scholarly journals Groundwater geochemistry of the Mt. Vesuvius area: implications for volcano surveillance and relationship with hydrological and seismic signals

2013 ◽  
Vol 56 (4) ◽  
Author(s):  
Cinzia Federico ◽  
Paolo Madonia ◽  
Paola Cusano ◽  
Simona Petrosino

<p>Geochemical data obtained between 1998 and 2011 at the Mt. Vesuvius aquifer are discussed, focusing on the effects of both the hydrological regime and the temporal pattern of local seismicity. Water samples were collected in a permanent network of wells and springs located in the areas that are mostly affected by the ascent of magmatic volatiles, and their chemical composition and dissolved gas content were analyzed. As well as the geochemical parameters that describe the behavior of groundwater at Mt. Vesuvius, we discuss the temporal distribution of volcano-tectonic earthquakes. The seismological data set was collected by the stations forming the permanent and mobile network of the Istituto Nazionale di Geofisica e Vulcanologia - Osservatorio Vesuviano (INGV-OV). Our analysis of seismic data collected during 1998-2011 identified statistically significant variations in the seismicity rate, marked by phases of decreasing activity from October 1999 to May 2001 and increasing activity from August 2004 to mid-2006. The water chemistry shows peculiar patterns, characterized by a changeable input of CO<span><sub>2</sub></span>-rich and saline water, which must be related to either a changing stress field or an increased input of CO<span><sub>2</sub></span>-rich vapor. The water chemistry data from 1999 to 2003 account for both higher fluid pressure (which induced the seismic crisis of 1999 that peaked with a 3.6-magnitude earthquake in October 1999) and the increased input of CO<span><sub>2</sub></span>-rich fluids. The highest emission of CO<span><sub>2</sub></span> from the crater fumaroles and the corresponding increase in dissolved carbon in groundwater characterize the phase of low seismicity. The termination of the phase of intense deep degassing is associated with a change in water chemistry and a peculiar seismic event that was recorded in July 2003. All these seismic and geochemical patterns are interpreted according to temporal variations in the regional and local stress field.</p>

2021 ◽  
Vol 73 (1) ◽  
Author(s):  
Takahiro Hosono ◽  
Chikashige Yamanaka

AbstractNatural springs containing volcanic and magmatic components occur in association with these activities. However, features of deeply originated fluids and solutes were less documented from fields, where active volcanic and magmatic activities are not distributed. To characterize the presence of deep components and identify their major pathways 28 groundwater samples (~ 1230 m deep) were collected from hot spring sites located at western coast of Kumamoto, southwestern Japan, where the typical subduction related magmatisms are absent. The samples were measured for dissolved ion concentrations and stable isotope ratios (δ2HH2O, δ18OH2O, δ13CDIC and δ34SSO4) that were compared with data of 33 water samples from vicinity surface systems. The groundwaters were classified into three types based on major hydrochemistry: high Cl− fluid, low concentration fluid, and high HCO3− fluid. Our data set suggests that the high Cl− fluid was formed by saline water mixing with aquifer waters of meteoric origin and subsequently evolved by reverse cation exchange. The low concentration fluid is identical to regional aquifer water of meteoric origin that was subjected to cation exchange. The high HCO3− fluid showed the highest HCO3− concentrations (~ 3,888 mg/l) with the highest δ13CDIC (up to − 1.9‰). Based on our carbon mixing model and observed δ2HH2O and δ18OH2O shifts, it is suggested that dissolved carbon of mantle origin and small fraction of fluids generated in deep crust were transported towards surface through structural weakness under open tectonic setting. These deeply derived components were then mixed with waters in the surface systems and diluted. Their impacts on surface hydrological systems were limited in space except few locations, where deeply connected pathways are anticipated along active structural deformations.


1992 ◽  
Vol 16 (3) ◽  
pp. 319-338 ◽  
Author(s):  
Trevor Hoey

Temporal variability in bedload transport rates and spatial variability in sediment storage have been reported with increasing frequency in recent years. A spatial and temporal classification for these features is suggested based on the gravel bedform classification of Church and Jones (1982). The identified scales, meso-, macro-, and mega- are each broad, and within each there is a wide range of processes acting to produce bedload fluctuations. Sampling the same data set with different sampling intervals yields a near linear relationship between sampling interval and pulse period. A range of modelling strategies has been applied to bed waves. The most successful have been those which allow for the three-dimensional nature of sediment storage processes, and which allow changes in the width and depth of stored sediment. The existence of bed waves makes equilibrium in gravel-bed rivers necessarily dynamic. Bedload pulses and bed waves can be regarded as equilibrium forms at sufficiently long timescales.


