scholarly journals Fuel Characterization of Agro-wastes and Briquettes Produced from Rice Husk, Groundnut Shell and Corncob Blends

2020 ◽  
Vol 5 (1) ◽  
Author(s):  
Kunle Oni ◽  
Ademola E Adeleke ◽  
Tunde O Ogundana ◽  
Adesola A Satimehin
Keyword(s):  
Density Ratio ◽  
Reduction Process ◽  
Cassava Starch ◽  
Rice Hull ◽  
Fuel Characterization ◽  
Fuel Characteristics ◽  
Groundnut Shell ◽  
Almost All ◽  
Compaction Ratio

The choice of agro waste for the production of briquettes for domestic and industrial cottage utilization depends on the residues’ physical and fuel characteristics. This study investigate the physical and fuel characteristics for both the residues and blends of rice hull, groundnut shell and corncob. The residues were subjected to size reduction process and variance analysis was used to establish the influence of each sample blends.  Different samples of briquettes were produced by blending rice hull (R), groundnut shell (G) and corncob(C) with different ratios of R:G:C respectively using cassava starch as a binder. The residue’ dimensions and densifications of the sample briquettes were determined using standard methods.The results revealed the following ranges of values; For the compressed residues, density (0.075 - 0.099Kg/m3), volume (0.001 - 0.002m3), height (1.0357 - 1.0343m). For the relaxed residues, density (0.049 - 0.210Kg/m3), volume (0.0001 -0.0002m3), height (1.0357 - 1.0343m). The residual density of rice hull, groundnut shell and corncob are 104, 105, and 103 (Kg/m3) respectively. The densification; compressed density (461.22 - 627.24 Kg/m3), relaxed density (285.47 - 393.63 Kg/m3), density ratio (0.56 - 0.66), relaxation ratio (1.52 - 1.79), and compaction ratio (1.46 to 2.01). Blend formulations affected the combustion characteristics of the briquettes, with low moisture briquettes possessing higher calorific values. The briquette formulation containing ratio 50:20:30 of rice hull: groundnut shell: corncob respectively had more positive attributes of biomass fuel such as lower relaxation ratio and high compaction ratio than the control and other formulated briquettes in this study. Generally, significant (p<0.05) differences existed between the samples in almost all the parameters.Keywords: Briquettes, Corn comb, Densification, Fuel Characterization, Groundnut shell, Rice hull.

A Thorough Theoretical Exploration of Intriguing Characteristics of Cyclo[18]carbon: Geometry, Bonding Nature, Aromaticity, Weak Interaction, Reactivity, Excited States, Vibrations, Molecular Dynamics and Various Molecular Properties

2019 ◽  
Author(s):  
Tian Lu ◽  
Qinxue Chen ◽  
Zeyu Liu
Keyword(s):  
Molecular Dynamics ◽  
Excited States ◽  
Electronic Excitation ◽  
Ring Structure ◽  
Molecular Properties ◽  
Molecular Vibration ◽  
Full Characterization ◽  
Long Time ◽  
Almost All

Although cyclo[18]carbon has been theoretically and experimentally investigated since long time ago, only very recently it was prepared and directly observed by means of STM/AFM in condensed phase (Kaiser et al., <i>Science</i>, <b>365</b>, 1299 (2019)). The unique ring structure and dual 18-center π delocalization feature bring a variety of unusual characteristics and properties to the cyclo[18]carbon, which are quite worth to be explored. In this work, we present an extremely comprehensive and detailed investigation on almost all aspects of the cyclo[18]carbon, including (1) Geometric characteristics (2) Bonding nature (3) Electron delocalization and aromaticity (4) Intermolecular interaction (5) Reactivity (6) Electronic excitation and UV/Vis spectrum (7) Molecular vibration and IR/Raman spectrum (8) Molecular dynamics (9) Response to external field (10) Electron ionization, affinity and accompanied process (11) Various molecular properties. We believe that our full characterization of the cyclo[18]carbon will greatly deepen researchers' understanding of this system, and thereby help them to utilize it in practice and design its various valuable derivatives.

