3D Characterization of Continuously Cast Slabs

2007 ◽  
Vol 537-538 ◽  
pp. 555-562
Author(s):  
Mihály Réger ◽  
Balázs Verő ◽  
Árpád Szélig
Keyword(s):  
Dendritic Structure ◽  
Transfer Model ◽  
Chemical Compositions ◽  
Research Activity ◽  
Casting Technology ◽  
Transition Position ◽  
Continuously Cast ◽  
Columnar To Equiaxed Transition ◽  
Semi Empirical

This paper deals with the characterization of solidification, cooling and expected properties of continuously cast slabs. Semi-empirical models based on theoretical consideration and on the results of heat transfer model are used for characterization of the following: surface and inner temperature distribution of the cast semis, liquid sump depth and shape, liquid motion intensity resulting in centerline segregation, parameters of the primary dendritic structure (primary and secondary dendritic spacings, columnar to equiaxed transition position, CET). This method provides an opportunity to make a realistic comparison between the solidification and final properties of semis with different chemical compositions as a function of applied casting technologies. The final goal of this research activity in the future is to define a comprehensive quality function for optimizing continuous casting technology.

Behavioral Study of IN-718 Due to High Pressure Shock Wave Loading in Contact Geometry

2009 ◽  
Author(s):  
Ashok K. Sharma
Keyword(s):  
New Technology ◽  
Dendritic Structure ◽  
Spectroscopic Studies ◽  
Sem Analysis ◽  
Chemical Compositions ◽  
Wave Loading ◽  
Properties And Characterization ◽  
Post Shock ◽  
Super Alloy

Shock waves when propagate through materials produce sudden changes of pressure and temperature which result in the production of new phases/transformations. This paper describes the experimental work for the shock synthesis of IN 718 with unique properties and characterization of its pre and post shock compacts by spectroscopic methods. Super alloy powders of IN 718 of various chemical compositions and unique physical properties have been shock compressed to develop a new technology. From the spectroscopic records, intensity of reflected beam at a particular angle, the spacing between parallel planes, the lattice constant, the radius of an atom, FWHM value for each peak, etc. have been analyzed to investigate the unique properties of shock compacts. No porosity has been observed in the shock compacted specimens. On retrieval of samples from the compaction systems, the specimens are subjected to chemical composition, stress analysis and various other spectroscopic studies. The dendritic structure has been clearly observed in the centre with dendrites oriented in the radial direction which also happens to be the direction of heat flow. SEM analysis has indicated that the crystalline structure is intact in the shock compressed specimens.

Spectro-mechanical Characterization of Aromaticity and Maturity of Kerogens in Oil Shale at 6 nm Spatial Resolution

2018 ◽  
Author(s):  
Devon Jakob ◽  
Le Wang ◽  
Haomin Wang ◽  
Xiaoji Xu
Keyword(s):  
Spatial Resolution ◽  
Oil Shale ◽  
Infrared Imaging ◽  
Mechanical Characterization ◽  
Optical Diffraction ◽  
Chemical Compositions ◽  
Valuable Insight ◽  
Eagle Ford Shale

<p>In situ measurements of the chemical compositions and mechanical properties of kerogen help understand the formation, transformation, and utilization of organic matter in the oil shale at the nanoscale. However, the optical diffraction limit prevents attainment of nanoscale resolution using conventional spectroscopy and microscopy. Here, we utilize peak force infrared (PFIR) microscopy for multimodal characterization of kerogen in oil shale. The PFIR provides correlative infrared imaging, mechanical mapping, and broadband infrared spectroscopy capability with 6 nm spatial resolution. We observed nanoscale heterogeneity in the chemical composition, aromaticity, and maturity of the kerogens from oil shales from Eagle Ford shale play in Texas. The kerogen aromaticity positively correlates with the local mechanical moduli of the surrounding inorganic matrix, manifesting the Le Chatelier’s principle. In situ spectro-mechanical characterization of oil shale will yield valuable insight for geochemical and geomechanical modeling on the origin and transformation of kerogen in the oil shale.</p>

scholarly journals Microstructure and Thermoelectric Properties of (Bi0.48Sb1.52)Te3 Thick Films Prepared with Tape Casting Method

Electronics ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 140
Author(s):  
Lichen Liu ◽  
Ziping Cao ◽  
Min Chen ◽  
Jun Jiang
Keyword(s):  
Thermoelectric Properties ◽  
Low Cost ◽  
Thick Films ◽  
Tape Casting ◽  
Casting Process ◽  
Casting Method ◽  
Glass Substrates ◽  
Conductive Films ◽  
Casting Technology

This paper reports the fabrication and characterization of (Bi0.48Sb1.52)Te3 thick films using a tape casting process on glass substrates. A slurry of thermoelectric (Bi0.48Sb1.52)Te3 was developed and cured thick films were annealed in a vacuum chamber at 500–600 °C. The microstructure of these films was analyzed, and the Seebeck coefficient and electric conductivity were tested. It was found that the subsequent annealing process must be carefully designed to achieve good thermoelectric properties of these samples. Conductive films were obtained after annealing and led to acceptable thermoelectric performance. While the properties of these initial materials are not at the level of bulk materials, this work demonstrates that the low-cost tape casting technology is promising for fabricating thermoelectric modules for energy conversion.

