Experimental Study of the Micromechanical Behaviour of Duplex Stainless Steel SAF 2507 and the Influence of Nitrogen Content

2011 ◽  
Vol 681 ◽  
pp. 516-521
Author(s):  
Ru Lin Peng ◽  
Guo Cai Chai ◽  
Tobias Stein ◽  
Thorsten Manns ◽  
Sten Johansson

The deformation behaviour of four super duplex stainless steels of the grade SAF 2507 (UNS S32750) were studied by X-ray diffraction experiment with in-situ uniaxial tensile load. The steels had different nitrogen contents, between 0.2 and 0.33%, and/or different volume fractions of the ferrite, between 37% and 49%, in balance with austenite. The development of phase-specific stresses under external loading up to over 10% tensile strain was followed. The X-ray diffraction measurements revealed that load partitioning between the phases changed with increasing applied load, as the ferrite and austenite exhibited different deformation hardening behaviours. At the onset of macroscopic yielding and low plastic strains, a load transfer from γ to α occurred due to higher yield strength and strain hardening rate of the ferrite but vice versa at larger plastic strains when the austenite hardened more rapidly than the ferrite. It was also concluded that both the yield and tensile strengthen of the steels increased with increasing nitrogen content due to increased strengthen of the austenite by additional solid solution hardening, whereas a higher volume fraction of austenite contributed to higher tensile strength.

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 710
Author(s):  
Natalia Narkevich ◽  
Yevgeny Deryugin ◽  
Yury Mironov

The deformation behavior, mechanical properties, and microstructure of Fe-Cr-Mn-0.53%N austenitic stainless steel were studied at a temperature range of 77 up to 293 K. The dynamics of the steel elongation were non-monotonic with a maximum at 240–273 K, when peaks of both static atom displacements from their equilibrium positions in austenite and residual stresses in the tensile load direction were observed. The results of X-ray diffraction analysis confirmed that the only stress-induced γ→ε-martensite transformation occurred upon deformation (no traces of the γ→α′ one was found). In this case, the volume fraction of ε-martensite was about 2–3%. These transformation-induced plasticity (TRIP) patterns were discussed in terms of changes in the phase composition of steel as the root cause.


2006 ◽  
Vol 524-525 ◽  
pp. 847-852 ◽  
Author(s):  
Ru Lin Peng ◽  
J. Gibmeier ◽  
Sebastian Eulert ◽  
Sten Johansson ◽  
Guo Cai Chai

The deformation behaviour of the super duplex stainless steel SAF2507 (UNS S32750) under successive uniaxial tensile loading-unloading was investigated with respect to load sharing and inter-phase interactions. The steel consists of 58% austenite and 42% ferrite in volume. By insitu X-ray diffraction experiment the evolution of phase-specific stresses with applied load was monitored for three successive loading-unloading cycles with the maximum total strains being 0.34%, 0.75% and 1.63%, respectively. It was found that yielding occurred earlier in the austenitic phase than in the ferritic phase during the first loading cycle. In the followed loading cycles, both phases yielded under larger but similar applied stresses. Due to a similar behavior of the phases in the elasto-plastic regime inter-phase interactions were relatively weak. Low microstresses induced by the plastic straining resulted in somewhat larger stresses in the ferritic phase.


2016 ◽  
Vol 30 (26) ◽  
pp. 1650328
Author(s):  
Yan Dong ◽  
Aimin Sun ◽  
Bin Xu ◽  
Hongtao Zhang ◽  
Meng Zhang

In this paper, the effect of tiny Y2O3 addition in (Bi,[Formula: see text]Pb)-2223 superconductor prepared by solid state reaction technique was studied. The properties of samples have been investigated via X-ray diffraction (XRD), resistance–temperature ([Formula: see text]–[Formula: see text]) curve, scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). XRD data indicated that all samples are multiphase and the major phases are high-temperature phases and low-temperature phases. The volume fraction of (Bi,[Formula: see text]Pb)-2223 is not great change with tiny Y2O3 addition. All samples exhibit superconducting phase with the critical transition temperature and one-step transition, however, the transition width was decreased with the Y2O3 addition up to 0.04 wt.% and sharp increased with the excessive oxide addition. SEM pictures show that the Y2O3 appeared on the flake-type grains surface obviously, but the number and size of the hole between grains are decreased in the 0.04 wt.% addition.


1994 ◽  
Vol 08 (19) ◽  
pp. 1175-1183 ◽  
Author(s):  
G. RAVI CHANDRA ◽  
B. GOPALA KRISHNA ◽  
S. V. SURYANARAYANA ◽  
T. S. N. MURTHY

The effect of the addition of Sn on the superconducting properties of the Bi 1.7 Pb 0.3 Sr 2 Ca 2 Cu 3 O y system as functions of Sn concentration and heat treatment has been studied by dc electrical resistance, ac magnetic susceptibility, and X-ray diffraction. Tin addition suppresses the volume fraction of the high T c phase. Samples with Sn > 0.1 show metallic behavior up to LNT. The formation of the Ca 2 PbO 4 phase is promoted by Sn. This depletes the amount of Pb and Ca necessary for the formation of the 2223 phase, thus reducing the volume fraction of the 2223 phase. It is possible that at least a small fraction of tin substitutes some of the cationic sites of the starting composition. The results of the different measurements are presented.