A Thorough Theoretical Exploration of Intriguing Characteristics of Cyclo[18]carbon: Geometry, Bonding Nature, Aromaticity, Weak Interaction, Reactivity, Excited States, Vibrations, Molecular Dynamics and Various Molecular Properties

2019 ◽  
Author(s):  
Tian Lu ◽  
Qinxue Chen ◽  
Zeyu Liu
Keyword(s):  
Molecular Dynamics ◽  
Excited States ◽  
Electronic Excitation ◽  
Ring Structure ◽  
Molecular Properties ◽  
Molecular Vibration ◽  
Full Characterization ◽  
Long Time ◽  
Almost All

Although cyclo[18]carbon has been theoretically and experimentally investigated since long time ago, only very recently it was prepared and directly observed by means of STM/AFM in condensed phase (Kaiser et al., <i>Science</i>, <b>365</b>, 1299 (2019)). The unique ring structure and dual 18-center π delocalization feature bring a variety of unusual characteristics and properties to the cyclo[18]carbon, which are quite worth to be explored. In this work, we present an extremely comprehensive and detailed investigation on almost all aspects of the cyclo[18]carbon, including (1) Geometric characteristics (2) Bonding nature (3) Electron delocalization and aromaticity (4) Intermolecular interaction (5) Reactivity (6) Electronic excitation and UV/Vis spectrum (7) Molecular vibration and IR/Raman spectrum (8) Molecular dynamics (9) Response to external field (10) Electron ionization, affinity and accompanied process (11) Various molecular properties. We believe that our full characterization of the cyclo[18]carbon will greatly deepen researchers' understanding of this system, and thereby help them to utilize it in practice and design its various valuable derivatives.

Physicochemical and bacteriological characterization of hospital effluents and their impact on the environment

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Human Health ◽  
Fecal Coliforms ◽  
Chemical Pollution ◽  
Hospital Effluents ◽  
Biological Contaminants ◽  
Almost All ◽  
Direct Discharge ◽  
Significant Chemical

Liquid effluents discharged by hospitals may contain chemical and biological contaminants whose main source is the different substances used for the treatment of patients. This type of rejection can present a sanitary potentially dangerous risk for human health and can provoke a strong degradation of diverse environmental compartments mainly water and soils. The present study focuses on the quality of the liquid effluents of Hassani Abdelkader’s hospital of Sidi Bel-Abbes (West of Algeria). The results reveal a significant chemical pollution (COD: 879 mgO2/L, BOD5: 850 mgO2/L, NH4+ : 47.9 mg/l, NO2- : 4.2 mg/l, NO3- : 56.8 mg/l with respect to WHO standard of 90 mgO2/L, 30 mgO2/L, 0.5 mg/l, 1 mg/l and 1 mg/l respectively). However, these effluents are biodegradable since the ratio COD/BOD5 do not exceeded the value of 2 in almost all samples. The presence of pathogen germs is put into evidence such as pseudomonas, the clostridium, the staphylococcus, the fecal coliforms and fecal streptococcus. These results show that the direct discharge of these effluents constitutes a major threat to human health and the environment.

scholarly journals Stoichiometry and compositional plasticity of the yeast nuclear pore complex revealed by quantitative fluorescence microscopy

2018 ◽  
Vol 115 (17) ◽  
pp. E3969-E3977 ◽  
Author(s):  
Sasikumar Rajoo ◽  
Pascal Vallotton ◽  
Evgeny Onischenko ◽  
Karsten Weis
Keyword(s):  
Nuclear Pore Complex ◽  
Yeast Cells ◽  
Nuclear Pore ◽  
Altered Expression ◽  
Copy Numbers ◽  
Quantitative Image ◽  
Multiple Copies ◽  
Almost All ◽  
High Degree

The nuclear pore complex (NPC) is an eightfold symmetrical channel providing selective transport of biomolecules across the nuclear envelope. Each NPC consists of ∼30 different nuclear pore proteins (Nups) all present in multiple copies per NPC. Significant progress has recently been made in the characterization of the vertebrate NPC structure. However, because of the estimated size differences between the vertebrate and yeast NPC, it has been unclear whether the NPC architecture is conserved between species. Here, we have developed a quantitative image analysis pipeline, termed nuclear rim intensity measurement (NuRIM), to precisely determine copy numbers for almost all Nups within native NPCs of budding yeast cells. Our analysis demonstrates that the majority of yeast Nups are present at most in 16 copies per NPC. This reveals a dramatic difference to the stoichiometry determined for the human NPC, suggesting that despite a high degree of individual Nup conservation, the yeast and human NPC architecture is significantly different. Furthermore, using NuRIM, we examined the effects of mutations on NPC stoichiometry. We demonstrate for two paralog pairs of key scaffold Nups, Nup170/Nup157 and Nup192/Nup188, that their altered expression leads to significant changes in the NPC stoichiometry inducing either voids in the NPC structure or substitution of one paralog by the other. Thus, our results not only provide accurate stoichiometry information for the intact yeast NPC but also reveal an intriguing compositional plasticity of the NPC architecture, which may explain how differences in NPC composition could arise in the course of evolution.

