scholarly journals Effects of Diagenesis on the Reservoir Quality in the Upper Sands of Lower Goru Formation, Badin Block, Lower Indus Basin, Pakistan

2020 ◽  
Vol 11 (3) ◽  
pp. 22-30
Author(s):  
Muhammad Hassan Agheem ◽  
Humaira Dars ◽  
Sarfraz Hussain Solangi ◽  
Akhtar Hussain Markhand ◽  
Ali Ghulam Sahito ◽  
...  
Keyword(s):  
Xrd Analysis ◽  
Indus Basin ◽  
Reservoir Quality ◽  
Sem Images ◽  
Secondary Porosity ◽  
Spatial And Temporal Scales ◽  
Potential Reservoir ◽  
Lower Goru Formation ◽  
Late Diagenesis ◽  
Quartz Grains

The core samples of B member of upper sand reservoir rocks of the lower Goru Formation from three wellsof the Badin block were studied using thin section, XRD, and SEM techniques to investigate the diagenetic trends andtheir effect on reservoir quality. Microscopic study indicates that the B sand unit is mature with quartz as thepredominant mineral constituent with variable amount of feldspar and lithic minerals. The QFL plot indicates that mostof the samples are plotted in the field of quartz arenite, sub-litharenite and sub-arkose respectively. A few samplesbelong to the category of litharenite and feldspathic litharenite. The feldspars were partially to completely altered tokaolinite and other clay minerals. Coarse-crystalline or micro-crystalline calcite is the predominant cementing material.Bulk rock XRD analysis also confirms that the main mineral constituents of there samples are quartz and calcite invariable proportions. The undulose extinction and fracturing of quartz grains indicate that the area remained understress. Moreover, such fracturing is post-depositional and therefore is the product of late diagenesis. Scanning ElectronMicroscopic (SEM) images at 50 micrometer (μm) size show irregular type of fracturing within the quartz grains. Thislate stage fracturing of quartz has also generated various types of channels which may serve as secondary porosity. Thequartz overgrowth was observed in some samples due to late stage diagenesis. The micro-crystalline cement in the formof calcite is mostly present within the pores in fractured quartz. The results indicate that the diagenesis played asignificant role in improving the reservoir characteristics of B sand by increasing the porosity due to quartz fracturing,feldspar dissolution, alteration and quartz corrosion. Hence, better understanding of reservoir heterogeneities inporosity through diagenetic studies can be helpful in evaluating potential reservoir horizons for hydrocarbonaccumulation on spatial and temporal scales.

scholarly journals Fast Dissolving Electrospun Nanofibers Fabricated from Jelly Fig Polysaccharide/Pullulan for Drug Delivery Applications

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 241
Author(s):  
Thangavel Ponrasu ◽  
Bei-Hsin Chen ◽  
Tzung-Han Chou ◽  
Jia-Jiuan Wu ◽  
Yu-Shen Cheng
Keyword(s):  
Drug Delivery ◽  
Water Vapor Permeability ◽  
Electrospun Nanofibers ◽  
Average Diameter ◽  
Xrd Analysis ◽  
Water Soluble ◽  
Vapor Permeability ◽  
Uv Spectrum ◽  
Sem Images ◽  
Triton X

The fast-dissolving drug delivery systems (FDDDSs) are developed as nanofibers using food-grade water-soluble hydrophilic biopolymers that can disintegrate fast in the oral cavity and deliver drugs. Jelly fig polysaccharide (JFP) and pullulan were blended to prepare fast-dissolving nanofiber by electrospinning. The continuous and uniform nanofibers were produced from the solution of 1% (w/w) JFP, 12% (w/w) pullulan, and 1 wt% Triton X-305. The SEM images confirmed that the prepared nanofibers exhibited uniform morphology with an average diameter of 144 ± 19 nm. The inclusion of JFP in pullulan was confirmed by TGA and FTIR studies. XRD analysis revealed that the increased crystallinity of JFP/pullulan nanofiber was observed due to the formation of intermolecular hydrogen bonds. The tensile strength and water vapor permeability of the JFP/pullulan nanofiber membrane were also enhanced considerably compared to pullulan nanofiber. The JFP/pullulan nanofibers loaded with hydrophobic model drugs like ampicillin and dexamethasone were rapidly dissolved in water within 60 s and release the encapsulants dispersive into the surrounding. The antibacterial activity, fast disintegration properties of the JFP/pullulan nanofiber were also confirmed by the zone of inhibition and UV spectrum studies. Hence, JFP/pullulan nanofibers could be a promising carrier to encapsulate hydrophobic drugs for fast-dissolving/disintegrating delivery applications.

