Corrosion Behavior of Twin-Wire Metal Inert Gas Arc Welds in 7A52 Al Alloy Plate

2011 ◽  
Vol 314-316 ◽  
pp. 918-922
Author(s):  
Xi Wei Zhai ◽  
Fu Rong Chen ◽  
Rui Ling Jia ◽  
Xiao Dong Wang
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Inert Gas ◽  
Al Alloy ◽  
Alloy Plate ◽  
Welding Joint ◽  
Tandem Welding ◽  
7A52 Aluminum Alloy

Abstract. 7A52 aluminum alloy plate was welded using twin-wire metal inert gas arc welding (TANDEM welding). Corrosion behavior of the welded joint was investigated by immersion in 3.5% NaCl solution. Scanning electron microscopy (SEM) and electrochemical inspections, specifically, polarization curves and electrochemical impedance spectroscopy (EIS), were conducted to understand corrosion behavior of the TANDEM welding joint of 7A52 aluminum alloy. It was found that the heat affected zone (HAZ) exhibited higher corrosion susceptibility than the weld beam (WB), fusion zone (FZ) and base metal (BM). The electrochemical results showed that the WB with higher corrosion potential and larger impedance had highest corrosion resistance. Variations in the composition and grain size might have led to the differences in corrosion resistance because the welding process influenced microstructures of the TANDEM welding joint of 7A52 aluminum.

A Study on the SCC Susceptibility of Twin-Wire Metal Inert Gas Arc Welds in 7A52 Al Alloy Plate

2011 ◽  
Vol 311-313 ◽  
pp. 619-623
Author(s):  
Xiao Dong Wang ◽  
Rui Ling Jia ◽  
Hui Xia Zhang ◽  
Hua Jian Lui ◽  
Xi Wei Zhai ◽  
...  
Keyword(s):  
Arc Welding ◽  
Electrochemical Impedance ◽  
Weld Zone ◽  
Electrochemical Corrosion ◽  
Parent Material ◽  
Test Method ◽  
Inert Gas ◽  
Al Alloy ◽  
Alloy Plate ◽  
Electrochemical Corrosion Behavior

7A52 Al alloy plates was welded using twin-wire metal inert gas arc welding (TMW) .Stress corrosion cracking (SCC)behavior of the parent material and the welded specimens was investigated by the slow strain rate tensile(SSRT)test method respectively. Electrochemical impedance spectroscopy (EIS) was conducted to understand electrochemical corrosion behavior of 7A52 Al alloy and its TMW weldment. It was found that the welded specimens exhibited higher SCC susceptibility than the parent materials under SSRT testing in seawater. The EIS result showed that the weld zone exhibited higher corrosion resistance than that of the parent material. Hydrogen embrittlement is a crucial factor that leads to the failure of the welded specimens during SSRT test in seawater.

scholarly journals Corrosion Behavior of AA6012 Aluminum Alloy Processed by ECAP and Cryogenic Treatment

Metals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 408 ◽  
Author(s):  
Annamaria Viceré ◽  
Gabriella Roventi ◽  
Chiara Paoletti ◽  
Marcello Cabibbo ◽  
Tiziano Bellezze
Keyword(s):  
Plastic Deformation ◽  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Electrochemical Impedance Spectroscopy ◽  
Corrosion Behavior ◽  
Room Temperature ◽  
Electrochemical Impedance ◽  
Cryogenic Treatment ◽  
Angular Pressing ◽  
Ecap Process

In this work, the corrosion behavior of an AA6012 aluminum alloy, submitted to a T6 strengthening treatment (solubilization and aging), and later to a severe plastic deformation, through equal channel angular pressing (ECAP) was studied. Some of these samples were submitted to a cryogenic treatment before the ECAP process. The analysis of corrosion behavior of the AA6012 samples was carried out at room temperature by means of electrochemical characterization in 0.1 M Cl− deaerated and aerated solution at pH 2. For this purpose, Tafel plots and electrochemical impedance spectroscopy tests were performed. The evolution of the microstructure was studied by means of SEM and TEM observations. The experimental results show that the cryogenic treatment does not influence the corrosion behavior of the studied alloy submitted to T6 treatment. Moreover, it was found that the ECAP technique does not induce a marked deterioration of the analyzed samples in terms of corrosion resistance.

