Effects of Different Lithium Admixtures on Ordinary Portland Cement Paste Properties

2014 ◽  
Vol 919-921 ◽  
pp. 1780-1789 ◽  
Author(s):  
Yu Hai Deng ◽  
Chang Qing Zhang ◽  
Hai Qiang Shao ◽  
Han Wu ◽  
Nie Qiang Xie
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Setting Time ◽  
Lithium Carbonate ◽  
Lithium Hydroxide ◽  
Strength Development ◽  
Lithium Nitrate ◽  
Cement Pastes ◽  
Compressive Strength Development ◽  
Paste Properties

Lithium-based chemicals are known to their signal effect on restraining alkali-silica reaction but uncertain influence on workability and mechanical property in the concrete. The aim of this research is to analyze the effects of three lithium additiveslithium nitrate (LiNO3), lithium hydroxide (LiOH) and lithium carbonate (Li2CO3) at various dosages, with an extensive comparison on fluidities, setting times and compressive strength of cement pastes. The experimental study shows that test results vary with the type of admixture. In general, three conclusions can be made: 1) lithium nitrate and lithium hydroxide can enhance the fluidity of cement paste, but lithium carbonate has opposite effects; 2) all three lithium salts shorten setting time as well as decrease the strength at suitable dosages; 3) the variations in lithium additives dosages have different influence on the cement pastes setting time and compressive strength development.

scholarly journals Effect of Calcium Nitrate on the Properties of Portland–Limestone Cement-Based Concrete Cured at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1611
Author(s):  
Gintautas Skripkiūnas ◽  
Asta Kičaitė ◽  
Harald Justnes ◽  
Ina Pundienė
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Setting Time ◽  
Calcium Nitrate ◽  
Curing Temperature ◽  
Hardened Concrete ◽  
Cement Pastes ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Early Strength

The effect of calcium nitrate (CN) dosages from 0 to 3% (of cement mass) on the properties of fresh cement paste rheology and hardening processes and on the strength of hardened concrete with two types of limestone-blended composite cements (CEM II A-LL 42.5 R and 42.5 N) at different initial (two-day) curing temperatures (−10 °C to +20 °C) is presented. The rheology results showed that a CN dosage up to 1.5% works as a plasticizing admixture, while higher amounts demonstrate the effect of increasing viscosity. At higher CN content, the viscosity growth in normal early strength (N type) cement pastes is much slower than in high early strength (R type) cement pastes. For both cement-type pastes, shortening the initial and final setting times is more effective when using 3% at +5 °C and 0 °C. At these temperatures, the use of 3% CN reduces the initial setting time for high early strength paste by 7.4 and 5.4 times and for normal early strength cement paste by 3.5 and 3.4 times when compared to a CN-free cement paste. The most efficient use of CN is achieved at −5 °C for compressive strength enlargement; a 1% CN dosage ensures the compressive strength of samples at a −5 °C initial curing temperature, with high early strength cement exceeding 3.5 MPa but being less than the required 3.5 MPa in samples with normal early strength cement.

scholarly journals Influence of Mechanical and Mineralogical Activation of Biomass Fly Ash on the Compressive Strength Development of Cement Mortars

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6654
Author(s):  
Jakub Popławski ◽  
Małgorzata Lelusz
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Silica Fume ◽  
Cement Mortar ◽  
Setting Time ◽  
Green Energy ◽  
Biomass Combustion ◽  
Strength Development ◽  
Compressive Strength Development ◽  
Biomass Fly Ash

Biomass combustion is a significant new source of green energy in the European Union. The adequate utilization of byproducts created during that process is a growing challenge for the energy industry. Biomass fly ash could be used in cement composite production after appropriate activation of that material. This study had been conducted to assess the usefulness of mechanical and physical activation methods (grinding and sieving), as well as activation through the addition of active silica in the form of silica fume, as potential methods with which to activate biomass fly ash. Setting time, compressive strength, water absorption and bulk density tests were performed on fresh and hardened mortar. While all activation methods influenced the compressive strength development of cement mortar with fly ash, sieving of the biomass fly ash enhanced the early compressive strength of cement mortar. The use of active silica in the form of silica fume ensured higher compressive strength results than those of control specimens throughout the entire measurement period.