Li(Ni1/3Co1/3Mn1/3)O2 with High Rate Capability Synthesized via a Novel Gel-Combustion Method

2011 ◽  
Vol 391-392 ◽  
pp. 973-977
Author(s):  
Jing Mao ◽  
Ke Hua Dai ◽  
Yu Chun Zhai
Keyword(s):  
Energy Dispersive Spectrometer ◽  
Rate Capability ◽  
Chelating Agent ◽  
Combustion Method ◽  
Xrd Analysis ◽  
High Rate ◽  
High Rate Capability ◽  
Sem Images ◽  
Gel Combustion ◽  
Gel Combustion Method

Li(Ni1/3Co1/3Mn1/3)O2material with high rate capability was synthesized by a novel gel-combustion method using polyvinylpyrrolidone as a polymer chelating agent and a fuel. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were used to study the structure, morphology and element distribution of the Li(Ni1/3Co1/3Mn1/3)O2material. XRD analysis showed that all samples were α-NaFeO2structure and Li(Ni1/3Co1/3Mn1/3)O2prepared at 900 °C had the highest c/a of 4.977 indicating the highest layered-ness. EDS scan demonstrated that the precursor was homogeneous. SEM images indicated all samples were well crystallized. Charge and discharge tests showed all samples had good rate capability. Among them, Li(Ni1/3Co1/3Mn1/3)O2prepared at 900 °C had the highest capacity and the best rate capability. It delivered 162.1 mAh•g−1at 0.25 C between 2.5 and 4.3 V and the capacity retention was about 81% compared to that of 0.25C rate.

The Uniqueness of Heterogeneous Globigerina Limestone Reservoir and The Importance of Integrated Rock Type Definition for Field Development Plan: Case Study in Madura Strait, East Java

2021 ◽  
Author(s):  
E. P. Putra
Keyword(s):  
Water Saturation ◽  
Rock Type ◽  
Reservoir Rock ◽  
Reservoir Quality ◽  
Secondary Porosity ◽  
Field Development ◽  
Core Data ◽  
Type Definition ◽  
Volume Porosity ◽  
Porosity And Permeability

The Globigerina Limestone (GL) is the main reservoir of the seven gas fields that will be developed in the Madura Strait Block. The GL is a heterogeneous and unique clastic carbonate. However, the understanding of reservoir rock type of this reservoir are quite limited. Rock type definition in heterogeneous GL is very important aspect for reservoir modeling and will influences field development strategy. Rock type analysis in this study is using integration of core data, wireline logs and formation test data. Rock type determination applies porosity and permeability relationship approach from core data, which related to pore size distribution, lithofacies, and diagenesis. The analysis resulted eight rock types in the Globigerina Limestone reservoir. Result suggests that rock type definition is strongly influenced by lithofacies, which is dominated by packstone and wackestone - packstone. The diagenetic process in the deep burial environment causes decreasing of reservoir quality. Then the diagenesis process turns to be shallower in marine phreatic zone and causes dissolution which increasing the reservoir quality. Moreover, the analysis of rock type properties consist of clay volume, porosity, permeability, and water saturation. The good quality of a rock type will have the higher the porosity and permeability. The dominant rock type in this study area is RT4, which is identical to packstone lithofasies that has 0.40 v/v porosity and 5.2 mD as average permeability. The packstone litofacies could be found in RT 5, 6, 7, even 8 due to the increased of secondary porosity. It could also be found at a lower RT which is caused by intensive cementation.

scholarly journals An integrated analysis of mineralogical and microstructural characteristics and petrophysical properties of carbonate rocks in the lower Indus Basin, Pakistan

