The Preparation of Flexible Substrate Using BaTiO3/Polymer Composites for Application in High Frequency Devices

2012 ◽  
Vol 512-515 ◽  
pp. 1142-1145 ◽  
Author(s):  
Chien Min Cheng ◽  
Kai Huang Chen ◽  
Yuan Tai Hsieh ◽  
Fuh Cheng Jong

BaTiO3/ which has good dielectric properties, they were widely used in ceramic capacitors, thermistors, etc. In this study, BaTiO3/ ceramics prepared by sol-gel powder, then mixed in the organic polymer polyether imide (PEI) and dispersant (surface active agents) and silane coupling agent (Silane Coupling Agent) of the composite material on flexible substrates, And analysis of its properties and electrical properties. Increase by a ceramic powder, to explore the impact of the substrate. In the physical analysis is used XRD, SEM to measure the intensity of crystalline phase and surface uniformity of the electrical measurement using HP4294 measuring dielectric constant and dielectric loss.

2012 ◽  
Vol 200 ◽  
pp. 321-324 ◽  
Author(s):  
Zhao Xia Wang ◽  
De Gao ◽  
Wen Cai Xu

Mechanical properties of the calcium-plastic composite have a great influence on the containers. The main factors affecting the mechanical properties are the process and material formulations. This paper mainly describes its impact of the addition of coupling agent. Under the usage of analysis of variance on single factor experiment, the mechanical properties of the calcium carbonate-plastic composite with three different coupling agents (silane, titanate and aluminate) were studied in the same test conditions. The results show that: The type and quantity of the coupling agent effect a lot on the mechanical properties of the composite. The silane coupling agent is the most suitable for calcium carbonate-plastic composite packaging materials, and the compatibility of calcium carbonate and polyethylene can be improved. When the silane coupling agent was at a 2.25 wt. % concentration, the tensile and flexural strength were improved obviously, especially the tensile strength increased by 23.24%, but the impact strength improved slightly.


2004 ◽  
Vol 829 ◽  
Author(s):  
Norio Murase ◽  
Chunliang Li

ABSTRACTPhotoluminescence (PL) efficiency of thioglycolic-acid (TGA)-stabilized CdTe nanocrystals in water depends strongly on the amount of TGA upon synthesis. The less the amount, the higher the PL efficiency obtained if the colloid is not precipitated. When the molar ratio of TGA against Cd2+ upon preparation is ca. 1.3, PL efficiency of as-prepared solution becomes the maximum and exceeds 60% in red-emitting region. In this case, the spectral widths of the PL become the minimum. We have encapsulated these highly luminescent nanocrystals into glass matrices by using a sol-gel method. Silane coupling agent having an amino-group is effective to preserve the surface of the nanocrystals. The glass thus prepared is stable and shows PL efficiency as high as 40%.


2012 ◽  
Vol 622-623 ◽  
pp. 420-425
Author(s):  
Alex Kwasi Kumi ◽  
Allan Chelashaw ◽  
Yu Mei Zhang ◽  
Li Feng Li

Ceramic coatings based on sol-gel method have increasingly gained much attention in recent times. In order to ascertain important experimental factors (variables) influencing surface properties, such as adhesion, pencil hardness and advancing contact angle (non-stick) of sol coatings, a 26-1-factorial screening design with six experimental variables, precursor mole ratio, low surface energy polymer concentration, silane coupling agent (SCA) concentration, silica nanoparticles concentration (SNP’s),curing temperature and three responses ( surface properties) were investigated. The results indicate that silane coupling agent concentration, SNP’s concentration and their interaction were the most significant experimental factors influencing advancing contact angle. None of the experimental factors studied were statistically significant with respect to hardness and adhesion.


Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 947 ◽  
Author(s):  
Min Wu ◽  
Xuetong Tong ◽  
Hui Wang ◽  
Lin Hua ◽  
Yizhe Chen

Adhesive bonding is widely used in the joining of metals and carbon fiber-reinforced plastics (CFRPs). Ultrasonic vibration was used to improve adhesive bonding of CFRP/Al alloy joints grafted with silane coupling agent, and the effect of the ultrasound on the bonding was studied. The surface of Al alloy was treated with a silane coupling agent, and then the ultrasonic vibration was applied on the adherend during the adhesive bonding process. The shear strength was tested, and the mechanism was analyzed by scanning electron microscope (SEM) and Fourier transform infrared spectrometer (FTIR). It is found that the ultrasonic assisting can further promote the bonding of the Al alloy and the adhesive. For the test joins, the shear strength was increased by 267.50% using the silanization treatment plus the ultrasonic assisting. The ultrasonic assisting promoted the grafted epoxy group to react with the adhesive more sufficiently at the Al/adhesive interface by causing micro-mixing and intensified molecule collision, and thus more chemical bond was formed. Under the ultrasonic action, the interface and the adhesive layer became tighter owing to the impact contact at the interface and the oscillating flow in the adhesive layer. The ultrasonic vibration assisting increased the bonding strength by promoting the chemical bond and improving physical morphology.


2015 ◽  
Vol 731 ◽  
pp. 476-480
Author(s):  
Zheng Jian Zhang ◽  
Li Ying Yang ◽  
Shi Liang Zhu ◽  
Hai Ying Yang

Using UV inkjet printing can achieve three-dimensional printing of ceramic materials, but there is low ink adhesion, easy to fall off and other issues, surface coated modification to high smoothness ceramic materials can solve the above problems [1]. In this study, the silane coupling agent, adhesive, resin and other raw materials prepared for transparent coating, which applied to the surface of the ceramics. The impact of process parameters and coating formulation on the UV print quality of the ceramic base was systematic analyzed, the result shows that the volume concentration of 10% KH550 silane coupling agent as primer, and using 20wt% 102 multipurpose plastic glue for surface coating, better ink adhesion and printing quality can be obtained.


2014 ◽  
Vol 1004-1005 ◽  
pp. 51-54
Author(s):  
Su Zhao ◽  
Sha Sha Liu ◽  
Yan Jun Guo ◽  
Wei Wei

In order to prepare high reflectivity titanium dioxide, by sol - gel method after nano-titanium dioxide powder, which silane coupling agent KH-570 covering it and make its surface modification.When the reaction temperature is 40 °C, drop accelerated rate 1.5mL/min, calcination temperature about 600 °C, got titanium dioxide with relatively high reflectivity and particle size in around 65 nm.When the amount of the silane coupling agent is 0.5%, the pH of reaction system is 6.5, and the reaction time was 1.5h, the nano-modified titanium dioxide particles with high reflectance.


2010 ◽  
Vol 105-106 ◽  
pp. 104-107 ◽  
Author(s):  
Zhi Qi Zhuo ◽  
Li Min Dong ◽  
Cheng Wang ◽  
Qing Feng Zan ◽  
Jie Mo Tian

This paper focuses on the influence on the mechanical properties of hydroxyapatite / poly-hydroxybutyrate (HA / PHB) composites by different HA contents, and the effect of Silane coupling agent on improving the interface of HA/PHB composite materials. The HA/PHB composites were prepared by ball milling, hot-pressing, the HA content were 0, 5, 10, 15, 20 and 30wt%, respectively. Silane coupling agent was used for HA surface treatment in HA/PHB composites to compare with not having HA surface treatment in HA/PHB composite materials. The impact strength and flexural strength of HA / PHB composites were tested, and the microstructure of the fracture surface was observed by SEM. The results showed that HA could enhance the bending strength of HA/PHB composites. With HA content increased, the bending strength increased first and then decreased, when the HA content was 10wt%, the maximum bending strength reached 32.74MPa, increased about 41% comparing with pure PHB. Silane coupling agent can improve the interface of HA / PHB, then enhance the mechanical strength. When the HA content was 15wt%, the maximum bending strength reached 46.6MPa, Increased about 56% comparing with the same proportion of untreated HA/PHB composite material, and about double comparing with pure PHB.


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