A Pilot Test Using Microbial Paraffin-Removal Technology in Daqing Oilfield

2012 ◽  
Vol 550-553 ◽  
pp. 1299-1303 ◽  
Author(s):  
Jiang Hong Liu ◽  
Yun Peng Jia ◽  
Rui Dan Xu ◽  
Peng Ju Zhao

Microorganisms were screened from oil wastewater in Daqing Oilfield, by acclimatization, isolation and purification of microorganisms, bacterium as the only nitrogen source was obtained, which was named for strain Y-1. Experiment of identification showed that Y-1 was identified to Bacillus Cereus. Strain Y-1 was used for paraffin removal on three wells: Well Nos. 12-36, 13-39 and 14-43 in Yushulin Zone Daqing Oilfield. The results indicated that the tested wells obtained good effects after microbial treatment: the reduction rate of oil viscosity was 23.6%, the freezing point of crude oil reduced by 2.1°C, the reduction rate of oil surface tension was 38.0%, pH value was reduced from 7.2 to 6.2, daily oil production increased from 1.7t·d-1 to 2.4t·d-1, the rate of growth was 41.2%, the period of hot washings prolonged from 40d to 149d and the number of hot washings reduced by 4 times in Well 12-36; the reduction rate of oil viscosity was 24.8%, the freezing point of crude oil reduced by 2.7°C, the reduction rate of oil surface tension was 42.5%, pH value was reduced from 7.2 to 6.8, daily oil production increased from 1.2t·d-1 to 1.6t·d-1, the rate of growth was 33.3%, the period of hot washings prolonged from 45d to 158d and the number of hot washings reduced by 5 times in Well 13-39; the reduction rate of oil viscosity was 22.5%, the freezing point of crude oil reduced by 3.2°C, the reduction rate of oil surface tension was 42.5%, pH value was reduced from 7.2 to 6.4, daily oil production increased from 0.8t·d-1 to 1.1t·d-1, the rate of growth was 37.5%, the period of hot washings prolonged from 30d to 122d and the number of hot washings reduced by 5 times in Well 14-43. The direct economic income exceeded 210,000 Yuan.

2012 ◽  
Vol 268-270 ◽  
pp. 237-240
Author(s):  
Jiang Hong Liu ◽  
Yun Peng Jia ◽  
Rui Dan Xu ◽  
Yi Tong Chen

By separation and purification experiment, microorganisms were obtained. The paraffin removal strain was named for SW-1. Microscopic and morphological examinations showed strain SW-1 was to be Bacillus Cereus. After strain SW-1 treatment, the number of strain SW-1 increased from 2.7×106/mL-1to 3.5×108/mL-1, which increased by two orders of magnitude; the degradation rate of paraffin could reach to 64% within one month; the prevention rate of paraffin could reach to 43%; the viscosity of crude oil reduced from 35.9mPa•s to 26.8mPa•s, the reduction rate of viscosity was 25.3%, and the freezing point of crude oil reduced by 4.3°C; surface tension reduced from 44.5mN•m-1to 29.1mN•m-1, the reduction rate of surface tension was 34.6%, and pH value was reduced to 6.3. These phenomenon indicated that strain SW-1 has better removal paraffins effect.


Complexity ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Zhenfu Ma ◽  
Kai Zhang ◽  
Mengjie Zhao ◽  
Lu Liu ◽  
Chao Zhong ◽  
...  

In view of the problems of low permeability, high oil viscosity and freezing point, and low productivity of single well in Luo 321 and Luo 36 blocks of Luojia Oilfield, the chemical viscosity-reducing cold production technology was studied. By analyzing the properties of crude oil, it is concluded that the reason for high viscosity and high freezing point is the high content of asphaltene, pectin, and wax. The viscosity is mainly affected by asphaltene; the wax precipitation point and pour point are mainly affected by the wax; and the solidification point is affected by the wax and asphaltene. The treatment idea of reducing viscosity and inhibiting wax is determined. By compounding the synthetic pour point depressant POA-VA and the viscosity reducer DBD-DOPAMA, the effect of reducing the viscosity and freezing point of crude oil was evaluated. PD-7 (POA-VA 40%, DBD-DOPAMA 50%, and P-10C 10%) system was selected as the optimal formula. When the concentration of the system is 10%, the viscosity reduction rate reaches 95.2%; the freezing point can reduce by 10.2°C; it has good oil sample adaptability, salinity resistance, and temperature resistance; and the oil washing rate can reach more than 60%. The oil displacement system was injected into the formation by means of multiconcentration and multislug and was applied in the field of Luo 321-2 Well. A total of 500 t of the oil displacement system was injected, and the effect of measures lasted for 400 days, with a cumulative oil increase of 883 t. It has been applied in different blocks 30 times and achieved a good field application effect.


