scholarly journals Matrix Method for X-Ray Stress Measurement in Single Crystals, and the Rational Planning of the Measurements

2014 ◽  
Vol 996 ◽  
pp. 58-63
Author(s):  
Balder Ortner
Keyword(s):  
Single Crystals ◽  
Matrix Method ◽  
Stress Measurement ◽  
X Ray Diffraction ◽  
X Ray ◽  
Stress Calculation ◽  
Rational Planning ◽  
The Matrix ◽  
Experimental Effort

With the so-called matrix method stress calculation from x-ray diffraction measurements is much easier than it used to be with older methods. The matrix method is also well suited to optimize the choice of reflections (hkl) to be measured in order to obtain the best results with least experimental effort. Pseudocodes for the stress calculation are given.

Two-Dimensional X-Ray Diffraction for Structure and Stress Analysis

2005 ◽  
Vol 490-491 ◽  
pp. 1-6 ◽  
Author(s):  
Bob B. He ◽  
Ke Wei Xu ◽  
Fei Wang ◽  
Ping Huang
Keyword(s):  
Stress Analysis ◽  
Stress Measurement ◽  
Unit Vector ◽  
Sample Space ◽  
Matrix Transformation ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Texture Measurement ◽  
X Ray ◽  
The Matrix

This paper introduces the recent progress in two-dimensional X-ray diffraction as well as its applications in microstructure and residual stress analysis. Based on the matrix transformation between diffraction space, detector space and sample space, the unit vector of the diffraction vector can be expressed in the sample space corresponding to all the geometric parameters and Bragg conditions. The same transformation matrix can be used for texture and stress analysis. The fundamental equations for both stress measurement and texture measurement are developed with the matrix transformation defined for the two-dimensional diffraction. Stress measurement using twodimensional detector is based on a direct relationship between the stress tensor and the diffraction cone distortion. The two-dimensional detector collects texture data and background values simultaneously for multiple poles and multiple directions.

The Matrix Method for Data Evaluation and its Advantages in Comparison to the Sin2ψ and Similar Methods

2011 ◽  
Vol 681 ◽  
pp. 7-12 ◽  
Author(s):  
Balder Ortner
Keyword(s):  
Matrix Method ◽  
Stress Measurement ◽  
Data Evaluation ◽  
Traditional Methods ◽  
X Ray ◽  
Data Treatment ◽  
The Matrix

This article gives an overview of different methods for data treatment in x-ray stress measurement, and how these methods should be replaced with the matrix method, which in general is more versatile, more accurate and, in most cases, also easier to handle. It also shows how much the accuracy could be improved by replacing the traditional methods with the matrix method.

Dependence of Stress Constant on Microstructure of Quenched and Tempered Steels in X-Ray Stress Measurement

1991 ◽  
Vol 35 (A) ◽  
pp. 519-525
Author(s):  
Masanori Kurita ◽  
Akira Saito
Keyword(s):  
Residual Stress ◽  
Stress Measurement ◽  
Practical Importance ◽  
Carbon Steels ◽  
X Ray Diffraction ◽  
Tempered Martensite ◽  
Tempering Temperature ◽  
X Ray ◽  
The Matrix ◽  
High Residual Stress

AbstractThe residual stress measurement of quenched and tempered steels is of practical importance because the quenching can sometimes induce the high residual stress which affects the strength of materials. The stress constants of carbon steels quenched and tempered at various temperatures were measured in order to determine the residual stress of steels by x-ray diffraction. The stress constant increased slowly with increasing tempering temperatures below 500°C; it increased rapidly with tempering temperatures above about 500°C, This rapid increase in the stress constant is closely related to the change in microstructure of the steels in tempering; above the tempering temperature of around 500°C, the tempered martensite recrystallized and transformed to ferritic iron and fine cementite particles dispersed in the matrix; these coalesced and grew to be speroidized cementites and finally laminar cementite plates.

Effect of trytophan as dopant on potassium acid phthalate single crystals

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Single Crystals ◽  
Room Temperature ◽  
Visible Region ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Evaporation Technique ◽  
Absorption Studies ◽  
Evaporation Technique ◽  
Potassium Acid Phthalate ◽  
Acid Phthalate

Optically transparent single crystals of potassium acid phthalate (KAP, 0.5 g) 0.05 g and 0.1 g (1 and 2 mol %) trytophan were grown in aqueous solution by slow evaporation technique at room temperature. Single crystal X- ray diffraction analysis confirmed the changes in the lattice parameters of the doped crystals. The presence of functional groups in the crystal lattice has been determined qualitatively by FTIR analysis. Optical absorption studies revealed that the doped crystals possess very low absorption in the entire visible region. The dielectric constant has been studied as a function of frequency for the doped crystals. The thermal stability was evaluated by TG-DSC analysis.

scholarly journals Some Novel Cobalt Diphenylphosphine Complexes: Synthesis, Characterization, and Behavior in the Polymerization of 1,3-Butadiene

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4067
Author(s):  
Giovanni Ricci ◽  
Giuseppe Leone ◽  
Giorgia Zanchin ◽  
Benedetta Palucci ◽  
Alessandra Forni ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Single Crystals ◽  
The Novel ◽  
X Ray Diffraction ◽  
X Ray ◽  
And Behavior

