Processing Changes of Cement Based Composites Reinforced with Silane and Isocyanate Eucalyptus Modified Fibres

2012 ◽  
Vol 517 ◽  
pp. 437-449
Author(s):  
Gustavo Henrique Denzin Tonoli ◽  
M.N. Belgacem ◽  
G. Siqueira ◽  
J. Bras ◽  
Lourival M. Mendes ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Water Retention ◽  
Cement Matrix ◽  
Cement Composites ◽  
Cellulose Fibres ◽  
Dimensional Changes ◽  
Cellulose Pulp ◽  
Pulp Fibres ◽  
Fibre Cement ◽  
Dimensional Instability

Fibre-cement products had been widely used in the world due to their versatility as corrugated and flat roofing materials, cladding panels and water containers presented in large number of building and agriculture applications. The main reason for incorporating fibres into the cement matrix is to improve the toughness, tensile strength, and the cracking deformation characteristics of the resultant composite. One of the drawbacks associated with cellulose fibres in cement application is their dimensional instability in the presence of changing relative humidity. The objective of the present work is to evaluate the effect of surface treatment of eucalyptus cellulose pulp fibres on the processing and dimensional changes of fibre-cement composites. Surface modification of the cellulose pulps was performed with methacryloxypropyltri-methoxysilane (MPTS), aminopropyltri-ethoxysilane (APTS) and n-octadecyl isocyanate, an aliphatic isocyanate (AI), in an attempt to improve their dimensional instability into fibre-cement composites. X-ray photoelectron spectroscopy (XPS) showed the chemical changes occurred at the surface, and contact angle measurements showed the changes in the surface energy. MPTS-and AI-treated fibres presented lower hydrophilic character than untreated fibres, which led to lower water retention values (WRV). APTS increased the water retention value of the pulp and improved the capacity of hydrogen bonding of the fibres. MPTS-and AI-treated fibres led to low final water/cement ratios and reduced volume changes after pressing. MPTS-treated fibres decreased the water and dimensional instability of the fibre-cement composites, while the contrary occurred with APTS-modified and AI-modified fibres.These results are promising and contribute for new strategy to improve processing and stability of natural fibres-reinforced cement products.

Isocyanate-treated cellulose pulp and its effect on the alkali resistance and performance of fiber cement composites

Holzforschung ◽  
2013 ◽  
Vol 67 (8) ◽  
pp. 853-861 ◽  
Author(s):  
Gustavo Henrique Denzin Tonoli ◽  
Rafael F. Mendes ◽  
Gilberto Siqueira ◽  
Julien Bras ◽  
Mohamed N. Belgacem ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Natural Fibers ◽  
Accelerated Aging ◽  
Cellulose Fiber ◽  
Modulus Of Rupture ◽  
Alkali Resistance ◽  
Cement Matrix ◽  
Cement Composites ◽  
Cellulose Pulp ◽  
The Impact

Abstract The impact of grafted surface of cellulose fibers on the mechanical and physical properties of fiber-cement composites (FCC) has been investigated. The grafting was performed with n-octadecyl isocyanate [i.e., with an aliphatic isocyanate (AI)], with the intention to protect the cellulose fiber from alkali degradation in the cement matrix. The chemical changes, observed by contact angle measurements and X-ray photoelectron spectroscopy, showed a higher hydrophobic character of AI-treated fibers. The strength of FCC was tested during 28 days of curing treatment. The extracted AI-treated fibers contributed to higher specific energy and final specific deflection after accelerated aging cycles in comparison with the reference composites reinforced with untreated fibers. The higher values of limit of proportionality and modulus of elasticity for composites with AI-treated fibers are an evidence of the densification of the fiber-matrix transition zone. The modulus of rupture values were higher for composites with AI-treated and Soxhlet-extracted fibers after 200 soak and dry aging cycles. In comparison with the reference, AI-treated fibers decreased the water absorption and the apparent porosity of the FCC. The modification of fibers could be a new strategy to improve the performance and stability of cement products reinforced with natural fibers.

scholarly journals Characterization of cement composites based on recycled cellulosic waste paper fibres

2018 ◽  
Vol 8 (1) ◽  
pp. 363-367 ◽  
Author(s):  
Nadezda Stevulova ◽  
Viola Hospodarova ◽  
Vojtech Vaclavik ◽  
Tomas Dvorsky ◽  
Tomas Danek
Keyword(s):  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Waste Paper ◽  
Strength Parameter ◽  
Hardened Cement ◽  
Cement Composites ◽  
Cellulose Fibres ◽  
Wood Processing ◽  
Fibre Cement ◽  
Cellulosic Fibres

