Comparison on Separation of Low-Content Nickel and Cobalt in Bioleaching Solution in Different Extraction System

2014 ◽  
Vol 915-916 ◽  
pp. 968-973
Author(s):  
Gui Ying Zhou ◽  
Ji Hong Liu ◽  
Jian Kang Wen ◽  
Yong Sheng Song
Keyword(s):  
Extraction Efficiency ◽  
Ph Value ◽  
Synergistic Extraction ◽  
Extraction System ◽  
Test Results ◽  
Good Separation ◽  
Separation Effect ◽  
Initial Ph ◽  
Individual Contributions ◽  
Effects Of Temperature

As an effective method for increase extraction efficiency and selectivity,synergistic extraction has been studied for many years because the theoretical and applicative importance. Using synergistic effect of two extractants, distribution ratios of their mixture can be obviously enhanced than those of their individual contributions. Separation of nickel and cobalt for bioleaching solution were studied using a synergistic extraction system with P507 andCyanex272. The test results indicate that the system has better extraction effect. Contrasts the separation effect on nickel and cobalt using three extraction systems of P507, Cyanex272, P507-Cyanex272. Identified during the initial pH value of 1.5-2.2, balance pH value under the condition of 4.0-5.0,synergistic extraction system of P507-Cyanex272 have a good separation effect of nickel and cobalt. The extraction kinetics was investigated using a constant interfacial cell with laminar flow. The effects of temperature, extractant and cobalt concentration were studied. Co extraction rate was compared in the different extraction systems of individual P507 and synergistic P507-Cyanex272 .The results indicated that the extraction apparent action energy in synergistic system was lower than that of signal P507.The separation factor of nickel and cobalt was increased in synergistic system.

Synergistic Extraction of Gold by Di-(2-ethylhexyl)phosphoric Acid - Isodecanol

2019 ◽  
Vol 12 (1) ◽  
pp. 54-60
Author(s):  
Mohd Jumain Jalil ◽  
Nurul Afwanisa ◽  
Intan Suhada ◽  
Noor Hidayu Abdul Rani
Keyword(s):  
Heavy Metal ◽  
Synergistic Effect ◽  
Phosphoric Acid ◽  
Extraction Efficiency ◽  
Synergistic Extraction ◽  
Extraction System ◽  
Optimum Temperature ◽  
Single Extraction ◽  
Leaching Solution

Objective and Background: Synergistic extraction was introduced to replace single extraction due to enhanced extraction efficiency of heavy metal. Methodology: In order to improve extraction efficiency, di-(2-ethylhexyl) phosphoric acid (D2EHPA) was mixed with isodecanol to provide a synergistic effect together with leaching solution which is thiourea. From the single extraction system, the optimum temperature is found at 30°C producing the highest yield of %E of 91.30%. The single extraction also happened better with the presence of Fe(III) solution and thiourea as the %E is at 91.23%. Results and Conclusion: It was found that the synergistic D2EHPA-isodecanol extraction is successful as it yields higher %E than the single D2EHPA extraction.

Remediation of Cadmium Contamination in Soil by Washing

2013 ◽  
Vol 295-298 ◽  
pp. 26-29 ◽  
Author(s):  
Yu Shuang Li ◽  
Xiao Jun Hu ◽  
Xue Ying Song
Keyword(s):  
Contaminated Soil ◽  
High Stability ◽  
High Selectivity ◽  
Extraction Efficiency ◽  
Ph Value ◽  
Soil Washing ◽  
Attractive Alternative ◽  
Cadmium Contamination ◽  
Initial Ph ◽  
Remediation Of Soil

Soil washing is a possible remediation technique for contaminant extracting from the soil. Thiacalix[4]arenetetrasulfonate has become an alternative to metal extractants due to its high selectivity and high stability. Batch soil-washing experiments were conducted to investigate the effect of pH on extraction efficiency of Cd from soil by the thiacalix[4]arenete-trasulfonate solution. Results showed that more than 82 percent of cadmium was extracted by the thiacalix[4]arenetetra- sulfonate solution from the artificially contaminated soil with the concentration of 562 mg/kg cadmium at the initial pH value of 11. Thiacalix[4]arenetetrasulfonate could be an attractive alternative in washing remediation of soil contaminated by Cd.

DIP quality influenced by process water quality

TAPPI Journal ◽  
2014 ◽  
Vol 13 (9) ◽  
pp. 51-60
Author(s):  
DENNIS VOSS ◽  
HANS-JOACHIM PUTZ ◽  
SAMUEL SCHABEL
Keyword(s):  
Water Quality ◽  
Surface Tension ◽  
Ph Value ◽  
Water Hardness ◽  
Process Water ◽  
Test Results ◽  
Negative Effects ◽  
Water Parameters ◽  
Effects Of Ph ◽  
Contamination Levels

The need for deinking mills to reduce their fresh water consumption has resulted in higher loads of various contaminants in the process water. Lower recovered paper quality also leads to higher contamination levels in the mills. This higher load has an influence on achievable target brightness. The objective of the work was to determine and explain the main reasons for relatively poor deinked pulp quality or poor deinking potential based on the influence of recovered paper composition and process water quality. The process water parameters significantly affect the deinking potential of recovered paper. The test results showed the negative effects of increased water hardness. For standard recovered paper mixtures, flotation selectivity is higher with increasing flotation pH-value. Good results were realized for standard recovered paper with low hardness, low surface tension, and high pH-value. The results for recovered paper containing flexo newsprint could be slightly improved with low hardness, low surface tension, and low pH-value. The results of the test program using design of experiments showed interacting effects of pH-value and surface tension on luminosity and flotation selectivity.