2021 ◽  
Author(s):  
Hannah M. Palmer ◽  
Veronica Padilla Vriesman ◽  
Roxanne M. W. Banker ◽  
Jessica R. Bean

Abstract. The shells of marine invertebrates can serve as high-resolution records of oceanographic and atmospheric change through time. In particular, oxygen and carbon isotope analyses of nearshore marine calcifiers that grow by accretion over their lifespans provide seasonal records of environmental and oceanographic conditions. Archaeological shell middens generated by Indigenous communities along the Northeast Pacific coast contain shells harvested over multiple seasons for millennia. These shell middens, as well as analyses of archival and modern shells, have the potential to provide multi-site, seasonal archives of nearshore conditions throughout the Holocene. A significant volume of oxygen and carbon isotope data from archaeological shells exists, yet is separately published in archaeological, geochemical, and paleoceanographic journals and has not been comprehensively analyzed to examine oceanographic change over time. Here, we compiled a database of previously published oxygen and carbon isotope data from archaeological, archival, and modern marine molluscs from the North American coast of the Northeast Pacific (32° N to 50° N). This database includes oxygen and carbon isotope data from over 550 modern, archaeological, and sub-fossil shells from 8880 years before present (BP) to the present, from which there are 4,845 total δ13C and 5,071 total δ18O measurements. Shell dating and sampling strategies vary among studies (1–118 samples per shell) and vary significantly by journal discipline. Data are from various bivalves and gastropod species, with Mytilus spp. being the most commonly analyzed taxon. This novel database can be used to investigate changes in nearshore sea surface conditions including warm-cool oscillations, heat waves, and upwelling intensity, and provides nearshore calcite δ13C and δ18O values that can be compared to the vast collections of offshore foraminifera calcite δ13C and δ18O data from marine sediment cores. By utilizing previously published geochemical data from midden and museum shells rather than sampling new specimens, future scientific research can reduce or omit the alteration or destruction of culturally valued specimens and sites. The data set is publicly available through PANGAEA at https://doi.org/10.1594/PANGAEA.932671 (Palmer et al., 2021).


2019 ◽  
Author(s):  
Matthew Gard ◽  
Derrick Hasterok ◽  
Jacqueline Halpin

Abstract. Dissemination and collation of geochemical data are critical to promote rapid, creative and accurate research and place new results in an appropriate global context. To this end, we have assembled a global whole-rock geochemical database, with other associated sample information and properties, sourced from various existing databases and supplemented with numerous individual publications and corrections. Currently the database stands at 1,023,490 samples with varying amounts of associated information including major and trace element concentrations, isotopic ratios, and location data. The distribution both spatially and temporally is quite heterogeneous, however temporal distributions are enhanced over some previous database compilations, particularly in terms of ages older than ~ 1000 Ma. Also included are a wide range of computed geochemical indices, physical property estimates and naming schema on a major element normalized version of the geochemical data for quick reference. This compilation will be useful for geochemical studies requiring extensive data sets, in particular those wishing to investigate secular temporal trends. The addition of physical properties, estimated by sample chemistry, represents a unique contribution to otherwise similar geochemical databases. The data is published in .csv format for the purposes of simple distribution but exists in a format acceptable for database management systems (e.g. SQL). One can either manipulate this data using conventional analysis tools such as MATLAB®, Microsoft® Excel, or R, or upload to a relational database management system for easy querying and management of the data as unique keys already exist. This data set will continue to grow, and we encourage readers to contact us or other database compilations contained within about any data that is yet to be included. The data files described in this paper are available at https://doi.org/10.5281/zenodo.2592823 (Gard et al., 2019).


Radiocarbon ◽  
2020 ◽  
Vol 62 (2) ◽  
pp. 289-311
Author(s):  
Alex da Silva de Freitas ◽  
Javier Helenes Escamilla ◽  
Cintia Ferreira Barreto ◽  
Alex Cardoso Bastos ◽  
Estefan Monteiro da Fonseca ◽  
...  

ABSTRACTMicropaleontological and geochemical data were applied to sediments from southeastern Brazil to study the hydrodynamics associated with the Holocene sea level rise. Sediment cores were taken around Vitória Bay, examined for dinoflagellate cysts and subjected to isotopic analysis. The cyst assemblage mainly dominated by autotrophic species most notably O. centrocarpum, L. machaerophorum and T. vancampoae. The influence of the marine transgression and subsequent regression observed during the Holocene along the coast of Brazil could have initially favored the establishment of an oligotrophic and higher energy environment. The inflow of continental water from tributaries combined with a higher inflow of saline water into the estuarine system could have favored the establishment and subsequent deposition of the dinocysts.