Study on the Early Hydration of Cement Paste Containing Sodium Chloride

2014 ◽  
Vol 621 ◽  
pp. 35-38 ◽  
Author(s):  
Rahimah Embong ◽  
Andri Kusbiantoro
Keyword(s):  
Compressive Strength ◽  
Sodium Chloride ◽  
Cement Paste ◽  
Setting Time ◽  
Chloride Ion ◽  
Strength Development ◽  
Early Hydration ◽  
Initial Setting Time ◽  
Additive Component ◽  
Initial Setting

This paper studies the effect of sodium chloride as the additive component in cement paste. Sodium chloride was included at 0.5%, 1%, 1.5%, and 2% by weight of cement content. Analysis on the performance of this reagent was conducted via setting time, compressive strength, and porosity test. Based on the setting time analysis, the inclusion of sodium chloride can extend the initial setting time of cement paste up to 24.91% longer than control specimen. Obstruction on the formation of calcium silicate hydrate gel by sodium and chloride ion was one of the possible causes to this phenomenon. Acceleration on the compressive strength development by sodium chloride was also detected. It appears that sodium chloride was able to de-flocculate the coagulated cement particles and reduced the viscosities of cement slurries; hence resulted in faster early hydration process.

scholarly journals Effect of Bacillus cohnii on Some Physicomechanical and Microstructural Properties of Ordinary Portland Cement

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Ngari Reginah Wangui ◽  
Joseph Karanja Thiong’o ◽  
Jackson Muthengia Wachira
Keyword(s):  
Compressive Strength ◽  
Setting Time ◽  
Microstructural Analysis ◽  
Strength Development ◽  
Microstructural Properties ◽  
Calcite Precipitation ◽  
Strength Tests ◽  
Compressive Strength Development ◽  
Sustainability Challenges ◽  
Cement Setting

Cement-made materials face durability and sustainability challenges. This is majorly caused by the presence of cracks. Cracking affects the mechanical strength of cement-based materials. Microbiologically induced calcite precipitation (MICP) has been found to enhance compressive strength, thus enhancing on the mechanical and durability properties of these materials. This paper presents the findings of a study conducted to investigate the effect of Bacillus cohnii on compressive strength development of OPC mortar prisms and the effect of Bacillus cohnii on cement setting time and soundness. Microbial concentration of 1.0 × 107 cells·ml−1 was used. Compressive strength tests analyses were carried out for each category of mortar prisms. Compressive strength tests were carried out on the 2nd, 7th, 14th, 28th, 56th, and 90th day of curing in distilled water and microbial solutions. All microbial mortars exhibited a greater compressive strength compared to the control with the highest observed at 90 days. Highest percentage gain in compressive strength was observed at 90 days which is 28.3%. Microstructural analysis was carried out using a scanning electron microscope (SEM) after 28 days of curing. The results indicated the presence of calcium carbonate and more calcium silicate hydrate (CSH) deposits on the bacterial mortars. The bacteria did not have an effect on cement soundness. Setting time was significantly accelerated.

scholarly journals The impact of lithium nitrate on the physical and mechanical properties of Portland cement)

2018 ◽  
Vol 163 ◽  
pp. 04002
Author(s):  
Justyna Zapała-Sławeta ◽  
Zdzisława Owsiak
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Portland Cement ◽  
Isothermal Calorimetry ◽  
Setting Time ◽  
Physical And Mechanical Properties ◽  
Strength Development ◽  
Lithium Nitrate ◽  
Early Hydration ◽  
The Impact

The effectiveness of lithium nitrate as a chemical additive which reduces the negative effects of alkali aggregate reaction was subject to research by scientists in many centres around the world. The literature data on the impact of lithium nitrate on the physical and mechanical properties of cements are rare. Without a precise definition of the impact of lithium nitrate on the cement properties, it is extremely hard to determine its real advantages in practical usage. In this paper, studies were undertaken to assess the impact of LiNO3 on the properties of pastes and mortars with Portland cement. The rate of hydration of the cement with lithium additive was examined by isothermal calorimetry, measurements of setting time and phase composition of cement pastes in the initial stages of hydration. The influence of the admixture on the compressive strength development of mortars after 2, 7 and 28 days of hardening was also researched. Results indicate that lithium nitrate accelerates the early hydration of Portland cement, affecting the precipitation of hydration products. The compressive strength of mortars with lithium admixture decrease after 28 days, although 2 an 7-day strength were greater than the control mortars.

Sign in / Sign up

Export Citation Format

Share Document