SPE Journal ◽  
2008 ◽  
Vol 13 (02) ◽  
pp. 153-163 ◽  
Author(s):  
Jean Cristofari ◽  
Louis M. Castanier ◽  
Anthony R. Kovscek

Summary Application of cyclic solvent injection into heavy and viscous crude oil followed by in-situ combustion of heavy residues is explored from a laboratory perspective. The solvent reduces oil viscosity in-situ and extracts the lighter crude-oil fractions. Combustion cleans the near-well region and stimulates thermally the oil production. Both solvent injection and in-situ combustion are technically effective. The combination of the two methods, however, has never been tried to our knowledge. Hamaca (Venezuela) and West Sak (Alaska) crude oils were employed. First, ramped temperature oxidation studies were conducted to measure the kinetic properties of the oil prior to and following solvent injection. Pentane, decane, and kerosene were the solvents of interest. Second, solvent was injected in a cyclic fashion into a 1-m-long combustion tube. Then, the tube was combusted. Hamaca oil presented good burning properties, especially following pentane injection. The pentane extracted lighter components of the crude and deposited preferentially effective fuel for combustion. On the other hand, West Sak oil did not exhibit stable combustion properties without solvent injection, following solvent injection, and even when metallic additives were added to enhance the combustion. We were unable to propagate a burning front within the combustion tube. Nevertheless, the experimental results do show that this combined solvent combustion method is applicable to the broad range of oil reservoirs with properties similar to Hamaca. Introduction This article investigates the effect of solvent injection on the subsequent performance of in-situ combustion. The work is based on experimental results obtained by a combination of these two successful in-situ upgrading processes for viscous oils. It is envisioned that application in the field occurs first by a cycle of solvent injection, a short soak period, and subsequent oil production using the same well (Castanier and Kovscek 2005). By mixing with oil, the solvent decreases the oil viscosity and upgrades the crude by extracting in-situ the lighter ends of the crude oil. The heavy ends, that are markedly less interesting, are left behind. Injection of solvent and oil production occurs for a number of cycles until the economic limit is reached or until the deposition of crude oil heavy ends damages production. The solvent injection phase is followed by in-situ combustion that burns the heavy ends left from the solvent injection. By switching from air to nitrogen injection, the combustion is extinguished. Again, oil is produced by the same well used for injection in a cyclic fashion. Combustion enhances the production by decreasing thermally the oil viscosity and adding energy to the reservoir through the formation of combustion gases. The combustion also upgrades the oil through thermal cracking (Castanier and Brigham 2003). For our experiments, two oils of particular interest were used. The first experiments employed crude oil from Hamaca (Venezuela), where the field location requires important costs of transporting crude to upgrading facilities. The second set of experiments was conducted with viscous West Sak oil (Alaska), where steam injection currently appears to be unsuitable because of heat losses to permafrost. While the presence of oil in the Orinoco heavy-oil belt, in Central Venezuela, was discovered in the 1930s, the first rigorous evaluation of the resources was made in the 1980s, and the region was divided into four areas: Machete, Zuata, Hamaca, and Cerro Negro. It contains between 1.2 and 1.8 trillion recoverable barrels (Kuhlman 2000) of heavy and extra-heavy oil. The 9-11° API density crude is processed at the Jose refinery complex on the northern coast of Venezuela. The cost of transporting heavy oils to the northern coast provides an incentive to investigate in-situ upgrading. In 2003, the total production from these projects was about 500,000 B/D of synthetic crude oil. This figure was expected to increase to 600,000 B/D by 2005 (Acharya et al. 2004). West Sak is a viscous oil reservoir located within the Kuparuk River Unit on the North Slope of Alaska. It is part of a larger viscous oil belt that includes Prudhoe Bay. The estimated total oil in place ranges from 7 to 9 billion barrels, with an oil gravity ranging from 10 to 22°API. The reservoir depth ranges from 2,500 to 4,500 feet, with gross thickness of 500 feet and an average net thickness of 90 feet. The temperature is between 45 and 100°F, and there is a 2,000-ft (600-m) -thick Permafrost layer. In March 2005, 16,000 BOPD were produced and 40,000 BOPD are planned for 2007 (Targac et al. 2005). Within the scope of this study, West Sak is of particular interest because there are technical difficulties with steam injection that include (Gondouin and Fox 1991):Surface-generated steam passing through a thick permafrost layer; the well would sink if the permafrost melted.The reservoirs consist of thin, medium-permeability layers.The formation may contain swelling clays that reduce the rock permeability when exposed to steam condensate. Solvent injection and in-situ combustion are effective in a variety of fields. Both techniques upgrade the oil directly in the reservoir, thereby making heavy resources easier to exploit. The combination of these two processes is applicable at large scale to recover viscous oil, or in-situ combustion could be applied on an ad hoc basis to clean the wellbore region, increase the permeability, and thus act as a stimulation process.