The Inhibiting Effect of Monoethanolamine on 6063 Aluminum Alloy in Sodium Chloride Solution

2013 ◽  
Vol 652-654 ◽  
pp. 1149-1152
Author(s):  
Hui Cheng Yu ◽  
Yi Chun Wei ◽  
Xue Yi Huang ◽  
Fu Hou Lei
Keyword(s):  
Weight Loss ◽  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Corrosion Potential ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Al Alloy ◽  
Test Results ◽  
6063 Al Alloy ◽  
6063 Aluminum Alloy

Monoethanolamine (MEA) was investigated as corrosion inhibitors of a 6063 aluminum alloy in 3.5 % solution using polarization and electrochemical impedance spectroscopy techniques and weight loss. The polarization curves show that monoethanolamine (MEA) can increase corrosion potential (Ecorr) and pitting corrosion potential (Epit), and decrease corrosion current density (icorr) of the 6063 aluminum alloy. EIS results indicate that monoethanolamine (MEA) can increase impedance of the 6063 aluminum alloy. The results show that monoethanolamine exhibits better inhibitor properties for the 6063 aluminum alloy. Electrochemical test results show monoethanolamine (MEA) can improve corrosion resistance and the inhibition action depends on the concentration of the inhibitor. The weight-loss experiment also proves that monoethanolamine (MEA) can improve the corrosion resistance of the 6063 Al alloy.

scholarly journals Surface Modification of Aluminum 6061-O Alloy by Plasma Electrolytic Oxidation to Improve Corrosion Resistance Properties

Coatings ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 4
Author(s):  
Dmitry V. Dzhurinskiy ◽  
Stanislav S. Dautov ◽  
Petr G. Shornikov ◽  
Iskander Sh. Akhatov
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Aluminum Alloys ◽  
Plasma Electrolytic Oxidation ◽  
Electrochemical Impedance ◽  
High Strength ◽  
Electrolytic Oxidation ◽  
Coating Layers ◽  
Plasma Electrolytic ◽  
High Strength Aluminum Alloys

In the present investigation, the plasma electrolytic oxidation (PEO) process was employed to form aluminum oxide coating layers to enhance corrosion resistance properties of high-strength aluminum alloys. The formed protective coating layers were examined by means of scanning electron microscopy (SEM) and characterized by several electrochemical techniques, including open circuit potential (OCP), linear potentiodynamic polarization (LP) and electrochemical impedance spectroscopy (EIS). The results were reported in comparison with the bare 6061-O aluminum alloy to determine the corrosion performance of the coated 6061-O alloy. The PEO-treated aluminum alloy showed substantially higher corrosion resistance in comparison with the untreated substrate material. A relationship was found between the coating formation stage, process parameters and the thickness of the oxide-formed layers, which has a measurable influence on enhancing corrosion resistance properties. This study demonstrates promising results of utilizing PEO process to enhance corrosion resistance properties of high-strength aluminum alloys and could be recommended as a method used in industrial applications.

scholarly journals Assessment of nickel titanium and beta titanium corrosion resistance behavior in fluoride and chloride environments

2013 ◽  
Vol 83 (5) ◽  
pp. 864-869 ◽  
Author(s):  
Elisa J. Kassab ◽  
José Ponciano Gomes
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Fluoride Concentration ◽  
Nickel Titanium ◽  
Localized Corrosion ◽  
General Corrosion ◽  
Nacl Solution ◽  
Galvanic Coupling ◽  
Beta Titanium