scholarly journals New Insights into the Crystal Chemistry of Elpidite, Na2Zr[Si6O15]·3H2O and (Na1+YCax□1−X−Y)Σ=2Zr[Si6O15]·(3−X)H2O, and Ab Initio Modeling of IR Spectra

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2160
Author(s):  
Alexander Bogdanov ◽  
Ekaterina Kaneva ◽  
Roman Shendrik
Keyword(s):  
Ir Spectra ◽  
Structural Models ◽  
Chemical Characterization ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Special Group ◽  
X Ray ◽  
Influence Of Water ◽  
Radioactive Species

Elpidite belongs to a special group of microporous zirconosilicates, which are of great interest due to their capability to uptake various molecules and ions, e.g., some radioactive species, in their structural voids. The results of a combined electron probe microanalysis and single-crystal X-ray diffraction study of the crystals of elpidite from Burpala (Russia) and Khan-Bogdo (Mongolia) deposits are reported. Some differences in the chemical compositions are observed and substitution at several structural positions within the structure of the compounds are noted. Based on the obtained results, a detailed crystal–chemical characterization of the elpidites under study was carried out. Three different structure models of elpidite were simulated: Na2ZrSi6O15·3H2O (related to the structure of Russian elpidite), partly Ca-replaced Na1.5Ca0.25ZrSi6O15·2.75H2O (close to elpidite from Mongolia), and a hypothetical CaZrSi6O15·2H2O. The vibration spectra of the models were obtained and compared with the experimental one, taken from the literature. The strong influence of water molecule vibrations on the shape of IR spectra of studied structural models of elpidite is discussed in the paper.

scholarly journals Mineralogical and chemical properties inversed from 21-lunar-day VNIS observations taken during the Chang’E-4 mission

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Qinghong Zeng ◽  
Shengbo Chen ◽  
Yuanzhi Zhang ◽  
Yongling Mu ◽  
Rui Dai ◽  
...  
Keyword(s):  
Impact Crater ◽  
Near Infrared ◽  
Infrared Imaging ◽  
Chemical Properties ◽  
Landing Site ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Chemical Compositions ◽  
Impact Melt ◽  
And Chemical Properties

AbstractWe report on the mineralogical and chemical properties of materials investigated by the lunar rover Yutu-2, which landed on the Von Kármán crater in the pre-Nectarian South Pole–Aitken (SPA) basin. Yutu-2 carried several scientific payloads, including the Visible and Near-infrared Imaging Spectrometer (VNIS), which is used for mineral identification, offering insights into lunar evolution. We used 86 valid VNIS data for 21 lunar days, with mineral abundance obtained using the Hapke radiative transfer model and sparse unmixing algorithm and chemical compositions empirically estimated. The mineralogical properties of the materials at the Chang’E-4 (CE-4) site referred to as norite/gabbro, based on findings of mineral abundance, indicate that they may be SPA impact melt components excavated by a surrounding impact crater. We find that CE-4 materials are dominated by plagioclase and pyroxene and feature little olivine, with 50 of 86 observations showing higher LCP than HCP in pyroxene. In view of the effects of space weathering, olivine content may be underestimated, with FeO and TiO2 content estimated using the maturity-corrected method. Estimates of chemical content are 7.42–18.82 wt% FeO and 1.48–2.1 wt% TiO2, with a low-medium Mg number (Mg # ~ 55). Olivine-rich materials are not present at the CE-4 landing site, based on the low-medium Mg #. Multi-origin materials at the CE-4 landing site were analyzed with regard to concentrations of FeO and TiO2 content, supporting our conclusion that the materials at CE-4 do not have a single source but rather are likely a mixture of SPA impact melt components excavated by surrounding impact crater and volcanic product ejecta.

Relation between Magnetic, Spectroscopic and Structural Properties of Binuclear Copper(II) Complexes of Pentadentate Schiff-base Ligand, Semi-empirical and ab-initio Calculations

2003 ◽  
Vol 58 (5-6) ◽  
pp. 363-372 ◽  
Author(s):  
Y. Elerman ◽  
H. Kara ◽  
A. Elmali
Keyword(s):  
Ab Initio ◽  
Coupling Constants ◽  
Antiferromagnetic Coupling ◽  
X Ray Diffraction ◽  
Hartree Fock ◽  
Ligand Orbital ◽  
Rhf Calculations ◽  
The Difference ◽  
Semi Empirical

The synthesis and characterization of [Cu2(L1)(3,5 prz)] (L1=1,3-Bis(2-hydroxy-3,5-chlorosalicylideneamino) propan-2-ol) 1 and of [Cu2(L2)(3,5 prz)] (L2=1,3-Bis(2-hydroxy-bromosalicylideneamino) propan-2-ol) 2 are reported. The compounds were studied by elemental analysis, infrared and electronic spectra. The structure of the Cu2(L1)(3,5 prz)] complex was determined by x-ray diffraction. The magnetochemical characteristics of these compounds were determined by temperaturedependent magnetic susceptibility measurements, revealing their antiferromagnetic coupling. The superexchange coupling constants are 210 cm−1 for 1 and 440 cm−1 for 2. The difference in the magnitude of the coupling constants was explained by the metal-ligand orbital overlaps and confirmed by ab-initio restricted Hartree-Fock (RHF) calculations. In order to determine the nature of the frontier orbitals, Extended Hückel Molecular Orbital (EHMO) calculations are also reported.

