Effect of Plasticizing Admixtures on the Development of Hydration Temperatures and the Properties of Cement Pastes

2018 ◽  
Vol 761 ◽  
pp. 116-119
Author(s):  
Martin Sedlmajer ◽  
Jiri Zach ◽  
Jitka Hroudova

The hydration of cement is a very intricate process. A great amount of heat is generated during the reaction, which requires close monitoring especially in large concrete members. Modified cement pastes are simpler systems and can be easily used to observe the effect of plasticizing admixtures on the development of temperatures during cement hydration as well as its rheology and mechanical properties. Knowledge of the development of hydration temperatures can be of assistance in deliberate regulation of cement hydration and the generation of hydration heat. The paper describes what influence different amounts of different plasticizers have on the properties of cement pastes, with added focus on the development of their hydration temperatures, rheology and compressive strength.

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Chunhua Feng ◽  
Libo Wang ◽  
Wenyan Zhang

Delaminated MXene was incorporated into cement to improve the properties of cement composites, and its effects on the hydration process, microstructures, and mechanical properties were investigated, respectively. The investigation results showed that delaminated MXene was well-dispersed in the cement matrix and significantly reinforced the compressive strength of cement, especially when the addition is 0.01 wt%. Meanwhile, the total hydration heat of cement hydration and the quantity of hydration products were increased with the addition of delaminated MXene. In addition, the formation of HD C-S-H gel was promoted, and the microstructure of hydrated cement became more compact.


Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3753 ◽  
Author(s):  
Yahui Wang ◽  
Jiawen Yang ◽  
Dong Ouyang

The effects of the water–binder ratio and different graphene oxide (GO) sizes on the mechanical properties of GO-cement composites were systematically studied by preparing GO-cement mortars. The scanning electron microscopy observation (SEM) of the surface and fracture surface of cement pastes was carried out to study the morphology of cement hydration crystals in GO-cement systems under different space conditions. It was found that GO nanosheets significantly improved the compressive, flexural, and tensile strengths of cement mortars. When the dosage of GO nanosheets was 0.03% by weight of cement, the compressive, flexural, and tensile strengths at 28 days increased by 21.37%, 39.62%, and 53.77%, respectively, but GO was not found to be able to regulate the formation of flower-like cement hydration crystals. It was only shown that the growth space had an important influence on the morphology of hydrates. A possible working mechanism was proposed by which GO nanosheets prevented the expansion of microcracks in the cement pastes via a shield effect, thus enhancing the strength and toughness of the cement composites.


2014 ◽  
Vol 629-630 ◽  
pp. 91-95
Author(s):  
Qian Qian Zhang ◽  
Jian Zhong Liu ◽  
Wei Lin

Nanotechnology is being used in UHPC for achieving more dense structural packing and better physical and mechanical properties. In this paper, nanosilica particles (0-1wt %) by cement were incorporated in cement pastes and mortars with water-binder ratio of 0.2, and their effect on fresh properties was addressed. The fresh properties of mixtures were investigated by spread, rheology and cohesiveness. In addition, effect of nanosilica on cement hydration was also investigated. The results show that significant increase of yield stress, viscosity and cohesiveness is observed with nanosilica above 0.005 wt% by cement, but nanosilica with content below 0.005% presents an improvement of workability especially with content of 0.002%. Moreover, the addition of nanosilica in cement pastes obviously accelerates the early cement hydration rate, but does not increase the cumulative heat evolution.


2017 ◽  
Vol 1144 ◽  
pp. 54-58
Author(s):  
Zdeněk Prošek ◽  
Karel Šeps ◽  
Jaroslav Topič

This article was focused on the influence of the micronized waste marble powder on mechanical properties of cement pastes. Resulting blended cement was composed of Portland cement CEM I 42.5 R and micronized marble powder with different percentage amounts (0 wt. %, 5 wt. %, 10 wt. % and 15 wt. %). Testing was carried at prismatic samples of dimension 40 × 40 × 160 mm. The investigated mechanical properties were dynamic modulus of elasticity, dynamic shear modulus, flexural strength and compressive strength for the 28 days old samples. The results obtained from these materials were compared with reference material.


2016 ◽  
Vol 51 (17) ◽  
pp. 2491-2503 ◽  
Author(s):  
Roukaya Mejdoub ◽  
Halim Hammi ◽  
Joan Josep Suñol ◽  
Mohamed Khitouni ◽  
Adel M‘nif ◽  
...  