2019 ◽  
Vol 11 (1) ◽  
pp. 1151-1167
Author(s):  
Waheed Ali Abro ◽  
Abdul Majeed Shar ◽  
Kun Sang Lee ◽  
Asad Ali Narejo
Keyword(s):  
Thin Section ◽  
Carbonate Rocks ◽  
Carbonate Rock ◽  
Indus Basin ◽  
Reservoir Quality ◽  
Data Sets ◽  
Petrophysical Properties ◽  
X Ray ◽  
Lower Indus Basin

Abstract Carbonate rocks are believed to be proven hydrocarbon reservoirs and are found in various basins of Pakistan including Lower Indus Basin. The carbonate rock intervals of the Jakkher Group from Paleocene to Oligocene age are distributed in south-western part of Lower Indus Basin of Pakistan. However, there are limited published petrophysical data sets on these carbonate rocks and are essential for field development and risk reduction. To fill this knowledge gap, this study is mainly established to collect the comprehensive high quality data sets on petrophysical properties of carbonate rocks along with their mineralogy and microstructure. Additionally, the study assesses the impact of diagenesis on quality of the unconventional tight carbonate resources. Experimental techniques include Scanning Electronic Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), and X-ray diffraction (XRD), photomicrography, Helium porosity and steady state gas permeability. Results revealed that the porosity was in range of 2.12 to 8.5% with an average value of 4.5% and the permeability was ranging from 0.013 to 5.8mD. Thin section study, SEM-EDS, and XRD analyses revealed that the samples mostly contain carbon (C), calcium (Ca), and magnesium (Mg) as dominant elemental components.The main carbonate components observed were calcite, dolomite, micrite, Ferron mud, bioclasts and intermixes of clay minerals and cementing materials. The analysis shows that: 1) the permeability and porosity cross plot, the permeability and slippage factor values cross plots appears to be scattered, which showed weaker correlation that was the reflection of carbonate rock heterogeneity. 2) The permeability and clay mineralogy cross plots have resulted in poor correlation in these carbonate samples. 3) Several diagenetic processes had influenced the quality of carbonates of Jakkher Group, such as pore dissolution, calcification, cementation, and compaction. 4) Reservoir quality was mainly affected by inter-mixing of clay, cementation, presence of micrite muds, grain compactions, and overburden stresses that all lead these carbonate reservoirs to ultra-tight reservoirs and are considered to be of very poor quality. 5) SEM and thin section observations shows incidence of micro-fractures and pore dissolution tended to improve reservoir quality.

Pb(Zr0.52Ti0.48)O3 Ceramics Synthesized Using Planetary Ball Mill

2012 ◽  
Vol 620 ◽  
pp. 486-490
Author(s):  
Shafiza Afzan Sharif ◽  
Julie Juliewatty Mohamed ◽  
W.A.W. Yusoff
Keyword(s):  
Lead Zirconate Titanate ◽  
Ball Mill ◽  
Single Phase ◽  
Perovskite Phase ◽  
Xrd Analysis ◽  
Lead Zirconate ◽  
Planetary Ball Mill ◽  
X Ray Diffraction ◽  
Sem Images ◽  
Pzt Ceramics

Lead zirconate titanate Pb (Zr0.52Ti0.48)O3, (PZT) ceramic was successfully prepared from the mixture of commercial PbO, TiO2and ZrO2powders using planetary ball mill at room temperature. The phase formation and microstructure of the milled powders were characterized using X-ray diffraction (XRD) and Scanning Electron Microscope (SEM). XRD results indicated that the perovskite phase of PZT was formed from the mixture of starting materials after milling for 40 h. The grain sizes of the powders have been estimated from the SEM images to be ~200 nm. The compacted PZT samples were then sintered at 950 °C for 1 h. The samples were characterized by XRD and SEM, meanwhile the density was measured by Archimedes principle. XRD analysis on the sintered samples revealed the formation of single phase Pb (Zr0.52Ti0.48)O3ceramics while the SEM images estimated the grain size to be ~2 µm. The relative density of the obtained sintered PZT ceramics was measured to be approximately 99.93 % of the theoretical density. The results hence indicate that planetary ball mill is an effective preparatory technique to improve the sinterability of PZT ceramics.