Some novel cobalt diphenylphosphine complexes were synthesized by reacting cobalt(II) chloride with (2-methoxyethyl)diphenylphosphine, (2-methoxyphenyl)diphenylphosphine, and 2-(1,1-dimethylpropyl)-6-(diphenylphosphino)pyridine. Single crystals suitable for X-ray diffraction studies were obtained for the first two complexes, and their crystal structure was determined. The novel compounds were then used in association with methylaluminoxane (MAO) for the polymerization of 1,3-butadiene, and their behavior was compared with that exhibited in the polymerization of the same monomer by the systems CoCl2(PnPrPh2)2/MAO and CoCl2(PPh3)2/MAO. Some significant differences were observed depending on the MAO/Co ratio used, and a plausible interpretation for such a different behavior is proposed.

scholarly journals Statistical analysis of the reproducibility of residual stress measurements in cold extruded parts

2021 ◽  
Author(s):  
Fabian Jaeger ◽  
Alessandro Franceschi ◽  
Holger Hoche ◽  
Peter Groche ◽  
Matthias Oechsner
Keyword(s):  
Residual Stress ◽  
Statistical Analysis ◽  
Stress Measurement ◽  
Industrial Applications ◽  
Cold Extrusion ◽  
X Ray Diffraction ◽  
Forming Process ◽  
X Ray ◽  
Stress States ◽  
Key Aspects

AbstractCold extruded components are characterized by residual stresses, which originate from the experienced manufacturing process. For industrial applications, reproducibility and homogeneity of the final components are key aspects for an optimized quality control. Although striving to obtain identical deformation and surface conditions, fluctuation in the manufacturing parameters and contact shear conditions during the forming process may lead to variations of the spatial residual stress distribution in the final product. This could lead to a dependency of the residual stress measurement results on the relative axial and circumferential position on the sample. An attempt to examine this problem is made by the employment of design of experiments (DoE) methods. A statistical analysis of the residual stress results generated through X-Ray diffraction is performed. Additionally, the ability of cold extrusion processes to generate uniform stress states is analyzed on specimens of austenitic stainless steel 1.4404 and possible correlations with the pre-deformed condition are statistically examined. Moreover, the influence of the coating, consisting of oxalate and a MoS2 based lubricant, on the X-Ray diffraction measurements of the surface is investigated.

scholarly journals Growth of sillenite Bi12FeO20 single crystals: structural, thermal, optical, photocatalytic features and first principle calculations

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Durga Sankar Vavilapalli ◽  
Ambrose A. Melvin ◽  
F. Bellarmine ◽  
Ramanjaneyulu Mannam ◽  
Srihari Velaga ◽  
...  
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Photoelectron Spectroscopy ◽  
Diffraction Method ◽  
Lattice Parameter ◽  
First Principle ◽  
X Ray Diffraction ◽  
X Ray ◽  
First Principle Calculations ◽  
Photodegradation Efficiency

AbstractIdeal sillenite type Bi12FeO20 (BFO) micron sized single crystals have been successfully grown via inexpensive hydrothermal method. The refined single crystal X-ray diffraction data reveals cubic Bi12FeO20 structure with single crystal parameters. Occurrence of rare Fe4+ state is identified via X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The lattice parameter (a) and corresponding molar volume (Vm) of Bi12FeO20 have been measured in the temperature range of 30–700 °C by the X-ray diffraction method. The thermal expansion coefficient (α) 3.93 × 10–5 K−1 was calculated from the measured values of the parameters. Electronic structure and density of states are investigated by first principle calculations. Photoelectrochemical measurements on single crystals with bandgap of 2 eV reveal significant photo response. The photoactivity of as grown crystals were further investigated by degrading organic effluents such as Methylene blue (MB) and Congo red (CR) under natural sunlight. BFO showed photodegradation efficiency about 74.23% and 32.10% for degrading MB and CR respectively. Interesting morphology and microstructure of pointed spearhead like BFO crystals provide a new insight in designing and synthesizing multifunctional single crystals.

scholarly journals Modeling of magneto-conductivity of bismuth selenide: a topological insulator

2021 ◽  
Vol 3 (4) ◽  
Author(s):  
Yogesh Kumar ◽  
Rabia Sultana ◽  
Prince Sharma ◽  
V. P. S. Awana
Keyword(s):  
Magnetic Field ◽  
Magnetic Fields ◽  
Single Crystal ◽  
Single Crystals ◽  
X Ray Diffraction ◽  
Field Range ◽  
X Ray ◽  
Bulk Carriers ◽  
Different Temperatures

AbstractWe report the magneto-conductivity analysis of Bi2Se3 single crystal at different temperatures in a magnetic field range of ± 14 T. The single crystals are grown by the self-flux method and characterized through X-ray diffraction, Scanning Electron Microscopy, and Raman Spectroscopy. The single crystals show magnetoresistance (MR%) of around 380% at a magnetic field of 14 T and a temperature of 5 K. The Hikami–Larkin–Nagaoka (HLN) equation has been used to fit the magneto-conductivity (MC) data. However, the HLN fitted curve deviates at higher magnetic fields above 1 T, suggesting that the role of surface-driven conductivity suppresses with an increasing magnetic field. This article proposes a speculative model comprising of surface-driven HLN and added quantum diffusive and bulk carriers-driven classical terms. The model successfully explains the MC of the Bi2Se3 single crystal at various temperatures (5–200 K) and applied magnetic fields (up to 14 T).

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