Rheological Study of Composite Materials Based on Thermosetting Matrix and Fillers Mineral

2013 ◽  
Vol 550 ◽  
pp. 79-84
Author(s):  
Amar Irekti ◽  
B. Bezzazi

In the development of composites materials, the matrix acts as a binder of different reinforcements can distribute the stress, provide good resistance to chemical structure and the desired shape to the final product. But there are still some drawbacks that arise in the physicochemical and mechanical properties of thermosetting matrices. Our job is to synthesize composite materials with news formulations of thermosetting matrices (Granitex products) by the incorporation of 40% of local mineral fillers. The latter give the matrix properties which it does not have, first, to reduce the cost of composite materials, and secondly, to improve implementation by increasing the viscosity and reducing the withdrawal to its minimum value. Rheological testing of mixtures prepared is made on the cone-plate viscometer, or the sample undergoes a shear in the conical space between the plane and the cone. The geometry of the cone - package ensures constant velocity gradient throughout the volume. The rheograms obtained, represents the evolution of the shear stress as a function of shear rate of resin mixtures containing 35% of mineral filler (pozzolan). The mineral filler increases significantly in rheological parameters, whatever the nature of the mineral filler. Compared to the control without charges, an increase of 60% of the shear stress and that of plastic viscosity were recorded for the epoxy resin. The software Rheowine viscometer, enabled us to model and identified the rheological behavior of these mixed with resin. The results obtained in this modeling, confirmed that the resin mixtures have shear-thinning rheological behavior and their behavior follows the model of the Ostwald of Waele.

Author(s):  
Dayane Izidoro ◽  
Maria-Rita Sierakowski ◽  
Nina Waszczynskyj ◽  
Charles W. I. Haminiuk ◽  
Agnes de Paula Scheer

The effects of ingredients on the sensory evaluation and rheological behavior of two brands of mayonnaise were examined in this work. Mayonnaise samples were examined by Analytical Descriptive Test and Ranking Test of Preference. The rheological parameters were determined at 25°C using a concentric cylinder Brookfield rheometer with a spindle SC4-34. The results showed that standard mayonnaise as opposed to low-fat mayonnaise gained higher grades for most sensory attributes. All samples were found to exhibit non-Newtonian pseudoplastic behavior described by Herschel–Bulkley model. A decrease in the yield stress, viscosity and shear stress with the decrease in oil content was observed in all products, which confirm that the rheological characterization is capable of distinguishing rather well between mayonnaises made with different formulation.


Author(s):  
Charles Windson Isidoro Haminiuk ◽  
Giselle M. Maciel ◽  
Manuel Salvador Vicente Plata-Oviedo ◽  
Alessandra Quenehenn ◽  
Agnes P Scheer

In this work the rheological behavior of two varieties of honey were evaluated using a Brookfield viscometer R.V.T in a temperature range of 5-20°C. In order to interpret the experimental results in terms of viscosity, the torque-speed data and scale readings were converted into shear stress-shear rate relations using numerical conversion values proposed by Mitschka. This method offers excellent potential for quality control testing in the food industry. Samples exhibited Newtonian behavior and the temperature effect on the viscosity followed an Arrhenius-type relationship.


2013 ◽  
Vol 401-403 ◽  
pp. 602-605
Author(s):  
Li Jun Zhu ◽  
Kai Wen Tian ◽  
Wen Lu Shi ◽  
Chao Yang ◽  
Zhen Ming Wang ◽  
...  

The effect of yield strength and elastic modulus of matrix on shear stress in two phases of composite reinforced with W fiber under pulse loading was simulated by ANSYS software. The results show that the effect of mechanical properties of matrix on composite should be taken into consideration in designing composite. The matrix with high yield strength and low elastic modulus can reduce the shear stress in W fiber, and is beneficial to keeping the integrity of W fiber during penetration, thus resulting in the improvement of penetration capacity.