Nanofibrillated cellulose from eucalyptus pulp, produced by high-pressure homogenization, was used as cement partial replacement for cement paste at a content ranging from 0% to 0.5% by weight of cement. The effect of the content of nanofibrillated cellulose on porosity, thermal properties, compressive strength and degree of cement hydration was investigated. Results have shown an improvement in the compressive strength by more than 50% with 0.3 wt% of added nanofibrillated cellulose. The porosity was reduced by nanofibrillated cellulose addition, and the greatest result was achieved with mixture incorporating 0.3 wt% nanofibrillated cellulose. The coefficient of thermal expansion and the thermal conductivity measurements, relative to nanofibrillated cellulose-reinforced cement pastes, have pointed out the reinforcement effectiveness of nanofibrillated cellulose. The degree of cement hydration has increased with nanofibrillated cellulose content. This trend was confirmed by X-ray diffraction and Fourier Transform Infrared spectroscopy. These analyses have revealed that the presence of nanofibrillated cellulose promoted the hydration of cement, by producing more portlandite and calcium silicate gel, which is likely the main reason accounting for the strong enhancement in the compressive strength.


2016 ◽  
Vol 722 ◽  
pp. 254-259 ◽  
Author(s):  
Jaroslav Topič ◽  
Jan Trejbal ◽  
Tomáš Plachý ◽  
Zdeněk Prošek

This article deals with utilization of recycled concrete in form of high-speed milled powder into cement based materials. Recycled concrete powder in that form is used as microfiller and cement replacement. This article contains results of mechanical properties of the cement pastes with different amount of recycled concrete powder. The mechanical properties as the compressive strength, flexural strength, dynamic Young's and share moduli are observed during 409 days. According to results can be assumed that recycled concrete powder can be used as microfiller and cement replacement under 30 wt. % of total amount. Especially the results of compressive strength are comparable with reference sample. But there are some abnormalities in long term development of the strength that need to be explained.


2017 ◽  
Vol 12 (2) ◽  
pp. 101-106 ◽  
Author(s):  
Galyna Kotsay

Abstract Application of nano-materials in cement products significantly, improves their properties. Of course, the effectiveness of the materials depends on their quantity and the way they are introduced into the system. So far, amongst nano-materials used in construction, the most preferred was nano-silica. This research investigated the effect of synthetic precipitated nano-silica on the cement hydration as well as, on the physical and mechanical properties of pastes and mortars. Obtained results showed that admixture of nano-silica enhanced flexural and compressive strength of cement after 2 and 28 days, however, only when admixture made up 0.5% and 1.0%. On the other hand, the use of nano-silica in the amount 2% had some limitations, due to its ability to agglomerate, which resulted in deterioration of the rheological and mechanical properties.


2013 ◽  
Vol 284-287 ◽  
pp. 1235-1241
Author(s):  
Si Yu Zou ◽  
Ran Huang ◽  
An Cheng ◽  
Wei Ting Lin ◽  
Jia Liang Chang

The study evaluates the properties of concrete mixed with inorganic silicate admixture. The admixture was used in proportions of 3%, 5%, and 7% of the weight of the cement. We performed tests on compressive strength and elastic modulus to evaluate the mechanical properties of concrete. Results show that the addition of the inorganic silicate admixture has a positive influence on the mechanical properties of concrete, with the best results obtained with 3% admixture. MIP porosity measurements determined that the addition of inorganic silicate admixture increased the density of the porous structure. SEM microscopic analysis revealed many needle-like protrusions into the porous structure of concrete. XRF chemical composition analysis indicated that these structures comprised mainly Na2O and SiO2. Can with cement hydration products Ca(OH)2 bring in Chemical reaction. Inferred pore structure Within be C-S-H gel of needle-like protruding structure. it can improve the main cause of mechanical properties of concrete.


2019 ◽  
Vol 10 (8) ◽  
pp. 2627-2638 ◽  
Author(s):  
Pawel Sikora ◽  
Krzysztof Cendrowski ◽  
Mohamed Abd Elrahman ◽  
Sang-Yeop Chung ◽  
Ewa Mijowska ◽  
...  

AbstractThis contribution investigates the effects of seawater and colloidal silica (NS) in the amounts of 1, 3 and 5 wt%, respectively, on the hydration, strength development and microstructural properties of Portland cement pastes. The data reveal that seawater has an accelerating effect on cement hydration and thus a significant contribution to early strength development was observed. The beneficial effect of seawater was reflected in an improvement in compressive strength for up to 14 days of hydration, while in the 28 days compressive strength values were comparable to that of cement pastes produced with demineralized water. The combination of seawater and NS significantly promotes cement hydration kinetics due to a synergistic effect, resulting in higher calcium hydroxide (CH) production. NS can thus react with the available CH through the pozzolanic reaction and produce more calcium silicate hydrate (C-S-H) gel. A noticeable improvement of strength development, as the result of the synergistic effect of NS and seawater, was therefore observed. In addition, mercury intrusion porosimetry (MIP) tests confirmed significant improvements in microstructure when NS and seawater were combined, resulting in the production of a more compact and dense hardened paste structure. The optimal amount of NS to be mixed with seawater, was found to be 3 wt% of cement.


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