Effect of Kaolin on the Properties of Flue Gas Desulphurization Gypsum-Steel Slag Cementitious Materials

2011 ◽  
Vol 306-307 ◽  
pp. 1553-1556
Author(s):  
Lei Zhang ◽  
Zhi Wang ◽  
Li Ying Fan ◽  
Guo Pu Shi

The effects of kaolin on the properties of flue gas desulphurization gypsum-based steel slag composites were analyzed in this article and the influence rules of setting time, final setting time on the flexural strength and compressive strength of cementitious composites were also discussed. The micro-morphology of the composite was observed by scanning electron microscope. At the same time, the excitation mechanism of kaolin on gas desulphurization gypsum-based steel slag was put forward. It was demonstrated that kaolin with content of 3% in the composites can better stimulate the activity of steel slag and improve the mechanical properties of cementitious composites.

2011 ◽  
Vol 250-253 ◽  
pp. 990-993
Author(s):  
Zhi Wang ◽  
Lei Zhang ◽  
Li Ying Fan ◽  
Guo Pu Shi

The effects of cement clinker on the properties of flue gas desulphurization gypsum-based steel slag composites were analyzed in this article and the influence rules of setting time, final setting time, flexural strength and compressive strength of cementitious composites were also discussed. The micro-morphology of the composite was observed by scanning electron microscope. At the same time, the excitation mechanism of cement clinker on gas desulphurization gypsum-based steel slag was put forward. It was demonstrated that cement clinker with content of 2% in the composites can better stimulate the activation of steel slag and improve the mechanical properties of the composites.


2014 ◽  
Vol 665 ◽  
pp. 379-382
Author(s):  
Ren Ping Liu ◽  
Rui Yao

Some semi-dry Flue Gas Desulfurization ash (SDFGDA) were taken from sinter gas of steel factory and been oxidized at experimental condition. Oxidized ash, granulated blast-furnace slag (GBFS) and steel slag were grinded and used to prepare cementing materials. Scanning electron microscope (SEM) was employed to identify the samples in order to investigate their hydration structure. The result shows that cementing materials have good hydration properties and mechanical properties, the initial and final setting time are qualified. It is recommended to control the Blaine fineness, mount of SDFGDA, ratio of GBFS/steel slag, mount of clinker to be 4500cm2/g, 19%, 1:4, 20%, respectively, when prepare eco-cement with those materials.


2011 ◽  
Vol 105-107 ◽  
pp. 2204-2208 ◽  
Author(s):  
Run Xia Hao ◽  
Xiao Yan Guo

The properties of flue gas desulphurization (FGD) gypsum were analysized by Thermo-gravimetry/differential scanning calorimetry (TG/DSC), technical performance analysis, optical microscope and Scanning electron microscope (SEM). Mechanical properties of FGD gypsum-steel slag powder cementitious material were researched. The results revealed that FGD gypsum have similar moisture content, major component CaSO4·2H2O with natural gypsum, and has better technical performance than natural gypsum. The results of optical microscope and SEM of the FGD gypsum hydration support this further. When the dosage of steel slag powder is 15%, containing activator ,better mechanical properties can be obtained. Key words: FGD gypsum, Property, Cementitious material


2011 ◽  
Vol 71-78 ◽  
pp. 842-846
Author(s):  
Miao Miao Chen ◽  
Yun Wei Yu ◽  
Chun Hua Feng ◽  
Dong Xu Li

Flue gas desulphurization (FGD) gypsum and fly ash are two kinds of solid waste in coal-fired power plant. The possible displacement content of fly ash in gypsum plaster was investigated in this paper. The effect of various chemicals retarders, such as Citric acid, sodium citrate and SC gypsum retarder, and water retention agent on the setting time, flexural strength and compressive strength of gypsum plaster was also studied. The results demonstrate that gypsum plaster has maximum mechanical properties and enough setting time at the rate of 20% fly ash replacing calcined gypsum; SC gypsum retarder effectively delays the setting time and has lower strength loss; The optimum level of water-retention agent for effective utilization of gypsum plaster is 0.2%.