scholarly journals Hydrothermal Synthesis of Various Shape-Controlled Europium Hydroxides

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 529
Author(s):  
Hongjuan Zheng ◽  
Kongjun Zhu ◽  
Ayumu Onda ◽  
Kazumichi Yanagisawa
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Ph Value ◽  
Hydrothermal Temperature ◽  
X Ray ◽  
Hydrothermal Reactions ◽  
Starting Solution ◽  
Initial Ph ◽  
Shape Controlled ◽  
Scanning Electron

Eu(OH)3 with various shape-controlled morphologies and size, such as plate, rod, tube, prism and nanoparticles was successfully synthesized through simple hydrothermal reactions. The products were characterized by XRD (X-Ray Powder Diffraction), FE-SEM (Field Emission- Scanning Electron Microscopy) and TG (Thermogravimetry). The influence of the initial pH value of the starting solution and reaction temperature on the crystalline phase and morphology of the hydrothermal products was investigated. A possible formation process to control morphologies and size of europium products by changing the hydrothermal temperature and initial pH value of the starting solution was proposed.

scholarly journals The sorption of inorganic arsenic on modified sepiolite: Effect of hydrated iron(III)-oxide

2014 ◽  
Vol 79 (7) ◽  
pp. 815-828 ◽  
Author(s):  
Nikola Ilic ◽  
Slavica Lazarevic ◽  
Vladana Rajakovic-Ognjanovic ◽  
Ljubinka Rajakovic ◽  
Djordje Janackovic ◽  
...  
Keyword(s):  
Sorption Capacity ◽  
Arsenic Removal ◽  
Ph Value ◽  
Inorganic Arsenic ◽  
Arsenic Species ◽  
Deionized Water ◽  
Order Kinetic ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The sorption of inorganic arsenic species, As(III) and As(V), from water by sepiolite modified with hydrated iron(III) oxide was investigated at 25 ?C through batch studies. The influence of the initial pH value, the initial As concentrations, the contact time and types of water on the sorption capacity was investigated. Two types of water were used, deionized and groundwater. The maximal sorption capacity for As(III) from deionized water was observed at initial and final pH value 7.0, while the bonding of As(V) was observed to be almost pH independent for pH value in the range from 2.0 to 7.0, and the significant decrease in the sorption capacity was observed at pH values above 7.0. The sorption capacity at initial pH 7.0 was about 10 mg g?1 for As(III) and 4.2 mg g?1 for As(V) in deionized water. The capacity in groundwater was decreased by 40 % for As(III) and by 20 % for As(V). The Langmuir model and pseudo-second order kinetic model revealed good agreement with the experimental results. The results show that Fe(III)-modified sepiolite exhibits significant affinity for arsenic removal and it has a potential for the application in water purification processes.

Selective Leaching Nickel from the Pre-Reduced Limonitic Laterite Ore at Atmospheric Pressure

2012 ◽  
Vol 560-561 ◽  
pp. 494-498
Author(s):  
Yong Feng Chang ◽  
Chuan Lin Fan ◽  
Bin Chuan Li ◽  
Xiu Jing Zhai ◽  
Ting An Zhang
Keyword(s):  
Atmospheric Pressure ◽  
Ph Value ◽  
Test Results ◽  
Selective Leaching ◽  
Nickel Extraction ◽  
Extraction Degree ◽  
Leaching Solution ◽  
Novel Method ◽  
Leaching Condition ◽  
Laterite Ore

In this paper a novel method for selective leaching nickel from pre-reduced laterite ore at atmospheric pressure was reported. The reduced calcine was leached in thin acid liquor to liberate the nickel and iron together firstly. By properly controlling the leaching condition, the leached iron ion could hydrolyze as goethite precipitate and regenerate the acid consumed in the leaching procedure. Finally, the nickel is selectively extracted into the leaching solution. The main factors in the leaching process, such as reduction degree of the laterite ore, acidity of the leaching solution were investigated as influence on the nickel extraction. The test results showed that selectively leaching of nickel could be achieved with an extraction degree up to 90% by reducing most of the iron in the lateritic ore to wuestite and controlling the pH value of the leaching solution below 2.5.

scholarly journals The Removal of Methylene Blue Dye from Aqueous Solutions Using Activated and Non-Activated Bentonites

2003 ◽  
Vol 21 (5) ◽  
pp. 451-462 ◽  
Author(s):  
Sameer Al-Asheh ◽  
Fawzi Banat ◽  
Leena Abu-Aitah
Keyword(s):  
Methylene Blue ◽  
Ph Value ◽  
Sodium Dodecyl ◽  
Freundlich Isotherm ◽  
Blue Dye ◽  
Batch Adsorption ◽  
Ionic Surfactant ◽  
Methylene Blue Dye ◽  
X Ray Diffraction ◽  
Initial Ph

An improvement in the adsorption capacity of naturally available bentonite towards water pollutants such as Methylene Blue dye (MBD) is certainly needed. For this purpose, sodium bentonite was activated by two methods: (1) treatment with sodium dodecyl sulphate (SDS) as an ionic surfactant and (2) thermal treatment in an oven operated at 850°C. Batch adsorption tests were carried out on removing MBD from aqueous solution using the above-mentioned bentonites. It was found that the effectiveness of bentonites towards MBD removal was in the following order: thermal-bentonite > SDS-bentonite > natural bentonite. X-Ray diffraction analysis showed that an increase in the microscopic bentonite platelets on treatment with SDS was the reason behind the higher uptake of MBD. An increase in sorbent concentration or initial pH value of the solutions resulted in a greater removal of MBD from the solution. An increase in temperature led to an increase in MBD uptake by the bentonites studied in this work. The Freundlich isotherm model was employed and found to represent the experimental data well.

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