2020 ◽  
Vol 91 (6) ◽  
pp. 3622-3633
Author(s):  
Rufus D. Catchings ◽  
Mark R. Goldman ◽  
Jamison H. Steidl ◽  
Joanne H. Chan ◽  
Amir A. Allam ◽  
...  

Abstract The 2019 Ridgecrest, California, earthquake sequence included Mw 6.4 and 7.1 earthquakes that occurred on successive days beginning on 4 July 2019. These two largest earthquakes of the sequence occurred on orthogonal faults that ruptured the Earth’s surface. To better evaluate the 3D subsurface fault structure, (P- and S-wave) velocity, 3D and temporal variations in seismicity, and other important aspects of the earthquake sequence, we recorded aftershocks and ambient noise using up to 461 three-component nodal seismographs for about two months, beginning about one day after the Mw 7.1 mainshock. The ∼30,000Mw≥1 earthquakes that were recorded on the dense arrays provide an unusually large volume of data with which to evaluate the earthquake sequence. This report describes the recording arrays and is intended to provide metadata for researchers interested in evaluating various aspects of the 2019 Ridgecrest earthquake sequence using the nodal data set.


Geophysics ◽  
2009 ◽  
Vol 74 (5) ◽  
pp. B183-B195 ◽  
Author(s):  
K. De Meersman ◽  
J.-M. Kendall ◽  
M. van der Baan

We relocate 303 microseismic events recorded in 1998 by sensors in a single borehole in the North Sea Valhall oil field. A semiautomated array analysis method repicks the P- and S-wave arrival times and P-wave polarizations, which are needed to locate these events. The relocated sources are confined predominantly to a [Formula: see text]-thick zone just above the reservoir, and location uncertainties are half those of previous efforts. Multiplet analysis identifies 40 multiplet groups, which include 208 of the 303 events. The largest group contains 24 events, and five groups contain 10 or more events. Within each multiplet group, we further improve arrival-time picking through crosscorrelation, which enhances the relative accuracy of the relocated events and reveals that more than 99% of the seismic activity lies spatially in three distinct clusters. The spatial distribution of events and wave-form similarities reveal two faultlike structures that match well with north-northwest–south-southeast-trending fault planes interpreted from 3D surface seismic data. Most waveform differences between multiplet groups located on these faults can be attributed to S-wave phase content and polarity or P-to-S amplitude ratio. The range in P-to-S amplitude ratios observed on the faults is explained best in terms of varying source mechanisms. We also find a correlation between multiplet groups and temporal variations in seismic anisotropy, as revealed by S-wave splitting analysis. We explain these findings in the context of a cyclic recharge and dissipation of cap-rock stresses in response to production-driven compaction of the underlying oil reservoir. The cyclic nature of this mechanism drives the short-term variations in seismic anisotropy and the reactivation of microseismic source mechanisms over time.


Sensors ◽  
2019 ◽  
Vol 19 (24) ◽  
pp. 5513
Author(s):  
J.P. Mendes ◽  
L. Coelho ◽  
B. Kovacs ◽  
J.M.M.M. de Almeida ◽  
C.M. Pereira ◽  
...  

A sensing configuration for the real-time monitoring, detection, and quantification of dissolved carbon dioxide (dCO2) was developed for aquaculture and other applications in freshwater and saline water. A chemical sensing membrane, based on a colorimetric indicator, is combined with multimode optical fiber and a dual wavelength light-emitting diode (LED) to measure the dCO2-induced absorbance changes in a self-referenced ratiometric scheme. The detection and processing were achieved with an embeded solution having a mini spectrometer and microcontroller. For optrode calibration, chemical standard solutions using sodium carbonate in acid media were used. Preliminary results in a laboratory environment showed sensitivity for small added amounts of CO2 (0.25 mg·L−1). Accuracy and response time were not affected by the type of solution, while precision was affected by salinity. Calibration in freshwater showed a limit of detection (LOD) and a limit of quantification (LOQ) of 1.23 and 1.87 mg·L−1, respectively. Results in saline water (2.5%) showed a LOD and LOQ of 1.05 and 1.16 mg·L−1, respectively. Generally, performance was improved when moving from fresh to saline water. Studies on the dynamics of dissolved CO2 in a recirculating shallow raceway system (SRS+RAS) prototype showed higher precision than the tested commercial sensor. The new sensor is a compact and robust device, and unlike other sensors used in aquaculture, stirring is not required for correct and fast detection. Tests performed showed that this new sensor has a fast accurate detection as well as a strong potential for assessing dCO2 dynamics in aquaculture applications.


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