2012 ◽  
Vol 550-553 ◽  
pp. 1364-1368 ◽  
Author(s):  
Jiong Hong Liu ◽  
Yun Peng Jia ◽  
Rui Dan Xu

Microorganisms were obtained by separation and purification experiment from waxy oil production wells in Daqing Oilfield. The paraffin removal strain was named for S1, and the biological surfactant strain was named for G1. Microscopic and morphological examinations showed strain S1 was to be Bacillus Subtilis and strain G1 was to be Bacillus Cereus. As an indicator of the degradation of paraffin, strain S1 and strain G1 were added in different proportions, the optimum proportion was 5:2. In this proportion the degradation rate of paraffin could reach to 64%, the prevention rate of paraffin could reach to 55%. By experiment after mixed bacteria group treatment, the viscosity of crude oil reduced from 36.9mPa•s to 27.8mPa•s, the reduction rate of viscosity was 24.7%, and the freezing point of crude oil reduced by 3.6°C, paraffinic hydrocarbons of crude oil were degraded.


2012 ◽  
Vol 430-432 ◽  
pp. 2083-2086 ◽  
Author(s):  
Zheng Jun Long ◽  
Ya Rong Fu ◽  
Dong Qing Li ◽  
Yuan Hong Cai

To solve the single tube gathering process paraffin oil viscosity reduction shaft and gathering the problem of high back pressure. Technical application of crude oil pour point depressant, mixed ester, benzene, ethylene oxide such as octylphenol ether compound by an oil-soluble DRA. Dosage in the 50 ~ 100mg/l to meet the water when the wellbore is less than 25% of the wax viscosity and single-tube process requirements gathering, can be compared to the multi-port wells, monitoring data before and after dosing showed that the crude oil after dosing freezing point decreased 5.6 °C, the average rate of 87.4% viscosity reduction, the average rate of 91.5% paraffin. Pipeline wellhead back pressure reduced by 20 to 30 percentage points


2021 ◽  
Vol 931 (1) ◽  
pp. 012002
Author(s):  
A Pituganova ◽  
I Minkhanov ◽  
A Bolotov ◽  
M Varfolomeev

Abstract Thermal enhanced oil recovery techniques, especially steam injection, are the most successful techniques for extra heavy crude oil reservoirs. Steam injection and its variations are based on the decrease in oil viscosity with increasing temperature. The main objective of this study is the development of advanced methods for the production of extra heavy crude oil in the oilfield of the Republic of Tatarstan. The filtration experiment was carried out on a bulk model of non-extracted core under reservoir conditions. The experiment involves the injection of slugs of fresh water, hot water and steam. At the stage of water injection, no oil production was observed while during steam injection recovery factor (RF) achieved 13.4 % indicating that fraction of immobile oil and non-vaporizing residual components is high and needed to be recovered by steam assisted EORs.


2019 ◽  
pp. 30-38
Author(s):  
Oleg B. Bocharov ◽  
Igor G. Telegin

The article deals with the modification of the Muskat — Leverett model, taking into account the dependence of oil viscosity on dynamic water saturation. We fulfill numerical analysis of the solutions structure and show the effect of viscosity changes on the convective, capillary and graphite flows. The article investigates the change in the rate of flooding of the oil reservoir while reducing the oil viscosity.


TAPPI Journal ◽  
2014 ◽  
Vol 13 (9) ◽  
pp. 51-60
Author(s):  
DENNIS VOSS ◽  
HANS-JOACHIM PUTZ ◽  
SAMUEL SCHABEL

The need for deinking mills to reduce their fresh water consumption has resulted in higher loads of various contaminants in the process water. Lower recovered paper quality also leads to higher contamination levels in the mills. This higher load has an influence on achievable target brightness. The objective of the work was to determine and explain the main reasons for relatively poor deinked pulp quality or poor deinking potential based on the influence of recovered paper composition and process water quality. The process water parameters significantly affect the deinking potential of recovered paper. The test results showed the negative effects of increased water hardness. For standard recovered paper mixtures, flotation selectivity is higher with increasing flotation pH-value. Good results were realized for standard recovered paper with low hardness, low surface tension, and high pH-value. The results for recovered paper containing flexo newsprint could be slightly improved with low hardness, low surface tension, and low pH-value. The results of the test program using design of experiments showed interacting effects of pH-value and surface tension on luminosity and flotation selectivity.


2017 ◽  
Vol 10 ◽  
pp. 120-124
Author(s):  
R.S. Khisamov ◽  
◽  
R.A. Gabdrahmanov ◽  
A.P. Bespalov ◽  
V.V. Zubarev ◽  
...  

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