Study of Low-Grade Nickel Laterite Processing Using Palm Shell Charcoal as Reductant

2020 ◽  
Vol 1000 ◽  
pp. 436-446
Author(s):  
Bambang Suharno ◽  
Nolzha Primadha Ilman ◽  
Achmad Shofi ◽  
Deni Ferdian ◽  
Fajar Nurjaman
Keyword(s):  
Sodium Sulfate ◽  
Selective Reduction ◽  
Reduction Process ◽  
Low Grade ◽  
X Ray Diffraction ◽  
X Ray ◽  
Palm Shell ◽  
Higher Temperature ◽  
Nickel Grade

This study was conducted to investigate the effect of palm shell charcoal reductant in the selective reduction of nickel ore with the addition of additive at various temperatures and times. In this present work, 10 wt. % of sodium sulfate as additive and 5, 10, 15 wt. % of palm shell charcoal as reductants were used. The reduction of nickel ore was performed at 950oC, 1050oC, and 1150oC for 60, 90, and 120 minutes. A wet magnetic separation method was then carried out to separate the concentrates and tailings. Characterization of reduced ore was performed by X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM) with Energy Dispersive X-ray Spectroscopy (EDS), while the composition of ferronickel in concentrate was identified by X-Ray Fluorescence (XRF). The result showed that the higher temperature reduction, the higher of nickel grade, and its recovery at the concentrate. Nevertheless, the longer reduction time and the more reductant in nickel ore lowering the nickel grade and its recovery in the concentrate. The optimum condition in this selective reduction process was obtained with the addition of 5 wt. % of reductant and 10 wt. % of sodium sulfate in nickel ore, which was reduced at 1150oC for 60 minutes. It resulted in 4.60% and 73.23% for nickel grade and its recovery, respectively.

Characterization of Nigerian Clay as Porous Ceramic Material

2013 ◽  
Vol 845 ◽  
pp. 256-260 ◽  
Author(s):  
M. Abubakar ◽  
A.B. Aliyu ◽  
Norhayati Ahmad
Keyword(s):  
Thermal Properties ◽  
Bulk Density ◽  
Sintering Temperature ◽  
Starch Content ◽  
Porous Ceramic ◽  
Porous Ceramics ◽  
Cassava Starch ◽  
Compaction Method ◽  
Percentage Porosity

Porous ceramics were produced by compaction method of Nigerian clay and cassava starch. The samples were prepared by adding an amount from 5 to 30%wt of cassava starch into the clay and sintered at temperature of 900-1300°C. The influence of cassava starch content on the bulk density and apparent porosity was studied. The result of XRD and DTA/TGA shows that the optimum sintering temperature was found to be 1300°C. The percentage porosity increased from 12.87 to 43.95% while bulk density decreased from 2.16 to 1.46g/cm3 with the increase of cassava starch from 5 to 30%wt. The effect of sintering temperature and cassava starch content improved the microstructure in terms of porosity and the thermal properties of porous clay for various applications which requires a specific porosity.

Study of Painting Materials and Techniques in the 18th Century St.Athanasius Church in Moschopolis, Albania

2007 ◽  
Vol 1047 ◽  
Author(s):  
Eleni Pavlidou ◽  
N. Civici ◽  
E. Caushi ◽  
L. Anastasiou ◽  
T. Zorba ◽  
...  
Keyword(s):  
18Th Century ◽  
Orthodox Church ◽  
Wall Paintings ◽  
Cultural Center ◽  
Green Earth ◽  
Almost All ◽  
The City ◽  
The Church ◽  
Compositional Characterization