ABSTRACT Objective: To assess the influence of fluoride concentration on the corrosion behavior of nickel titanium (NiTi) superelastic wire and to compare the corrosion resistance of NiTi with that of beta titanium alloy in physiological solution with and without addition of fluoride. Materials and Methods: NiTi corrosion resistance was investigated through electrochemical impedance spectroscopy and anodic polarization in sodium chloride (NaCl 0.15 M) with and without addition of 0.02 M sodium fluoride (NaF), and the results were compared with those associated with beta titanium. The influence of fluoride concentration on NiTi corrosion behavior was assessed in NaCl (0.15 M) with and without 0.02, 0.04, 0.05, 0.07, and 0.12 M NaF solution. Galvanic corrosion between NiTi and beta titanium were investigated. All samples were characterized by scanning electron microscopy. Results: Polarization resistance decreased when NaF concentration was increased, and, depending on NaF concentration, NiTi can suffer localized or generalized corrosion. In NaCl solution with 0.02 M NaF, NiTi suffer localized corrosion, while beta titanium alloys remained passive. Current values near zero were observed by galvanic coupling of NiTi and beta titanium. Conclusions: There is a decrease in NiTi corrosion resistance in the presence of fluoride. The corrosion behavior of NiTi alloy depends on fluoride concentration. When 0.02 and 0.04 M of NaF were added to the NaCl solution, NiTi presented localized corrosion. When NaF concentration increased to 0.05, 0.07, and 0.12 M, the alloy presented general corrosion. NiTi corrosion resistance behavior is lower than that of beta titanium. Galvanic coupling of these alloys does not increase corrosion rates.

scholarly journals Stress corrosion behavior of friction stir welding joint of 7N01 aluminum alloy

2021 ◽  
Vol 15 ◽  
pp. 1130-1144
Author(s):  
Yuzhe Pan ◽  
Yu Wang ◽  
Fuqiang Guo ◽  
Tiehao Zhang ◽  
Kenji Matsuda ◽  
...  
Keyword(s):  
Aluminum Alloy ◽  
Friction Stir Welding ◽  
Stress Corrosion ◽  
Corrosion Behavior ◽  
Friction Stir ◽  
Welding Joint

Computational and Experimental Insights into the Role of Acidic Molecules on the Corrosion Behavior on 7A46 Aluminum Alloy

2021 ◽  
Vol 21 (4) ◽  
pp. 2221-2233
Author(s):  
Yaru Liu ◽  
Qinglin Pan ◽  
Xiangdong Wang ◽  
Ye Ji ◽  
Qicheng Liu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Corrosion Behavior ◽  
First Principles ◽  
First Principles Calculations ◽  
Corrosive Media ◽  
Corrosion Depth ◽  
Corrosion Mechanisms ◽  
Nanoscale Level

The corrosion mechanisms for different corrosive media on the aged 7A46 aluminum alloy were systematically investigated at nanoscale level. The combination of empirical intergranular and exfoliation corrosion behavior was employed, and coupled with first-principles calculations. Results revealed that the dispersed distribution of matrix precipitates (MPs) leads to the enhancement of the corrosion resistance pre-ageing (PA) followed by double-ageing (PA-DA) alloy. The deepest corrosion depth of PA-DA alloy was in hydrochloric acid, and the calculation result demonstrates that the passivation effect in combination with the accumulation of corrosion products in nitric acid protect the PA-DA alloy from further corrosion.

Evaluation of the corrosion behavior of AZ31 magnesium alloy with different protein concentrations

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Yucong Ma ◽  
Mohd Talha ◽  
Qi Wang ◽  
Zhonghui Li ◽  
Yuanhua Lin
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Surface Film ◽  
Energy Dispersive Spectrometer ◽  
Inhibitory Effect ◽  
Corrosion Process ◽  
High Concentration ◽  
Content Type ◽  
Atomic Force

Purpose The purpose of this paper is to study systematically the corrosion behavior of AZ31 magnesium (Mg) alloy with different concentrations of bovine serum albumin (BSA) (0, 0.5, 1.0, 1.5, 2.0 and 5.0 g/L). Design/methodology/approach Electrochemical impedance spectroscopy and potential dynamic polarization tests were performed to obtain corrosion parameters. Scanning electrochemical microscopy (SECM) was used to analyze the local electrochemical activity of the surface film. Atomic force microscope (AFM), Scanning electron microscope-Energy dispersive spectrometer and Fourier transform infrared spectroscopy were used to determine the surface morphology and chemical composition of the surface film. Findings Experimental results showed the presence of BSA in a certain concentration range (0 to 2.0 g/L) has a greater inhibitory effect on the corrosion of AZ31, however, the presence of high-concentration BSA (5.0 g/L) would sharply reduce the corrosion resistance. Originality/value When the concentration of BSA is less than 2.0 g/L, the corrosion resistance of AZ31 enhances with the concentration. The adsorption BSA layer will come into being a physical barrier to inhibit the corrosion process. However, high-concentration BSA (5.0 g/L) will chelate with dissolved metal ions (such as Mg and Ni) to form soluble complexes, which increases the roughness of the surface and accelerates the corrosion process.