2010 ◽  
Vol 654-656 ◽  
pp. 819-822
Author(s):  
Genki Kikuchi ◽  
Hiroshi Izui ◽  
Yuya Takahashi ◽  
Shota Fujino

In this study, we focused on the sintering performance of Ti-4.5Al-3V-2Mo-2Fe (SP-700) and mechanical properties of SP-700 reinforced with titanium boride (TiB/SP-700) fabricated by spark plasma sintering (SPS). TiB whiskers formed in titanium by a solid-state reaction of titanium and TiB2 particles were analyzed with scanning electron microscopy and X-ray diffraction. The TiB/SP-700 was sintered at temperatures of 1073, 1173, and 1273 K and a pressure of 70 MPa for 10, 30, and 50 min. The volume fraction of TiB ranged from 1.7 vol.% to 19.9 vol.%. Tensile tests of TiB/SP-700 were conducted at room temperature, and the effect of TiB volume fraction on the tensile properties was investigated.


2020 ◽  
Vol 90 (5) ◽  
pp. 795
Author(s):  
Р.В. Селюков ◽  
В.В. Наумов

Textured Pt films with thickness h=20-80 nm were sputter deposited on oxidized c-Si (100) wafers and annealed in vacuum at 500°C/60 min. The thickness dependencies of the crystalline texture parameters and of the fraction of crystalline phase δ are obtained for as-deposited and annealed films using X-ray diffraction. The determination of δ in textured films is carried out by the new method based on rocking curve analysis. It is found that annealing leads to the texture improvement and to the increasing of δ for all h. The less h, the stronger effects of texture improvement and of δ increasing. These results are explained by the annealing-induced formation of large secondary grains whose volume fraction increases as h decreases. The inhomogeneity of the depth distributions of texture parameters and of δ are investigated for the as-deposited Pt films.


2011 ◽  
Vol 2011 ◽  
pp. 1-9 ◽  
Author(s):  
Moukrane Dehmas ◽  
Jacques Lacaze ◽  
Aliou Niang ◽  
Bernard Viguier

Inconel 718 is widely used because of its ability to retain strength at up to 650∘C for long periods of time through coherent metastable Ni3Nb precipitation associated with a smaller volume fraction of Ni3Al precipitates. At very long ageing times at service temperature, decomposes to the stable Ni3Nb phase. This latter phase is also present above the solvus and is used for grain control during forging of alloy 718. While most works available on precipitation have been performed at temperatures below the solvus, it appeared of interest to also investigate the case where phase precipitates directly from the fcc matrix free of precipitates. This was studied by X-ray diffraction and transmission electron microscopy (TEM). TEM observations confirmed the presence of rotation-ordered domains in plates, and some unexpected contrast could be explained by double diffraction due to overlapping phases.


1999 ◽  
Vol 557 ◽  
Author(s):  
D. Peiró ◽  
C. Voz ◽  
J. Bertomeu ◽  
J. Andreu ◽  
E. Martínez ◽  
...  

AbstractHydrogenated microcrystalline silicon films have been obtained by hot-wire chemical vapor deposition (HWCVD) in a silane and hydrogen mixture at low pressure (<5 × 10-2 mbar). The structure of the samples and the residual stress were characterised by X- ray diffraction (XRD). Raman spectroscopy was used to estimate the volume fraction of the crystalline phase, which is in the range of 86 % to 98%. The stress values range between 150 and -140 MPa. The mechanical properties were studied by nanoindentation. Unlike monocrystalline wafers, there is no evidence of abrupt changes in the force-penetration plot, which have been attributed to a pressure-induced phase transition. The hardness was 12.5 GPa for the best samples, which is close to that obtained for silicon wafers.


2012 ◽  
Vol 535-537 ◽  
pp. 14-17
Author(s):  
Long Hua Zhong ◽  
Yu Tao Zhao ◽  
Song Li Zhang ◽  
Rong Wen

In situ TiB2/6061 composites have been successfully synthesized through chemical reaction between 6061 master alloy, Al-3B master alloy and Ti powder. The composites fabricated by direct melt mixing method was investigated by Scanning Electron Microscope (SEM), Energy Dispersive x-ray Spectroscopy (EDS) and X-Ray Diffraction (XRD), The results shown the existence of TiB2particles. The size of most TiB2particles were just in micron level, and even reached to sub-micron level. The increase in microhardness and tensile strength for the as-prepared composites with 5% particulate volume fraction (PVF) are up to 26.8% and 51.2% respectively.


2019 ◽  
Vol 53 (15) ◽  
pp. 2091-2104 ◽  
Author(s):  
Gaurav Arora ◽  
Himanshu Pathak ◽  
Sunny Zafar

Carbon nanotubes have been used as reinforcements in polymers due to their high elasticity, flexibility, and thermal conductivity. In this study, pellets of high-density polyethylene +20 wt% carbon nanotube and polypropylene +20 wt% carbon nanotube were cured using microwave energy. X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, uniaxial tensile test, and scanning electron microscopy was used to study morphology, thermal stability, and mechanical performance of the microwave-cured composites. X-ray diffraction analysis confirmed the bonding between the polymer and carbon nanotube as the peaks shifted and intensified. From the thermal study, it was observed that melting point of the composites is affected by microwave curing and the crystallinity of high-density polyethylene/carbon nanotube and polypropylene/carbon nanotube changed by 57.67% and 47.28%, respectively. Results of the uniaxial tensile test indicated that Young’s modulus of microwave cured high-density polyethylene/carbon nanotube and polypropylene/carbon nanotube composites were improved by 295% and 787.8%, respectively. Scanning electron microscopic fractography shows the stretching of polymer over-lapped on carbon nanotubes in the direction of the applied load.


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