AbstractNowadays, there is paying an attention to the utilization of natural, renewable and biodegradable resources of raw materials of lignocellulosic character, residues from agricultural crops and wood processing as well as waste from papermaking industry in building composite materials preparing. Also recycled fibres coming from waste paper are considered as valuable material. The objective of this study is to utilize these recycled cellulosic fibres into cement composites and characterise their impact on resulting physical and mechanical properties of fresh and hardened cement composites. Manufactured cement composites contained 0.2%, 0.3% and 0.5% addition of cellulosic fibres. In fresh fibre cement mixtures reduction in workability with increasing amount of cellulose fibres was noticed. Density as well as compressive and flexural strength of 28 and 90 days hardened fibre cement composites was tested. Distribution of cellulosic fibres with 0.5% addition in hardened fibre cement composites was also observed. The results of density determination of 28 and 90 days hardened fibre cement composites showed reduction in their values related to weight lighter concretes. Compressive strengths of fibre cement composites have shown decreasing character with increasing added amount of cellulosic fibres into the mixture up to 0.5%. Maximal decrease in compressive strength values was observed in composites containing 0.5% of cellulosic fibres. However, obtained strength parameter values of hardened composites had satisfying results for their application in construction as non-load bearing building material.

Non-Destructive and Destructive Monitoring Methods of Fibre Concrete Homogeneity

2017 ◽  
Vol 259 ◽  
pp. 9-14 ◽  
Author(s):  
René Čechmánek ◽  
Martina Drdlová ◽  
Martin Bohac
Keyword(s):  
Cement Matrix ◽  
Fibre Reinforcement ◽  
Cement Composites ◽  
Monitoring Methods ◽  
Destructive Testing ◽  
Thin Sections ◽  
Wide Range ◽  
Fibre Cement ◽  
Non Destructive ◽  
Destructive Methods

Design, preparation and testing of fibre-cement composites are a task of wide range of research workplaces and universities in our country and abroad. However, a question on homogeneity of all cement matrix components and mainly optimal dispersion of fibre reinforcement in a mixture has not been yet solved sufficiently. Within testing of properties of such designed composites there is usually a realized fact, that variability of these properties is distinctive mainly for the reason of uneven dispersion of commonly used fibres in a whole matrix volume. Elimination of this phenomenon could be achieved by means of a design of the optimal homogenization process of dry mixture components with fibre reinforcement. The aim of research works was to find suitable homogenization techniques, design of mixing process and optimal dosing of individual components. By means of these actions it is possible to achieve the best dispersion of selected fibre types, both metal and non-metal, in fine-grained cementitious matrixes, which is subsequently verified in hardened composites at first by non-destructive and then by destructive methods. Four different fibre-cement mixtures were chosen as representatives for commonly used reinforcement in fibre-cement composites and test specimens with a thickness of 40 mm were prepared using processes suitable for the specific fibre reinforcement. At the first stage non-destructive testing by means of ultrasound waves was carried out at first on a compact test slab with dimensions 500 x 500 x 40 mm and subsequently on individual test specimens with dimensions 250 x 40 x 40 mm, cut from the test slab according to a designed pattern. At the second stage destructive testing of test specimens was performed, mainly evaluation of flexural strength with 4-point bending and subsequently preparation of thin sections from the failure area for observation by means of polarizing microscopy. A purpose of all these research works is finding of correlation between testing by means of destructive and non-destructive methods.

scholarly journals Effect of experimental wet and dry cycles on bamboo fibre reinforced acrylic polymer modified cement composites

2020 ◽  
Vol 29 (1) ◽  
pp. 86-93
Author(s):  
Banjo A. Akinyemi ◽  
Temidayo E. Omoniyi
Keyword(s):  
Dimensional Stability ◽  
Harmful Effect ◽  
Fibre Surface ◽  
Modulus Of Rupture ◽  
Cement Matrix ◽  
Cement Composites ◽  
Acrylic Polymer ◽  
Vegetable Fibre ◽  
Fibre Cement ◽  
Wet And Dry Cycles