2014 ◽  
Vol 599 ◽  
pp. 346-349
Author(s):  
Lin Chen ◽  
Jun Cai ◽  
Bao Quan Li ◽  
Xin Yan Zhang

In this paper, a novel composite cementitious material was prepared by using steel slag and rice husk ash. The appreciate treatment processes of composite cementitious material prepared were investigated. At same time its basic performance of cement mortar, such as water demand ratio, setting time, soundness and strength were also investigated and discussed. Experimental results show that the cementitious materials prepared has good basic properties with appreciate treatment processes. It concluded that the properly treated steel slag and rice husk ash can be used to prepare cementitious material.


Author(s):  
Mahmud Sami Döndüren ◽  
◽  
Mohammed Gamal Al-Hagri ◽  

There are some problems and weaknesses related to cement-based materials, such as their very low tensile strength, low chemical resistance and the huge contribution of cement production to industrial CO2 emissions. One possible method to reduce the impacts of such problems is the partial replacement of cement in cementitious materials with nano materials. This work provides a detailed review of incorporation of one of the most widely used nano materials, namely nano-titanium dioxide, and its effect on the properties of cementitious composites. Different properties have been considered in the current study, such as fresh properties, mechanical properties (compressive strength, split tensile strength and flexural strength), durability (permeability, ultrasonic pulse velocity (UPV), electrical resistivity, carbonation resistance, freeze and thaw resistance and sulfate attack resistance) and microstructural properties. This paper also investigates the optimum content of nano-TiO2 in cement-based materials. Moreover, the cost effectiveness of use on nano-titania in cementitious composites has been discussed. Nano titania reduces the workability and setting time of cement-based materials. It can be very effective in improving the mechanical properties, durability and microstructural properties of cementitious composites.


2013 ◽  
Vol 743-744 ◽  
pp. 275-279 ◽  
Author(s):  
Hui Rong ◽  
Chun Xiang Qian ◽  
Long Zhi Li

Microbe cement is a new generation cement due to the ever increasing awareness of environmental protection. Microbe cement is a new strengthening material based on microbiologically induced precipitation of calcium carbonate. This paper presents the results from laboratory research on the influence of magnesium additive concentration (1.0mol/L3.0mol/L5.0mol/L and 7.0 mol/L) on the mechanical properties of microbe cementitious materials. In addition, the micro-morphology and microstructure of microbe cementitious materials were analyzed by scanning electron microscopy (SEM). The experimental results indicate that when the magnesium additive concentration was 1.0 mol/L, the compressive strength of microbe cementitious materials can reach up to 6.2MPa at an age of 12 days. The microstructure of microbe cementitious materials depends on the content of mineral produced by microbially induced precipitation.


2012 ◽  
Vol 214 ◽  
pp. 40-44
Author(s):  
Yue Li ◽  
Jian Hui Wu ◽  
Bin Hao ◽  
Da Cheng Liu

The Crystal Transformation of flue gas desulphurization (FGD) gypsum was analyzed by differential thermal analysis (DTA) and X-ray Diffraction (XRD). FGD gypsum was used as cement setting retarder and the influences on the properties of cement were studied by treating FGD gypsum at different heat treatment processes. The results reveal that in the case of adding the same amount, the setting time of cement shortened with the increasing of heat treatment temperature of FGD gypsum. The influence of different heat treatment processes on the strength of cements was not obvious and the strength development was good. The water consumption of normal consistency for cements changed slightly. Stability was qualified.


2017 ◽  
Vol 898 ◽  
pp. 2010-2017 ◽  
Author(s):  
Xiao Ying Wang ◽  
Ming Zhang Lan ◽  
Wei Fang Hou ◽  
Bin Feng Xiang ◽  
Xu Dong Zhao

The effects of triethanolamine on the compressive strength and setting time of fly ash cementitious materials, slag cementitious materials, and limestone cementitious materials were investigated. The results show that the dosage of 0.04% of triethanolamine can significantly improve the 3d, 7d and 28d compressive strength of fly ash cementitious materials. It possesses less impact on the setting time. The dosage of 0.04% of triethanolamine can significantly improve the 3d and 7d compressive strength of slag cementitious materials while the effect of late strength is not obvious. It extends the initial setting time and the final setting time is not changed, which has retarding effect. The results of hydration heat and XRD show that triethanolamine extends the induction period of cement hydration, and gypsum is exhausted in advance during the hydration process. Triethanolamine promotes the transformation of AFt to AFm and there is no effect on the type of hydration products.


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