Characterization of Al65.0Cu32.9Co2.1 Alloy Containing Nanofibres

2012 ◽  
Vol 186 ◽  
pp. 212-215
Author(s):  
Jacek Krawczyk ◽  
Włodzimierz Bogdanowicz ◽  
Grzegorz Dercz ◽  
Wojciech Gurdziel
Keyword(s):  
Electron Microscopy ◽  
Average Diameter ◽  
Chemical Compositions ◽  
X Ray ◽  
Transmission Electron ◽  
Orthogonal Set ◽  
T Phase ◽  
Terminal Area ◽  
Scanning Electron

Microstructure of terminal area of Al65Cu32.9Co2.1ingots (numbers indicate at.%), obtained via directional solidification was studied. Scanning Electron Microscopy, Transmission Electron Microscopy and X-ray powder diffraction were applied. Point microanalysis by Scanning Electron Microscope was used for examination of chemical compositions of alloy phases. It was found that tetragonal θ phase of Al2Cu stoichiometric formula was the dominate phase (matrix). Additionally the alloy contained orthogonal set of nanofibres of Al7Cu2Co T phase with the average diameter of 50-500 nm and oval areas of hexagonal Al3(Cu,Co)2H-phase, surrounded by monoclinic AlCu η1phase rim. Inside some areas of H-phase cores of decagonal quasicrystalline D phase were observed.

Characterization of Horizontal Loads in the Production of Asymmetrical Parts

2011 ◽  
Vol 473 ◽  
pp. 223-228 ◽  
Author(s):  
Bernd Arno Behrens ◽  
Anas Bouguecha ◽  
Richard Krimm ◽  
Thorsten Matthias ◽  
Valerian Salfeld
Keyword(s):  
Thin Sheet ◽  
Research Centre ◽  
Computational Accuracy ◽  
Research Activity ◽  
German Research Foundation ◽  
The Press ◽  
German Research ◽  
Thin Sheet Metal ◽  
Complex Parts

The vision of Transregional Collaborative Research Centre 73 of the German Research Foundation (DFG) is the development of a new manufacturing technology, sheet-bulk metal forming. The research activity is focused on the manufacturing of geometrically complex parts with functional elements from thin sheet metal. This paper gives an overview about the challenges in forming of asymmetrical parts with regard to the forming forces and resulting displacements of the press components. Furthermore, it introduces an appropriate approach for consideration of machine characteristics in order to improve the computational accuracy of the process modelling.

Design and Characterization of a Novel Upward Flow Reactor for the Study of High-Temperature Thermal Reduction for Solar-Driven Processes

2017 ◽  
Vol 139 (5) ◽  
Author(s):  
H. Evan Bush ◽  
Karl-Philipp Schlichting ◽  
Robert J. Gill ◽  
Sheldon M. Jeter ◽  
Peter G. Loutzenhiser
Keyword(s):  
High Temperature ◽  
Flow Reactor ◽  
Thermal Reduction ◽  
Heat Fluxes ◽  
O2 Evolution ◽  
Transfer Model ◽  
Upward Flow ◽  
Heating Rates ◽  
Solar Simulator

The design and characterization of an upward flow reactor (UFR) coupled to a high flux solar simulator (HFSS) under vacuum is presented. The UFR was designed to rapidly heat solid samples with concentrated irradiation to temperatures greater than 1000 °C at heating rates in excess of 50 K/s. Such conditions are ideal for examining high-temperature thermal reduction kinetics of reduction/oxidation-active materials by temporally monitoring O2 evolution. A steady-state, computational fluid dynamics (CFD) model was employed in the design to minimize the formation of eddies and recirculation, and lag and dispersion were characterized through a suite of O2 tracer experiments using deconvolution and the continuously stirred tank reactors (CSTR) in series models. A transient, CFD and heat transfer model of the UFR was combined with Monte Carlo ray tracing (MCRT) to determine radiative heat fluxes on the sample from the HFSS to model spatial and temporal sample temperatures. The modeled temperatures were compared with those measured within the sample during an experiment in which Co3O4 was thermally reduced to CoO and O2. The measured temperatures within the bed were bounded by the average top and bottom modeled bed temperatures for the duration of the experiment. Small variances in the shape of the modeled versus experimental temperatures were due to contact resistance between the thermocouple and particles in the bed and changes in the spectral absorptivity and emissivity as the Co3O4 was reduced to CoO and O2.

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