2001 ◽  
Vol 10 (6) ◽  
pp. 096369350101000 ◽  
Author(s):  
N. E. Zafeiropoulos ◽  
C. A. Baillie ◽  
F. L. Matthews

In recent years there has been an increasing interest in using natural fibres as potential reinforcements for polymers. It is well known that the properties of composite materials are controlled by the properties of the matrix and the fibre, as well as of the interface. The most usual methods of strengthening the interface involve the application of surface modification methods on the fibres, or the application of compatibilisers in the matrix. However, it may be possible that one may achieve similar results just by simply controlling the processing conditions, and thus avoiding the application of chemicals that tend to increase the cost. In the present study the effect of cooling rates upon the interface in flax fibre/iPP composites was investigated by means of fragmentation tests. It was found that slower cooling leads to a stronger interface for two different grades of flax fibres; dew retted and green flax.


2013 ◽  
Vol 550 ◽  
pp. 49-56
Author(s):  
B. Boukert ◽  
A. Benkhedda ◽  
S. Bergheul

In recent years composite materials are widely used in the aerospace industry. The advantages of these materials are derived from their high strength, rigidity and lightness. More importantly, they have the potential to reduce the cost of construction, while improving structural reliability and increasing safety. Aircraft structural parts made of composite materials with polymeric matrix, subject to variables conditions and severe environments, require a good knowledge of their behavior under humidity and temperature. The matrix is very sensitive to these parameters. A degradation of properties is then observed [1-1.


Author(s):  
A. I. Belousov

The main objective of this paper is to prove a theorem according to which a method of successive elimination of unknowns in the solution of systems of linear equations in the semi-rings with iteration gives the really smallest solution of the system. The proof is based on the graph interpretation of the system and establishes a relationship between the method of sequential elimination of unknowns and the method for calculating a cost matrix of a labeled oriented graph using the method of sequential calculation of cost matrices following the paths of increasing ranks. Along with that, and in terms of preparing for the proof of the main theorem, we consider the following important properties of the closed semi-rings and semi-rings with iteration.We prove the properties of an infinite sum (a supremum of the sequence in natural ordering of an idempotent semi-ring). In particular, the proof of the continuity of the addition operation is much simpler than in the known issues, which is the basis for the well-known algorithm for solving a linear equation in a semi-ring with iteration.Next, we prove a theorem on the closeness of semi-rings with iteration with respect to solutions of the systems of linear equations. We also give a detailed proof of the theorem of the cost matrix of an oriented graph labeled above a semi-ring as an iteration of the matrix of arc labels.The concept of an automaton over a semi-ring is introduced, which, unlike the usual labeled oriented graph, has a distinguished "final" vertex with a zero out-degree.All of the foregoing provides a basis for the proof of the main theorem, in which the concept of an automaton over a semi-ring plays the main role.The article's results are scientifically and methodologically valuable. The proposed proof of the main theorem allows us to relate two alternative methods for calculating the cost matrix of a labeled oriented graph, and the proposed proofs of already known statements can be useful in presenting the elements of the theory of semi-rings that plays an important role in mathematical studies of students majoring in software technologies and theoretical computer science.


2011 ◽  
Vol 233-235 ◽  
pp. 1998-2001 ◽  
Author(s):  
Ming Zhao ◽  
Xiao Zhong Lu ◽  
Kai Gu ◽  
Xiao Min Sun ◽  
Chang Qing Ji

The rheological behavior of PA6/montmorillonite(MMT) by reactive extrusion was investigated using cone-and-plate rheometer. The experimental results indicated that PA6/MMT exhibited shear-thinning behavior. The shear stress of both neat PA6 and PA6/MMT increased with the increase in the shear rate. The reduction of the viscous activation energy with the increase of shear stress reflected PA6/MMT can be processed over a wider temperature.


2011 ◽  
Vol 311-313 ◽  
pp. 1535-1538 ◽  
Author(s):  
Hong Juan Wang ◽  
Hai Yan Xiao ◽  
Feng Qiang Sun ◽  
Jian Hua Zhang

Novel bio-based composites were developed from maleate castor oil (MACO) and lignin through free radical initiated copolymerization between MACO and diluent monomer styrene(St). The morphology and structure of the composites were characterized by Fourier transform infrared spectroscope (FTIR) and scanning electron microscope (SEM). The mechanical and thermal behaviors of the composites were investigated, which showed the incorporation of a little of lignin in the castor oil based polymer can enhance the tensile properties of the matrix polymer greatly. This work provides a facile route to prepare bio-based composite materials from castor oil and lignin and can be extended to prepare other bio-based materials from reproducible resources.


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