate ◽  
Hydraulic Activity ◽  
Interesting Object

The aim of this work was to investigate the effect of addition of elements present in secondary raw materials on the hydration and compressive strength of Portland cement. Ordinary Portland cement (OPC) has been used to solidify hazardous waste for about 25 years and the effect of waste components on the hydraulic activity is an interesting object for the research. In this study Zn nitrate, chloride and oxide were added to Portland cement. The concentrations of 0.1 and 1.0 weight percent of zinc in cement were tested. After 1, 7 and 28 days the compressive strength was reduced or similar by the addition of zinc in comparison with pure cement. This difference is probably due to a delay in tricalcium silicate hydration as shown by isothermal calorimetry.

scholarly journals Influence of quartz powder and silica fume on the performance of Portland cement

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Ludmila Rodrigues Costa Tavares ◽  
Joaquim Francisco Tavares Junior ◽  
Leonardo Martins Costa ◽  
Augusto Cesar da Silva Bezerra ◽  
Paulo Roberto Cetlin ◽  
...  
Keyword(s):  
Portland Cement ◽  
Silica Fume ◽  
Electrical Resistance ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Heat Of Hydration ◽  
Supplementary Cementitious Materials ◽  
Cementitious Composites ◽  
Quartz Powder ◽  
Hydration Properties

AbstractSupplementary cementitious materials interact chemically and physically with cement, influencing the formation of hydrate compounds. Many authors have analyzed the filler and pozzolanic effect. However, few studies have explored the influence of these effects on hydration, properties in the fresh and hardened states, and durability parameters of cementitious composites separately. This study investigates the influence of the replacement of 20% of Portland cement for silica fume (SF) or a 20-µm medium diameter quartz powder (QP) on the properties of cementitious composites from the first hours of hydration to a few months of curing. The results indicate that SF is pozzolanic and that QP has no pozzolanic activity. The use of SF and QP reduces the released energy at early times to the control paste, indicating that these materials reduce the heat of hydration. The microstructure with fewer pores of SF compounds indicates that the pozzolanic reaction reduced pore size and binding capability, resulting in equivalent mechanical properties, reduced permeability and increased electrical resistance of the composites. SF and QP increase the carbonation depth of the composites. SF and QP composites are efficient in the inhibition of the alkali-aggregate reaction. The results indicate that, unlike the filler effect, the occurrence of pozzolanic reaction strongly influences electrical resistance, reducing the risk of corrosion of the reinforcement inserted in the concrete.

Prediction Model and Relationship of Compressive and Tensile Strengths for High Performance Concrete

2013 ◽  
Vol 377 ◽  
pp. 92-98
Author(s):  
Mohammad Iqbal Khan
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Portland Cement ◽  
Silica Fume ◽  
High Performance ◽  
Ordinary Portland Cement ◽  
Prediction Models ◽  
High Performance Concrete ◽  
Analytical Prediction ◽  
Fuel Ash

Analytical models for compressive strength and tensile strength of high performance concrete are presented. High performance concrete was developed using binary and ternary blending combinations consisting of ordinary Portland cement, pulverised fuel ash and silica fume. Pulverised fuel ash and silica fume were incorporated as partial cement replacements for the preparation of various combinations of blended systems. Compressive strength and tensile strength of concrete containing ordinary Portland cement, pulverised fuel ash and silica fume at various ages are reported. Based on the experimentally obtained results, analytical prediction models were developed. These models enabled the establishment of isoresponse contours showing the interactive influence between the various parameters investigated.

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