AbstractThis study experimentally evaluated the effect of accelerated wet/dry cycles on the dimensional stability and some selected mechanical properties of polymer modified vegetable fibre cement composites. The bamboo fibres were pre-treated with 10% conc. of sodium hydroxide and varied from 0 – 2.0% while acrylic polymer admixture of 10% w/w of cement was added to improve the properties. The modified fibre-cement composites were subjected to 50 cycles of wet/dry processes to simulate natural weathering process of the environment. The samples were subjected to water absorption, thickness swelling, modulus of rupture (MOR) and modulus of elasticity (MOE) after 28 days of curing and aging cycles respectively using 5 replicates. One way ANOVA at p<0.05 was used to analyse the results. Scanning electron microscope (SEM) and Fourier Transformer Infrared Spectroscopy (FTIR) analyses were conducted on the samples. The results showed improvement of 33.3, 64, 71 and 57% in MOR and 135, 85, 101 and 188% in MOE for samples with 0.5, 1, 1.5 and 2% fibre inclusion after ageing tests. Significantly improved dimensional stability values were observed in this study in comparison with data from similar ageing tests conducted on unmodified vegetable fibre-cement matrix. SEM micrographs showed marginal increase in the size of the pores before and after ageing tests. FTIR analysis indicated increase in intensities during the ageing tests especially for spectra bands located at 3384 – 3520cm−1 which are denoted for OH vibration stretching as well as 1676, 1726 and 1794 cm−1 which depict the presence of carbonyl groups because of absorption of polymers to the fibre surface during the ageing cycles. The study has shown thatwet/dry ageing cycles showed less harmful effect on vegetable fibre cement composites provided the cement matrix is modified with polymer admixtures.

Bio-Corrosion of Fibrous Cement Boards and Cement Composites

2015 ◽  
Vol 227 ◽  
pp. 207-210
Author(s):  
Vlasta Ondrejka Harbuľáková ◽  
Adriana Eštoková ◽  
Alena Luptáková ◽  
Martina Kovalčíková
Keyword(s):  
Slovak Republic ◽  
Xrd Analysis ◽  
Cement Matrix ◽  
Cement Composites ◽  
Liquid Media ◽  
Abiotic Environment ◽  
X Ray ◽  
Fibre Cement ◽  
The Comparative Study ◽  
Surface Changes

The paper deals with the comparative study of bio-corrosion of fibrous cement boards and Portland cement composites. Fibre-cement flat boards are widely used materials in the Slovak Republic for exterior and interior cladding, as fibre-cement slates for roofing and cladding and as fibre-cement corrugated sheets for roofing and cladding. Bio-corrosion of studied materials has been simulated in laboratory conditions during 80 days. Effect of sulphur-oxidizing bacteria Acidithiobacillusthiooxidans on the specimens was investigated. The bio-deterioration processes have been manifested by leaching of main cement components as well as by surface changes. The calcium and silicon contents in leachates were evaluated during the experiments using X – ray fluorescence method (XRF). Concluding the results of the concrete’s biodeteriogens influence on the analyzed samples (fiber boards and cement composites) more extensive leaching of calcium ions from the cement matrix was confirmed as assumed by bacteria influence when compared to the abiotic environment. Mixture of white compounds on the samples surface was identified by SEM microscopy and XRD analysis as sulphate products (ettringite, thaumasite, gypsum). Shift of pH of liquid media to alkaline region up to 7.2 due to alkaline products leaching were noticed for all studied samples.

Effect of cellulose pulp fibres on the physical, mechanical, and thermal performance of extruded earth-based materials

2021 ◽  
Vol 39 ◽  
pp. 102259
Author(s):  
Tido Tiwa Stanislas ◽  
Josepha Foba Tendo ◽  
Ronaldo S. Teixeira ◽  
Emeso B. Ojo ◽  
Gbétoglo Charles Komadja ◽  
...  
Keyword(s):  
Thermal Performance ◽  
Cellulose Pulp ◽  
Pulp Fibres

scholarly journals Preparation and Mechanical Properties of Graphene Oxide: Cement Nanocomposites

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Fakhim Babak ◽  
Hassani Abolfazl ◽  
Rashidi Alimorad ◽  
Ghodousi Parviz
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Graphene Oxide ◽  
Cement Mortar ◽  
Cement Matrix ◽  
Cement Composites ◽  
Xrd Diffraction ◽  
Calcium Silicate Hydrates ◽  
The Matrix ◽  
Scanning Electron