OIL MIGRATION HISTORY OF THE OFFSHORE CANNING BASIN

2000 ◽  
Vol 40 (2) ◽  
pp. 133 ◽  
Author(s):  
M. Lisk ◽  
J. Ostby ◽  
N.J. Russell ◽  
G.W. O’Brien
Keyword(s):  
Fluid Inclusion ◽  
Acid Leaching ◽  
Reservoir Quality ◽  
Oil Migration ◽  
North West ◽  
Canning Basin ◽  
Carbonate Cement ◽  
Migration History ◽  
Potential Reservoir ◽  
Porosity And Permeability

The dual issues of the presence or absence of a viable, oil-prone petroleum system and reservoir quality represent key exploration uncertainties in the lightly explored Offshore Canning Basin, North West Shelf. To better quantify these factors, a detailed fluid inclusion investigation of potential reservoir horizons within the basin has been undertaken. The results have been integrated with regional petroleum geology and Synthetic Aperture Radar (SAR) oil seep data to better understand the oil migration risk in the region.The fluid inclusion data provide confirmation of widespread oil migration at multiple Mesozoic and Palaeozoic levels, including those wells that are remote from the likely source kitchens. The lack of evidence for present or palaeo-oil accumulations is consistent with the proposition that none of the currently water-wet wells appear to have tested a valid structure. These observations, when combined with the presence of numerous direct hydrocarbon indicators on seismic data and a number of oil slicks (from SAR data) at the basin’s edge, suggest that the potential for oil charge to valid structures is much higher than previously recognised.Petrographic analysis of the tight, gas-bearing, Triassic sandstones in Phoenix–1 suggests that the low porosity and permeability is the result of late poikilotopic carbonate cement. Significantly, the presence of oil inclusions within quartz overgrowths that pre-date the carbonate indicates that oil migration began prior to crystallisation of carbonate. Fluid inclusion palaeotemperatures combined with a 1D basin model suggest that trapping of oil as inclusions occurred in the Early to Middle Cretaceous and that predictions of reservoir quality using available water-wet wells could seriously under-estimate porositypermeability levels in potential traps that were charged with oil at about 100 Ma. Indeed, acid leaching of core plugs from Phoenix–1 indicates that removal of diagenetic carbonate results in significant permeability increase with obvious implications for the producibility of any future oil discovery. Further, evidence of Early Cretaceous oil charge has implications for the size and locality of source kitchens compared to that observed at the current day.Collectively, the data indicate the area has received widespread oil migration and suggest future exploration, even to relatively deep levels, may be successful if valid traps can be delineated.

PREDICTION OF CARBONATE RESERVOIRS AND TRAPS BY APPLYING SEQUENCE STRATIGRAPHY IN THE EASTERN WARBURTON BASIN, SOUTH AUSTRALIA

1998 ◽  
Vol 38 (1) ◽  
pp. 380 ◽  
Author(s):  
X.W. Sun
Keyword(s):  
Seismic Reflection ◽  
South Australia ◽  
High Amplitude ◽  
Carbonate Reservoirs ◽  
Source Rocks ◽  
Shelf Edge ◽  
Secondary Porosity ◽  
Sandy Limestone ◽  
Potential Reservoir ◽  
Early Palaeozoic