AbstractIn this paper are presented the studies of the paint materials and the technique used in 18th century wall paintings, originated from the orthodox church of St Athanasius, in the city of Maschopolis, a flourishing economical and cultural center, in Albania. The church was painted in 1745 by Konstantinos and Athanasios Zografi, and during the last years, restoration activities are being performed at the church. Samples that included plasters and pigments of different colors were collected from important points of the wall paintings. Additionally, as some parts of the wall-paintings were over-painted, the analysis was extended to the compositional characterization of these areas. The identification of the used materials was done by using complementary analytical methods such as Optical Microscopy, Fourier Transform Infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM-EDS) and X-ray fluorescence (TXRF).The presence of calcite in almost all the pigments is indicative for the use of the fresco technique at the studied areas, while the detection of gypsum and calcium oxalate, indicates an environmental degradation along with a biodegradation. Common pigments used in this area at 15-16th centuries, such as cinnabar, green earth, manganese oxide, carbon black and calcite were identified.

Experimental Study of Ductile Fracture for Non-Aligned Multiple Flaws in a Plate

2009 ◽  
Author(s):  
Katsumasa Miyazaki ◽  
Kunio Hasegawa ◽  
Koichi Saito ◽  
Bostjan Bezensek
Keyword(s):  
Experimental Study ◽  
Ductile Fracture ◽  
Estimation Procedure ◽  
Maximum Load ◽  
Experimental Results ◽  
Collapse Load ◽  
Plate Specimen ◽  
Fracture Tests ◽  
Almost All

The fitness-for-service code requires the characterization of non-aligned multiple flaws for the flaw evaluation, which is performed using a flaw proximity rule. Worldwide almost all codes provide own proximity rule, often with unclear technical bases of the application of proximity rule to ductile fracture. To clarify the appropriate proximity rule for non-aligned multiple flaws in fully plastic fracture, fracture tests on flat plate specimen with non-aligned multiple through wall flaws were conducted at ambient temperature. The emphasis of this study was put on the flaw alignment rule, which determines whether non-aligned flaws are treated as independent or aligned onto the same plane for the purpose of flaw evaluations. The effects of the flaw separation and flaw size on the maximum load were investigated. The experimental results were compared with the estimations of the collapse load using the alignment rules in the ASME Section XI, BS7910 and API 579-1 codes. A new estimation procedure specific to the fully plastic fracture was proposed and compared with the comparison with the experimental results.

scholarly journals Isolation and Characterization of Bacteriophage ZCSE6 against Salmonella spp.: Phage Application in Milk

Biologics ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 164-176
Author(s):  
Abdallah S. Abdelsattar ◽  
Anan Safwat ◽  
Rana Nofal ◽  
Amera Elsayed ◽  
Salsabil Makky ◽  
...  
Keyword(s):  
Pathogenic Bacteria ◽  
Raw Milk ◽  
Salmonella Spp ◽  
Isolation And Characterization ◽  
Food Borne ◽  
Wide Range ◽  
Almost All ◽  
And Control ◽  
Milk And Dairy Products

Food safety is very important in the food industry as most pathogenic bacteria can cause food-borne diseases and negatively affect public health. In the milk industry, contamination with Salmonella has always been a challenge, but the risks have dramatically increased as almost all bacteria now show resistance to a wide range of commercial antibiotics. This study aimed to isolate a bacteriophage to be used as a bactericidal agent against Salmonella in milk and dairy products. Here, phage ZCSE6 has been isolated from raw milk sample sand molecularly and chemically characterized. At different multiplicities of infection (MOIs) of 0.1, 0.01, and 0.001, the phage–Salmonella interaction was studied for 6 h at 37 °C and 24 h at 8 °C. In addition, ZCSE6 was tested against Salmonella contamination in milk to examine its lytic activity for 3 h at 37 °C. The results showed that ZCSE6 has a small genome size (<48.5 kbp) and belongs to the Siphovirus family. Phage ZCSE6 revealed a high thermal and pH stability at various conditions that mimic milk manufacturing and supply chain conditions. It also demonstrated a significant reduction in Salmonella concentration in media at various MOIs, with higher bacterial eradication at higher MOI. Moreover, it significantly reduced Salmonella growth (MOI 1) in milk, manifesting a 1000-fold decrease in bacteria concentration following 3 h incubation at 37 °C. The results highlighted the strong ability of ZCSE6 to kill Salmonella and control its growth in milk. Thus, ZCSE6 is recommended as a biocontrol agent in milk to limit bacterial growth and increase the milk shelf-life.

Sign in / Sign up

Export Citation Format

Share Document