We investigate the performance of graphene oxide (GO) in improving mechanical properties of cement composites. A polycarboxylate superplasticizer was used to improve the dispersion of GO flakes in the cement. The mechanical strength of graphene-cement nanocomposites containing 0.1–2 wt% GO and 0.5 wt% superplasticizer was measured and compared with that of cement prepared without GO. We found that the tensile strength of the cement mortar increased with GO content, reaching 1.5%, a 48% increase in tensile strength. Ultra high-resolution field emission scanning electron microscopy (FE-SEM) used to observe the fracture surface of samples containing 1.5 wt% GO indicated that the nano-GO flakes were well dispersed in the matrix, and no aggregates were observed. FE-SEM observation also revealed good bonding between the GO surfaces and the surrounding cement matrix. In addition, XRD diffraction data showed growth of the calcium silicate hydrates (C-S-H) gels in GO cement mortar compared with the normal cement mortar.

scholarly journals Application of the nanoindentation method in assessing of properties of cement composites modified with silica-magnetite nanostructures

2018 ◽  
Vol 163 ◽  
pp. 02002 ◽  
Author(s):  
Elzbieta Horszczaruk ◽  
Roman Jedrzejewski ◽  
Jolanta Baranowska ◽  
Ewa Mijowska
Keyword(s):  
Mechanical Properties ◽  
Magnetite Nanoparticles ◽  
Positive Influence ◽  
Cement Matrix ◽  
Core Shell ◽  
Indentation Modulus ◽  
Cement Composites ◽  
Interfacial Zone ◽  
Berkovich Indenter ◽  
The Core

The results of investigation of the cement composites modified with 5% of silica-magnetite nanostructures of the core-shell type are presented in the paper. The nanoindentation method employing three-sided pyramidal Berkovich indenter was used in the research. The mechanical properties and microstructure of the modified cement composites were evaluated on the basis of the values of hardness and indentation modulus measured inside the cement matrix and in the aggregate-paste interfacial zone. The results were compared with those obtained for the reference composites without nanostructures. The positive influence of the presence of silica-magnetite nanoparticles on the tested properties was found out.

scholarly journals Properties of cement composites based on limestone depending on their granulometric composition

Vestnik MGSU ◽  
2020 ◽  
pp. 999-1006
Author(s):  
Svetlana V. Samchenko ◽  
Olga V. Alexandrova ◽  
Anton Yu. Gurkin
Keyword(s):  
Composite Materials ◽  
Portland Cement ◽  
Granulometric Composition ◽  
Coarse Grained ◽  
Cement Matrix ◽  
Cement Composites ◽  
Construction Costs ◽  
Initial Strength ◽  
Fine Grained ◽  
Additional Formation

Introduction. The use of limestone in cement compositions as an additional cementing agent solves both environmental and economic problems, namely, reduction of construction costs. In this regard, the study of the properties of the granulometric composition and volumetric content of cement composites, containing limestone, becomes increasingly important. The mission of this research is to optimize the properties of composite materials containing Portland cement and limestone by changing the granulometric composition of flour limestone. Materials and methods. Limestone, having three different Blaine milling fineness values of 250, 300 and 450 m2/kg, was used; its content reached 10, 15, 25 and 35 %. Cement and sand mortars were applied for testing purposes. The influence of the granulometric composition of limestone on the workability and compressive strength of composite cement was determined. Results. The effect of limestone on the limit shear stress becomes more pronounced when the amount of limestone increases to 25 and 35 %. This is most noticeable for limestone with a high content of fine fractions of 5–20 µm. The use of finely milled limestone increases the initial strength of the composite material. By adding 10 and 15 % of such limestone we can increase the strength by 16–20 %, and supplementary 25–35 % of limestone increases strength by 5–8 %. Strength enhancement is due to the reactivity of limestone and formation of calcium hydrocarbon aluminate 3CaO∙Al2O3∙СаСО3∙12H2O, which promotes formation of the crystal framework of the cement matrix. Additional formation of crystalline hydrates in the initial coagulation structure deteriorates the mortar workability, but increases its strength. Conclusions. The use of coarse-grained limestone significantly improves mortar workability, while the use of fine-grained limestone increases its content without reducing its strength. The granulometric composition of ground limestone shall be as close as possible to the granulometric composition of cement for the properties of composite materials containing Portland cement and limestone to be optimized.

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