scholarly journals Microstructure and Mechanical Properties of Thick Plate Friction Stir Welds for 6082-T6 Aluminum Alloy

2019 ◽  
Vol 38 (2019) ◽  
pp. 525-532 ◽  
Author(s):  
Zhimin Liang ◽  
Xue Wang ◽  
Congwei Cai ◽  
Dianlong Wang
Keyword(s):  
Aluminum Alloy ◽  
Thick Plate ◽  
Frictional Heating ◽  
High Heat ◽  
Tensile Fracture ◽  
Alloy Plate ◽  
Friction Stir ◽  
Welding Joint ◽  
High Heat Input ◽  
Two Sides

Abstract6082-T6 aluminum alloy plate with thickness of 42mm was butt welded by friction stir welding (FSW) from two sides. The microstructures of the joints exhibited different grain sizes because of unequal frictional heating and plastic flow during FSW process. The transition from the heat affected zone (HAZ) to the nugget zone (NZ) in thermos-mechanical affected zone of advancing side (AS-TMAZ) was more sudden than thermos-mechanical affected zone of retreating side (RS-TMAZ). Kissing bond (KB) defect throughout the entire FSW joint was displayed both at the grain boundary and in the interior of the grain with semi-continuous bands. KB had no direct effect on tensile properties. Vickers hardness of the FSW joint was lower than the BM because its high heat input, dissolved and coarsened precipitates and little to the grain size after FSW. Hardness distribution of double-sided welding joint showed X-shaped area softening characteristics, that is to say the lowest hardness was the junction of two welding joint of NZ and the junction of TMAZ and HAZ. The tensile fracture position occurred in the lowest hardness region of the FSW joint, and it did not occur in the KB defect position.

scholarly journals ESTUDIO DE LA RESISTENCIA A LA CORROSION DEL ALUMINIO 6063 ANODIZADO

2017 ◽  
Vol 22 (2) ◽  
pp. 17
Author(s):  
Karín Paucar Cuba ◽  
Hugo Rojas Flores ◽  
Abel Vergara Sotomayor
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Sulfuric Acid ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Aluminum Surface ◽  
Equivalent Circuits ◽  
Acid Salt ◽  
Mass Losses ◽  
Palabras Clave

El estudio de la resistencia a la corrosión del anodizado de una aleación de aluminio (AA6063) en ácido sulfúrico a diferentes tiempos de anodizado: 30, 45 y 60 min. se realizó usando la espectroscopia de impedancia electroquímica (EIE) y el ensayo de niebla salina ácida. (ASTM B287). Los datos obtenidos por EIE y su correlación con los circuitos equivalentes más apropiados permitieron determinar los parámetros asociados a la capa porosa y a la capa barrera del óxido protector formado sobre la superficie del aluminio en estudio. La exposición de las muestras anodizadas durante 250h a una niebla salina ácida permitió observar variaciones en su masa. De los resultados obtenidos por EIE y las pérdidas de masa de las muestras anodizadas se estableció que la película de anodizado de 45 minutos mostró una mayor resistencia a la corrosión en comparación con la obtenida a 60 y 30 min., respectivamente. Palabras clave.- Aluminio, Anodizado, Impedancia electroquímica, Niebla salina ácida. ABSTRACTThe study of the corrosion resistance of anodized on aluminum alloy (AA6063) in sulfuric acid to different times: 30, 45 and 60 min. was performed using electrochemical impedance spectroscopy (EIS) and the acid salt spray test (ASTM B287). The EIS’data and its correlation with the most appropriate equivalent circuits allowed to determine the parameters associated with the porous layer and the oxide layer protective barrier formed on the aluminum surface under study. Exposure of the samples anodized for a 250h salt spray acid allowed to observe changes in their mass. From the results obtained by EIS and the mass losses of the anodized samples was established that the anodized film of 45 minutes showed higher corrosion resistance compared to that obtained at 60 and 30 min, respectively. Keywords.- Aluminum, Anodized, Electrochemical impedance, Acid salt spray.

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