The Early Palaeozoic eastern Warburton Basin unconformably underlies the Cooper and Eromanga Basins. Four seismic sequence sets (I−IV) are interpreted. Among them, sequence set II is subdivided into four Cambro-Ordovician depositional sequences. Sequence 1, the oldest, is a shallow shelf deposit that occurs only in the Gidgealpa area. Sequences 2 and 3 were deposited in a wider area; from west to east, environments varyied from deep siliciclastic ramp, carbonate inner-shelf, peritidal, shelf edge, and slope-to-basin. Their seismic reflection configurations are high-amplitude, regionally parallel-continuous, layered patterns, locally mounded geometry, as well as divergent-fill patterns. Sequence 4, the youngest, was deposited in a mixed siliciclastic and carbonate, storm-dominate shelf. Its seismic reflection configurations are moderate amplitude, parallel-layered patterns, decreasing in amplitude upwards.Boundaries between the four sequences generated good secondary porosity in the carbonates. Karst development is interpreted to have generated much of this porosity in shelf and peritidal carbonates, and carbonate build-ups. Shoal-water sandy limestone and calcareous sandstone of Sequence 4 may be other potential reservoir rocks. Potential source rocks comprise mudstone and shale of slope and basin lithofacies. There are two kinds of stratigraphic trap. One is in Sequences 2 and 3, associated with high-relief carbonate build-ups encased in lagoonal mudstone and shelf edge sealed by transgressive siltstone and shale. The other is a transgressive marine shale enclosing porous dolostone of the karstified Sequence 1. In addition, petroleum may have migrated from Permian source rocks of the Cooper Basin to karstified carbonate reservoirs of the Warburton Basin at unconformities.

Effect of Cobalt Content on the Structural Properties of Zirconia Prepared by Sol-Gel Method

2020 ◽  
Vol 1000 ◽  
pp. 227-232
Author(s):  
Nurhayati Indah Ciptasari ◽  
Adri Nora ◽  
Lutviasari Nuraini ◽  
Lusiana ◽  
Nono Darsono ◽  
...  
Keyword(s):  
Structural Properties ◽  
Sol Gel ◽  
Cobalt Content ◽  
Secondary Phase ◽  
Xrd Analysis ◽  
Weight Percent ◽  
Sem Images ◽  
Monoclinic Crystal ◽  
Gel Method ◽  
Sol Gel Method

Zirconia (ZrO2) powders doped with cobalt were prepared by sol-gel method using inorganic salt of zirconium (IV) chloride (ZrCl4) as precursor. The amount of cobalt was varied in the range of 4–16% weight percent to study the effect to structural properties. X-ray diffraction (XRD) analysis suggested the resulting phases were zirconium oxide (Baddeleyite) with monoclinic crystal system along with cobalt oxide as secondary phase. The increasing cobalt content caused the XRD peaks to shift into lower angle due to substitution of Zr atom to smaller Co atom in crystal lattice. Scanning electron microscope (SEM) images showed the samples with higher Co content had smoother surface. Generally, the microstructures of Co doped zirconia powders consisted of large agglomerates with small particles on the surface.

scholarly journals Green Synthesis of Silver Nanoparticles in the Presence of Polysaccharide: Optimization and Characterization

2020 ◽  
Vol 2020 ◽  
pp. 1-10 ◽  
Author(s):  
Margarita I. Skiba ◽  
Victoria I. Vorobyova ◽  
Alexander Pivovarov ◽  
Natalya P. Makarshenko
Keyword(s):  
Silver Nanoparticles ◽  
Sodium Alginate ◽  
Xrd Analysis ◽  
Face Centered Cubic ◽  
Colloidal Solutions ◽  
Ag Nps ◽  
Sem Images ◽  
Spherical Powder ◽  
Stabilizing Agent ◽  
Vis Spectroscopy

The process of obtaining aqueous solutions of silver nanoparticles with the use of a low-temperature nonequilibrium contact plasma and stabilizing agent—polysaccharide (sodium alginate)—has been examined. The synthesized Ag NPs were characterized by using UV-Vis spectroscopy, dynamic light scattering (DLS), scanning electron microscope (SEM), and XRD analysis. The effect of concentration of Ag+, sodium alginate, duration of processing by plasma discharge, and pH of liquid on the production of silver nanoparticles has been studied. The results demonstrated that synthesis provides the formation of silver nanoparticles for investigated concentrations of Ag+ (0.3-3.0 mmol/l) and 5.0 g/l Na-Alg (pH=7–10) within 1–5 minutes. From the SEM images, the silver nanoparticles are found to be almost spherical. Powder XRD results reveal that Ag nanoparticles have a face-centered cubic crystal structure. Zeta potential of plasma-chemically obtained colloidal solutions at various concentrations of Ag+ ions and stabilizing agent varies from −32.8 to −39.3 mV, indicating the moderate stability of synthesized nanoparticles.

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